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Prior to the merger of BHP and Billiton, both companies had a keenfocus on improving their performance in health, safety, environment and community (HSEC) matters. This shared intent, albeit executed insomewhat different ways, provided an excellent foundation for the newCompany. During the integration planning phase, a team was formed toconsider the organisational design for consistently achieving world class HSEC performance. The design included the policy platform, resources, structures, standards and procedures to be implemented in the merged entity. A key aspect of the design was the fully integrated HSECManagement Standards. These Standards create the framework for theconsistent application of BHP BillitonÆs HSEC Policy at all of ourmanaged operations across the world. The Standards have their origin in similar frameworks adopted by BHP during the 1990s, as well as thewell-known quality related standards (eg ISO 14001). However, they areunique in that they combine all aspects of HSEC management into asingle integrated set of auditable standards. By combining these areas and integrating our HSEC Management Standards with other aspects of the æBHP Billiton WayÆ, we are establishing a holistic, line management driven improvement approach. Over time, the BHP Billiton Way will embed a systematic improvement philosophy that we expect will become a key source of competitive advantage. The HSEC Management Standards are consistent with ISO 14001,OHSAS 18001, the Australian Minerals Industry Code for EnvironmentalManagement and generally aligned with SA8000. While compliance withthese external standards ensures that a systematic approach andimprovement plans are in place, BHP BillitonÆs HSEC Standards gofurther to include minimum performance requirements that reflect theintent of our HSEC Policy. Therefore, implementation at site levelensures that robust systems are in place to implement our Policy and that accreditation can be achieved to external standards if required.To assess implementation of the HSEC Management Standards anaudit system has been designed which incorporates both self-assessmentand peer review. Each site is required to undertake an annualself-assessment of compliance with the Standards using a commonassessment protocol. Every three years a peer review is conducted at each site to confirm the results of self-assessment and to provide a means of sharing knowledge throughout the Company. The review teams are composed of line managers and HSEC professionals from around theCompany, representatives of our joint venture partners and independentspecialists as required. The Company has committed to public reportingof the audit results through our annual HSEC report and this is reflected in our published targets. From a wider perspective, as we in the resources industry strive tocollectively raise our HSEC performance and reputation, there may be arole for industry based HSEC Management Standards complemented bya level of independent review.

Jan 1, 2002

By G Munro

he Melbourne City Link project will complete a missing link between two existing major freeways in the Melbourne road network, providing a much needed bypass of the Central Business District for through traffic. The project, which is being financed under a BOOT arrangement with the Victorian State Government, involves the upgrading of significant stretches of existing freeway and the construction of new sections involving viaducts and tunnels. The tunnel sections, which are the focus of this paper, are beneath residential and business areas, the Yarra River, the Royal Botanic Gardens and significant sporting facilities where surface construction would be either impossible or unacceptable (reference Figure 1). The shorter, 1.62 km west bound Domain tunnel comprises two cut and cover sections through Olympic Park then the Yarra River, the driven section of 0.68 km length and exits through a common cut and cover section with the east bound tunnel under St Kilda Road and Sturt Street. The longer 3.76 km east bound tunnel commences at the common portal, through cut and cover under St Kilda Road then 2.86 km of driven section before exiting at a cut and cover section at Burnley. The longer Burnley tunnel has an access and ventilation shaft at approximately its mid point.

Jan 1, 1999

Elimination of zinc by the reduction of iron works dusts is examined. The process consists of blending, filtration, drying, balling, preheating and reduction in the rotary kiln. Dust slurries and dry dusts are mixed and stored in slurry basins and the blended slurry is filtered. In the balling process it is important to make green pellets which will withstand Thermal shock in the preheater and rotary kiln. Preheating to about 2000C is preferred to ensure effective use of coke fines in the blast furnace dust. The coke retained in the pellets accelerates the reduction rate. However, at the initial stage of the reduction the pellets become weakened and have to be heated slowly to prevent ring formation. In order to ensure zinc vaporization, pellets should be heated to a temperature of 1100-11500C in the kiln with injection of l ignite fines from the discharge end. Pellets having a degree of metallization of more than 90% and containing less than 0. 1% zinc have been obtained using a test kiln. The final pellet product is intended for use as blast furnace feed. A new plant with a capacity of 20, 000 tonne of dust per month is now under construct- ion and will be in operation next year.

