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By M Hino, Y Sasaki

Sustainable handling of municipal waste and sewage sludge has an important goal to recycle resources without supply of harmful substances to humans or the environment. The gasification mechanism of phosphorus from municipal waste and sewage sludge during the incineration process has been investigated to develop a phosphorus recovery system. Quadrupole mass spectrometer coupled to an electric furnace is applied to study the vaporisation behaviour of phosphorous gas phases from municipal solid waste (MSW) incinerator ash of sludge during solid-state reduction by carbon. Measurements are carried out in vacuum conditions of 2 x 10-6 Torrs and furnace temperature range 573 - 1773 K, at a heating rate of 7.22 K/minute. It has been found that most of the phosphorus is vaporised as PO2, P2 and P4, in agreement with thermodynamic estimation despite a shift in the temperature regimes.

Jan 1, 2006

ALTHOUGH the mineral Stannite (Cu2S, FeS, SnS2 , also known as "bell 'metal" ore, tin pyrites, etc.) is found in various parts of the world, in only three iocalities has development proved it to exist in sufficient quantity to warrant the erection of treatment plants. Two of those mines are in New South Wales and one is an Tasmania. The writer will deal with the latter-the Conah mine, Zeehan, Tasmania, it being the most important and extensive occurrence so far worked. The Conah mine was first worked by a Tasmanian company for silver-Iead, and was fairly remunerative until the zone of secondary enrichment was passed through, when the lodes became too poor for further exploitation. During the time that the line was thus operated the stannite lode was discovered. It occurs in a graphitic slate, which, in common with the slates and spilites of the Zeehan field, is probably underlain by the stanniferous granite which outcrops two miles to the west. The Conah stannite lode is older than the galena lodes of the district, being faulted by one of the latter. Near the surface the lode was very rich.Shipments were sent out assaying 150 oz. of silver per ton, 20% copper, and 18% tin. An .apparently homogeneous sample of stannite, analyzed by the writer for the Tasmanian Geological survey, gave the following results:

Jan 1, 1915

This paper provides a brief fundamental insight regarding the fabric media concept for liquor filtration. The subject matter will be of interest to metallurgists and engineers with professional responsibility for world class design of solid liquid separation processes and efficient lowest cost operation of existing mineral process plant. Avocet Mining commissioned the worldÆs first mineral liquor clarification process incorporating a fabric media liquor filter at their Lanut gold mine in Sulawesi, in 2004 with design consulting provided by the Australian company SLS Technology Pty Ltd. Development of the technology continues with applied research focused on selecting textile parameters to apply filtration to a wider range of particle and contaminant types, higher solids concentrations, and different process liquors. Liquor filtration with the Fabric Media technology offers an array of attractive benefits. For Avocet Mining, filtration of pregnant liquor directly from the heap leach pad has enabled removal of the sediment pond and sand filters from the traditional process flow sheet, thus providing significant cost and installation time savings. Avocet Mining has recently expressed confidence in the technology indicating selection preference of the technology for the expansion at Lanut and for a new project. The application design window for the Fabric Media concept is extremely flexible with the technology now successfully applied to many different liquor chemistries and application objectives around the world. Potential cost savings for solid liquid separation process plant, such as counter current decantation circuits, clarifier vessels and thickener tanks can be calculated from laboratory measurements or pilot plant demonstrations.

Jan 1, 2008

AustraliaÆs record-breaking drought, efforts towards environmental best practice and the current commodities boom is demanding water use and reuse as never before. Mining practices, processing, the remote communities and support industries require vast amounts of specific quality water. Sustainability of water use has been a key factor in mine development, expansion of existing operations and increasing profitability of processes involving water. Developments in water treatment technology have enabled the use of a range of processes to produce this water reliably at ever decreasing costs. This increasing acceptance of new technologies has seen seawater desalination, recycling of plant wastewater streams, municipal wastewater reuse and others to become commonplace. Processes including seawater and groundwater reverse osmosis (RO), low pH RO, thermal desalination, high rate clarification, brine water treatment, ion exchange and other advanced treatment technologies are now used as part of mining operations. This paper surveys the trends in water treatment for the mining industry both in Australia and internationally with a review of technologies and case studies of operating plants. The key technologies are explained with an emphasis on the specific requirements for mining operations û unusual raw water, process and operations limitations, environmental concerns, as well as harsh climate. Case study information from several mining operations is included.

