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By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By F. Mallozzi

"With the requirements of air pollution codes becoming more and more critical, the role of the ventilation engineer in industry has become an extremely important one. The ventilation engineer must provide the expertise for the selection of equipment and the design of systems which will reduce pollution to an acceptable level. Because pollution control systems involve considerable capital and operating expense, he must have the ability to select, from a wide range of products, the collector which will provide the required performance with a minimum of down time for maintenance. This paper discusses the principles of wet collection and the forces used to separate particulate matter from a gas stream. Important factors in the selection of equipment, such as collection efficiency, horsepower requirements and water consumption for the various types of collectors, are discussed in detail, as well as the construction features normally incorporated to circumvent potential problems."

Jan 1, 1971

By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By E. Ghali, C. Su, G. Houlachi

"The influence of lead ions on zinc electrowinning process was investigated by means of electrochemical noise measurements (ENMs) and cyclic voltammetry in conjunction with scanning electron microscopy and X-ray diffraction. All electrochemical experiments were performed in sulphuric acid electrolyte containing different lead ion concentrations as impurity. Lead was added in six trace levels between 0.05–0.8 mg/L in the bath. The lead content of the zinc deposits was dependent on the introduced lead concentrations. The overpotential associated with zinc electrodeposition shifted to higher values with the increase of lead concentration in the solution. An appropriate correlation was found between the different concentrations of lead in the electrolyte and the morphology of zinc deposit by ENM. The results showed that the increase of lead ion concentrations is generally accompanied with the decrease of skew and increase of kurtosis values that could be related to the morphology of zinc deposit. Effectively, the morphology changes from well-defined hexagonal platelets to large hexagonal, layered platelets and finally to non-symmetric refined crystalline structure, respectively.INTRODUCTION In commercial zinc electrowinning, zinc oxide is leached from the roasted calcine with an aqueous acid sulfate electrolyte. Then the zinc-rich solution is purified and transferred into an electrolytic cell. During electrolysis, zinc is deposited on aluminum cathode where lead-silver or pure lead is served as anode. Electrodeposition of zinc could be influenced by several parameters such as bath acidity, temperature, current density, the nature and concentration of impurities as well as additives in electrolyte. Metallic impurities play a complex role during zinc electrowinning and they can adversely"

Jan 1, 2016

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Numerous schemes have been proposed in the past to evaluate the shear strength of rock discontinuities based on in situ and laboratory testing. Due to scale effects, in situ testing is the most reliable way to assess the shear strength parameters. However, practical reasons often impede this kind of testing. This is unfortunate because advances in theoretical rock mechanics are still dependant on qualitative experimental works. This paper presents a mobile high capacity shear apparatus developed for in situ direct shear testing of discontinuities along with testing methodology. The apparatus has the advantage of being simple, although of high capacity, and can be moved to different site locations for other tests. The in situ test was performed on a natural rock outcrop of schist with subvertical schistosity. A concrete block 50 x 50 cm with a base layer of high strength mortar was cast on the rock surface. Prior to the test, the concrete block was lifted and repositioned to have an unbonded joint but with interlocking asperities. The shear load was applied perpendicularly to the schistosity direction. The test was conducted in a constant normal load (CNL) condition. Both normal and shear loads were applied manually. The instrumentation consisted of two load cells for shear and normal loading, eight displacement laser extensometers for shear, normal, and lateral displacements and fourteen acoustic emission sensors for monitoring evolution of asperities’ degradation during the test. The friction angle obtained is 72° for the peak and 58° for the residual. The high values of friction angle indicates that first-order roughness and good interlocking of the joint surfaces can result in high shear strength parameter values in a rock generally regarded to have low values.

