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By A Holmgren, W Forsling

In the present study infrared attenuated total reflection (IR-ATR) was used to monitor the rate of in situ adsorption of heptyl xanthate on a layer of zinc sulfide synthesised on a germanium ATR crystal. The zinc sulfide surface was characterised using x-ray photoelectron spectroscopy (XPS). The absorbance of heptyl xanthate measured increased with increasing bulk concentration of the adsorbate up to an equilibrium plateau value corresponding to a fractional coverage of the surface sites of the substrate. For the adsorption from solutions of concentrations between 10-3 and 10-5 M, the rate of adsorption increased with increasing bulk concentration. At higher concentrations the measured absorbance should be corrected for the absorbance due to the concentration of xanthate in bulk solution. The present work provides a discussion of this correction. Assuming the adsorption stage to be rate-controlling and proportional both to the concentration of the adsorbing species in solution and unreacted surface area, a rate law governing this type of transient adsorption kinetics was derived. By means of absorbance data for the concentrations 0.1 and 0.01 mM, the rate constant of adsorption was calculated. From the initial part of a Langmuir adsorption isotherm, the absorbance at monolayer coverage and the equilibrium constant of adsorption could be estimated.

Jan 1, 2005

Average annual growth in consumption of primary energy in Australia over the past 10 years has been 5·5 per cent compared to a world average of 4·1 per cent.Over the next 10 years growth rate is expected to increase to 6 per cent per annum due largely to the rapid development in the mineral processing industry.By the end of the 19705 natural gas is expected to supply more than 9 per cent of Australia's primary energy market. Coal will supply 40 per cent and petroleum products 47 per cent. Nuclear energy will make its appearance but will make only a small contribution in the period.Australia has adequate reserves of natural gas and coal to supply its needs in the 1970s and beyond. However the newly developed reserves of crude oil, while supplying 60-70 per cent of requirements in the initialyears, will need regular and sizable additions if they are to keep pace with the expanding consumption. For Australia to become self sufficient in the period 1970-1990 it is estimated that new discoveries will need to approximate ten times the volume of recoverable reserves found in Australia to date.

Jan 1, 1971

By Kennewell G. J

This paper aims to present the evolution of the mining method in the Prince Lyell orebody. Initial strategy and practical experience are detailed as are the reasons for and benefits of changes to the method since 1972 when underground mining began. This section of the paper starts with ten series and concludes with 40 series which was completed in 1989/90.In addition, to update the series of papers written by various authors over the past ten years on Mount Lyell, a review of the experience in the current 50 series lift of mining will be given. As well, the basic planning guidelines are discussed for 60 series - the final lift of the Prince Lyell orebody.

Jan 1, 1992

By J E. Powalisz

"The application of automated sampling techniques can help to provide a representative sample of process fluids and slurries that provide data for controlling process, custody transfer and quality assurance and quality control purposes.The automation of sampling provides a more consistent and reliable sampling process and eliminates many of the human-induced errors. Automated sampling can also provide a higher degree of safety in the plant/processing environment as well as better bottom-line results.Automated, fixed volume samplers can provide a very representative sample by integrating many small ‘grabs’ of sample from a process. Automated samplers can be controlled in a variety of ways to optimise the sampling process, including:cycle ratedwell timetotal volume.Properly selected and applied, an automated sampler can effectively isolate the operator from the process fluid during sampling and, to a great degree, during sample container collection.A variety of materials of construction, including seals, are available to handle demanding mining applications. Alloy 625, alloy 2205, AL6XN® and even certain plastics are used successfully in mining slurry applications.This paper explores the application of automated, fixed volume, batch style samplers in copper/nickel and gold processing, specifically pregnant leach solution and extraction fluids.Several specific field applications are discussed, including process installation details, hardware and operation.CITATION:Powalisz, J E, 2014. The application of automated samplers in copper/nickel processing, in Proceedings Sampling 2014, pp 35–42 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 29, 2014