Jan 1, 1974

Optimisation and sensitivity analysis of final pit limits is now an accepted procedure for open pit planning studies. Tools to assist the design engineer in an underground metalliferous mine to make optimal choices for the selection of major development, stope geometry and cut-off grade analysis have not been available. The engineer has had to rely on experience and a limited analysis of design alternatives. A new tool called the `floating stope' has been developed to define the optimal (boundary) limit for material that can be economically extracted by underground stoping methods. The method is analogous to the `floating cone' method of open pit optimisation. The geology and mineralisation are modelled as a regular or subcell block model. Included in the model are structural and geotechnical features, and any previously mined out areas. Inputs to the procedure include the minimum stope dimensions, cut-off grade, stope head grade, and the way in which dilution is to be calculated. The optimisation procedure can be directed to maximise ore tonnes, grade, contained metal or the economic (dollar) value of material mined. The procedure can be applied at each stage of mine evaluation and design to assist with preliminary resource appraisal, selection of stoping methods, and detailed mine design. As with open pit optimisation procedures, manual intervention by an experienced engineer is required to produce practical and detailed designs. This practical design should follow the optimised design as closely as possible. The paper outlines the algorithms used in the definition of the stope envelope, and describes the analysis and results of several case studies where the optimisation procedure has been applied.

Jan 1, 1995

By J A. Shonhardt, I Porter

All types of coal are liable to spontaneous combustion to a variable degree according to the inherent characteristics of the coal and also extrinsic factors. In order to successfully extract coal from highly capital-intensive longwall mining operations it is necessary to evaluate and manage any risks that may be present due to spontaneous combustion. A spontaneous combustion risk management plan for longwall mining is described in this paper. This risk management system comprises identification of conditions promoting spontaneous combustion risk, a laboratory or empirical risk classification system, determination of gas ladder, adoption of adequate ventilation plans and gas monitoring systems that will lead to the development of the spontaneous combustion action plan. The risk management system was applied to a greenfield site in NSW in 1992 when prediction of a high-risk category for the coal seam was made. After commencement of production a spontaneous heating problem emerged as predicted. Description of the case history of spontaneous combustion risk management for a longwall operation in this coal seam is included in this paper.

Jan 1, 2003

By G R. Hancock

A common and cost-effective method for post-mining landscapes is to construct linear hillslopes with a break in the hillslope at appropriate distances to reduce hillslope length and resultant erosion risk (Figure 1). The break in slope occurs at a point that has been found by local experience to be appropriate for the materials and climate. Further enhancement of the linear hillslope may be assisted by surface treatment such as ripping (Saynor, Lowry and Boyden, 2019) (Figure 1). Firstly, ripping introduces surface roughness which breaks up flow paths reducing flow velocity thereby reducing erosion potential. The depression produced by the ripping acts as a trap which captures water, sediment and organic matter

Aug 2, 2023

By Y Tsukurimichi, D Asahina, T Endo, T Takemura

Scientific knowledge of Mars’ surface morphology and internal geological structure has been accumulated through satellite imagery and numerical topographic data using remote sensing technology, as well as seismic surveys by the on-site lander. Recent studies show that Marsquakes could be caused by the release of strain energy generated by the contraction of Mars. In particular, Marsquakes occur around the graben where many faults are existed and formed regularly spaced patterns. This implies that Marsquakes occur when the stress field of the Martian crust is an extension condition, and normal faults appear on the surface. We focus on the linear relationship between the fault spacing and the thickness of the mechanical layer as an approach to studying the internal structure from satellite images. Mechanical layer is a layer that composes of the same mechanical properties and is mainly bounded by lithology (Narr, 1991; Gross, 1993). The linear relationship between the thickness of the mechanical layer and the joint spacing has been studied and its slope is called the Fracture-Spacing Index (FSI) (Narr and Suppe, 1991). Soliva, Benedicto and Maerten (2006) showed that the stress drop zone (stress shadow) due to the fault activities affects the fault spacing. Figure 1 shows the approach used to estimate the thickness of the mechanical layer from the fault spacing on Mars. This paper aims to better understand the internal mechanical structure of Mars estimated by the geometrical pattern of faults on the Martian surface. We report the initial studies of this work. The lab-scale physical experiments and numerical experiments were presented to demonstrate the relationship between the thickness of the mechanical layer and the geometric pattern of fractures

