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By Kenneth N. Pike

The need to comply with environmental regulations and increase production has resulted in modifications to the East Penn blast furnace operation. Changes made include furnace design modifications, closed loop water cooling with heat recovery, automated weighing and charging, automated tuyere punching, ammonia scrubbing of tail gases and improved metal and slag handling to minimize environmental impact. These changes have resulted in a marked increase in yearly production and compliance with many of the air, water and solid waste regulations.

Jan 1, 1990

Rotary kiln incinerators are widely used in the incineration of various types of hazardous wastes. However, the complex transport processes within the incinerator are not well understood. Due to large variations in waste types and difficulties in feed characterization, the incineration process meets great challenges in a smooth operation, and expects uncertainties in the process chemistry and emission control. In order to get better understanding of the incineration process, process simulation was made on the kiln behavior by using Computational Fluid-dynamics (CFD) to characterize gas flow, temperature distribution and waste combustion in the incinerator. Temperature measurement was conducted in an operating incinerator to validate the CFD model. This paper addresses the environmental issues related to the hazardous incineration process, and reports the recent simulation results on gas flow and mixing, combustion heat transfer, and potentials to reduce emissions.

Jan 1, 2002

By Chuanyu Feng

In this paper, a load-based micro-indentation technique suitable for field applications was developed. This technique bears the same theoretical background as traditional load-depth sensing indentation, and does not need any direct measurement of indentation depth or contact area. The removal of this requirement will reduce much of the cost associated with traditional instrumented indentation. To demonstrate the feasibility, a portable indentation system suitable for online material characterization was developed. Design issues of the portable unit were discussed and preliminary results using the portable unit were also presented.

Jan 1, 2009

By Jun Miao, Kang Liu, Jilai Xue, Jun Zhu

CO2 emissions must be reduced by at least 50 % by 2050, and hence the technical solutions to capture and convert CO2 into value–added products should be considered. A Cobalt(III) Schiff base complex (Salen–Co(III)) has been investigated as a catalyst for synthesis of cyclic carbonate from CO2 and epichlorohydrin(ECH) with tetrabutylammonium bromide (TBAB) as co–catalyst. To recover Salen–Co(III) for the next cycling operation, it was immobilized onto zeolite 13X through excessive impregnation method. The immobilized catalyst was characterized using XRD, SEM, BET and ICP–AES techniques. Catalytic tests showed that yield of cyclic carbonate reached 90 % using 0.5 mol % Salen–Co(III) at ambient conditions. The immobilized Salen–Co(III) exhibited better catalytic activity than the homogenous one when used at the first cycle, but the yield decreased by some 20 % after five cycles.

Jan 1, 2015

By Minjun Tang, Jianfeng Zhou, Linjiang Qing, Yufeng Guo, Tao Jiang

"For the comprehensive recovery ofV, Ti, Fe in vanadium-titanium magnetite in the process of pre-reduction-electric furnace smelting, it is expected that vanadium oxide is reduced into molten iron and titanium oxide is available in the slag. Thus the effect of slag basicity, the content of MgO, MnO and CaF 2 of slag content on the separation of slag and molten iron and the comprehensive recovery of V, Ti, Fe were investigated. The results show that increasing slag basicity, MgO, MnO and CaF2 are all beneficial to the separation of slag and molten iron. Higher slag basicity and the addition of CaF2 strengthen the reduction of vanadium oxide, and inhibite the reduction of titanium oxide, which are in favour of the recovery ofV and Ti. However, the addition ofMgO, MnO was not efficient for the comprehensive recovery ofV, Ti, Fe. For the vanadium-titanium magnetite of Panxi in China, the recovery of Fe was over 98%, the recovery ofV in molten iron was over 85% and the Ti02 content in slag was about 43% under the optimal conditions of slag phase type.IntroductionIt is well known that there are abundant vanadium-titanium magnetite resources which are located in Panzhihua of Sichuan Province[!]. At present the vananium-titanium magnetite concentrates are smelted in the blast furnace, which just make use of iron and vanadium, but lots of titanium is discarded in the slag. At the same time, the process has a large number of disadvantages, such as low recovery of vanadium, long route, pollutions, large investment and expenditure of energy[2-3]. In recent years, in order to efficiently utilize the vanadium-titanium magnetite concentrates, several new non-blast furnace processes have been proposed, such as pre-reduction-electric furnace, pre-reduction-grinding separation and so on[4]. Especially pre-reduction-electric furnace is operating well in South Africa and New Zealand,However,Du to the high slag basicity of the slag, the grade ofTi02 of slag is Corresponding author:Minjun Tang.E-mail:450435123@qq.com. Tel:13627429224."

