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By S. P. Kinney, A. C. Fieldner, S. H. Katz

"The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rub¬ber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber.A sample of gasoline was obtained from the tank in which Cunningham met his death. Examination by Dr. E. W. Dean of the Petroleum Division of the Bureau of Mines gave the following results.This shows the gasoline to be heavy and typical of the gasolines sold throughout Colorado for motor fuel A. Salvus half hour oxygen apparatus was arranged with the breathing bag only in a gas tight box in which the space was kept saturated with the vapor of this gasoline. The main part of the apparatus was outside the box. Oxygen from the apparatus was breathed by a man in the usual manner. Gas samples were taken from the box at intervals to determine the concentration of gasoline vapor, also samples of the oxygen breathed were taken from a side tube in the mouthpiece. The room temperature was 75°F. The concentration of gasoline vapor in the box at the beginning of the test was 4.3%. The man breathing from the apparatus thought he detected gasoline in his oxygen in two minutes after starting the test. Analysis of the inspired oxygen at this time showed 0.03% gasoline vapor. The same man remained on the apparatus for 18 1/2 minutes without suffering any ill effects. His place vas then taken by another man who wore the apparatus until the oxygen was exhausted without noticing more than a trace of gasoline at any time. At the end of the test the inspired oxygen contained 0.07% gasoline vapor. The total time of test was 38 minutes."

Dec 1, 1919

By J. F. Barkley

During the present war emergency, under the urge of the Federal Government to store coal, the following; questions are arising n the minds of coal users: (a) Will the coal lose any of its heating value in storage? (b) Will it slack and give a smaller-size coal? (c) Will its burning characteristics change in any way? (d) Will it catch fire from spontaneous combustion? (e) What precautions should be taken when storing coal? In regard to the loss of heating value of coal in storage, tests made by the Bureau of Mines show that the loss commonly has been overestimated. Various types of storage tests were made on New River, Pocahontas, Pittsburgh Gas, and Sheridan Wyoming coals. The following is quoted from Bureau of Mines Bulletin 136, Deterioration in the Heating; Value of Coal During Storage, by H. C. Porter and F. K. Ovitz:

Jan 1, 1942

By D. A. Reynolds, A. C. Fieldner, S. H. Katz

"03-01-192403-31-2019RI 2591 - Reports of Investigations - Department of the Interior - Bureau of MinesBureau of MinesPittsburgh Experiment Station American Society of Heating and Ventilating EngineersU.S. Public Health ServicesTucson Experiment Station Introduction.""Carbon monoxide self-rescuers,"" or simply ""self-rescuers,"" are pocketsize gas respirators which protect the wearer from air contaminated with poisonous carbon monoxide gas. On March 6, 1924, the Bureau of Mines approved the ""M.S.A. self-rescuer’ manufactured by the Mine Safety Appliances Co., Pittsburgh, Pa., after the M.S.A- self-rescuer bad passed all the tests and requirements of the Bureau's Schedule 14A4.The purpose of the self-rescuer is to help miners to escape from mines in which fires are burning or explosions have occurred, by providing protection from carbon monoxide for at least one half-hour. The self-rescuer can be used similarly by workers above ground who may through accident become surrounded or entrapped by atmospheres containing carbon monoxide.no hazards threaten the miner, who escapes serious injury by fire or violence in a large mine fire namely, ( 1) asphyxiation by poisonous carbon monoxide gas; and (2) suffocation by insufficient oxygen to support life. In order to save himself, the miner must either erect a barrica4e5 against afterdamp and wait restoration of ventilation and rescue or take a long chance at getting out of the mine through entries not permeated by afterdamp.. The self-rescuer removes the hazard of carbon monoxide poisoning for one half-hour or more, and accordingly greatly increases the miner's chance of saving his life.This paper describes the construction and details of the M.S.A. self-rescuer as approved by the Bureau of Mines, and discusses its performance under test condition"

Mar 1, 1924

By F. H. Gibson

An investigation was made by the Federal Bureau of Mines of methods for determining phosphorus in coal, coal ash, and coke ash. Several of these methods are being considered for international standardization. As might be expected, methods and proposals from other countries for determining phosphorus differ considerably from those accepted an standard in the United States. Some of the methods differ fundamentally in principle from the American Society for Testing Materials (ASTM) standard used in the United States; others differ only in details of procedure. Because the Bureau considered that certain of the proposed methods might offer advantages in obtaining increased accuracy and precision or in decreasing the time required for making analyses, these methods were investigated, and the results compared with those obtained by the ASTM method. The methods investigated may be grouped into three types--volumetric, colorimetric, and gravimetric. All were about equally accurate and may be used alternatively. From a practical viewpoint, when only a limited number of analyses are made intermittently, the gravimetric procedure probably is the most suitable because no special apparatus or standard solutions are required. The volumetric methods are more rapid when more analyses are made. For mass production, the colorimetric methods, although requiring a suitable photometer or spectrophotometer, are more suitable because a large throughput should be feasible.

