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By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By Gaoming Wang

Outline 1. The Gangdese porphyry Cu-Mo belt 1.1 Regional geological background 1.2 Cu-Mo-bearing porphyries 1.3 Mineralization and alteration 2. Dating methods and results 2.1 Qulong porphyry 2.2 other porphyries 3. Geodynamic implications 4. Conclusions 5. Acknowledgements

May 1, 2004

By J. Holder

"A key barrier to vertical mineshaft construction is the construction access required for workers. A suspended work stage is used to provide this access for the mechanical, electrical and structural applications and other tasks. Work stage design is complicated considering the numerous types of construction activities that are executed simultaneously, the confined environment in which the work stage operates, the significant corrosion attack that is present, the weight limitations imposed by the mechanical hoist systems, and the risks associated with worker safety. Also complicating the design, these structures and their construction environment can vary with time. Hence, they can be described as 4D structures. The author has discovered significant synergies and advantages with integrating engineering design with detailed three-dimensional (3D) fabrication design. The significant reduction of minor design errors needing field correction will be underscored. The tender process is also accelerated since the design output is fabrication shop drawings including a detailed quantity takeoff output which lists each component required and its specific quantity. The paper presented will document the numerous advantages to the project using this approach. INTRODUCTION A key barrier to vertical mineshaft construction lies in the access for the workers to execute the construction. Suspended work stages are used to provide this access for the mechanical, electrical and structural applications as well as other tasks. The design of such work stages is complicated considering the numerous types of construction functions that need to be executed simultaneously, the confined environment in which it operates , the significant corrosion attack that is present, the weight limitation imposed by the mechanical systems for suspension, and the risks associated with worker safety. Also complicating the design, these structures and their construction environments can vary with time. They can be described as 4D structures with the fourth dimension being time. This design is a time consuming process. The post tender award is meticulous and requires strong teamwork between the steel fabricator and the consulting engineer. This teamwork may or may not be present and is dependant on the experience and relationship the team members have working together as well as other factors."

Jan 1, 2019

By Alex Henderson

The underground hard rock mining industry has had little change since the mobile equipment era began in the 1970s. Equipment has become larger and faster but has not kept pace with the following challenges: ? Improvements in safe production, ? Increasing demand for metals, ? Environmental improvements, ? Decreasing grades, ? Increasing depth of mining, ? More metal from underground vs. surface mining, and ? Energy and green house gas awareness. We are on the cusp of a new mining era and must rethink how underground hard rock mining must change in order to meet these challenges. This paper will show historical changes and propose a set of guiding principles for the next era of mining. Mining has changed over the last century. Initially mining was primarily an endeavor carried on by private companies with minor environmental controls and few social expectations other than employment. In the mid to later part of the century the mining industry was facing new challenges: deeper mines, the London Metals Exchange markets for pricing, and environmental concerns related to acidic rock drainage coming to the forefront. In today?s context, mining has evolved in complexity with the social and environmental aspects equally or surpassing the technical complexities such as expanding from mining hard rock to laterites, and mining lower grades or at greater depths. Nowadays, communities must be considered as partners, both locally and globally and the increased international visibility pushes the mining sector to take a more balanced approach to the business of mining (Fig. 1).

May 1, 2011

Shafts are the most important workings in the underground mines. Their technical state to a large extent determines the safety and efficiency of mining operations. However, in many cases periodically performed inspections show unsatisfactory technical state of the shaft lining (local defects, cracks, cavities, losses of the outer surface of the lining or, in case of the bricks, losses of the masonry). The most common cause of these types of damage is progressive deterioration of the lining material, impact of aggressive mine waters, impact of mining operations, deformation of the lining due to the rock mass saturation, seismic activity or periodic freezing of the lining in the upper part of a shaft. The paper presents legal requirements associated with the use of mine shafts in Polish coal mines as well as the ways and range of their control. Furthermore, examples of typical damage to shaft lining and ways to repair it, such as additional bolting, filling cavities or a wire mesh and shotcrete installation, are shown. In the final part, the paper presents a short example of a shaft, in which damage to the lining was one of the main causes of the shaft's failure. Due to the damage to the shaft lining, at the depth of approx. 65.0 m, the shaft was spontaneously filled with overburdened soil material. It resulted in a large crater to come to the surface, which, in turn, caused damage to the buildings and facilities present in the impact zone. On the surface the diameter of the crater was approx. 60.0 m, its depth approx. 11 m and the estimated volume was of about 30,000 m³. The disaster also caused disturbance in the ventilation of two neighbouring mines and the increase in methane hazard. Given the size of the crater, the measures to eliminate consequences of the catastrophe were undertaken in several stages.