Jan 1, 2013

By Hideki Yarnarnoto

The simultaneous removal for NH4+ and PO43- in aqueous solution was carried out by using Ca type zeolite synthesized from coal fly ash. The effect of pH on the cation exchange capacity and adsorption properties of the obtained zeolite, the simultaneous removal of NH4' and ~04'. in various solutions and the mechanism of simultaneous removal were investigated respectivel? ,The Ca type zeolite used in this study can simultaneously remove NH4+ and PO43- In aqueous solution without releasing counter ion, and this method gives great advantage over the other ordinary removal methods.

Jan 1, 2002

By Zhihe Dou, Zimu Zhang, Guozhi Lv, Yan Liu, Xiaoli Jiang

"Cyclic heat stewed slag washing water carries high content of alkali and calcium and may cause serious tube scaling and impose an adverse impact on normal production. This study proposes a solution to utilize washing water by absorbing and mineralizing CO2, potentially restraining scaling and being able to create calcium carbonate powders. Effects of water flux on water quality, utilization ratio of CO2 and yield of calcium carbonate powder have been investigated; meanwhile, features of calcium carbonate powder are also represented. On the other hand, effects of factors such as as injection flux, pressure of CO2 on utilization ratio of CO2, morphology and purity of calcium carbonate are also investigated. The results show unambiguously that after soften injection of CO2, calcium ions were removed effectively via precipitation, alleviating the scaling problem. High purity yet fine carbonate powder could be achieved.IntroductionNowadays, 0.34 tons of blast furnace slags will be produced when producing 1 ton of pig iron; ensuing that, 0.12 tons of steel slag will be generated with 1 ton steel production while 1.57 billion tons of steel output all over the world in the year of 2012. It is therefore a critical issue to realize zero discharge of steel slags to achieve sustainable development and cyclic economy of iron and steel industry. In recent years, research institute of MCC and China JINGYE engineering company developed a heat stewed steel slag self-decomposition technology GENERATION III to solve the problem of instability of steel slags and realize the zero discharge. However, the problem of circulation line scaling which may cause the clogging, even exploding, need to be solved. The principles of the technology are: directly spraying water to the high temperature steel slag when it is poured into the hot closed pot, realizing the selfdecomposition via utilizing the waste heat of steel slag. The washing water is recycled to achieve a cyclic utilization. The process is shown in Figure 1."

Jan 1, 2014

By Yan Beygelzimer, Alexander Spuskanyuk, Victor Varyukhin

"The main idea of the report is that the yield surface can be presented as thick, ""foamed surface"" with dimensionality exceeding two. By other words, perhaps, the yield surface is fractal, i.e. it belongs to the class of geometric objects with fractional dimensionality. Apparently, fractal structure of the yield surface is determined by the fractal structure of natural materials. ""Cloud of internal stresses"" term is introduced to describe the stress distribution in representative volume element. Its plastic flow is determined by the interaction of this cloud with the thick yield surface. Thick yield surface and internal stress cloud concepts allow to determine an additional correlation between micro mechanical models of polycrystals and phenomenological theory of plasticity.1. IntroductionClassical plastic flow models are not satisfying the modem requirements. There are two main directions in their development. The first, mathematical, is connected with the development of the general theory of rheological relationships; the second, physical, is connected with the development of the representative volume element (RVE) models which are based on specific ideas about deformation mechanisms. Within the framework of the first direction, the macroscopic experimental data is formalized; the second approach deals with the generalization of physical research results for the different scale levels that are involved in plastic deformation.These approaches have advantages and disadvantages. In phenomenological theories, the advantages are the mathematical simplicity and laconic formulation of constitutive relations, which allows using them in practical calculations. However, the mathematical models of this class can not be considered as general, they are useful only for the description of limited range of deforming processes. On the other hand, physical theories that are based on the description of real plastic deformation mechanisms are very explanatory and predictive, but they lack mathematical simplicity. The above circumstances lead us to the necessity of compromise that can be found in determining the constitutive relations for RVE, which structure and parameters would bear the information about rnicrolevel and mesolevel phenomena. In this synthesis direction, the fundamental role belongs to [1,2], etc."