Jan 1, 2015

By Kai Zhang, Aijun Huang, Jeremy H. Rao, Xinhua Wu, Paul Rometsch

"As one of the most typical additive manufacturing (AM) technologies, selective laser melting (SLM) removes many of the shape restrictions that limit materials design, thereby allowing computationally optimised and high performance structures to be directly produced and tested. Due to the high reflectivity and lower absorptivity of Al alloy A357 powder during high temperature laser melting, one of the issues SLM might bring is the surface roughness and defects present on the parts. In this regard, this study investigates the surface roughness – fatigue property relationship for a heat-treated aluminium alloy A357 after SLM. Via the adjustment of SLM parameters, an ultrafine microstructure can be obtained due to the fast solidification rate. Therefore, comparable or even better mechanical properties can be achieved with respect to traditional A357 casting counterparts. Meanwhile, the surface roughness conditions of the SLMed Al alloy are also influenced by various processing parameters, raw powder properties, and sample building methods. For selective laser melted Al alloy A357 specimens, a dense part with a smoother surface would be expected to correspond with a good fatigue performance.INTRODUCTION Additive Manufacturing (AM), also known as 3D printing, is a process in which a complex part is fabricated layer by layer from a digital design package (Martin et al., 2017). AM has the potential to conserve raw materials, reduce the energy consumption, part cost, and fabrication time. Furthermore, as a typical additive manufacturing (AM) process, selective laser melting (SLM) was originally developed from selective laser sintering (SLS) based on higher quality lasers (Rao, Zhang, Fang, Chen, Wu, & Davies, 2017b). Different from conventional casting consuming valuable time and energy, SLM is now used as a cost effective method for the manufacturing of metals, such as Al-Si alloys, to produce almost full density parts using fine metallic powder and high power laser beam (Tang & Pistorius, 2017)."

Jan 1, 2018

By J. R. Johanson, A. W. Jenike

"A solid flows out of a bin provided that the outlet is sufficiently large so that stable obstructions to flow do not develop. The geometry and surface finish of a bin and the construction of the feeder determine the type of flow pattern which then develops within the bin. The pattern, in turn, affects the uniformity and consistency of the stream, segregation, caking, degradation, live capacity and the action of level measuring devices.In most bins now in operation, material flows toward the feeder through a channel which forms within the stationary solid. This is referred to as funnel flow. If the hopper of the bin is sufficiently steep and smooth and the feeder capable of drawing material across the whole area of the outlet, all the solid flows whenever the feeder is in operation; this is referred to as mass flow. Mass-flow bins are usually far superior to funnel-flow bins; their initial cost is also usually higher.The paper describes the design criteria used in deter-mining the minimum bin outlet needed for flow and the bin geometry needed for mass flow."

Jan 1, 1970

Thermal barrier coating (TBC) systems provide thermal insulation to high temperature for aero¬propulsion. A fracture mechanical model developed earlier for multilayer systems is applied on TBC to realize superior performance by enhancement of fracture resistance. Functionally gradient materials (FGM) solution concept is the basis of approach followed here. A few realistic FGM TBCs are considered in the analysis in addition to a conventional TBC as the base case and a hypothetical worst case with YSZ-YSZ interface. Parameters like number, composition and thickness of graded layers and elastic modulus are considered for the analysis and quantitative improvement of fracture resistance of TBCs. The analysis is confined to deep crack with crack size to width ratio as 0.5.

