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By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924

By S. W. Marcuson

In the late 1960's concerns about the natural environment reached high levels within North America and provided activists with suitable platforms for exerting influence over the general public and politicians. In response a host of regulatory mechanisms were developed, statutes, voluntary measures, land grants, codes of practices etc. Emerging environmental awareness from the era provided impetus for rapid technological change that encompassed all industries, especially the base metal business. The resulting clean up impacted all aspects of copper production, dealing with issues such as waste disposal, water and air quality with specific impact on emissions of sulfur dioxide and particulate. This paper provides a perspective of these changes reviewing the macro-economic impact of environmental movement in mining with its specific implications to the copper smelting industry. The fundamental challenges that were faced by the old, but capital-intensive North American plants and the approaches taken to deal with the changing times are reviewed with special emphasis on the conceptual approach to smelter S02 abatement and different paths taken in the USA and Canada. The role of economics, sustainable R&D and presence of technical infrastructure that facilitated the change process is elucidated, and speculations are made about the future state of pyrometallurgy and the natural environment. Cu2007 -

Jan 1, 2007

By D. M. Baird

"THE Island of Newfoundland lies on the extreme eastern edge of the continent of North America and at the extreme northeastern end of the Appalachian geological province. Its belonging to the Appalachian province is shown in the geological history of the region and in the rock types and structures.Geosynclinal sedimentation in early and middle Palaeozoic times was interrupted by Taconic and, more profoundly, by Acadian, mountain building activity. Mid-Palaeo-zoic intrusions range from masses of serpentinized ultrabasic rocks to granite batholiths. A Carboniferous overlay of continental and shallow, drying sea types covers the earlier developed complex. Local basins in these times were filled with products of the erosion of tl1e earlier rocks, and, locally, grew the right kind of vegetation to make thin, discontinuons seams and pockets of coal. Post-early Pennsylvanian history is one of erosion and pene-planation with renewal of movement along many of the older fault systems."

Jan 1, 1960

By Frederik H. Kriel, John Ralston, Craig Priest

"Stream-based microfluidic solvent extraction offers a novel alternative to bulk-scale mixer-settler operations. However present maximum throughputs are restrictive and there are engineering challenges that need to be overcome before the technology is robust. This is especially the case for mineral processing, where circuits must be able to handle variable feed streams with long retention times and where maintenance should be minimized. This paper highlights research directed at investigating and evaluating these challenges for actual mineral leach solutions of metal ions. Molecular and particulate channel fouling is discussed. Most extraction systems studied to date show no effects that would preclude use of the technology. For rare earth elements (REE) with fast extraction rates, scale-up of volumetric throughput to 100 L/h using suitable arrays of channels, microfluidic chips and modules is shown to be achievable using a small contactor (approx. 2 m3) platform. This requires only 2–3 % of the typical aqueous phase inventory and residence time used in an equivalent mixer-settler. For a circuit with 100 contactors, the overall residence time would be less than 1 h, using an aqueous inventory of 40 L.INTRODUCTIONHydrometallurgy is of pivotal importance in many mineral processing circuits around the world, with liquid-liquid solvent extraction (SX) a key step in the separation of many base metals (e.g. Cu and Ni), radioisotopes, precious metals, and the ‘technology’ metals, such as rare earth elements (REEs) (Ritcey & Ashbrook, 1979). The standard equipment for SX in mineral processing is the mixer-settler, in which liquid dispersions are created, by agitation, to increase the surface-to-bulk ratio and, thus increase the mass transfer rate between the liquid phases. In stream-based microfluidic SX (microSX), these high surface-to-volume ratios are achieved by contacting microscopic streams (Ciceri, Perera, & Stevens, 2014), rather than forming small droplets, so that phase disengagement can be accelerated (essentially instantaneous via branching of the two streams of liquid at a channel junction). MicroSX is profoundly different from bulk mixer-settler SX operations and offers exciting opportunities for processing hydrometallurgy solutions (Kriel, Holzner, Grant, Ash, Woollam, Ralston, & Priest, 2015; Priest, Zhou, Klink, Sedev, & Ralston, 2012). Nonetheless, the advantages of using microfluidic environments are presently balanced by very significant challenges relating to throughput, process control, coupling of stages, flow stability, and fouling. If these challenges can be met using smart chip designs, process control and clever engineering, high-value/low-volume SX processes stand to benefit greatly."

Jan 1, 2016

By van der Meer. F. P.

