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By C Fountain

It is commonly known that copper smelter terms include penalties if the concentrations of elements, such as arsenic, mercury and fluorine, exceed stipulated limits. It is less commonly known that the behaviour of these elements in the smelters can depend on the processes used to treat the concentrate. The principle behind the penalties is to compensate the smelters and refineries for additional costs caused by the presence of the penalty elements, but these costs will vary depending on the process used and the location of the smelter.The issues caused by the minor elements include effects on the occupational health of smelter workers, increased environmental disposal costs, increased operating costs and reduced cathode copper quality.The effects of minor elements can be surprising. High levels of arsenic in concentrate are considered undesirable, but some smelters add arsenic to anode copper to improve the performance of the refinery.Excess concentrations of some elements will result in rejection of concentrates by smelters. China has blanket import bans on copper concentrates with concentrations of lead, arsenic cadmium, fluorine and mercury exceeding specified levels.This paper will review the behaviour of minor elements in smelters and refineries, explaining the deleterious effects of each of them, to provide a greater understanding for people and organisations wishing to market copper concentrates.CITATION:Fountain, C, 2013. The whys and wherefores of penalty elements in copper concentrates, in Proceedings MetPlant 2013 , pp 502-518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

Mining engineering, metallurgy and minerals-related geology have proud traditions and are essential professions to support a safe and sustainable minerals industry. However, the future of these professions is under threat. The courses that produce such graduates are disappearing worldwide and the number of graduates available to enter the industry has been falling in English speaking countries for at least a decade. It is unlikely that this problem will be remedied by æsupply and demandÆ. Instead, some active intervention is required.

Jan 1, 2004

In the wake of the United Nations Conference on Environment and Development (UNCED) held in Rio de Janeiro in June 1992, evolved AGENDA 21. This document which was adopted at the Conference, provides a global action guideline for sustainable development into the 21st century.Sustainable mining requires a complete understanding of the `mineral cycle', including government legislation, mineral exploration, mining operations, rehabilitation, product use, re-cycling and waste disposal that takes into consideration associated social and environmental considerations and achieves economic objectives.

Jan 1, 1993

By Hamilton LH, Campbell PB

Since fundamental research in applied coal petrography is carried out mostly on polished surfaces, backscattered electron microscopy is most applicable for studying coal in the SEM. By employing this technique coal macerals can be easily identified , and information on the relations between maceral groups, mineral matter and trace elements are highlighted by grey level contrasts. This type of information is valuable in coal technology and cannot by normally revealed by the light microscopy (e.g. the distribution of inherent mineral matter).

Jan 1, 1989

By Tilyard P. A

Pasminco has tested a Valmet ES1 ceramic disc vacuum filter at its Broken Hill concentrators. On lead and, particularly, zinc concentrates at the ZC Mine the filter performed well but on North Mine lead concentrate problems were experienced with deposition on the disc, which resisted both ultrasonic and acid cleaning. A preliminary financial analysis showed that the application of the filter at the ZC concentrator was worth pursuing. Accordingly an ES30 machine has been hired for plant evaluation.

Jan 1, 1989

The BHP Steel Group embarked on a Total Quality Control (TQC) programme in 1984 in response to enquiries from a major customer regarding procedures for quality in materials supply.The TQC initiative has been adopted by all seven Divisions of the Steel Group and covers a broad and comprehensive range of management and workforce improvement initiatives.The development of the TQC initiative in the Collieries Division of BHP Steel over the past eighteen months has resulted in important experiences and leanings.

Jan 1, 1991

By J Demchak, L M. McDonald

The duration of acid mine drainage flowing out of underground mines is important in the design of watershed restoration and abandoned mine land reclamation projects. People conducting land reclamation projects usually employ remediation strategies once (reshaping land, revegetating soils, and installing water treatment) with the hope that these methods will adequately improve water quality for a long time, with little planning for future changes. An understanding of changing acid water conditions from underground mines over time will help in designing efficient and cost-effective treatment methods. Past studies have reported that acid water flows from underground mines for hundreds of years with little change, while others state that poor drainage quality may last only 20 to 40 years. Several factors are important in making a prediction of drainage quality over time, such as inundation or flooding history, coal seam characteristics (primarily sulfur content), residence time of water in the mine, time since mine closure, mining method and amount of coal remaining, collapse of roof and other disturbances within the mine, and subsequent nearby surface mining. More than 150 above-drainage (those not flooded after abandonment) underground mine discharges were located and sampled during 1968 in northern West Virginia, and we revisited 44 of those sites in 2000 and measured water flow, pH, acidity, alkalinity, Fe, Al, and sulfate. All 44 discharges were from mines in the Pittsburgh and Upper Freeport coal seams, and both seams have been extensively mined in this area during the past 70 years. We sampled during the same months (June to October) as were sampled in 1968, and we found no significant difference in flows between 1968 and 2000. Therefore, we felt that the water quality data could be compared and that the data represented real changes in pollutant concentrations. There were significant water quality differences between year and coal seam, but no differences between disturbed and undisturbed mines. Average acidity declined 79 per cent between 1968 and 2000 in Pittsburgh mines (from 3342 to 702 mg/L), and 56 per cent in Upper Freeport mines (from 1189 to 519 mg/L). Iron decreased an average of about 80 per cent across all sites (from an average of 345 to 69 mg/L), while sulfate decreased between 50 to 75 per cent. Pittsburgh seam discharge water was much worse in 1968 than Upper Freeport seam water. Twenty of our 44 sites had water quality information during 1980, which served as a midpoint to assess the slope of the decline in acidity and metal concentrations. Almost all parameters showed an exponential rate of decline in acidity, iron, and sulfate.