Aug 1, 2013

By T. H. Etsell, P. C. Holloway

The fly ash produced by oil sands operations in northern Alberta represents a large, high-grade, potential resource for vanadium production in Canada. After extensive batch testing at the University of Alberta, a conceptual process flowsheet for the recovery of vanadium from oil sands fly ash has been developed. The various unit operations for this process, including decarbonization, roasting, leaching, desilication, precipitation, salt recovery and byproduct recovery, are described. Processes for the recovery of molybdenum and ammonium chloride from waste streams from this process, are proposed, as are potential uses for the ash residue; these byproducts represent significant potential sources of secondary revenue while reducing the environmental impact from the process. A preliminary economic analysis for vanadium recovery from oil sands fly ash using this process is also included and several major economic factors influencing its commercialization are discussed.

Jan 1, 2004

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By John E. Udd

The stability of a rock mass is influenced by the presence of discontinuities. In assessing stability, it is required that one should know the frictional and cohesive properties of these contained weaknesses. In the study performed by the authors, a number of samples of diamond drill core containing open discontinuities were tested in shear. The results obtained were compared with values which resulted from back analyses of instabilities in the field.

Jan 1, 1979

By Norman Lecuyer, Jacque Nantel

"The Chadbourne Project, located within the limits of the town of Noranda, Quebec, will make use of backfill materials to fill the voids left by the mining of stopes and pillars. A series of tests were conducted on different mixtures of slag and pyrrhotite tailings materials to evaluate their properties. The tests are described and some pertinent results are given in the paper.IntroductionThe Chadbourne Project is located in the centre of the Town of Noranda, Quebec, with houses as close as 120 m from the blasting operations. The ore is mined using the vertical crater retreat method. The voids left by mining activities will be filled. A program of pillar recovery will follow.Considering the proximity of houses and the need to recover pillars, the backfill program must be carefully laid out. No subsidence can be tolerated on surface.With these objectives in mind, a test program was undertaken by Nantar Engineering Limited and Queen's University to evaluate the possible ba ckfilling alternatives available to Chadbourne. One of the possibilities retained was the use of a backfill composed of broken slag material from the Horne Smelter and pyrrhotite tailings deposited on the Horne's pond a number of years previously.The back fill used at the Horne Mine until the mine closed in 1975 was composed of a mixture of 97% granulated slag and 3% pyrrhotite tailings. The tests leading to its use underground at the Horne Mine were described by Patton in 1952. The structural properties of the Horne backfill were ""intuitively"" known; it was agreed by all at the Horne Mine that the backfill was behaving remarkably well. Some were labeling it ""the best backfilling material in the world"". Its strength was said to be that of a weak concrete. All of the preceding indicate that the Horne backfill had never had its structural and other properties determined in the laboratory."

Jan 1, 1983

Ion Exchange is finding a greater role in copper processing, and hydrometallurgy in general, both as a technique for removing impurities and as a means of adding value through the recovery of secondary metals. Both the gold and uranium industries use resin adsorption as a primary production technique. While hydrometallurgical processes predominantly rely on solvent extraction as the mainstay of copper recovery there are a number of projects, in particular polymetallic deposits, which are considering the use of resin recovery as an alternative or supplemental production technique. A number of applications have been developed and proven at commercial scale for the removal/control of impurities (iron, antimony and bismuth) from copper electrolytes. These are well documented ion exchange applications. Increasing metal values and scarcity of certain metals are focusing companies to look at secondary metals recovery rather than losing these often highly valuable metals to tails residues. Bleed streams are being seen as valuable opportunities to recover contained metals; iron, copper, nickel, cobalt, bismuth, antimony and rhenium are all metals being targeted for removal or recovery from process solutions, electrolytes and bleed streams. An overview of currently applied techniques as well as some developmental technologies for impurity removal and secondary metals recovery is presented to provide insight into the advantages and flexibility of ion exchange applications in metals processing.