Jan 1, 2006

By D Alexander

For nearly 100 years, the flotation plant metallurgist has often wondered what is happening æbeneath the frothÆ. To assist in unravelling this mystery, new technology has been developed as part of the Australian Mineral Industries Research Association (AMIRA) P9 project, to measure gas dispersion characteristics (such as gas hold-up, superficial gas velocity and bubble size) in industrial flotation cells. These measurements have been conducted in a large number of cells of different types and sizes by researchers from the Julius Kruttschnitt Mineral Research Centre (JKMRC) and JKTech. A large database has been developed and the contents of this database are described in this paper. Typical cell characterisation measurements show a wide spread in values, even in the same cell types and sizes performing similar duties. In conventional flotation cells, the typical gas hold-up values range from 3 - 20 per cent, bubble sizes range between 1 and 2 mm, and superficial gas velocity ranges from 1 to 2.5 cm/s. The ranges of cell characterisation measurements given in this paper will enable plant personnel to compare their operation to other similar types of operations from around Australia and the rest of the world, giving opportunities for further improvement to flotation plant operations.

Jan 1, 2005

The Perth Mint receives gold and silver from various sources for evaluation and refining. The metals are received in many forms and vary widely in assay. Refining is carried out using the Miller Process and the and the resulting market quality bullion is sold in a range of weights and alloys to suit the international bullion market and public demand. INTRODUCTION The Perth Mint was established in the late nineties as a branch of the Royal Mint, London, to refine the gold from the newly established gold- fields in Western Australia. The branch was opened for business in June, 1899. After refining, the bulk of the gold was used in the manufacture of sovereigns and half-sovereigns. Nowadays, although most of the gold received comes from the W.A. goldfields, some gold is deposited by producers in other states and in Papua-New Guinea, as well as scrap and trade wastes from manufacturing jewellers and old jewellery from the general public. Silver is deposited in the form of old silverware, recoveries from-photographic processes etc. Gold or silver may be lodged at the Mint in person, through a bank or other agency or by registered post. Telegraphic advice is usually given when gold is sent by the latter, so that insurance may be effected.

Jan 1, 1982

By N Kusuma

Recoverable copper and gold estimates for resource models and ore control routing decisions at Batu Hijau were initially based on flotation testwork from several commercial laboratories. Due to the greater number of copper and gold assay grade available, regression relationships were developed between assay grades and flotation recoveries. Other recovery controlling variables such as oxidation and lithology were included to improve the regression models. With additional drilling, more flotation work was carried out and the regression models were revised to include the new flotation data, also alteration classification and in situ pH. The regression models were replaced in favour of spatially derived models for ore control and short range mine planning. To harness local variability in the block model, blast hole flotation testing is carried out in unison with routine grade assaying. Recovery data are processed (kriged) simultaneously with grade assay data prior to ore polygon delineation. Short range mine planning utilises this model in conjunction with a spatial recovery model derived from drill core flotation data. Long range mine planning utilises the æhybridÆ recovery model whereby the globally robust regression recovery models are overprinted by a spatial (kriged) recovery estimate where flotation data density is adequate (Phase II reserve).

Jan 1, 2002

By Burman B. C

This paper describes studies into two particular aspects of the Lochiel deposit which formed part of feasibility level geot2chnical and hydrogeological investigations for proposed open cut mine development. The two aspects were depressurisation of thick beds of silt located through the profile and the determination of characteristics and origins of soil structure and their effect on pit stability. The studies were very detailed and multi disciplinary and highlight the integration of geology, geotechnics, hydrogeology and mining that is required for mine development studies. It is considered that as more marginal deposits are developed throughout the world the demands for efficient economic mining together with in- creasing scales of operation will require simi- lar types of studies. As such the studies pre- sented herein are likely to be a forerunner to a,emerging trend for development of open pit mines in difficult ground and water conditions.