Jan 1, 2010

By Tong Qin, Jinxia Zhang, Fusheng Niu, Limei Bai

"The interaction between a deformable bubble and a rigid particle in viscous liquids under microgravity conditions is studied by direct numerical simulation via an Arbitrary-Lagrangian-Eulerian (ALE) method. Due to the microgravity, the bubble will stay as a sphere in the fluid without external forces and its deformation is caused by the moving particle. In this study we assume the flow field is axisymmetric and the motion of the gas inside the bubble is neglected. The particle equations and the Navier-Stokes equations for the fluid are solved in a unified finite element framework. The particle obtains an impact velocity by an external force and the impact velocity is varied over a wide range. A ‘critical time scale’ T0 was identified for the interaction process. For successful contacts between particle and bubble, the time scale of their relative motion must be less than T0.INTRODUCTIONThe particle-bubble interaction is an important process in many applied industrial domains such as water treatment, froth flotation and liquid steel purification. It is a complex three phase process in that it embraces many research areas: fluid hydrodynamics, interfacial forces, particle and bubble behaviour and solution chemistry.Derjaguin and Dukhin(1961) clarified the particle-bubble interaction by introducing three-zone model for small and medium size particles. When the particle is far away from the bubble surface, the hydrodynamic forces are dominant. The particle is driven toward the bubble surface by the particle inertial and gravity. This region is regarded as Zone 1 and the interaction in this zone is a collision subprocess. As the particle gets close to the bubble, it exits a zone where the liquid flow around the bubble surface creates a tangential stream from the upper surface of the bubble toward the rear of the bubble. This is Zone 2 which is called the diffusiophoretic zone. In Zone 3, the particle is very closed to the bubble, surface forces like van der Waals, electrostatic and structural forces are considered. Contrast to Zone 1, Zone3 can be regarded as an attachment subprocess."

Jan 1, 2016

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By G. G. Campbell

"HistoricalBARYTES was mined in Nova Scotia as early as 1874 from a deposit at Five Islands, on the north shore of Minas Basin. The first record of the presence of the mineral at the Walton site appears in a report by Selwyn in l893, who states: ""Barytes in considerable quantity occurs in veins in lime-stones at Walton and Pembroke"". The exact site of the present workings was marked •on a map published by Fletcher in 1905.The economic •possibilities of this deposit, however, were not recognized until 1940, at which time we were at war with Germany, who up to that time had supplied 50 per cent of the world's requirements.At that time the Nova Scotia Department of Mines, recognizing the need for certain strategic minerals, induced Canadian Industrial Minerals, Limited, to send prospectors into 'the area to look for manganese. No manganese deposits were found, but a deposit of barytes was directed to their attention, and exploration and development work on the occurrence was proceeded with.IntroductionThe south shore of Minas Basin between the Avon river at Windsor and the Stewiacke river at Maitland has long been known as a potential source of mineral wealth. It had attracted the attention of mineralogists and in the past had produced considerable tonnages of manganese ore and gypsum. Depletion of ore in surface and near surface deposits resulted in a dwindling production, until today only deposits of gypsum are worked."

Jan 1, 1952

By P. Chollet, A Constant

THE RESULTS of a previous investigation ( 1) on the work-softening of some heat-treated steels have led to the conclusion that the occurrence and intensity of the phenomenon is possibly governed by the work-hardening capacity of the material, and the relative amount of retained austenite. The first assumption is compatible with Polakowski's theory (2) that the absence of work-softening, in steels quenched and tempered at relatively low temperatures, may be attributed to the high rate of work-hardening which compensates for, and even out-weighs, the loss of internal energy associated with the simultaneous rearrangement of the original system of internal stresses. Indeed, Polakowski first considered the work-softening as a manifestation of a partial release (by cold-working) of the latent strain energy stored in

Jan 1, 1962

By M. R. Julien

"The geomechanical behavior of rocksalt shows very distinctive features. The response of this most ductile of all low porosity rocks is dominated by inelastic processes that are strongly time- and historydependent. These characteristics must be taken into account when analyzing underground openings. Different constitutive models have been proposed and used for this purpose, and this paper presents the general formulation and applications of one of these. The SUVIC model relies on a unified approach with internal state variables producing mixed hardening to represent the inelastic behavior, which lead to specific solutions for plasticity and creep. The model equations have been implemented into a finite element code to perform numerical analyses. Simulations results are presented to show that this model captures essential aspects of rocksalt behavior under simple and complex laboratory testing conditions. Simulations are also conducted to analyze the response of underground openings. INTRODUCTIONPredicting the response of man-made excavations in rocksalt can be quite a challenge as it requires a reliable constitutive model to represent the material behavior. This softest of all low porosity rocks shows a highly non-linear inelastic behavior, very sensitive to history and rate effects (e.g. Senseny et al., 1993; Cristescu & Hunsche, 1997; Julien, 1999; Wittdke, 2014). The many deformation (micro) mechanisms acting locally in rocksalt make the construction of appropriate constitutive equations quite complex. Nonetheless, there have been significant progresses made over the last two decades or so; many of these developments have been included in a series of specialized Conferences Proceedings (Ghoreychi et al., 1996; Aubertin & Hardy, 1998; Cristescu et al., 2002; Wallner et al., 2007; Bérest et al., 2012)."

