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By R. S. Celmer

The distributions of cobalt, molybdenum, copper, and selenium between nickel matte and silica-saturated iron silicate slag have been determined in the region of the metallic saturation boundary, at 1523 K. Results are given as a function of the composition of the coexisting Fe-Ni alloy and the activity of iron in the system. Under strongly reducing conditions, these minor elements display a marked preferential accumulation in the sulphide phase. It is shown that the dissolution of cobalt and molybdenum in slag follows an oxidative mechanism, and distribution equilibria are correlated with the oxygen potential. From these data, the thermodynamic properties of cobalt in nickel matte are computed. Further, comparisons of minor element partitions are made between the nickel and copper matte smelting cases under metal saturation conditions.

Jan 1, 1988

By Xuewei Lv

An intelligent recognition and quantification system for the micrographs iron ore sinter was developed in the current paper. The average distribution parameters in a gray histogram of minerals by a Gaussian gray distribution model were obtained. The feature curves of the gray histogram of two minerals were achieved by combining the two density functions. The feature indexes, such as the number and position of the peaks and the valleys of two minerals in different ratios, were quantified by differentiating the distribution functions. This algorithm is able to extract the feature of the minerals adequately and accurately for recognizing the composition and phases of the minerals intelligently.

Jan 1, 2009

By Hao Rang

The article Is specially to Introduce the recovery process of Nb, Mn, P from slags and reutilization techniques of the remaining slags. Nb-Mn-Fe alloys which contain 14-16% Nb, 40-60% Mn can be obtained after using fire refining process of " Blast Furnace-Revolving Furnace-Electric Furnace -Electric Furnace, "meanwhile, phosphorous slags which the content of phosphorus pentoxide Is 29.21%. Further going through wet metallurgical processing and electrowinning technics to recover grading 99°o metallic manganese. Finally, phosphorous slags are grinded finely to be as phosporous fertilizers to be directly used for farmlands. Small particle size (0-8mm) rich slags are mixed with slight solid additions for balling directly, and taken Into blast furnace with blocky slags all together. The remaining tall slags are fully used as constructional materials, slags cement as well as a serial of wall materials, road materials, ground ornamental materials without burning operation and steam curing. The compressive strength range of those materials is up to 15-30 MPa. There is no more solid waste slags effluent In the full technical process.

Jan 1, 1994

By M. G. Basavaraj, S. Sarkar, G. S. Gupta, P. D. Patil

"Previous experimental study on raceway size hysteresis on two-dimensional cold model showed that the inter-particle and wall-particle friction had a very large effect on the raceway size. Existing literature correlations for raceway size ignore the frictional effects. It has also been shown in the present study that their applicability to the ironmaking blast furnace is questionable. To take into account the effect of friction on the raceway size a stress analysis has been done for the raceway region. Two-dimensional fluid flow equations under turbulent conditions have been developed and solved computationally in order to get the pressure forces. The frictional forces were obtained in terms of stresses. To predict the raceway size a force balance was done for the raceway zone considering the pressure force, the frictional force and the bed weight. The resulting equations from the force balance are able to describe the raceway hysteresis phenomena reasonably well along with the raceway size. A two dimensional experimental set up has been fabricated in order to validate the computer predictions. Predicted values agree well with the experimental values.IntroductionWhen a high velocity blast of air is introduced into a packed bed through a tuyere, a cavity is formed in front of the tuyere. This cavity, formed in the iron-making blast furnace, is called the raceway. Coke tumbles down and bums in this raceway, generating heat and reducing gases for the iron-making process. The raceway is responsible for producing most of the reducing gasses in the blast furnace. In addition, the size and shape of the raceway determines the movement of solids within the blast furnace, the distribution of gases and liquids (slag and metal), setting the location where the primary chemical reactions occur and the temperature profile in the lower part of the blast furnace.Due to the importance of the raceway, many investigators l - 6 have studied it and have predicted the raceway size using the empirical correlations based on experimental (hot & cold) and mathematical models. A number of correlations have been reported in the literature to predict the raceway size by various investigators3 - 6 which are different to each other. Each of the correlations shows a different dependence of raceway diameter (DR) on bed height, particle size, solid density, bed voidage and blast velocity. None of the correlations includes the effect of solid stresses on the raceway size and shape. The magnitude of these stresses will depend on the bulk solids properties (internal angle of friction, wall angle of friction) and the bed dimensions."