The selection and implementation of the right technology for a project is critical to the future development of the resource industry. It is essential for companies to ensure ongoing competitive viability that where practical new or alternative technology be adopted. Analysis of historical data relating to development of resource-based process plants provides an enlightening insight into the key factors which influence their success or failure. The adoption of new technology does not guarantee the success of a project. The outcomes of this analysis have been used to develop some general guidelines and principles the author believes are useful in the selection and implementation of new or alternative technology in resource projects. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

By Van Weert G

Ferrous chloride solution pyrohydrolysis is a successful IICI regeneration process which is carried out in either a spray roaster or a fluid bed. Pyrohydrolysis is not restricted to ferrous chloride only, every metal chloride can theoretically be hydrolysed. In practice, however, the conditions for ferrous chloride pyrohydrolysis differ from those of many non-ferrous metal chlorides eg zinc, lead and cadmium. Hence, a pyrohydrolyser could function as a ferrous/non-ferrous separator, eg an iron oxide and zinc chloride separator. Most pyrohydrolysers operate on solutions, in which case more than 50 per cent of the process energy is needed for heating and evaporating water. However, this disadvantage would be diminished by feeding a slurry to the reactor. Against this background it was decided to investigate the chloridisation of zinc ferrite which is an iron bearing solid with a non-ferrous impurity, and subject to processing and disposal problems. Synthetic zinc ferrite was chloridised in a tube furnace. The gas atmosphere in the tube furnace resembled that of a fluid bed pyrohydrolyser and consisted of HCI, 1120 and nitrogen. Gas composition, temperature, residence time and sample mass were varied. The experiments showed that complete (99.6 per cent) zinc extraction from synthetic zinc ferrite was possible in a simplified pyrohydrolyser atmosphere at 1100 K in four hours. The zinc ferrite was converted into gaseous zinc chloride, and hematite and magnetite solids. It was also found that zinc removal from the zinc ferrite lattice caused not only rccrystallisation of the zinc ferrite into hematite, but also hematite crystal

Jan 1, 1993

The need to solve the problems associated with spontaneous combustion, system of ventil- ation and methane drainage in gassy coal mines has brought about the development of mining and degassing methods which has made possible up to 80% gas recovery in retreating longwalls. Beneficial results also were obtained mostly in the double or multiple-entry systems, but for single-entry systems and for a seam thickness exceeding 3 m, gas recovery rate is still very low. With some single-heading systems, such as those where a return roadway is not maintained in the goaf behind the face line, a new methane drainage technology is practiced. Attempts were made to extract methane from roof holes drilled from offsets in the ribside of the longwall block. The inclinations and lengths of the boreholes were planned and designed on the basis of the geological and mining condit- ions encountered at the time and every second hole was terminated precisely at the point where the previous hole intersected the immed- iate roof goaf area above the face. There are mathematical relations approp- riate to the design of the above drainage systems to give optimum methane recovery under the given conditions. Some examples of drainage have reached 87% recovery and have attained 94% CH4 purity.

Jan 1, 1982

For too long we, as an industry, have borne the brunt of irrational claims, poor science and even worse, journalism with regards to our affect on the environment. To some of us, the overwhelming media attention on greenhouse warming, the polluting outputs of mineral processing or unthinkable depletion of natural resources has left us embarrassed and more unfortunately has turned bright young people away from a career in the minerals industry.This paper shows the hypocrisy associated with an element of the green movement and dispels some general myths on mining disseminated by radical environmentalists.The fallacy of the greenhouse warming effect will be scrutinised by common sense and the mining industryÆs use of land will be discussed and put in proper perspective.Problems associated with safety and emissions and the means to overcome such are discussed briefly.