Jan 1, 2003

The accuracy with which block values are known can have a fundamental effect on the success of an operation.From a geostatistical study the variance of the error in extending sample values to block values can be determined and the engineer must ensure that this is sufficiently small by adjusting the size of blocks or moreintensive sampling. A study is given for a deposit showing a high degree of anisotropy and it is shown that the shape of the block is not important in determining the estimates.

Jan 1, 1976

Deformation of the lithosphere by tectonic forces is investigated from both observational and theoretical standpoints. Global and regional geophysical data bases, coupled with the means for their rapid display and analysis, facilitate recognition of areas of the con- tinents and oceans where the response of the lithosphere to these deforming processes might fruitfully be studied. Gravity anomalies, from Seasat altimeter data and from land and shipboard measurements, provide critical infor- mation on the isostatic state of deformed lithosphere and therefore on its thermal and mechanical properties.

Jan 1, 1987

The Greens are asking the question: what do our mining towns look like in 2050 and how can we be better prepared? The resources boom brought enormous profits to the main players and was partly responsible for insulating Australia through the worst of last year's global economic turmoil. However, with indicators of a resurgent mining boom, it is essential we learn from the recent past. The last boom saw housing stress at levels unseen in the big cities, health services strained to breaking point, and Aboriginal poverty side by side with some of the most lucrative industrial precincts in the country. Much of the wealth still flies right over the heads of regional communities as fly-in, fly-out operations proliferate.   Behind these local stresses, resources booms rely on the stripping of non-renewable resources which will eventually run out, and the unique environment of the north-west is taking a battering.    Communities of the north-west have a perilously narrow economic base which must be broadened if townships of the Pilbara and Goldfields are to avoid the fate of places such as Goldsworthy and Wittenoom. Unless this is informed by local communities, decisions will be made in capital cities thousands of kilometres away by people largely ignorant of the unique conditions prevailing in regional Western Australia.   Global climate change negotiations and oil depletion will heavily penalise emissions-intensive economies like Australia which fail to keep up as the world moves to a low-carbon environment. This is an ABSTRACT ONLY no paper was prepared for this presentation.

Jun 1, 2010

The purpose of any feasibility study is to determine whether a particular investment or management program will enhance shareholder wealth by, for example, producing an economic return in excess of the cost of equity capital.The threshold rate of return conventionally used in gold feasibility studies is higher than the cost of equity capital, meaning that some viable projects are wrongly described as being sub-economic with their development deferred.Is the industry failing to fully realise its potential? Aside from important technical considerations that determine the cost of exploiting inground inventories, feasibility studies need to incorporate expectations about future gold prices, exchange rates, interest rates and tax rates.Rather than revert to speculation, insights from capital markets give a rigorous framework in which these parameters can be determined for feasibility purposes. Separate questions sometimes, and then inadequately, addressed by feasibility studies include: ò Is it optimum? Many projects are expanded soon after project commissioning - what does this say about the quality of the initial feasibility study? Moreover, does the rate of extraction really matter? ò What is it worth? Although feasibility studies are designed to address viability rather than valuation, such studies are never- theless used by the industry as further evidence that the equity markets have got it wrong again! More likely the problem is with the financial slide rule being used. ò Can it be debt financed? The bankable feasibility study has entered the vocabulary of the gold mining industry but what does it mean? Does it matter anyway how the project is to be Financed?

Jan 1, 1991

By E Drueppel, F M. Meyer, P N. Martens, J P

The present study shows a calculation of the amount of copper contained in the initial reserves that remains un-extracted. The study is based on data of 271 producing copper mines and includes geological parameters, mining methods used and the processing recovery. Estimations disclose that approximately 25 per cent of the metal contained in the original reserves is not extracted. One third of this value can be attributed to mining, whereas two thirds are related to processing. However, values differ for different ore deposit types and mining districts.

Jan 1, 2003

The excavator selection process is quite complex due to the large number of influencing factors, many of these are variable and difficult to accurately define. The majority of mining companies prepare a tender of general specifications and suppliers will then match a product to those specifications. The mining company will then evaluate the tenders on the basis of the best available deal. In this paper, the importance of open pit excavator selection in terms of its impact on operating costs is analysed and discussed. A rigorous process for selection is then outlined.