High Pressure Grinding Roll (?HPGR?) technology is applied in a broadening range of minerals processing applications for relatively wet or moist materials. HPGR grinding of dry material or involving drying and air classification is more common, for example in cement manufacturing. A number of minerals processing plants are also operating with dry material, either due to process reasons, such as considerations of preceding or subsequent process stages, or as dictated by local conditions of arid areas and scarcity of water. The present world-wide expectation of decreasing availability of water supply urges us to look for alternatives that minimize water consumption. Recently established and envisaged future HPGR applications with dry ores have indicated that the technology of dry crushing and classification as practiced in cement and limestone grinding can be applied in minerals processing. Moreover, dry technology could very well be applied for generating a final fine product at sizes near or below 100 microns, as may be required for beneficiation by, for instance, flotation, magnetic separation or tank leaching. Dry HPGR grinding requires special attention in maintaining suitable process economics, when considering power input in grinding, drying and classification. In some cases, HPGR capacity and roll surface wear life may be negatively affected by a lack of moisture in the feed. This publication summarizes some of the features of, and experiences in dry HPGR applications. This includes design aspects of the classification system and discussion of the wear protection of the roll surfaces. The paper also includes examples of operational experiences of dry practices in minerals processing and cement plants.

Jan 1, 2012

By R. D. Clarke, E. De Souza

"A framework for ventilation planning, with a focus on planning to the end-of-mine life, was developed for the Diavik Diamond Mine, Northwest Territories. This framework was successfully used by Diavik’s mine engineers to select a cost-effective ventilation plan that met the life-of-mine requirements. The framework achieved this result by reconciling the production plan with the ventilation plan. A set of design acceptability criteria was created and a PICK (possible, implement, challenge, kill) chart was used to quickly narrow down the generated ideas for detailed assessment and economic analysis. RÉSUMÉ Un cadre de planification de l’aérage, qui met notamment l’accent sur la planification jusqu’à la fin de vie de la mine, a été développé pour la mine de diamants Diavik. Les ingénieurs miniers de Diavik ont su mettre à profit ce cadre pour sélectionner un plan d’aérage rentable qui répondait aux exigences propres à la durée de vie de la mine. C’est en conciliant le plan de production et le plan d’aérage que cet objectif a pu être atteint. Un ensemble de critères d’acceptabilité de la conception a été créé et un tableau PICK (de l’anglais possible, implement, challenge, kill, une méthode donnant la priorité à certaines actions proposées ou à des idées visant à résoudre des problèmes) a été utilisé pour rapidement limiter les idées générées et les soumettre à une évaluation et une analyse économique détaillées.INTRODUCTION The Diavik Diamond Mine, Northwest Territories, has been an underground-only operation since 2012 and has a remaining mine life of 8 years. In the first year of underground-only operations, the production rate increased from 60 kt of ore per month to more than 160 kt of ore per month. In subsequent years, this rate was continuously increased (Table 1) because the operation went through various improvement initiatives. By the end of 2016, Diavik’s total production was 0.41 Mt (+22.8%) ahead of the 2012 budget for 2016 production."

Jan 1, 2018

By F. R. Erick Mulder

"AbstractTwo bottom-hole samples have been taken from two new completions in the Turner Valley field, Royalite Lowery No. 8 on the west flank and Royalite No. 73, which was deepened into a lower fault block, on the northeast flank. From the bottom-hole oil of Royalite Lowary No. 8 a synthetic sample was prepared to simulate the original fluid in the reservoir, saturated at the gas-oil contact conditions. The sample from Royalite Lewery No. 8 has been shown to be the original fluid present at this well and represents the oil phase near the oil-water contact in• the reservoir. Complete chemical analysis, P.V.T., and viscosity data have been obtained on these reservoir fluids, which represent the range of saturation from the gas-oil to the oil-water contact in the Turner Valley oil structures. Sampling techniques and the application of the analytical data to reservoir conditions and field operations are discussed. Super-compressibility curves for an average separator tail gas have also been prepared. These data have not been available before. They will be of fundamental value in futu.re reservoir engineering studies of this field and will also serve as a guide in determining operating practices."