Jan 1, 2015

By D. Nie, M. Ren, T. Mo

This paper studied the phenomenon of room temperature creep deformation at crack tip and its effect on fatigue crack growth rate of a X-70 pipeline steel using compact-tension (CT) specimen on a MTS 810 testing machine. Time-dependent deformation at the crack tip under constant load was observed in this steel at room temperature and the amount of deformation produced was seen to depend on loading rate and the magnitude of stress intensity factor. It is found that there exists a critical stress intensity factor below which the deformation decreases with time when the applied load remains constant. It is also found that the occurrence of room temperature creep obviously affects the subsequent fatigue crack growth rate. The observed behavior was explained based on dislocation theory.

Jan 1, 2005

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By V. Bonilla-Sierra, M. Elmouttie, L. Scholtès, F. V. Donzé

In the presence of joint sets sub-parallel to a slope face, the stability of the rock mass is controlled by the shear strength of the joints. On one hand, if the joints are persistent their shear strength can be assessed according to Mohr-Coulomb criterion, assuming appropriate values for the cohesion and the friction angle on the joint surface. On the other hand, if the joints are non-persistent with their continuity being interrupted by the presence of rock bridges, their shear strength will increase considerably. In this latter case, the contribution of the rock bridges to the shear strength of the joint has to be accounted for in order to better assess the stability of the rock mass. A numerical analysis of the progressive failure of a rock slope involving a non-persistent joint has been set up based upon simulations performed using a Discrete Element Method (DEM) algorithm specifically enhanced for the modeling of jointed rock masses. Pre-existing discontinuities are explicitly accounted for in the model by using a modified contact logic that ensures an explicit and constitutive mechanical behavior of the joint planes. In addition, rock bridges can be spatially distributed along these joint planes following a prescribed probabilistic technique. Jennings’ formulation (Jennings, 1970) is considered as one of the first rock slope analysis that evaluates the shear resistance to sliding as a weighted combination of the shear resistance of the intact rock and the joint planes. The validity of this formulation is discussed in the present study. Contrary to the Jennings’ formulation, we show that tensile failure is an important mechanism, particularly as the dip angle of the sliding plane increases.

Jan 1, 2015

By R. Kamguem

The surface of a mechanical part plays an important role in determining performance in service. The presence of scratches left by the cutting or tearing of the material on the surface of the workpiece supports the concentration of stress and strain. This article presents the experimental study for high speed milling of the aluminum alloy 7075-T6, using cutting tools different by the nose radius and coatings (TiCN, TiAIN, TiCN + A12O3 + TiN). A multi levels factorial design of experiment (DOE) and statistical analysis was used. The roughness parameters investigated are Ra, Ra, Rv, Rc, Rsm, and Rk. The results show that the feed rate, the types of coatings and the geometry of the cutting tools have the most significant impact on the surface roughness profil. Surface finish charts according to feeds and cutting speeds were established for each tool tested.

Jan 1, 2011

By D. Pérez Escobar

Multiphase steels are quite sensitive to hydrogen embrittlement. Laboratory tests to evaluate this often use electrochemical, charging to introduce hydrogen into the sample, but damage purely caused by hydrogen charging has to be avoided. A ferrite-bainite steel, was charged using various conditions to identify when surface blisters occurred. Samples were also checked for internal, damage by electron microscopy. This study was repeated for three other multiphase steels and pure iron. An HSLA steel, was found to be more resistant whereas pure iron was quite susceptible to internal, hydrogen damage. For al, industrial, steels, cracks concentrated in the middle of the sample were attributed to inclusions and segregations, inherent to production.

Jan 1, 2010