Nov 29, 2022

By T Raynlyn, A Edenton, M Adam, R J. Holmes, J R. Manuel, N Ware, R Smyth

Due to ongoing demand and increasing depletion of high-grade iron ore resources from large deposits, Australian iron ore producers are developing smaller size deposits to maintain current export levels. The iron grade, mineralogy, chemical and physical characteristics of iron ore fines being mined from different deposits vary considerably. It is therefore imperative to develop long-term strategies to maintain the quality and consistency of iron ore fines while moving to a larger diversity of smaller deposits. Blending is a common practice in sinter plants as it is almost impossible to produce a high performance sinter mixture displaying the required characteristics from one single ore. Blending is also one of the most effective options being used by iron ore producers to ensure the long-term stability of their products while increasing production. When designing a blend, the blend components are selected to support each other to achieve the required overall balanced metallurgical performance of the final product at a relatively low cost. To do so, a fundamental understanding of the key characteristics of iron ore fines and their potential impacts on the iron ore sintering process and sinter quality are required. In this paper, the sintering process and sinter structure have been analysed and the key factors affecting the sintering performance of iron ore fines, including productivity and quality, identified. Under fixed sintering conditions, the granulation efficiency, nuclei stability and the volume and properties of the primary sinter melt are believed to have important impacts on both sintering productivity and sinter quality. Discussion is then focused on the effects of ore chemical, physical and mineralogical characteristics on the key factors identified and in turn the consequences for sintering productivity and sinter quality.

Jan 1, 2009

By E Forbes, G V. Franks

"This study investigates the dual function of a temperature responsive anionic co-polymer of poly (N-isopropyl acrylamide) (PNIPAM) as a selective flocculant/flotation collector. PNIPAM is used for separating hematite from 50:50 mixtures of hematite and quartz, at a variety of particle sizes. The performance of PNIPAM in this system is compared to that of conventional flotation collectors: sodium oleate and sodium dodecyl sulfate. The results of the study demonstrate that anionic PNIPAM used at 50¦C (above the lower critical solution temperature (LCST)) is the most effective flotation collector for hematite particles in the size range between 10 and 20 ¦m. This is attributed to the increased probability of both particle/bubble collision and particle/bubble attachment through the formation of hydrophobic hematite aggregates. Anionic PNIPAM used at 50¦C also produced the highest hematite recoveries for very fine hematite particles (circa 1 ¦m). However this recovery was completely unselective. This lack of selectivity is partially attributed to the activation of quartz particles by PNIPAM, but is thought to mainly occur as a result of entrapment of quartz particles within the matrix of hematite aggregates.CITATION:Forbes, E and Franks, G V, 2013. Selective separation of hematite from quartz by flotation using a temperature responsive polymer, in Proceedings Iron Ore 2013, pp 381-390 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By J Meinhart, J Rodler, I Katolicky

The ever increasing number of vehicles is leading to slow-moving and even stationary traffic sitting longer in traffic jams over extensive city areas. This traffic situation causes a sharp increase in pollutant emissions from vehicles, and high levels of pollution usually result throughout the built-up area. Reducing the pollution level by using traffic routing measures to speed up the flow of traffic in the existing street network is only possible in exceptional cases.In many cases the only option for achieving a significant improvement in traffic conditions is to shift the traffic underground using a road tunnel or underpass. Such tunnel routes suck off the traffic from large sections of the city, thereby easing the overall traffic flow. Thus on the one hand it produces a sharp reduction in pollution levels in the area of the tunnel route, but on the other hand it can result in locally increased exhaust pollution levels from longer tunnel systems that require mechanical ventilation. The air extracted by the ventilation system is blown out into the atmosphere either directly through the tunnel portal, or via a venting tower. Pollution can therefore occur in the area surrounding such exhaust air outlets.Thus if a tunnel is planned in a city, then closer investigation is required of both aspects: the reduction in pollution in the area of the tunnel route thanks to relocating the traffic and easing congestion, and the increased short-range pollution around the tunnel portals (shafts).