Jan 1, 2001

By Jose Antonio Silva Souza, Emanuel Negrao Macedo, Iara Ferreira Santos, Otacilio Dias, Luis C. A. Venancio

"The Bayer process alumina production generates 0.7 to 2.0 ton of bauxite residue (BR) and an average of 1.0 ton of C02 per ton of alumina produced. The direct reaction of exhaust gases to reduce the alkalinity of the BR may allow a triple gain: improve the storage conditions, open a range of new applications for BR and sequester from 16 to 102 kg of C02 per ton of alumina. This paper shows the measurement of C02 captured during a pilot scale reaction of a suspension of BR in water with flue gas, produced from direct oil burning. Three different types of reactors were used: one spray tower and two packed columns. The inlet and exhaust gases were analyzed using electrochemical and non dispersive infrared sensors. The pH of the suspension was monitored during and after the reaction to evaluate the buffer effect.IntroductionAlumina is mainly produced from refining bauxite using the Bayer process. This process consists of extracting the aluminum oxide through its dissolution in caustic soda and the separation of insoluble residues. The remaining bauxite residue (BR) although not particularly toxic, poses risks to the environment due to the large volume and its reactivity. According to the latest technology it is stacked on sealed deposits specially constructed. To date the vast majority of the bauxite residue that has been produced was stored and were not incorporated into any existing production processes to significant amount with exception to some extent of the sintering process residue at Russia and China [l]. On the other hand, a strategic goal was set in 2010 by the Bauxite and Alumina Committee of the International Aluminium Institute (formed by the majority of the industries) to reuse 20% of BR in 2025 [2]. China has established the same objective for 2015[1].This paper is a sequel of two others presented at TMS 2010/2012 [3-4] and describes:• A pilot plant assembled for testing the carbonation process of BR with gaseous effluents similar of the refining process.• The methodology used to measure the amount of C02 captured during the carbonation process.• The results of the carbonation process, the C02 capture and the buffering effect of the pH.This process is studied in order to consume minimal power and use the effluent as efficiently as possible in different reactors from low cost to ultra high performance. The process is designed for minimizing the power consumption and equipment investment."

Jan 1, 2013

By M. Bhattacharya, A. Dutta, P. Barat

"Pinning of dislocations at nanosized obstacles like precipitates, voids and bubbles, is a crucial mechanism in the context of phenomena like hardening and creep. The interaction between such an obstacle and a dislocation is often explored at fundamental level by means of analytical tools, atomistic simulations and finite element methods. Nevertheless, such studies fail to predict the effect on the overall plasticity on account of insufficient information about the underlying statistics of this process comprising a large number of dislocations and obstacles in a system. Here we propose a new statistical approach, where the statistics of pinning at idealized spherical obstacles is explored by taking into account the generalized size distribution of the obstacle along with the dislocation density within a three-dimensional framework. The application of this approach has been demonstrated for dislocation pinning at nanovoids in neutron irradiated type 316-stainless steel.IntroductionPresence of nanoscale obstacles like precipitates, voids and bubbles play a crucial role in determining the deformation behavior of a crystalline solid on account of the interactions between the line defects and such localized obstacles. In the context of the glide motion of dislocations, the obstacles can offer resistance to a moving dislocation, thereby causing a hardening effect [l-3]. In some other cases, inclusions like voids and bubbles can affect the rate of dislocation climb through diffusive [4] and non-diffusive [5] mechanisms. Over the last few decades, numerous studies have been performed to gain an insight of the dislocation-obstacle interactions at a fundamental level. These include the interactions responsible for the hardening effect, in addition to those pertaining to the non-conservative motion of dislocations.Although the elementary mechanisms of the various dislocation-obstacle interactions have been vastly explored and understood by means of analytical theory and numerical simulations, it remains difficult to quantitatively understand their effects on the macroscopic deformation behavior. This is due to the fact that their influence on the gross plastic deformation of a bulk sample would be the collective outcome of a large ensemble of such interactions. As a result, it becomes infeasible to predict the bulk deformation behavior of a material until the statistics of pinning of the dislocations at the localized obstacles is available. In the context of precipitate hardening, some well known attempts to extract the pinning-statistics were made by Friedel-Fleischer [6] and Mott [7] by analytical means, which were later tested through simplified 2-dimensional in-silica modeling [8]."