Jan 1, 1950

By Alfred C. Lane

Reference to the original use of the terms Laurentian and Huronian (and its extension), shows that the former was applied to granitized sedimentary and metamorphic pre-Cambrian rocks, and the gneissoid igneous rocks associated therewith, and the latter to non-fossiliferous rocks supposed to be later. But it appears from the work of Collins, Quirke and others that there is more or less of an overlap, and that of the original Laurentian the Grenville limestone, and some of the granites, may be later than the lowest part of the original Huronian. Before we can decide whether to abandon one or the other of the two terms, or how to delimit them, it is important to know the extent of this overlap. The Pb :U ratio, though not to be depended upon too minutely, does give a real idea of the age of a mineral as it increases with the decay of uranium, and so is greater the longer the time since the uranium was separated: and there are reasonable prospects of help there from in getting a knowledge of the relative age of different granites to assist in solving the problem, as facts already collected show. 1. Historical review of the use of the words Laurentian and Huronian: 2. Difficulty encountered: 3. Popular account of atomic disintegration: 4. Methods of estimating age by it: 5. Applications.

Jan 1, 1925

By Webber. G. R.

Variation in content of some of the major and minor elements in the Lake Dufault granodiorite near Noranda, Quebec has been studied. The element variation and specific gravity data show a pattern consistent with the concept of a concentrically zoned intrusive on the western side of Lake Dufault with a potassium-rich core and a calcium-rich inner zone. The part of the intrusive on the eastern side of Lake Dufault is of more problematical origin, but the suggestion is made that it has resulted from assimilation of volcanic rock by the intrusive. THE purpose of this investigation was to test the application of x-ray fluorescence analysis to the study of variation in chemical com-position of the Lake Dufault granodiorite. The Lake Dufault granodiorite is an intrusive body approximately six miles long by three miles wide located four miles north of Noranda, Quebec. This intrusive is of particular interest because of its -

Jan 1, 1962

By G. G. Hatch

FOLLOWING World War II there was an urgent need for the development of domestic sources of ilmenite to take care of the expanding needs of the titanium dioxide pigment industry. In addition, there was the interest by the pigment manufucturers and others in titanium metal. Prior to the war the pigment industry in the United States had obtained its major tonnage of ilmenite, analyzing 55- ?60 per cent Ti02, from India. However, as a result of the shipping situation which developed during the war, the pigment manufacturers had to consider the use of lower grades of ilmenite located on this continent .and several companies undertook extensive exploration programmes to locate and develop such orebodies. Probably the most significant deposit that was found as a result of these ?programmes was the orebody .at Allard Lake, Quebec, owned by the Quebec Iron and Titanium Corporation. This ?Company was formed in 1948 by the Kennecott Copper Corporation and the New Jersey Zinc Company to mine this ilmenite ore and treat it in electric furnaces to produce titanium dioxide slag for the pigment industry and iron for the steel industry.

Jan 1, 1956

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016

By Colleagues from Process and Operation departments, Guy Chevalier

"QCM's pellet plant, located in Port-Cartier, Quebec, produces up to 8.6 million tons of iron ore pellets annually. Four different types are produced: three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the installation of new process equipment to improve the reducibility of direct reduction pellets (DR pellet). The findings, the equipment selection and some post start-up modifications are presented.This low silica DR pellet is used in Midrex and HyL shaft furnaces. A good DR pellet has to meet strict chemical, physical and metallurgical specifications. An important metallurgical property is its ability to release oxygen when exposed to reducing gases. Considering that the market for DR pellets is expanding and being aware that reducibility is critical for our clients, a program to improve the latter was undertaken. Test work showed that one factor which has a negative effect on reducibility is the proportion of particles larger than 75 microns. Knowing that the best way to reduce the amount of coarse particles was to close our open grinding circuits, we began evaluating the most suitable classification equipment applicable to our process operations. We settled on hydro-classifiers based on their very sharp cut and their low operating costs. In light of the hydro-classifiers performance it was also decided to replace the hydro-cyclones of an already closed circuit.INTRODUCTIONAt the Québec Cartier Mining pellet plant, continuous improvement programs are aimed at increasing levels of consistency and improved chemical, physical and metallurgical properties. This is being accomplished while still maintaining pellet plant production volumes to satisfy market demands.QCM produces three types of pellets for blast furnace use: acid pellets, designated as ""BHF"", fluxed pellets, designated as ""BAF"", and low silica fluxed pellets, designated as ""BSA"". For direct reduction, a low silica acid pellet or DR pellet, designated as ""BBS"" is produced. This low silica DR pellet is used in Midrex and HyL shaft furnaces.The demand for DR pellets has been increasing during the last few years and is believed to continue so in the future. Wanting to be present in this growing market QCM found that it would be essential to work at improving its DR pellets quality. Efforts have been focused on improvements in three areas: SiO2 reduction, elimination of sticking and increasing reducibility. Improvement programs have begun with laboratory research followed by plant trials and full-scale implementation as a cooperative effort among QCM, COREM, and key customers."