Jan 1, 1999

For the last decade Australia has been the leading exporter of both steam and coking coal. In the ten-year period 1989 - 1998 steam coal exports increased by 93 per cent and metallurgical coal exports increased by 50 per cent. However, profitability of the steam coal sector has been disappointing. The coking coal sector, especially the hard coking coal segment, has fared better but its profitability was more because of its ability to maintain relatively high prices rather than its inherent productivity. Until quite recently the Australian coking coal sector was widely expected to be able to maintain this comfortable state without undue effort for the three major æpartnersÆ; the companies, the State Government and the unions. But coking coal could now be heading down the path followed by steam coal that ends with long-term over-supply and, despite steady improvements in productivity, poor profitability. Steam coal entered the ænewÆ era of long-term over-supply some years ago. Over-supply was due to the rapid increase in production in Indonesia, often from new mines and Australia. AustraliaÆs production rise was underlain by the apparent belief that the best way to lower costs was to increase production. In the first couple of years costs didnÆt fall much but the additional tonnage was sold at lower and lower prices into the spot market. By mid-1998 the difference between the contract price set with Japanese utilities and spot sales was often in excess of $US12 per tonne. Japanese contract prices and tonnages have since fallen significantly. Steam coal has moved from being a product to being a commodity. Any profits are due more to the low Australian dollar rather than inherent mine productivity. Seaborne coking coal trade has been dominated by Australia, Canada and the USA, with the USA becoming less competitive. Unfortunately, when the Queensland capacity expansion was well down the pipeline, the Asian financial crisis occurred and the Japanese economy entered what appears to be a long-term recession. Contract prices fell 18 per cent, tonnages decreased and some mines have been reclassified as supplying lower priced coking coal. The paper analyses past and expected future trends in labour and mine productivity, rail freight and FOB export port cash and total costs of the Australian steam coal and coking coal sectors and discusses the market outlook for Australia. The future economic viability of the industry is analysed and discussed in the light of the rapidly changing global environment.

Jan 1, 2000

Optimising a mining or a quarrying operation about the overall cost is quite a challenge as there never is a situation where we have exactly the same conditions regarding rock properties, explosives' performance, mining equipment or evironmental restrictions. The amount of endless influencing parameters and variables make the evaluation process difficult. The enormous progress we have seen during the recent two decades in computing has however significantly increased our ability to evaluate and process the information gathered, and refine our existing prediction models. Refined models demand an increasing volume of good quality information to show reliable conformity with reality. There is a great need for co-operative work in the mining and quarrying society if we shall be able to screen all available data, systematically find the key-parameters influencing the results and to build robust scientific models. No organisations today have all the skilled people needed or can afford to hire the necessary specialists in all the overlapping branches. This paper highlights some on-going work where the Dyno Explosives Group is adding some new pieces to the giant jigsaw puzzle representing the ultimate model of the mining and quarrying operations we all of this society would like to see completed.

Jan 1, 1995

By Mudge S. T

Tin mineralisation occurs at Renison Bell, near Zeehan in Tasmania, as a group of cassiterite-bearing massive pyrrhotite bodies in Cambrian sedimentary rocks. Mineralising fluids from the underlying Pine Hill Granite have replaced carbonate rocks with massive sulphides and cassiterite. The discrete blocks of massive pyrrhotite have high density and high magnetic susceptibility contrasts with the comparatively barren country rock. They are strongly remanently magnetised and are excellent geophysical targets. A detailed geophysical model of the mine was created from a database comprising 1:2500 scale geological mapping and geological logs of approximately 4000 drill-cores. The model comprises 93 parallel cross-sections, each 1.5 km long, spaced 20 m apart. Each cross-section is comprised of up to 150 polygons which represent all known individual rock types and orebodies. The magnetic response of the model was computed and the residual between the model and the observed response, measured by a low-level helicopter magnetic survey, revealed several anomalies unaccounted for by the model. Drill testing of these anomalies led to the discovery of several hitherto unknown massive sulphide occurrences. Surface gravity data of the mine and surrounding district were enhanced by applying digital terrain corrections. The corrected Bouguer anomaly revealed a hitherto unknown positive anomaly associated with the ore zones of the Renison mine. The gravity anomaly of the model was also computed. Unfortunately, the limited resolution of the observed data prevented the delineation of ore targets. The terrain-corrected Bouguer gravity data were also used to model the shape of the underlying non-magnetic Pine Hill Granite. A computer inversion method was implemented to build a 3D block model of the granite. Results agreed with previous conventional 3D modelling techniques but yielded improved resolution of the granite form. The project involved development of new computer software to build and edit the large and complex 3D geophysical model of the mine and to compute the model's magnetic and gravity responses. Software was also developed to build and compute the gravity response of a 3D block model of the underlying granite.