Jan 1, 2014

By Carla Lupi, Mauro Pasquali

"Photographic technology is based on light sensitivity of silver halides that, because of silver properties, are capable of forming photographic images. Photographic laboratories and hospital departments because of digital photographic systems less use this technology today. Nevertheless recovery of silver is still advantageous because environmental problems related to Ag ions danger to biological system. Many processes have been studied to treat silver containing photographic bath: cementation, chemical precipitation and electrowinning. In this work, after preliminary voltammetric tests, a batch electrometallurgical process has been studied to completely deplete the silver containing photographic fixing baths. The effect, of silver concentration in the electrolyte, varying over the range 0,2-1 g/L, bath stirring and current density ranging from 10 to 500 A/m2 on process yield and deposit quality, has been investigated. Introduction Photographic wastes, electronic scrap and spent catalysts constitute the main sources of materials for silver recycling. Among those silver secondary sources, the photographic discharged material could be still important and useful, even if photographic laboratories and hospital departments, because of digital photographic systems, less use photographic technology. Several processes have been developped in order to recover silver used in the field of photography from both photographic solutions and scrap film paper[1-5]. Fixing solutions are very complex baths but, because of silver position in the electromotive series, electrolysis could represent an advantageous method for silver recovery. Electrolysis produces high purity silver without generating new pollutants, while the fixer can be reused: obviously it is necessary to purge off a portion of this solution in order to avoid the excessive build up of other deleterious compounds into solution. A tested recovery method was constituted by the dissolution of silver from X-ray films with concentrated nitric acid. Internal electrolysis and external electrolysis methods were carried out using a steel electrode as cathode and a copper electrode as anode [6]. Silver recovery from photographic chemical solutions has been also performed in a special cell [7]: the solution is supplied to the bottom of a non-agitated cell having a vertically elongated form and including a central anode enclosed by a cathode. An other study discloses the use of an electrolytic cell comprising at least one anodic compartment and one cathodic compartment: the solution is treated in the cathodic compartment and then recycled in the anodic one [8]. A more recent work proposes the use of zirconium cathode for the recovery of silver from photographic fixing solution [9]: studies carried out by cyclic voltammetry showed that about 98% of total Ag can be recovered with an electrical efficiency close to 92%."

Jan 1, 2008

By Mingchun Lu, Yunjin Yan

"This paper describes a new type of bell-less top installed on two relined blast furnaces at Tianjin Iron Works and another new-built at Echeng Steel Works in China. A compact installation was presented for existing furnace top innovation with the least reformation of existing top structure. A water cooling and sealing gearbox used for driving the chute discards completely the traditional idea about necessity of continuous supply of cooling gas for the gearbox. A multiring spreader and its dozens of selectable charging patterns enables an operator to achieve optimal burden distribution easily under the condition of a minimum investment of control equipment. Some useful conclusions have been made through a small-size model and a full-scale model tests. The excellent characteristics and the superiority of the new top have been fully proved at both works.IntroductionIt is known that there are some advantages with the bell-less top of a blast furnace: suitable for furnace to operate at high top pressure, capable of realizing optimal burden distribution, less investment and maintenance costs, etc. But why do most of blast furnaces in the world still remain using conventional bell top. One of the concerns is that current bell-less tops still have some shortcomings:1) The height of a current bell-less top might be lower than three or four-bell top or two-bell plus valve seal top, but still much higher than an ordinary two-bell top.2) The gearbox for driving the rotating chute is positioned onto the lip of the furnace. It is subject to attack by crude hot bf gas. Continuously pumping cooling gas (pressurized nitrogen or clean bf gas) into the gearbox is indispensable to withstand such a harsh working environment. Therefore, a plant furnished with blower8 and its ancillaries has to be built, It involves a large sum of investment and much expense in its annual running costs.3) Although the current bell-less charging device as a means of controlling burden distribution possesses a wide range of freedom, it is difficult to realize optimal burden distribution. There are some large blast furnaces realized better burden distribution, but sophisticated control means is indispensable so that the investment of control means is much higher."