Jan 1, 2002

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By K. Harris, J. B. Wahl

Ni-base superalloy cast materials provide an outstanding balance of high temperature strength, fatigue resistance, oxidation resistance and coating performance and can be produced to very tight tolerances in extremely complex configurations, such as axial and centrifugal integral cast turbine wheels. As a result, cast superalloys are used in the most demanding applications of aero and industrial gas turbine engines. Use of these materials is expanding to smaller microturbine, turbojet, turbocharger and missile engine applications due to this unique combination of desirable properties. This paper will present an overview of the application of investment cast Ni-base superalloys and process capability to small turbine and missile engines.

Jan 1, 2010

By F. R. Archibald

Introduction It is the purpose of this paper to review the subject of roasting as preparation of refractory gold ores and concentrates for cyanidation, with particular reference to operations at the mill of Beattie Gold Mines (Que.), Ltd., Duparquet, Quebec. Two earlier papers relating to the Beattie roasting operations are cited as background to the ? present discussion, and more general reference is made to other publications relating? to geology and metallurgy at Beattie. The Beattie roasting plant was built in 1937 as an addition to the existing flotation and cyanidation plant to permit complete processing of the ore at the mine property. Previously, the flotation concentrate had been cyanided, yielding 70 per cent of the gold values, followed by re-flotation of a concentrate from the cyanide residue. This re-floated residue was shipped to a smelter for recovery of gold values unavailable from direct cyanidation. The roasting plant itself is of interest through application in its design of multiple-hearth roasters and a Cottrell plant for separate recovery of dust and arsenic. In the laboratory and plant studies that accompanied development of the plant into a dependable and efficient working unit have been found principles and ideas applicable to other roasting 'problems. Before enlarging on these aspects relating particularly to the Beattie problems and plant, brief consideration is given to roasting in general.

Jan 1, 1949

By H. Aaltonen, T. G. Robinson, M. Morimitsu

"The energy required to plate pure zinc can be the most significant operating cost for an operator in the production of electrolytic zinc. This paper reports on developments on low energy Outotec coated titanium anode process technology with fully amorphous coatings, MSA®, and its application to brownfield zinc electrowinning operations around the world. This technology aims to reduce the operating cost and increase productivity for zinc producers.INTRODUCTIONZinc electrowinning is an energy-intensive process using more than 3,000 kWh/t of electric energy [1-4], and the reduction of the energy consumption is one of the key issues. The high energy consumption is due to a high cell voltage during electrolysis, which is mainly caused by a high overpotential of oxygen evolution reaction on lead alloy anodes which have been widely used in commercial zinc electrowinning processes. The overpotential of oxygen evolution is 0.6 V or more and which is approximately 4 times higher on average than that of the cathodic reaction (zinc deposition) [3,4]. Therefore, the reduction of oxygen overpotential is significant to reduce the electric energy consumption, and this will become more significant with increasing demand in metal production and rising energy costs.Oxide coated titanium anodes have been widely investigated for the oxygen evolution anodes in order to replace the lead alloy anodes [5-9], because it is known that the oxygen overpotential strongly depends on the material and structure of the anode. The most typical example of such anodes is an IrO2-Ta2O5 coated titanium anode, which is usually prepared at thermal decomposition of a precursor solution containing metal salts at 450 oC or more and obtained mixed oxide coating consists of crystalline IrO2 and amorphous Ta2O5. On the other hand, one of the authors of this paper, Professor Morimitsu, Doshisha University in Japan, has developed a novel oxide coated titanium anode, MSA® [10-25]. The most specialized point of MSA® is that the catalytic coatings are prepared at low thermal decomposition temperature and amorphous IrO2 or RuO2 is contained as the components in the coatings. Such amorphous coatings have high catalytic activity for oxygen evolution compared to lead alloy or crystalline coatings. Outotec acquired the international specialized MSA® patent licensing rights from Doshisha University and has produced and commercialized the amorphous oxide coated titanium anodes. These anodes have already been utilized mainly in copper electrowinning plants worldwide and have demonstrated a significant voltage reduction, a cost-efficiency, and a long lifetime. This novel technology is also effective to zinc electrowinning process, thus this paper presents the characterization and performance of amorphous IrO2-Ta2O5 coated titanium anodes and amorphous RuO2-Ta2O5 coated titanium anodes for oxygen evolution in zinc electrowinning."