Jan 1, 1986

By A M. van Niekerk, W Mey

Coal mining has an impact on the water management of the water scarce Upper Olifants River Catchment. A prefeasibility study was carried out by Anglo Coal and Ingwe Collieries Limited to establish the water supply and demand in the catchment. A geohydrological model was used for the coalfields to determine the stored water and excess water available. Two distinct collective and treatment systems were proposed for the Witbank and Middelburg municipalities to treat excess water from the Anglo Coal and Ingwe Collieries Limited. The Emalahleni Water Reclamation Project for Witbank was initiated first. Water management and treatment experience gained at Anglo Coal was the cornerstone to develop the collection, treatment and distribution system. A full enquiry was issued to Keyplan, Veolia, Bateman Africa and IST Technik to construct, commission, operate and maintain a 20 ML/day desalination plant to treat acidic, saline mine waters to a South African National Standard (SANS) 0241 Class 0 potable water. After the technical and financial adjudication, Keyplan were awarded the contract. An integrated regulatory process was adopted through consultation with all the relevant regional and head office staff of the Department of Minerals and Energy, Department of Water Affairs and Forestry and the Mpumalanga Department of Land Affairs via an authorityÆs steering committee. A rock engineering evaluation was done to select both the plant and waste disposal sites as all possible sites are undermined. Various contracts are required with the individual mines for water supply, the Emalahleni Local Municipality for the delivery of potable water and for the disposal of wastes.

Jan 1, 2006

By Grobler H. P, Chitombo G. R

Production blasting of Dc Beers Consolidated Mines Limited, Koffiefontein and Finsch Mines involves both uphole trough rings of 9 to I I holes and near vertical 360 degree compound rings of 42-54 holes. The rate of production from these stages is dependent upon being able to achieve a specified fragmentation size range and this has driven the derivation of blasting practices to consistently achieve this target fragmentation. At the Dutoitspan Mine, in Kimberley, where mining of the kimberlite pipe is by block caving, 100 per cent extraction of the undercut level by ring blasting is essential. If this is not achieved, pillars are formed which not only inhibit the efficient initiation of the caving process, but also concentrates load onto the extraction level, causing damage to draw points and pillars. These two case studies demonstrate the importance of achieving optimum blasting performance for downstream mining efficiency; ie fragmentation for increased productivity at Koffiefontein Mine and 100 per cent undercut extraction for efficient initiation of the caving process at the Dutoitspan Mine. The case studies also serve to highlight the long road towards blast optimisation taken by De Beers Consolidated Mines Ltd (Koffiefontein. Finsch, Premier and Kimberley Mines) since 1989.

Jan 1, 1995

By Blattner P

The Late Miocene gold-silver bearing epithermal system at Waihi has some close similarities in its paleo-thermal and -geochemical structure with modern, volcanic-hosted geothermal systems such as Ohaaki-Broadlands. At Waihi an extensive braided quartz vein system is enveloped by hydrothermally altered andesites with minor tuff breccias and tuffs. A main stage of vein filling consists of multiple phases of chalcedonic quartz and fine to medium grained quartz, which are accompanied by pyrite, sphalerite, galena, chalcopyrite and acanthite below the base of oxidation. Platy calcite is present locally. Fluid inclusion studies indicate that the main stage quartz was deposited at temperatures of 189¦-273¦C from dilute (T¦ of -0.1 to -1.0¦C) fluids that were locally boiling. Homogenisation temperature Th versus T. data points lie within the field enveloped by dilution and boiling/gas loss paths determined for the Ohaaki geothermal field, and indicates that the parent hydrothermal fluid for the Waihi epithermal system had a similar composition to that at Ohaaki, ie 0.2 wt% equiv NaCI and 3.3 wt% equiv CO2. The hydrothermal alteration mineralogy and the isotopic composition of vein calcite indicate that the hydrothermal fluid contained relatively high concentrations of CO 2' as at Ohaaki. Oxygen isotope analyses of main stage quartz range from 6.1 to 11.6 %o and of vein calcite from 2.29 to 9.4% . Calculated d8Ow.½ values for the hydrothermal fluid that deposited the main stage quartz range from - 2.0 to -5.7%c , with a trend to less negative values with depth. They are similar to those in the deep chloride fluid in active geothermal systems with a substantial fluid throughput. A high fluid throughput at Waihi system is also evident from the extensive high intensity hydrothermal alteration and large volume of quartz deposited in the vein system.