Jan 1, 2000

By Raghavan Srinivasan, Y. V. R. K. Prasad, William G. Frazier, Steve C. Medeiros

"Aerospace gas turbine disks operate in an environment of relatively high stresses caused by centrifugal forces and elevated temperatures. These severe conditions necessitate the need for materials with good high temperature strength and low cycle fatigue resistance. One class of alloys used for this task is the nickel base superalloys, out of which, lN 718 is the most widely used in the aerospace industry [I]. The properties of IN 718 are attributed to the combined effects of the chemistry, heat treatment, and microstructure. The chemistry is tailored not only for solid solution strengthening but also for precipitation hardening developed during heat treatment, which combined with a fine grained microstructure lead to excellent mechanical properties such as low cycle fatigue resistance and elevated temperature strength. The properties of a gas turbine disk are sensitive to the microstructure, in particular the grain size, which is dependent on the processing history. The ability to precisely control the microstructural development during forging is dependent on controlling the process so that the workpiece is deformed within a ""safe"" region where no microstructural damage or flow instabilities occur. The microstructural mechanisms during deformation may themselves vary within the ""safe"" region and it is desirable to determine them within the range of parameters that are commonly used in industrial processing. The objective of this work is to establish a relationship between the grain size and the process control parameters i.e., temperature and strain rate, in the hot working of IN 178.BackgroundIN 718 belongs to a class of nickel-iron base superalloys with a face-centered cubic (FCC) austenitic matrix strengthened by precipitation of ordered intermetallic or carbide precipitates and is a nickel-rich alloy strengthened by ordered body centered tetragonal (BCT) precipitates, Y"". The alloying of nickel and iron results in the formation of the austenitic matrix, y, while the addition of chromium and molybdenum cause solid solution strengthening. Also, alloying with niobium causes precipitation of the metastable hardening constituent Y"" (Ni3(Nb,Ti)). Extended aging treatments in the temperature range 650 °C - 980 °C allow the more stable orthorhombic 8 phase (Ni3Nb) to form. Trace amounts of boron are also added to serve as grain boundary strengtheners for high temperature creep resistance. Hot deformation of IN 718 is performed between the Y"" and 8 solvus temperatures to facilitate recrystallization and to control grain growth. While deformation below the Y"" solvus (""""962°C) produces no change in grain size, deformation above the Y"" solvus but below the 8 solvus will lead to a dynamically recrystallized microstructure. The presence of the 8 precipitates will pin the grain boundaries after recrystallization and restrict grain growth so that a fine grain microstructure is obtained. Deformation above the 8 solvus ("""" 1038°C) will lead to a microstructure which has undergone grain growth during deformation."

Jan 1, 2000

A novel, low-pressure adaptation of Praxair?s coherent jet technology utilizing CoJet lances was developed for application at Inco&apos;s Copper Cliff Smelter where oxygen is available in large tonnage quantities but only at relatively low supply pressures (< 193 kPa header pressure). The project objectives were to evaluate the effect of coherent jet technology on controlling oxygen lance accretion (?horn?) formation and to increase oxygen efficiency in the Inco Oxygen Top-Blowing Nitrogen Bottom Stirring (TBBS) MK Reactor used for converting nickel- contaminated chalcocite to semi-blister copper. This paper describes the development and subsequent implementation and testing of two CoJet lances in this application.

Jan 1, 2005

By Yuanbo Zhang, Guihong Han, Guanghui Li, Tao Jiang, Zengqing Sun, Yanfang Huang