Jan 1, 2016

By G. Kolosay, J. Rajala, G. Deschênes, A. Romanov

ABSTRACT: The Kupol project, located in Far East Russia, treats a high-grade, free-milling ore containing 25.5 g/t Au, 298.3 g/t Ag, and 0.5% pyrite,with a P70of 53 microns. Most of the gold occurs as elec-trum and the silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite, andproustite. The mill reached the design throughput of 3,000 tpd six months after start-up. AKnelson con-centratorrecovers10.4% gold and 0.5% silver. Leaching (14.5 hours pre-treatment and 116 hours cyanidation)of gravity tailings is performed with the CANMET Enhanced Leach Process (CELP),using only 490 ppm NaCN (cyanide consumption of 1.1 kg/t). The precious metals are recovered by counter-current decantation and the Merrill-Crowe process. Calcium hypochlorite destroyscyanide and thiocyanate. Overall, gold and silver recoveries for 2008 were 95.4% and 85.6%,respectively (2.8% and7.5% higher than targets). In the first eight months of 2009, gold and silver recoveries were 95.0% and82.6%, respectively. By August 2009, the mill processed 1.42 million tons of ore with production of 1.1 million ounces of gold and 11.3 million ounces of silver. CELP performance was not affected by changes in feed grade and ore mineralogy. Additional modifications to the leaching strategy allowed further reduction in cyanide consumption and effluent treatment costs.

Jan 1, 2011

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017

By B. D. Sparks, I. E. Puddington, F. W. Meadus

The continuous separation of bitumen from Athabasca tar sands, with a high clay content, has been demonstrated. Recoveries of 95 per cent or higher have been obtained. Further processing of this product, to produce an accept-able type of crude oil, would require less heat than currently used in the hot-water process. Also, by comparison, substantial savings in equipment and operating costs are indicated.

Jan 1, 1971

By David E. Pearson

"Western Canadian coking coals are located in the Rocky Mountains arid foothills of British Columbia and Alberta. They are typical of non-marine coals, characterized by total sulphur contents of less than one per cent and with ash contents of 10-30 weight per cent. This mineral matter is composed principally of kaolinite and quartz.The petrographic compositions of most of the coking coals which constitute the 2.065 billion tonnes of British Columbia's measured reserves, and the compositions of the metallurgical coal currently exported from Alberta, show them to be rich in the inertinite macerals, macrinite, fusinite and semifusinite. When the mean maximum reflectance of vitrinite in oil/Romax) is used as the coal rank parameter, this high inertinite content is reflected in the lower volatile-matter yields, but the relatively inert character is also displayed by lower free swelling indices (PSI), lower maximum dilatations, lower maximum fluidities and lower coke strengths than other coals of the same rank, but richer in the reactive macerals, vitrinite, exinite and semifusinite. Despite these reduced values in the so-called caking tests, inertinite-rich coals produce strong coke.A system of classification of coking coals is introduced which is based on rank, as indicated by Ro max, and either petrographic composition, maximum dilatation, maximum fluidity or, to a lesser extent, PSI and volatile-matter yield. Six principal coal groups can be distinguished among coking coals using this versatile classification. Inertinite-rich coals are assigned to the Keystone Group (GI), Balmer Group (G3) or Moura Group (G4), each group being named for a coal typical of that population ofcoals. Reactive-rich coals are assigned to the Pittston Group (G2), Kellerman Group (G5) or Big Ben Group (G6). A multiple-regression analysis of coal quality versus price shows how the value of coking coal in the Japanese market appears to be related to reflectance and the free swelling index, and confirms the economic viability of the classification.British Columbia's measured reserves of coking coal contain representatives of four of these groups; Balmer Group (73%), Moura Group (/6%), Pittston Group (3.4%) and Kellerman Group (7.6%).This analysis of the quality of Western Canadian coking coal indicates that despite the need for large proportions of inertinite-rich coking coal in blends produced in the Japanese steel industry, there is nevertheless a demonstrated overabundance of Balmer Group and Moura Group coals available to the international coking coal market."

Jan 1, 1980