Jan 1, 2001

By C. J. McKee

A gold-silver-lead-zinc deposit at Montana Tunnels, Jefferson County, Montana is located in a diatreme of middle Eocene age (45 to 50 m.y.). Sulfide minerals within the diatreme occur as disseminations, veinlets, and locally as breccia matrix. Principal sulfide minerals are pyrite, sphalerite, and galena. The diatreme is a matrix-rich quartz latitic breccia with a fine grained rather soft matrix and heterolithic clasts. The ore deposit contains approximately 50 million tons of ore at a grade of 0.025 oz/ton Au, 0.5 oz/ton Ag, 0.25 % Pb, and 0.65 % Zn. Mining is by open pit methods. The original process flowsheet included flotation and cyanide leaching. Problems with the leaching circuit led to a change to the straight flotation process which is presently in use. To maintain a reason-ably uniform feed material, blending of ore is required for grades of four metals as well as for ore hardness and oxidation.

Jan 1, 1988

By Nobuyuki Masuda

In Japan, the municipal solid waste, which amounts to 50 million tons, is generated every year and most of it is incinerated. The fly ash from the municipal waste incineration (the primary fly ash) contains heavy metals, such as lead and zinc, etc., and dioxins. In case of melting, the fly ash from the process (the secondary fly ash) contains high concentration of heavy metals (e.g., Zn; 1-20%, Pb, 1-10%). Metal Mining Agency of Japan launched a four-year project in 1999 to establish the integrated technologies to recover the valuable metals from, and to decontaminate, the primary and secondary fly-ashes in the practical scale by utilizing the existing metallurgical processes and facilities, along with the energy saving. The segregation, flotation and chemical treatment are applied to the treatment of the primary fly ash. The secondary fly ash is treated with MY (Mitsui-type blast furnace) Process after the chlorine removal to recover the heavy metals in the ash, In this paper, the segregation and flotation process for primary fly ash and MF process for secondary fly ash are explained. The main results of experiments done from 1999 to the mid of 2001 to design the pilot plants and to optimize the operating conditions are described. The main results of the experiments are as follows: - The segregation reaction of Cu was confirmed by the experiment on the treatment condition of 800 and 900`C with adding oil cokes and water to the primary fly ash, and 99.98% (toxicity equivalent) of the dioxins were decomposed by the treatment. - Washing tests of secondary fly ash to feed MF resulted that more than 70% of chloride were removed, but still lower than expected, and agglomeration tests were successful by the results of the sufficient strength of briquettes produced though a little more binder for the agglomeration is required than usual operation. - Smelting experiment by downsized MF showed that valuable metals, such as zinc and lead, are recoverable in the furnace dust. Recovery ratios, Zn: 58% and 67%, Pb: 74% and 83%, are accomplished.

Jan 1, 2002

By N. A. Warner

To filly secure the environmental and social acceptability benefits of making a sulphide smelting facility and its ancillary sulphuric acid plant or other means for fixing sulphur, a virtually zero gas emission operation, it will be necessary to utilise exclusively technically pure oxygen. The strategy proposed for preventing the smelter from overheating involves highly efficient energy transfer by promoting sulphur trioxide formation at a relatively higher temperature than normal. A closed-loop gas circuit uses an eductor system actuated by the process oxygen to recirculate sulphur trioxide and unconverted sulphur dioxide back to the smelter, the endothermic dissociation of sulphur trioxide becoming a major contributor to the removal of excess heat. The only gases leaving the system relate to the bleed of nitrogen impurity introduced in the tonnage oxygen.