"Because of small specific surface area and poor ballability, vanadium/titanium-bearing magnetite is difficult for production of oxidized pellet. A novel organic copolymer binder, modified humic acid (MHA), has been authorized recently in China. Effects of the novel MHA binder on the quality of V/Ti-bearing magnetite pellets are studied in this paper. Experimental results show the MHA binder can obviously improve the strength of green pellet. Because of better heat endurance, the MHA binder pellet has a higher strength than Peridur pellet under the same preheating conditions. Moreover, TFe grade of pellet with the MHA binder is much higher than that of the bentonite pellet. The strength of preheated pellet containing MHA binder of 0.25%~1.0% meets the requirements of oxidized pellet production by grate-kiln process. Comparatively, MHA is a promising orgainc binder for iron ore pellets. Its price is only one tenth of Peridur price and about 3 times of bentonite price.IntroductionThe iron-making practices show that the use of pellet is beneficial to blast furnace life, productivity and fuel savings. Therefore, many iron-making plants have expanded the production of oxidized pellets in order to meet the needs of modern large-scale blast furnaces [1]. Presently, bentonite is widely used to improve the quality of iron ore pellets. The negative effects of using bentonite include decreasing total iron (TFe) grade and degrading the metallurgical properties of the final products [2, 3]. Many studies, therefore, have been conducted on the application of organic binders to overcome the weakness of the inorganic bentonite. In comparison with inorganic binders, one of the biggest strengths of organic binders is low residual silica content [4]. However, those studies showed that the economics of foreign organic binder addition into pellets was not attractive. For example, the compression strength of preheated pellets and roasted pellets are both too low, resulting in powder generation and ring formation in the industrial rotary kiln [3, 4]."

Jan 1, 2011

By Michael J. Marinigh

"Increased safety requirements, higher operational costs, greater environmental restrictions, and new competitive processing techniques are the challenges smelter operators must confront in order to remain economically viable.In converting furnaces which have tuyères such as the Noranda Reactor and the Teniente, Peirce- Smith and Hoboken converters, efficient tuyère line management is critical to optimizing blowing rates, increasing refractory life, and improving safety.This paper will describe recent improvements made to equipment used for tuyère punching, tuyère silencing, tuyère pyrometry and refractory drilling of tuyères and how the proper application of the equipment can lead to operational and safety improvements."

Jan 1, 2009

By Pengkai Wang, Huimin Lu, Xiaoxiang Zhang

"In this paper, it was studied an electrochemical reduction process of carbon dioxide in ionic liquids such as 1-n-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF6) as the electrolyte. The electrolysis experiments were carried out under current and potential controls. The cathode products contained carbon nanotubes, carbon nanofibers, nanographites, and amorphous carbon. To establish the actual current and potential ranges, the electroreduction of carbon dioxide dissolved in the ionic liquid was studied by cyclic voltammetry on glass-carbon (GC) electrode at room temperature. The electrochemical mechanism of carbon dioxide electroreduction was studied for explanation of all obtained results. Carbon dioxide in ionic liquids was electroreduced, similar to metals oxides being electroreduced in molten salts.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the most concerning environment problems, so the solution to this greenhouse effect is very urgent. However, the carbon dioxide is also a cheap and abundant raw material that represents a potential source for the production of chemicals and fuels. Therefore, the development of the technologies that achieve simultaneous reduction and conversion of carbon dioxide to fuels is important. The electrochemical reduction of carbon dioxide is one of the effective approaches to transform CO2. Many investigations have been carried out on the electrochemical reduction of CO2 in both aqueous [1] and non-aqueous [2] electrolyte solutions with different electrodes. The solubility of CO2 in water is very low even under high pressure of CO2, and some investigators have brought focus into the electrochemical reduction of carbon dioxide in organic solvents, because they dissolved much more CO2 than water did. However, the hazardous or toxic properties of organic solvents hinder their use."

Jan 1, 2009

By Ajit Kumar Jaiswal

"Electric Arc Furnace (EAF) being a power-intensive equipment, EAF based industries are highly dependent on scarce electric energy. This is the reason Government of India is highly concerned about this and laid emphasis on the conservation of electric energy.This paper highlights factors contributing to reduction in specific electric energy consumption in EAF and suggests measures not only for power saving, but also for productivity improvement. To name a few, these are proper sealing of furnace, introduction of oxy-fuel burners, foamy slag practice, increased usage of hot metal/DRI, post-combustion of CO gas for preheating of scrap, improved selection & design criteria of electrics, power demand management, and process automation. Few cases also have been cited, where the above measures have helped in reaping significant benefits.IntroductionFor a long time, Government of India had focused on increase in energy supply, in particular, through electricity generation. Now the emphasis of Government of India has shifted from electricity generation to its conservation for following two reasons:??Power plants have become very cost-intensive??By saving energy, more of it can be delivered at lower cost to the consumersPower generating units, transmission & distribution agencies as well as consumers all have roles to play in the area of energy conservation. By energy conservation, we mean curtailing energy requirement by reducing energy wastages and taking up measures to improve energy efficiency of electric equipment/appliances. In almost all cases, this would be economically beneficial.India’s cost-effective energy conservation potential has been estimated by the Planning Commission at 23 per cent of total commercial energy generated ?1?. A national movement for energy conservation can significantly reduce the need for fresh investment in energy supply systems in coming years. It is imperative that we make all-out effort to realize this potential. Whether a household or a factory, a small shop or a large commercial building, a farmer or an office worker, every user can and must make this effort for his own benefit and for the nation’s benefit as well."