Jan 1, 2007

By Raj Thamburaj, Li. Ping, Prakash C. Patnaik

"An effective prognosis system for aircraft engines may involve the application of a wide range of technologies and methodologies, which may include: - On-line, real-time and in-situ non-destructive inspection/detection/sensoring - Aircraft/engine instrumentation - Airborne data recording system - Advanced signal filtration - Data compression technologies - On-line engine health monitoring technologies - On-line engine component life usage monitoring technologies - Mission severity analysis algorithm based on life prediction and damage tolerance analysis models - Life assessment methodologies - Optimized repair/overhaul/maintenance planning - Optimization of mission assignment and homogeneous life usage - Web-enabled information delivery and sharing system - Decision making logistics This paper will demonstrate some efforts that Orenda has accomplished over the last decade in collaboration with the Institute for Aerospace Research of National Research Council Canada and the Department of National Defense. The presentation will focus on the following projects:"

Jan 1, 2004

"These guidelines, implemented in 2003, were recommended by the Diamond Exploration Best Practices Committee established by the Canadian Institute of Mining, Metallurgy and Petroleum. The guidelines are applicable to public companies and their consultants reporting diamond exploration results.“The guidelines are referenced in the Companion Policy of NI 43-101 with a statement that disclosure regarding the reporting of diamond exploration sampling results should conform to them.”Reporting GuidelinesThe following guidelines have been recommended by the Diamond Exploration Best Practices Committee established by the Canadian Institute of Mining, Metallurgy and Petroleum. These guidelines are applicable to public companies and their consultants reporting diamond exploration results.In respect of these guidelines, Diamond Exploration Results are results derived from the initial activities undertaken to investigate a diamond bearing prospect or deposit, to generate tonnage, grade and value estimates that cannot be classified as a Mineral Resource or Mineral Reserve. They do not address the earlier stage reporting of geophysical, geochemical or kimberlite indicator mineral results.Public reports of Diamond Exploration Results relating to mineralization not classified as Mineral Resource or Mineral Reserve must address the confidence limits of the result and contain sufficient information to allow a considered and balanced judgement of the significance of the results.The objective of these guidelines is to assist public companies and consultants in making appropriate disclosure of diamond exploration results by reporting in a manner which is:Uniform within the diamond exploration industry; Consistent with reporting from other industry sectors .Comprehensive .Unambiguous .The guidelines are not prescriptive. Materiality is the overriding principle that determines the information that should be disclosed. However, where a company or consultant deviates from the guidelines, the disclosure or technical report should state the extent to which the guidelines have not been followed, and the reasons for the deviation.The guidelines do not in any way replace jurisdictional reporting requirements (For example, the requirement for Canadian reporting issuers to comply with Canadian Securities Administrators National Instrument 43-101 by having technical disclosure endorsed by a Qualified Person as defined in that legislation)."

Jan 1, 2003

By S. Asano

Hydrometallurgical processes for treating copper sulfide concentrates have attracted considerable attention over thirty years and many processes have been developed. However there have been still problems in those processes because of difficulties of iron removal and high purity copper production with low operating cost. Although SX-EW is highly cost effective method, it is difficult to process the chalcopyrite. Sumitomo Metal Mining Co., Ltd. (SMM) conducted a review of hydrometallurgical copper concentrate processing and has successfully developed a novel process for the hydrometallurgical production of copper from copper concentrate. In this process, copper sulfide is leached by chlorine gas under atmospheric pressure. Most of hydro metallurgical processes can leach only some of chalcopyrite under atmospheric pressure then they need high pressure leaching facility like autoclave. In this process, copper in chalcopyrite can be leached completely by controlling oxidation reduction potential and chloride ion concentration. Cu(I) ion in leached liquor is separated from Fe(I!) ion by SX using TBP then pure copper powder is produced by electrowinning. Results in batch and continuous testworks and pilot plant tests at Niihama Research Laboratories are presented in this paper. Cu2007

Jan 1, 2007

WHAT IF? ?Mine closure and reclamation liabilities were fully funded -at all times from current mine revenues ?Unexpected & catastrophic events were insured ?Remediation costs could be capped ?Risk management was improved ?best practice and independent oversight ?Host communities?concerns were adequately addressed If this could be achieved within a cost-effective financial structure, this may be a solution to a complex issue for the mining industry