Jan 1, 2004

By Brinkmann J. R

The relative effects of the two basic mechanisms contributing to rock breakage during blasting, shock and gas penetration, are neither well understood nor well characterized, and need further clarification. Blasthole liner (BHL) tests separate the two effects, and by enabling direct measurement of borehole expansion give insight into the shock/gas energy partitioning in rock confinement. The hydrodynamic code DYNA2D is used to simulate the shock effect of the detonation of emulsion in a stainless steel lined hole, and the predicted expansion is compared with experiment. Workers in the past have neglected near-blasthole phenomena and have calibrated models based on stress measurements remote from the blasthole. Extrapolation back to the blasthole has inherent limitations, and indeed, one of the deficiencies of these models is that they have not been able to predict correct borehole expansions, as observed in BHL experiments. DYNA2D has been enhanced by the ICI group with a detonation model which resolves the explosive reaction zone. As a preliminary step towards the ultimate goal of devising a practical damage model, simulations are used to predict the maximum expansion that would take place if the rock were to remain undamaged. Various material parameters are investigated and it is shown that calculated liner expansions are appreciably lower than measured values for high rock yield strengths, while greater than values for low yield strengths.

Jan 1, 1990

By S Mundell, A Atkins, S van de Water

Geoscientific information management enables the capture, management and delivery of the original geoscientific observations and measurements of the earth’s natural resources. However, original observations and measurements are worth nothing if the quality and integrity of the data can’t be guaranteed. Geoscientific information is one of the fundamental assets enabling miners to make confident and accurate business decisions, whether that is defining a resource model, performing reconciliation, delivering ore reserve reports or meeting environmental compliance requirements. Without access to reliable, validated or verified data it increases the risk of miners using incorrect information for reporting and compliance. Industry codes, such as JORC, or government regulations, such as environmental compliance requirements, must be adhered to and companies should be able to confidently report to these standards. Without having a robust information management framework in place, it becomes a challenge to make trustworthy decisions, report confidently and reduce the risk of non-compliance. As a key initiative, good data governance should form one part of a miner’s information management strategy. Within the mining industry it is common for companies to only consider technology tools as the key focus for compliance whereas a mature information management focus will additionally consider people and process. All three pillars are critical for a miner to have confidence in their data driven decisions. This paper discusses an industry framework for best-practice geoscientific information management based on the observations gathered from analysing data management practices within the mining industry. It focuses on how the three pillars of people, process and technology are crucial elements to improve operational decisions and ensure companies are compliant.

Nov 8, 2021

By S van der Sluijs, M van Ende, Y Tang, A Emami

This paper presents a phenomena-based model for investigating the possibility of scrap melting in an Open Slag Bath Furnace (OSBF) for green ironmaking. The goal of this study is to enhance the circularity of the steelmaking process by utilising scrap as a green source of iron in OSBFs. The model takes into account the fundamental differences between OSBFs and traditional processes such as Electric Arc Furnaces (EAFs) and Basic Oxygen Furnaces (BOFs). The model considers three primary regions where scrap heating and melting occur: the solid feed pile, slag and hot metal. It accounts for factors such as the furnace geometry, scrap charging mechanism and specific heat and mass transfer properties of the reactor. The model was validated using literature data and was used to investigate the heating and melting behaviour of individual scrap particles under various process parameters. The study finds that the scrap melting process in OSBFs involves three stages: shell formation, shell remelting and subsequent melting of the parent scrap. The carbon content of the scrap and the liquid hot metal plays a critical role in determining the melting behaviour. Depending on the carbon concentration and temperature, the melting process can be heat transfer controlled or mass transfer controlled. The paper also examines the scrap feeding methods in OSBFs, including direct charging into the slag or charging through a feed pile. The model provides insights into the melting rate of scrap compared to Direct Reduced Iron (DRI) in OSBFs and highlights the role of carbon in this process. Overall, this phenomena-based model contributes to the understanding of scrap melting behaviour in OSBFs and provides valuable insights for optimising the circularity and efficiency of green ironmaking processes. The findings of this study can inform the design and operation of OSBFs, paving the way for increased utilisation of scrap as a sustainable feedstock in the steel industry.