Jan 1, 1998

By Chikabumi Yamauchi, Mitsuru Tanahashi, Tsuyoshi Taniguchi, Nobuo Furuta, Toshiharu Fujisawa

"It is essential to clarify the equilibrium relations among nonmetallic inclusions of the Mn0-SiO2-CrOx system and molten stainless steel in order to control non-metallic inclusions formed by the deoxidation of stainless steel with silicon. In the present study, the phase equilibria of the MnO-SiO2-CrOx system were measured by conducting the following experiments under controlled oxygen partial pressure, Po2, at 1873 K:1) Phase equilibria of the MnO-Cr20 3 binary system were measured for Po2 = 2 x 10-6 ~2 x 102 Pa.2) Phase equilibria of the MnO-SiO2-CrOx ternary system were measured for Po2 = 2 X 10-6 Pa.Based on the results, the phase diagram of this ternary system was established under the condition of the Si-deoxidation process of stainless steel (Po2 = 2 x 10-6 Pa and T = 1873 K).IntroductionAt the deoxidation stage in steelmaking process, generally multiple deoxidizers participate in deoxidation reactions, and the composition of deoxidation products ""non-metallic inclusions"" greatly varies depending on deoxidizing efoments and their contents. In order to control non-metallic inclusions formed by the refining process of steel, it is essential to clarify the equilibrium relations among non-metallic inclusions and molten steel.Especially, during the refining process of stainless steel, nonmetallic inclusions in molten steel seem to- change as follows. After the oxidation refining, Mn-chromite is formed in molten steel as non-metallic inclusion. By the deoxidation with silicon addition (mainly less than 1 mass%), Mn-chromite inclusions are changed their compositions to Mn-silicate. Segawa et al.[l] have reported the effect of amount of silicon addition on composition and mass ratio· of non-metallic inclusions during the Sideoxidation process of 18Cr-8Ni stainless steel at 1873 K, as shown in Figuri; L At higher silicon content than 0.5 mass%, only Mn-silicate was identified as non-metallic inclusion. On the other hand, at lower silicon content, both of Mn-chromite (MnO Cr2O 3) and Mn-silicate were identified. However, the thermodynamic and the kinetic analyses of the above-mentioned Sicdeoxidation process have not been made due to lack in the thermodynamic data for the non-metallic inclusions· of the MnO-SiO2-CrOx system, such as the phase diagrams, the activities of the components, and the free energy of intermediate compounds. In relation to the phase diagram of this system, those of the MnO-SiO2 [2] and the SiO2-Cr2O 3 [3] binary systems have been only reported"

Jan 1, 2000

By Keith Rozenburg, Ivar Reimanis, Jesus Chapa

"Experiments in conjunction with finite element analysis (FEA) are used to better predict crack propagation in ductile/brittle graded composites. Cu/W graded composites were fabricated by stacking discrete layers of powders and hot pressing. Crack propagation was studied by loading a notched beam in four point bending and examining the subsequent crack deflection. The notch was placed within a particular composition of material, oriented in a direction perpendicular to the gradient direction. Elastic and plastic mismatch between different constituents in the graded composite induce shifts in the phase angle of loading, thereby causing the crack to deflect. FEA indicates that thermal residual stress has a negligible ""influence on the crack path. The combined FEA and experimental results suggest that elastic mismatch is the single most important material property-related factor in controlling crack deflection.IntroductionMany 'applications would benefit or may even require materials whose performance or functionality must vary spatially. While the concept of functionally graded materials has existed for nearly one hundred years, it is only within the last fifteen years, that research efforts have focused on generic issues in processing, properties and performance of functionally graded materials. This generic research effort has brought together scientists and engineers from traditionally different disciplines to address common issues with graded composites. The current work focuses on issues in structural joining. A wide variety of applications require some type of joining between dissimilar materials. Examples include thermal barrier coatings for turbine engines, wear resistant coatings for tools, ceramic engine parts, and microeiectronic devices, as well as many traditional applications involving metallic welding. The joints may either be discrete, involving a single interface, or they may· be spatially graded in composition. Extensive theoretical and experimental information exists on discrete bimaterial and trimaterial joints, but relatively little exists for graded joints or composites"