Jan 1, 2009

The Kaldo furnace smelting technique was developed for oxygen steel production by the late Prof. Bo Kalling, Domnarvet, Sweden. Development started in 1948, and production in 1956. Five million tons of steel were produced in TBRC&apos;s in 1973. Mainly due to high TBRC maintenance costs, the steel industry now prefers non-rotating converters. In non-ferrous metallurgy, however, qualified new applications of the TBRC technique have been realized or are being considered. Inco, Canada, succeeded to convert nickel matte to metal in the Domnarvet pilot plant in 1959, and have now installed a commercial plant in Copper Cliff. La Metallo-Chimique, Belgium, has pioneered secondary copper smelting and refining in the TBRC, operating plants in Beerse, since 1968, and Alton, U.S.A. Peko-Wallsend Ltd., Tennant Creek, Australia, was faced with the problem of producing saleable blister from concentrates containing 1.5-2.0% Bi. The flash smelting matte, containing 0.2% Bi, could not be refined to an acceptable limit of 0.03% Bi in the blister copper in a Peirce-Smith converter. Tests at Domnarvet indicated that a TBRC would achieve satisfactory bismuth elimina- tion. Two TBRC&apos;s were installed in Tennant Creek and operated for 14 months during 1974-75. The problems encountered and how they were over- come are described. Further TBRC applications have been studied in Sweden.

Jan 1, 1976

By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996

By Takeo Fujino, Nobuaki Sato, Yarong Wang, Kohta Yamada

"Ternary mixed sulfides of some transition metals MTS3 (M=Ba, ·Pb, T=Ti, Zr) were synthesized by a relatively low temperature process using sulfur melt. The mixture of starting materials, such as, metals and/or binary sulfides and a large excess of sulfur was reacted in a vacuum-sealed Pyrex or quartz ampoule at 350- 600 °C for one to three weeks. After the reaction, the remaining sulfur was completely removed by a process composed of filtration of sulfur melt and followed dissolution in CS2• The binary sulfides impurities coexisted in the products were removed by rinsing the products in water and acetone. By using the above method, BaTiS3, PbTiS3 and BaZrS3 'Were obtained in pure form. The effect of addition of halides on the yields of these ternary sulfides were also discussed.IntroductionThere have been a vast number of studies on the preparation and physical and /or chemical properties of mixed metal oxides. As is well known, some of such compounds exhibit excellent materials properties, causing them for use in mechanical, electronic, magnetic and chemical devices. Not a few mixed metal sulfides show similar physico-chemical properties to those of the corresponding mixed metal oxides. However, the study of the mixed sulfide crystals is rather sparse mainly due to difficulties in preparing these compounds. In various methods which have been adopted for preparing mixed sulfides, the simplest method would be the solid-solid reaction of the component binary sulfides or elements. However, there are always diffusional constraints with regard to the reactions in solid phases causing it necessary to heat the reactants at sufficiently high temperatures, viz. 800-1200°C. On the other hand, some mixed sulfides are unstable at high temperatures or to change their materials properties due to sulfur nonstoichiometry and structural modification depending on temperature, i.e., synthesis of such compounds needs to be made at lower temperatures. Processing in alkali halide melts is hopeful to overcome the above problems but to obtain the halide melts the temperatures above ~ 600 °C is needed. Low temperature reaction has been carried out for the preparation of Hg1.24TiS4, which was formed by the ·combination of TiS2 and molten Hg metal at 320°C[l]. Reaction of WS2 with LiBH4 melt at 350°C yielded LixWS2[2]. These sophisticated methods, however, can be applied only to the vary special cases."