May 1, 2006

By D. R. BUDINSKI

Clinton Creek Mine in west-central Yukon produced 0.94 million tonnes of fibre from 15 million tonnes of asbestos ore between 1968 and 1978. The mine closed in 1978. The deposit lies along the margin of a medium sized ultramafic pluton that intrudes schistose and gneissic rocks of the Yukon Metamorphic Complex. Country rocks are metamorphic equivalents of a mixed sedimentary and volcanic assemblage deposited during Precambrian or early Paleozaic time. Movement along the north west-trending Tintina Fault System probably caused the fairly high meromorphic grade that altered the original rocks to schists and gneisses. The ultramafic pluton hosting Clinton Creek Mine is one of several bodies that were emplaced along a deep seated imbricate fault system parallel to the Tintina Trench. Most of rhe intrusions were hydrothermally altered to serpentinite, bur apparently only the one at Clinton Creek contains commercial quantities of asbestos. The Clinton Creek pluton was probably injecred slowly at relatively low temperatures into the crustal rocks as a "mush" that cooled gradually, allowing sufficient time for serpentinization and chrysotile fibre crystallizarion.

Jan 1, 1984

By R. P. Mahant

"Extensive pilot plant investigations were conducted both on partial roasting an d electric furnace smelting from September 1973 to August 1975.The objectives of the pilot plant investigations were:(I ) to confirm the application of available process technology to treatment of Falconbridge concentrate.(2) to examine partial roasting variables.(3) to investigate electric furnace smelting of roaster calcines .(4) to develop process design and operating parameters for a commercial plant.This part of the paper will cover the following topics:Partial Roasting InvestigationsPilot Electric Furnace InvestigationsPartial Roasting InvestigationsThe specific objectives were to:1. establish process variables for maximum oxygen efficiency and bed fluidi ation.2. determine the product distribution between the roaster and the various gas cleaning stages.3. produce a mass and thermal balance."

Jan 1, 1984

By E. W. Coderre, R. C. Baxter

"This paper describes the townsite of Wabush and the two railways operated by Wabush Mines for the loading and unloading of iron ore concentrate. The town of Wabush is located approximately 200 air miles north of Sept-Iles, Quebec and is in the Province of Newfoundland and Labrador. Construction of the town-site began in 1961 to provide housing accommodation for the construction force and permanent employees in the mining and milling operations located 4 miles away. Wabush Mines operates two short railway lines in loading and unloading concentrate between the concentrator, located at Wabush, and the pellet plant at Pointe Noire, Quebec. Both of these railways connect with the main line of the Quebec North Shore and Labrador Railway and provide a shuttle service between the two phases of the operation."

Jan 1, 1969

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

By A. Singh

"Flotation of fine (< 10 µm) minerals is a challenge exacerbated by the emerging practice of fine grinding flotation feed to better liberate targeted minerals; however, the ability of conventional flotation cells to float liberated fines remains questionable. The Gold Ore solution using Mach reactors was tested at Mintek, South Africa, and showed an ~180% increase in the Kelsall kfast factor, a projected recovery improvement of 4% for the Mach-reactor case, and final concentrate grade twice that of conventional flotation. Theory, pilot plant results, and key aspects of plant design, supplemented by operational plant observations after commissioning, are discussed.RÉSUMÉ Le procédé de flottation de minerais fins (< 10 µm) pose de grandes difficultés, lesquelles sont aggravées par la pratique émergente de l’alimentation du circuit de flottation avec des mailles de broyage très fines pour mieux libérer les minéraux ciblés ; la capacité des cellules de flottation classiques à flotter les fines de minerais libérées reste cependant discutable. La solution proposée par la société Gold Ore, qui utilise des réacteurs Mach, a été testée à Mintek, en Afrique du Sud ; elle affichait une augmentation d’environ 180 % du facteur kfast développé par M. Kelsall dans son modèle de flottation, une amélioration prévue de la récupération de 4 % dans le cas du réacteur Mach, et une teneur finale des concentrés deux fois plus importante que celle obtenue avec la flottation classique. Sont débattus dans cet article la théorie, les résultats générés par l’usine pilote ainsi que les principaux aspects de la conception de l’usine complétés par des observations relatives à l’usine en activité après sa mise en service."

Jan 1, 2018

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.

Jan 1, 2007