Jan 1, 2000

By S. M. McDeavitt

Waste form alloys are being developed at Argonne National Laboratory for the disposal of remnant metallic wastes from an electrometallurgical process developed to treat spent nuclear fuel. This metal waste form consists of the fuel cladding (stainless steel or Zircaloy), noble metal fission products (e.g., Ru, Pd, Mo and Tc), and other metallic wastes. The main constituents of the metal waste stream are the cladding hulls (85 to 90 wt%); using the hulls as the dominant alloying component minimizes the overall waste volume as compared to vitrification or metal encapsulation. Two nominal compositions for the waste form are being developed: (1) stainless steel-IS wt% zirconium for stainless steel-clad fuels and (2) zirconium-8 wt% stainless steel for Zircaloy-clad fuels. The noble metal fission products are the primary source of radiation in the metal waste form. However, inclusion of actinides in the metal waste form is being investigated as an option for interim or ultimate storage. Simulated waste form alloys were prepared and analyzed to determine the baseline alloy microstructures and the microstructural distribution of noble metals and actinides. Corrosion tests of the metal waste form alloys indicate that they are highly resistant to corrosion.

Jan 1, 1996

By Krzyszof Borowiec

With the aim of determining the thermodynamic conditions for sulfation of impurity elements, in particular magnesium, in titaniferous slags the equilibrium gas composition for the sulfation reaction: MO + so2 + 1/2 02 = MS04 has been studied by an EMF technique with a solid zro2 + Cao electrolyte. Here M denotes the impurity elements: Mg, Ca and Mn, and the following _oxide systems have been studied: Ti02-MgO-Fe2 o 3 , Ti02-MnO-Mn2 o 3 , and Ti02 -CaO-Si02 , all in the . temperature range 700-1000ºc. Reproducible EMF values were obtained by adding small amounts of -Na2so4 to the oxide-sulfate mixture. From the observed results the Gibbs energy of formation of the phases Mg 2Ti04 , MgTi03 , MgTi 2o 5 , MnTi03 , CaTi03 , and CaTiSio5 , as well as the activity of MgTi05 in the solid solution with Fe2Ti05 have been calculated. The results show that, from a thermodynamic viewpoint, sulfation of these impurities in titaniferous stags i:s favorable- at around and below 800ºC.

Jan 1, 1985

By John L. Sundstrom

Complete systems were designed -and are in operation to recycle the effluent streams and to remove impurities from tankhouse. electrolyte, Heavy em¬phasis was placed on making usable products from as many streams as poss¬ible at minimum capital and operating costs. Almost complete recycling: and reuse of water and sulfuric acid were paramount. Techniques used in-clude solvent extraction - electrowinning, evaporation - crystallization and filtration.

Jan 1, 1992

By C. Allen, A. Roy, J. W. Evans

A spouted bed electrode (SBE) has been used, in laboratory experiments, to electrowin zinc from zinc chloride electrolytes with the objective of determining the suitability of this electrode for commercial application. Zinc was successfully electrowon at current densities ranging up to 4,38 lA/m2, which are an order of magnitude larger than those used at present in the zinc industry. Current efficiencies, for the cell with the SBE, have been as high as 90% and DC energy consumption as low as 2.8 kWh/kg zinc deposited. The performance of the cell has been measured as a function of current density, anode type, cell diaphragm, addition of tributyl ammonium chloride and purging of the electrolyte (to remove dissolved chlorine).

Jan 1, 2000

By Cui Wang, Qian Li, Kexin Jiao, Haibin Zuo, Jianliang Zhang

Abstract：A rational cooling water system is the assurance for long campaign life of blast furnace．In the paper, the heat transfer of different furnace period and different furnace condition based on the water quality characteristics were analysed, and the reason of the heat flux over the normal from the hydrodynamics was analysed. The results showed that, the vapour-film and scale existence significantly influenced the hearth heat transfer, which accelerated the brick lining erosion. The water dynamic characteristics of the parallel inner pipe or among the pipes were the main reason for the abnormal heat flux and film boiling. As to the reasonable cooling water flow, the gas film and the scale should be controlled and the energy saving should be considered.