Jan 1, 2000

By Toshiaki Nakai, Kunihiko Takeda, Kimio Imaizumi, Hiroaki Shirasaka

"The new type of nano-porous silica particle was considered to be constructed by the spinodal decomposition-type process which was found to have narrower pores than those of conventional porous silica prepared from boron silicate or ""Shirasu"" balloon. Nano-porous silica particles were fabricated by the calcination of silica gel mixed with well-dispersed complex salts composed of phosphorous and molybdenum compounds. Both silica and inorganic salts were not perfectly dissolved in the suspension solution. After removing of the water, the silica-inorganic salts complex was volatized and successively calcinated at a temperature ranging from 650 °C to 800 °C. Then, the inorganic salts were removed by dissolving in hot water. Other inorganic salts such as potassium halides were also found to be effective as a pore-size controller.IntroductionControl of structure has an important role in the field of industry as well as in the separation and purification technology for metals and organic syntheses. Many studies on the control of material structures have been reported regarding porous materials with pores ranging from nanometer to micrometer scale. 1 ) One example is zeolite as a naturally yielded porous inorganic material. Various types of synthetic zeolites have been studied as ""molecular sieve"" materials with ordinary pore-size of less than one nanometer. In 1992, crystalline meso-porous material with a large surface area named MCM-41 was synthesized through the use of template synthesis. 2) In direct relation to our study, amorphous borate glass having 4 to 100 nm of fine pores known as Corning glass 3l or SiO2-Al2OrB2O 3-CaO porous glass having large pore dispersity ranging from 4 to 10,000 nm have been reported. 4 ) S) 6 ) Some examples of several reported studies are as follows: phase-separated porous glass consisting of B2OrAl2O3-ZrO2-RO-R2O complex oxide 7 ) glass with finer pore induced from hydrolysis of silane alkoxide, porous material attained by condensation polymerization through the use of sol-gel process 8), alumina meso-porous material 9 ) 10), silica-zirconia material 11), carbon porous material 12), etc.."

Jan 1, 2000

By Markus A. Reuter, Jacob Wood, Robert Matusewicz

Over the last 20 years, significant improvements in copper smelter productivity have been realized through the advent of continuous smelting processes. This progress has until recently however, not been carried through to copper converting. Peirce-Smith converting has been widely used by the copper industry for 100 years but is limited by its batch nature in achieving large scale of production. A logical next step is therefore copper converting on a continuous basis with its inherent environmental benefits. A number of continuous converting technologies are currently in use or being developed within the copper industry, the majority of these operating with calcium-ferrite slags. A notable exception however is the Ausmelt Continuous Copper Converting (C3) technology which has focused on operation with ferrous-calciumsilicate or loosely called olivine type slags. This paper discusses the merits of the Ausmelt C3 process and the advantages offered in terms of operational flexibility and process control arising from the use of lime modified iron silicate slags. It also examines the effects of key process variables pertinent to continuous copper converting from both a theoretical and experimental/operational perspective.

Jan 1, 2009

By Sugui Tian

By means of the T6 treatment, the measurement of creep curves and microstructure observation, the influence of T6 heat treatment on the microstructure and creep properties of Ti-6Al-4V alloy is investigated. Results show that the microstructure of the forged alloy consists of the banded-like a phase and networks b phase. After sub-temperture T6 treated, the microstructure of alloy consist of the block a phase and ?networks basket? structure. Under the conditions of the applied stress of 575 MPa at 4000C, the forged alloy displays a lower creep lifetimes, after T6 treated the creep lifetimes of the alloy is enhanced to 548 h from 66 h, which is attributed to the formation of the network basket structure in which the needle-like phase are dispersedly distributed. As creep goes on, the denser dislocations in the a phase are concentrated to occur the dynamic recrystallization for refining grain. which is a main reason of the alloy displaying a better creep lifetimes and plasticity. Thereinto, the creep mechanism of the forged alloy is thought to be the slip of the straight <a> and <a+c> dislocation are activated on the prismatic planes and pyramidal planes, while the creep mechanism of T6 treated alloy is that wave-like <a+c> dislocations are activated on the pyramidal planes.

Jan 1, 2009