Jun 19, 2024

According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980

By D Cumming-Potvin

Incidents that trap miners in underground mines have serious consequences for the miners and the mine operators involved. It is of utmost importance that mine operators utilise all available tools when trying to locate and rescue trapped miners. From testing conducted at underground hard rock mines, Cumming-Potvin et al (2013) found that pre-existing microseismic monitoring systems, which are routinely used for seismic risk management, have the potential to be used for detecting and locating trapped miners.This paper reflects on the Anzac Day seismic event that trapped two miners at Tasmania Mine, Beaconsfield, on 25 April 2006. The Anzac Day event occurred at 2123 on a Tuesday evening. Rescuers were unable to confirm that the trapped miners had survived until 1930 on Sunday evening. It is not possible to speculate on how the rescue operation may have been different had the technology to use the microseismic monitoring system for the purpose of detecting the trapped miners been available. However, it almost certainly would have been different. The recent research project has demonstrated that knowing the fate of the Beaconsfield miners might have been achievable up to 100 hours earlier than was the case in 2006. That knowledge would have been invaluable to the rescue effort.By examining the seismic array at the Tasmania Mine, the reliability of detection over the working levels of the mine could be quantified. Had the methodology been available, adding six additional sensors (at a cost of $40 000), would have been sufficient to increase the likelihood of detection to greater than 90 per cent in the working levels of the mine. This was true both at the time of closure of the mine in 2012, and just prior to the Anzac day event.CITATION:Cumming-Potvin, D and Hills, P B, 2014. Use of a pre-existing microseismic monitoring system to detect trapped miners (with reflections on Beaconsfield 2006), in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 143–150 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By Quast K. B

Laboratory batch rod and ball milling tests were conducted on samples of Heavy Medium Separator (HMS) sinks from Renison Tin Limited. The product size distributions for this heterogeneous material were very different to similarly sized homogenous material previously reported by the authors. The effects of pulp density on product size distributions were only evident at pulp densities greater than 80 per cent solids. At high solids density, the major weight distribution product peak fell and broadened indicating less efficient breakage, particularly for rod milling. Tin distribution in the ground products was also affected by pUlp density, and there was always less cumulative per cent tin than cumulative per cent weight, ie there was no tendency for cassiterite to slime down to 10/lm.

Jan 1, 1995

By Lee Y. K, Walker G. S, Bronswijk V. W

The effect of leaching three samples of Mt Weld ore with a-hydroxysulphonic acid [(CH3)2(COH)SO3H] was assessed. Apatite present in the samples was found to be readily soluble but calcination up to 600¦C was required to increase the solubility of crandallite. Increasing the calcination temperature increased dissolution of both phosphate and alumuuum. The optimum SO2 content in solution for the dissolution of crandallite ores was found to be lower than for apatite.

Jan 1, 1991

By Mosusu N

Geothermal anomalies of different types occur within distinct geological/structural settings in Papua New Guinea. According to R.F. Herring, geothermal occurrences in Papua New Guinea can be classified into two types, those related to vulcanism (Lihir, Rabaul and other series of islands along the volcanic arc) and those resulting from a regional heat flow probably caused by radiogenic sources, for instance those in the Wau/Bulolo area. The manifestation of this potential source of energy generally coincides with either converging or diverging tectonic plate boundaries. Previous inventories on thermal waters were carried out by vulcanologists from the Rabaul Observatory in the early 1960s. However, these studies rarely included chemical analyses of water and gas emissions and the investigations were carried out in an ad hoc manner, generally as a secondary activity. The most recent investigation on thermal waters was conducted on Lihir Island in connection with the development of the open pit gold mine. These studies included detailed exploratory drilling to a maximum depth of 730 m, and a water chemistry isotopic sampling and analysis programme. The hydrothermal waters were not considered as an energy source but as a hazard during the development stage of the mine. Nevertheless, the geothermal anomaly observed at Lihir includes hot springs emerging along the coastal zones with temperatures that approach 100¦C, steam, and thermal borehole waters with temperatures that exceed 200¦C. Chemical analysis results of thermal fluids from Rabaul, Talasea and other areas in Papua New Guinea generally show high total dissolved solids and low pH. In contrast, recent results from the deepest and hottest thermal source at Lihir shows a neutral pH, a Na-CI-SO4 composition and temperatures above 200¦C. Despite the concentration of chloride being similar to that of sea water, other chemical results and stable hydrogen and oxygen isotopic compositions of thermal fluids imply the source to be mixture of local meteoric water and deep thermal water rather than sea water. Results of geothermal modelling suggests that the total geothermal uptlow is equivalent to 54 MW.