Jan 1, 1997

By D Van Doorselaere

The purpose of blasting during mining is to produce a muck pile that can be efficiently loaded and transported. There is an increasing awareness of the variation in muck pile characteristics and its economic implications. It is well known that good fragmentation by itself is not sufficient to optimise the muck loading efficiency. The swelling and configuration of the muck pile also significantly affect the productivity of the loading equipment. The characteristics of a muck pile depend upon the blast design parameters, explosive properties and rock mass geology. This study has focused on the dependence of muck pile configuration on blast design parameters, explosive properties and size distribution of the muck.The field work was done in two phases. In the first phase 12 blasts were monitored, while in the second, three blasts were monitored. The blast design parameters and explosive properties for each blast were documented and the following muck pile characteristics were measured:muck pile height and its distance from the facedistance of throwwidth of the power troughsize distribution by image analysis technique.The effects of burden, bench height, heave energy of explosive, row-to-row delay, powder factor and the mean particle size of the fragments on muck pile configuration were examined. It was observed that muck pile height and distance of throw are strongly influenced by the burden, bench height, heave energy of the explosive and the size distribution of the muck. The width of the power trough depends upon the row-to-row delay, powder factor and total burden. In addition, the effect of the fragment size distribution on the muck pile parameters has also been discussed.CITATION:Singh, S P and Van Doorselaere, D, 2015. The relationship between blasting parameters and muck pile configuration, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 369–374 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By R M. Tosdal

Intrusion related ore deposits are widespread in the Central Peruvian Cordillera Occidental and adjacent high-plains to the east and include porphyry Cu (-Au, Mo; eg Morococha), Cu-Zn (Pb-) skarn (eg Antamina), Pb-Zn-Ag carbonate hosted vein deposits (eg Uchucchacua), cordilleran base metal (eg Cerro de Pasco) and epithermal deposits (eg Quicay). Geochronology and petrochemistry of intrusive rocks associated with mineralisation reveals that: most ore deposits were emplaced in the late middle to early late Miocene; and are related to calc-alkaline granodioritic igneous rocks with Sm/Yb >3, Sr/Y >40 and Y/Th <1.5. The largest deposits, including Antamina, Colquijirca and Cerro de Pasco are associated with intrusions with Sm/Yb >4 and which, as indicated by Pb and Sr isotopic data, have undergone relatively moderate middle and upper crustal assimilation. The chemical signature of igneous rocks related to mineralisation likely reflects melt equilibration in the lower crust at a crustal thickness of more than 45 km. Mineralisation was favoured by a change from normal to flat subduction, resulting in increased compression, crustal thickening and subsequent cessation of the magmatic arc. Premiocene ore deposits do occur, but are restricted to a broad E-W corridor between Uchucchacua and Milpo and probably were controlled by a crustal-scale structural discontinuity across the strike of theAndes. Not all igneous rocks with high Sm/Yb and Sr/Y ratios did acquire their trace element signature in the lower crust. Petrographic and Pb isotopic evidence indicates shallow crustal hornblende fractionation or assimilation of pelitic material as possible causes for high trace element ratios in some rocks. These are apparently unrelated to polymetallic mineralisation. Thus, critical evaluation of petrographic and geochemical data in metallogenetic studies, especially in areas with complex basement architecture such as Central Peru is critical and should not be reduced to simple trace element ratios. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

This paper describes an investigation of the sampling problems which contributed to erroneous Concentrator production forecasts at the mining operation of Bougainville Copper Ltd (BCL) in the North Solomons province of Papua/New Guinea.Reference figures provided by independently verified commercial shipment data demonstrated the existence of a bias in the calculated Concentrator production; the challenge was to identify systematic errors in each of the contributory measurements (feed tonnage and feed, tailings and concentrate grades).The uncertainty surrounding specific sampling and measurement errors precluded optimum metallurgical control and performance of the milling circuit, encouraged disputes about the difference between Mine versus Concentrator production estimates, and cast some doubt on efforts to follow political guidelines concerning a maximum feed tonnage or recovery oriented mill operating concept.An evaluation of routine results as well as specifically targeted test work identified the sampling errors associated with measured individual parameters.The emphasis in this report is on the procedure for quantitative error assessments.The measured performance of a mineral dressing plant is subject to a systematic error balance which can be derived from the more familiar weight and metal balances such as the two- or three-product formula.The resulting equations are generally valid, and they are applied to the measurements obtained at BCL's Concentrator to illustrate the method.