Jan 1, 1995

A non-contacting under-belt capacitance and gamma-ray backscatter technique has been developed for the on-line measurement of moisture in coal. In this technique, moisture was correlated with radio frequency susceptance and conductance determined using an under-belt capacitance sensor in which a fringing electric field Interrogates a layer of coal on the conveyor belt directly above the sensor. To compensate for variations in the density and thickness of the coal layer, an under-belt gamma-ray backscatter gauge was used to measure an equivalent volume of coal.A plant trial of the technique was conducted at Stockton Borehole Colliery, SW Australia, where the gauges were installed on the coking coal product conveyor. Product moistures, in the range 7 - 14%, were determined with r.m.s errors of 0.50 and 0.25 wt% using on-belt and static off-belt gauges, respectively. The difference in the on-belt and off-belt gauge measurement accuracy was attributed to sampling errors in the calibration of the onbelt gauge.

Jan 1, 1989

Polarization phenomena associated with the use of an agitated bed of particles as an electrode for metal deposition were studied. The concentration polarization at this type of electrode is much smaller than that occurring at a fixed or moving electrode surface. Agitated particle electrodes can be used to electro-reduce copper from solutions over a wide range of concentration and at cur·rent densities up to 2000 AIsq. ft. of bed cross section.

Jan 1, 1971

By B L. Dickson, J H. Hodgkinson

The self-organising map (SOM) is an exploratory data mining technique that is both non-traditional and underutilised. Methodologies based on SOM tend to be data-driven and unsupervised, which makes them ideal to assist in the integrated analysis and interpretation of complex and disparate æmineral explorationÆ data sets. While traditional statistical multivariate approaches have difficulty with relationships that are non-linear and data distributions that are not normal, SOM-based data mining procedures are useful in these circumstances. In a SOM analysis each sample is treated as a vector in a data space defined by the variables; and measures of vector similarity, such as the dot-product or Euclidean distance, are used to order or segment a data set into naturally occurring populations. These groupings are positioned as nodes, or groups of nodes, on a 2D rectilinear representation of the multi-dimensional ædata spaceÆ, which is the æself organized mapÆ. While it is common not to include a sampleÆs locational information in the actual SOM analysis, such information can be used to display the spatial location of samples coded by their SOM node or cluster. If one finds there are coherent spatial patterns belonging to samples from particular nodes, or groups of nodes, then there is strong evidence that the technique is determining patterns and relationships within the data that have natural significance. Variations of the SOM technique may be used to perform broad categories of operations, including: 1. outlier identification û for samples belonging to various nodes or grouping of nodes; 2. function fitting, prediction, estimation or imputation û for calibrating relationships between variables and determining replacement values for missing, null or censored values; 3. clustering, pattern recognition or noise reduction û for determining the natural patterns within a data set; and 4. classification û for classifying samples into the clusters determined in three. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By R K. W Merkle, E Whiteman

The anorthosite complexes and related rock types of the Indian Precambrian shield are primarily associated with either cratons or mobile belts. They were metamorphosed under amphibolite to granulite facies conditions. The major rock types are chromite-bearing meta-anorthosites, amphibolites, basic granulites, pink granites and gneisses. This study was carried out on chromitite bearing samples from Sittampundi Anorthosite Complex (SAC), Tamil Nadu, to evaluate the nature and textural settings of platinum-group minerals (PGM), using state-of-the-art technology. The structure and petrology of SAC were well studied by earlier workers (Subramanian, 1956), but only scanty data on geochemical, petrology and mineralogy of PGM are available. The mineralogy of the samples is dominated by chromite (>70 mass per cent), plagioclase (An90) and chlorite-actinolite with orthopyroxene (En85). Details of the petrological evolution of the Sittampundi complex will still have to be studied further, but indications of magma replenishment at the level of chromite formation and the elevated PGE values associated with the chromitite samples make the Sittampundi complex a promising target for future exploration activity.