Jan 1, 2003

All minerals contain radioactive elements, from the uranium ores of the Gabon, which contained sufficient uranium to initiate a natural nuclear reactor, to the very low levels of some recent evaporites. The commonly occurring heavy minerals such as ilmenite, rutile and zircon are no exception to this and contain varying qualities of radionuclides, depending on the source. With recent changes in legislation many natural minerals may become officially classed as radioactive. Such moves can inhibit the sales and exploration of many minerals in the heavy minerals suite. The many negative perceptions associated with the word radioactivity can produce an over cautious reaction from regulators and users. This paper presents a method of managing the radioactivity issues associated with minerals such that the safety aspects of workers and public are not compromised, whilst allowing the commercial use of such minerals to continue in a sensible manner. The paper focuses mainly on the mineral zircon and its uses. However the legislation changes particularly in Europe and the USA have the potential to affect all minerals imported into or produced in those countries. The model developed for addressing the issues of zircon radioactivity may be readily applied to other minerals since legislation governing such matters is not mineral specific. There is a strong need for education of both regulators and users of minerals. Regulators are usually not aware of the specific properties or uses of individual minerals. Similarly mineral users are not aware of the radioactive nature of their materials or how to manage this property. The paper concludes by recommending strong cooperative action by both producers and users of minerals to protect the future of their industry.

Jan 1, 2001

Builders have been very familiar with iron since ancient times, but because of its weathering characteristics it was relegated to use as a fastening material in unexposed places and bronze became the popular metal for exposed applications. It is of interest that iron nails buried deeply about A.D. 87 at a Roman fortress and carefully covered with clean beaten earth under conditions practically excluding oxygen were found to be almost unrusted 1870 years later. (1) Today, weathering steels, which contain less than 2% of alloying additions, can be used in exposed situations without protection and without experiencing continuous wastage. As we all know the steady access of atmospheric oxygen to the surface of plain steel causes continuous corrosion. Weathering steels, on the other hand, due to their alloying additions develop their own impervious surface layer which limits the access of atmospheric oxygen and effectively limits corrosion. Table 1 shows the chemical composition of a plain carbon steel and a typical weathering steel. Fig. 1 shows what we refer to as direct corrosion - time curves in which corrosion loss is plotted against time of exposure in an strial environment. The weathering steel has a high rate initially which then decreases steadily for about three years, as the stable rust film builds up. This is followed by a practically linear relation where the very low corrosion rate, according to one school (2), is due to a blocking of the rust pores by insoluble complex salts formed from interaction of the oxidation products of the separate alloying elements. The start of the linear region represents a total corrosion loss of only about 2 thousandths of an inch.

Jan 1, 1970

By T Christopher

The Campamento Au/Ag deposit, discovered by Linear Gold in 2004, is located in Chiapas State, southern Mexico. The deposit is hosted by a sequence of Pleistocene-Pliocene andesitic volcanic rocks that have been intruded by a feldspar-phyric porphyry complex. Measured and indicated resources are 852 000 oz Au and 3.46 million ounces Ag with inferred resources of 374 000 ounces Au and 920 000 oz Ag. Resources were estimated at a 1.0 g/t Au equivalent cut-off. This is an ABSTRACT only. A full-length paper was not prepared for this presentation.

Jan 1, 2008

Prior to the 20th century much of our infrastructure was provided by the private sector. This included toll roads, tunnels and bridges, power supply, transport and water.With the depressions of the 1890s and 1930s and the world wars, much of this infrastructure passed into public ownership. This was certainly the case in Australia as well as many other Western countries.In the last quarter of the 20th century we are seeing a swing back to private sector provision of infrastructure,-resulting'from increased needs for investment in infrastructure due to changes in

Jan 1, 1993

When mining of ilmenite deposits wet process of preparation is traditionally used. But this method needs large volume of water. The problem of water deficiency is characteristic of many regions of the Republic of Kazakhstan. The Satpayevskoye ilmenite deposit is situated in the East Kazakhstan, its location has problems with water, and the mineralogical composition of rock is unfavourable: rocks contain up to 40 per cent of clays. That is why designers made a decision to use dry process of preparation for processing of these ores. Offered scheme and equipment selection are presented in this paper.

Jan 1, 2003

Operation of the tankhouse at the Electro lytic Refining and Smelting Company's works has been improved, but further automation is re- quired to cut the labour intensive nature of the routine tasks. Anode quality, both chemical and physical, plays an important role in efficient refinery practice, and impurities such as lead, antimony and nickel have required careful monitoring for smooth operation. The gradual replacement of copper blanks by titanium has markedly improved the quality of starting sheets, but problems have been ex- perienced with surface preconditioning of the titanium blanks. Polishing with emery paper proved to be a successful technique.

Jan 1, 1976

By Stockton N. D

Gravity concentration of gold is an important facet of gold processing technology in Western Australia. While great interest has been directed at gold leaching technology and considerable developments achieved, gravity concentration has received much less attention and this paper provides an update on the current practice and developments that have been achieved in recent years.A survey of 72 gold processing plants in Western Australia was conducted in 1991 and some 31 questionnaires were returned for analysis. Of these, 19 plants were using gravity concentration and this paper highlights some of the features of these operations.

Jan 1, 1992