Jan 1, 1997

By Virtanen M

Grinding has been one of the areas of major development at Outokumpu's concentrators. During its early years the company used entirely rod and hall mills, but due to the high costs of metallic grinding it began the testing of autogenous grinding as early as the 1950s. In the late-1970s, the company's own modification for two stage autogenous grinding was ready for industrial use. Surprisingly late, in the 80s - 90s, an interest rose to check also the effects of grinding methods on flotation results. This paper firstly gives a short history of the development work of Outokumpu type autogenous grinding, called 'Outogenius'. The effects of some grinding methods on the process results of two nickel ores are then reviewed. The tests to date show notable effects of grinding methods on flotation.

Jan 1, 1996

By J Carrillo, A King

Gravity recoverable gold (GRG) is largely distinguished from other gold by its non-mineralised, metallic form, its high degree of liberation from the ore and its appreciable particle size. The gold mining industry has so widely accepted the use of batch centrifugal concentrators (BCC) and intensive cyanidation (IC) systems for the recovery of GRG that these may well be considered requirements of any plant processing ore containing appreciable GRG. The recovery of gold by gravity is quick, easy and cheap by comparison to alternatives. However, there are cases where attributes of the ore make recovery of gold by gravity and IC unusually challenging. This paper describes three examples where such challenges have been encountered and met, including those where the ore contains cyanide soluble base metals and where fine GRG is to be recovered from flotation concentrate.CITATION:King, A and Carrillo, J, 2018. Addressing challenging applications of intensive cyanidation in gravity gold recovery, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 283–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Y-B Kang, W-Y Cha, Y-M Cho

Molten slag used in the secondary refining process (RH process) for the production of Ultra-Low C (ULC) steel is typically composed of CaO-Al2O3-MgOsat.-FetO with minor constituents. FetO in the RH slag is the main source of reoxidation of the molten ULC steel in the ladle by 2Al + 3(FetO) = (Al2O3) + 3Fe, thereby serving as the source of the alumina inclusions. On the other hand, FetO also enhances the fluidity of the slag, thereby increasing inclusion absorption capacity. Optimum slag chemistry design is therefore required to produce clear ULC steel. The reoxidation kinetics was investigated in the present study by employing high-temperature experiments and developing the reaction rate model. Initial compositions of slag ((% CaO)0/(% Al2O3)0 and (% FetO)0)) and reaction temperature were varied and change of [% Al] in the molten steel was measured. The rate-controlling step was analysed. It was found that the rate-controlling step in some cases changed during the reoxidation: from a mass transport of Al in the molten steel to a mixed transport including Al2O3 in the molten slag. The experimental data validated the reaction rate model based on the elucidated reaction mechanism and FactSage thermodynamic database. The model suggested that high (% CaO)0/(% Al2O3)0 suppresses the reoxidation only when (% FetO)0 is low (5 or lower in the present study).

Jun 19, 2024

By Enga B. E

Following considerable laboratory studies concerning diesel particulate control systems for underground use, a Canadian program was initiated to implement practical, real-life systems. This program covers the application in seven mines throughout Canada, of a particulate control system, to 14 engine models from four engine manufacturers in 18 different vehicle types, for a total of 23 vehicles. Partially funded by the Canadian National Research Council (NRC), this program required detailed analysis of operating cycles, maintenance variabilities and installation problems. This paper summarizes the work carried out to date to define real-world targets and the success achieved so far in attaining practical underground particulate control.

Jan 1, 1988