Jan 1, 2008

By F Pavloudakis

The installation of on-line analysis systems in the open-pit mines of the Public Power Corporation SA (PPC, the state-owned electricity entity of Greece) is considered to be the key-parameter for performing improved quality control and blending/homogenisation of the produced lignite. In order to investigate the accuracy of these systems under the site-specific conditions of the Greek lignite deposits, a research project was carried out. This was necessary since there is lack of experience in using on-line analysers in mines that produce a fuel of such a poor and largely fluctuating quality. After thorough market research, a dual energy gamma ray transmission on-line ash analyser was installed in Kardia mine of Ptolemais û Amynteon Lignite Centre, which is located in West Macedonia, Greece. The initial results obtained after the realisation of a series of dual-comparison trials (ie using two series of reference values that allow three-way comparisons) pointed out several problems that obstacle the achievement of high accuracy on-line measurements. More specifically, the measurements obtained by the analyser were higher than the concentrations determined by the two laboratories when the ash content was lower than 12 per cent (in wet basis). On the contrary, when the ash content was higher than 12 per cent, the measurements of the on-line analyser were lower than the concentrations determined by the laboratories. In other words, the range of the measurements obtained by the analyser was narrower than that corresponding to the lab analyses results. Therefore, the use of this on-line analysis system under the site-specific operating conditions of Kardia mine does not guarantee improved quality control of the lignite fed to the mine-mouth located power plant. Most probable reasons that explain the above-mentioned problems are the following: The frequent and widely ranging fluctuations of the chemical and mineralogical composition of the lignite transported by the conveyor belt, especially as far as its calcium content is concerned. This result from the nature and the origin of the mineral matter co-excavated with the lignite, which varies from calcareous marls to sands and clays rich in aluminium and silica minerals. The fluctuations of the lignite quantity transported by the conveyor belt. The change of the linear concentration of iron contained in the fabric of different belt parts.

Jan 1, 2003

By M N. Ingham

X-ray fluorescence (XRF) spectrometry has always been considered to be a comparative method of analysis. Reference materials are required to calibrate the analytical system. This paper describes the use of a set of æsyntheticÆ oxide standards, made from commercially available high purity compounds, to calibrate a spectrometer for 21 major and minor oxides. The spectrometer software uses simple methods of background correction, and a fundamental parameter method of matrix correction. Sample preparation is by fusion in 66 per cent lithium tetraborate, 34 per cent lithium metaborate. The use of synthetic standards, made from traceable compounds, brings XRF significantly closer to being a primary rather than a comparative method. Reference materials were used to validate the method described and examples of accuracy for major constituents are given using ores and other minerals. This method has successfully been used to analyse a wide variety of minerals and ores, as validation data shows. A titanium process example clearly shows the benefits of highest accuracy analysis.

Jan 1, 2008

Wheal Gawler was Australia's first metal mine. This leader was followed by an army of other metalliferous underground mines and surface operations in Australia. As a mine it was not highly significant economically because its small total production of nearly pure galena had low multiplier effects on the economy of South Aus- tralia. Its importance lay in its symbolism: here was a silver-lead mine close to the new town of Adelaide posing the question of what other min- erals lay in the Mount Lofty ranges and in the fields beyond.

Jan 1, 1987

By McKendry J. B

Gretley Colliery is situated at Wallsend, a suburb of Newcastle in New South Wales and is owned and operated by the Newcastle Wallsend Coal Ccnpany, a wholly owned subsidiary of Peko Wallsend Limited. The mine has been an efficient bord and pillar producer by industry standards. However, its continued economic viability was threatened because the bulk of remaining reserves lie in more difficult mining conditions and are of poorer quality. Alternatives were examined to improve productivity and allow Gretley to become more competitive in the current difficult market Environment.

Jan 1, 1988

By Ryan CG, Both RA, Mernagh TP, Large RR, Hunns SR, Gemmell JB

The Hellyer and Mt. Chalmers deposits are mound-style volcanic-hosted massive sulphide (VHMS) deposits in Australia. Textural, petrographic and microthermometric investigations of fluid inclusions in the Hellyer stringer system indicate that Type I, primary, liquid-vapour inclusions are 10-15 pm in size, and yield homogenisation temperatures of 170-220¦C in early 2A veins, 165-322¦C in main-stage 2B veins and 190-256¦C in late-stage 2C veins. These data suggest a waxing and waning thermal history. However, the average salinity remained between 8-11 NaCl equiv. wt % in all Stage 2 veins. At Mt. Chalmers, Type I inclusions up to 20 ¦m are found in quartz from the mineralised zone, and these inclusions yielded homogenisation temperatures of 160-268¦C and salinities of 5-8 NaCl equiv. wt %. Laser Raman spectroscopic (LRS) analysis indicates the presence of CO2 (

Jan 1, 1995