Jan 1, 2015

By P. M. Tait, N. A. Warner

"The refining of thermally produced zinc is currently performed using a highly energy intensive and arguably outmoded process, distilling zinc under atmospheric pressure at temperatures of 900°C to 1000°C. In order to produce refined zinc more profitably and with less environmental impact a new process has been proposed. This process is generic to all thermal zinc smelters and aims to match the purity of zinc from current technology (99.99%-99.999%). The objective is to perform all separation processes using only the heat contained in the smelter product stream. Vacuum conditions are extensively used lowering operating temperatures and enhancing separations. As part of this process zinc is distilled under vacuum from high concentration obtaining a refined product with respect to lead content. A mathematical model has been developed from fundamental principles to describe this stage, the distillation of zinc across a temperature difference between two circulating zinc streams in open channels under vacuum. Heat for the distillation is supplied by the liquid phase, necessitating a large recycle to maintain high operating temperatures, and keep zinc concentrations high. In determining this model and the operating conditions required, relationships between temperature, pressure and composition are considered.IntroductionCurrent technology (the Refluxer) used to refine thermally produced zinc is both expensive and highly inefficient. At present 80% of the worlds zinc is produced via the electrolytic process reflecting the poorer performance of the thermal route, the zinc-lead blast furnace and Refluxer. A new process is proposed to overcome the drawbacks of current processes. These drawbacks are both economic and environmental. The Refluxer requires 6.6 GJ of energy to refine one tonne of SHG zinc 1, other disadvantages of the Refluxer stem from high operating temperature, around 900°C, and liquid zinc being highly corrosive towards ferrous metals. The Refluxer is constructed from silicon carbide sections which join together by means of flat machined faces making liquid metal leaks inevitable. The Refluxer columns are very sensitive to thermal cycling, thermal shock and mechanical vibration, which easily lead to structural failure. To avoid thermal stress on the columns the feed rate and feed temperature need to be kept constant which means the feed baths to the columns must be able to accept solid and liquid feed as the Refluxer has to operate when the smelter is shut down."

Jan 1, 1998

By M. Neises, M. Roeb, C. Sattler, S. Stenger

"A two-step thermo-chemical cycle process has been developed and investigated. It is based on metal oxide redox pair systems, which can split carbon dioxide as well as water molecules by extracting oxygen atoms and reversibly incorporating them into their lattice. If concentrated solar radiation is used as the heat source, a promising method exists to produce synthesis gas from water and CO2. An easy way of operation is gained by the combination of a ceramic substrate as the absorber structure, which can be heated to high temperatures with concentrated solar radiation, and of a metal oxide coating which is capable to carry out the redox reactions. The performance and kinetics of a ferrite based redox material coated on ceramic substrates were investigated in a laboratory set-up. CO2 could be reduced with significant conversions. In addition, several side reactions were observed like the formation of carbon and like the Boudouard reaction.IntroductionThe search for alternative energy carriers and for processes able to reuse carbon dioxide stimulates the research for sustainable routes of alternative fuel production. In the scope of this search thermo-chemical processes combined with sources of concentrated solar energy have become more and more attractive. Ideally, the only raw materials for such processes are water (H2O) and carbon dioxide (CO2) enabling not only a process free of emissions, but also allow to reduce emissions of other processes by reusing CO2 to provide synthesis gas, which itself can be applied to produce chemical commodities or even better synthetic fuels like methanol or petrol.In contrast to the direct splitting of those raw materials, thermochemical cycles split water and CO2 in several steps and enable hydrogen (H2) and carbon monoxide (CO) generation at temperatures controllable by today’s technical equipment. One of the most interesting thermochemical cycles is a two-step process using metal oxide based redox systems. During the first step of this cycle (the regeneration step) the metal oxide is reduced setting some of its lattice oxygen free according to reaction (1). In the next step (the splitting) the reduced and activated material is oxidised by withdrawing oxygen from water and CO2 and at the same time hydrogen and CO is set free according to reactions (2a) and (2b) respectively."

Jan 1, 2011