Jan 1, 1976

By Baafi EY

Open cut mining in Australia is facing the greatest challenge in its history in attempting to compete not only with other operations internationally, but also with underground operations domestically. Most flat dip and shallow depth surface-mineable coal reserves have been depleted during the last two decades and new open cut operations must extract deeper coal deposits. As open cut coal mines move into deeper areas and the stripping ratios increase, the relative cost of overburden removal also increases. It therefore becomes even more important to design the mine around the optimum overburden removal scheme. The deeper mines are usually multi-seam operations with a more complex geology and with more geotechnical and hydrological problems. Deeper mines are subjected to greater problems requiring more detailed mine planning and design, such as selection of the optimum mining method and pit layout. In planning and design of such operations, the number of alternative methods which need to be considered is consequently greater.Dragline productivity and its stripping capabilities are directly affected by the selection of digging method, strip layout and pit geometry. Every mine has a unique combination of geological conditions. The operating methods that work well at one mine may not necessarily work at another site. Selection of an optimal stripping method, strip layout and pit geometry for a given dragline must be considered with respect to the geological conditions of the mine. With increasing geological complexity of Australian strip mines, it is becoming more important to use sophisticated techniques such as computerised mine planning methods to assist in optimising dragline operations.

Jan 1, 1998

By D B, M A. Sares, D W. Coulter, D C. Peters

This presentation discusses NASA-funded research on the ability of hyperspectral remote sensing to map diagnostic acid rock drainage (ARD) mineralogy that adversely affects water quality within watershed and to determine the relative contributions of natural ARD sources of metals and acidity to that drainage. Ground-based reflectance spectroscopy, combined with water chemistry, is used to identify mineralogical and chemical variations throughout a watershed. Integrated with hyperspectral data acquired from airborne remote sensing platforms, such as the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, a methodology has been developed that should improve environmental assessments and tracking of impacts on and from drainages. Phase I of this project focuses on a drainage basin (Lake Creek), tributary to the upper Arkansas River in central Colorado, which is impacted by natural acid rock drainage from areas of high-sulfide hydrothermal alteration. This project builds upon research and inventory efforts by the Colorado Geological Survey (CGS) to identify hydrothermal alteration that is the primary source or is contributing to acidic and toxic drainage in Colorado. This presentation will cover ground and airborne hyperspectral remote sensing techniques and results and water analyses for seasonal high-flow and low-flow conditions in Lake Creek. Identifying correlations between mineralogy, especially mineralogy that can be identified through airborne remote sensing, and water chemistry is a key focus of this project. Of particular interest are low-pH iron phases such as jarosite, ferrihydrite, schwertmannite, copiapite, and transitional amorphous phases as well as AlOH phases from higher, although still acidic, pH environments which are observed to mix with the iron precipitates within the streams draining from the hydrothermal systems. Drainage in the Lake Creek watershed derives from the Grizzly Peak caldera (Oligocene), which exhibits extensive hydrothermal alteration. Alteration types include silicic, quartz-sericite, quartz-sericite-pyrite, advanced argillic, and argillic. By understanding the chemistry of a naturally impacted drainage and its relationship to the surrounding geology, the project goal is to allow more efficient and complete identification of such sources in mineralised terranes through remote sensing technology.

Jan 1, 2003

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

By Parer W. R

During the last fifteen years there has been a marked change in the demand and supply patterns of coking coal. The world demand, predominantly Japan, has increased from 23 million tonnes of world export/import coal in 1960 to an expected total of at least 100 million tonnes by 1975. In the last ten years Australia has been the main beneficiary in the growth of the export coal trade. This has been brought about by its proximity to Japan and its large econ- omically mineable reserves of coking coal. A feature of the recent coal development in Australia has been the requirement of companies in new areas to provide massive capital for infrastructure costs. The ability of the Australian coal industry to retain a large share of the world export market depends to a large extent on reasonable costs to transport coal from mine to the market place. In some areas of Australia this means that railway lines, loading and unloading facilities, and ports will have to be up-dated at substantial costs. On the long haul to Europe the recent increases in the prices of bunker fuel have made the price of coal less competitive when compared with sources

Jan 1, 1974