Jan 1, 1961

By Howard F. Puariea

This paper is one of a series describing methods and costs of recovering sand and gravel from alluvial deposits in the United States and deals directly with the methods employed by the Portland Gravel Co. in operating a clamshell dredge on the Willamette River near Portland, Oreg., and a pump dredge on the Columbia River near Vancouver, Wash. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local expenditures only and not total production costs. It is recognized that publication of total costs may in some instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand operating costs are essential to the technical discussion and study of methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By Paul M. Linebarger

This paper is one of a series of digests of foreign mining legislation and court decisions prepared in advance of a general report relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of Mexico has been pro oared from the best information available in Washington but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers, to whom it has been referred through the courtesy of the Department of State. INTRODUCTION Present-day Mexican mining legislation involves, not only the latest minim enactment (August 1, 1026), but many other enactments and regulations, principal among which are the Constitution, the Civil Code, the Code of Commerce, the Foreign Law, the Mining Tax Law, and. the Civil Jurisprudence of Mexico--the last-mentioned being based in Dart on Supreme Court decisions. Ere Mexican Federal Government is supreme in mining legislation because, among other reasons, a large part of the revenue of the Government must come from the fiscal control of the mines. All circulars, decrees, and rulings that affect the mines not only have their origin in the Central Government but are administered thereby. The Department of Industry, Commerce, and Labor is in control of all mines. Attention may here be called, however,

Jan 1, 1929

By LB. Berger

"INTRODUCTION The use of gasoline engines as the motive power for lift trucks, tractors, and other types of mobile equipment operated in enclosed spaces, such as industrial plants and warehouses, may create a hazard because of the carbon monoxide present in the exhaust gases of the engines; gasoline-powered equipment should not be used in mines or tunnels. Because the equipment is mobile, local ventilation usually is impracticable, and general ventilation of the spaces is nec-essary to dilute and remove the carbon monoxide. To estimate the rate of ventilation required in such situations, information is necessary on the concentration of carbon monoxide in the exhaust gas and the rate at which exhaust gas is produced under given operating conditions. The purpose of this paper is to present data that may be used in making estimates of ventilation requirements.COMPOSITION OF GASOLINE-ENGINE EXHAUST GASThe exhaust gas of a gasoline engine consists mainly of carbon dioxide, carbon monoxide, hydrogen, oxygen, and unburned hydrocarbons (usually reported as methane), together with the nitrogen present as a residue from the air sup-plied for combustion. 3/ The exhaust also contains water vapor resulting from combustion of the hydrogen of the fuel. The water-vapor content is not included in exhaust-gas analyses calculated on a ""dry"" basis and is not involved in the estimation of ventilation requirements."

Jun 1, 1947

By Lloyd A. Morley

This report abstracts project work performed under USBM Grant GO155003 during the period 4 November 1975 to 3 November 1976. The research was funded, as a continuance of previous support from USBM Grants GO133077 and G0155003, to gain further knowledge in mine electrical system safety. Five reports have been separately produced, all under the grant title, "Coal Mine Electrical System Evaluation," and are as follows: 1. Volume I - Continuous Monitoring, 2. Volume II - Transient Analysis, 3. Volume III - Shielded Cables, 4. Volume IV - Computer Modeling, and 5. Volume V - Battery and Battery-charging Safety. Abstracts of these comprise the balance of this document with one exception. The task ?d-c offsett currents," does not fall under the scope of the other report volumes and, further, the material to be presented does not justify a separate report. Hence, this subject concludes the Executive Summary.

Jan 1, 1977

By W. Bruce Montgomery

Manganese oxides occur, with some iron oxides, in small scattered lenses on property controlled by the Columbia Manganese Co. (1943) near Evington, Campbell County, Va. The company mined some manganese ore during 1917 and 1918. A preliminary examination in May 1942 indicated the possibility of finding additional ore. On August 21, 1942, the Bureau of Mines began prospecting to verify the continuity of the ore exposures. Work on this project continued until February 5, 1943. Prospecting and development work included shaft sinking, crosscutting, drifting, trenching, and test-pitting in six separate areas indicating two types of deposits. The most predominant type is a wide brecciated area in which occur lenses or pockets of nodular manganese oxides. The other type is characterized by more of a vein structure, including thin layers of manganese oxides.

Jan 1, 1949

By G. R. Palmer

The Bureau of mines evaluated the elution of uranyl carbonate from a strong base resin with a mixed carbonate eluant in a fluidized system. The system consisted of a multiple-compartment ion-exchange (MCIX) elution column with a continuous flow of solution, except for short periods when the resin increments were withdrawn. The exchange of uranyl carbonate from the mill-loaded strong base resin with an eluant composed of 1.0 [M] NaaCOs plus 1.0 [M] NH4HCO3 was studied. The effects of solution flow rate, aqueous-to-resin flow ratio, column diameter, compartment height, initial resin concentration, and column length were examined. The experimental data indicate that for the eluant examined, a resin residence time of 240 minutes is necessary to attain 90-percent elution efficiency. Also provided is a technique for sizing an elution MCIX column form pilot plant experimental data.

Jan 1, 1979

By Richard J. Mainiero

The Bureau of Mines has developed a prototype nonincendive explosive rock-breaker charge that can be fired unconfined in underground bituminous coal mines without the danger of igniting a flammable atmosphere that might be present. At present, unconfined shooting in underground coal mines is prohibited, but there are situations where the use of such shots would yield an overall improvement in safety. The charge consists of 1-1/2 lb of permissible water gel explosive in the form of a short cylinder 7 inches in diameter and 7/8 inches high, surrounded by a 1 1/2-inch-thick layer of damp salt, and encased in latex rubber reinforced with cheese cloth. The latex rubber housing provides a charge package that is strong enough to resist rough handling yet is pliable enough to conform to an irregular stone surface. A charge of this shape was found to be more effective at breaking rock than charges with lined or unlined cavities. Incendivity tests in a gallery have shown that the prototype charge will not ignite a flammable methane-air atmosphere when fired. Rock- breaking tests made with limestone boulders indicate that the charge will satisfactorily break stone slabs weighing 1 to 2 tons, and that two or more charges might be effective for slabs weighing up to 10 tons. In cooperation with the Mine Safety and Health Administration (MSHA), a test protocol for the certification of these charges as "permissible" for use in flammable atmospheres is being developed.

Jan 1, 1982

By Albert J. Forney

A process for the manufacture of high-Btu gas from coal has been developed by the Bureau of Mines. The process consists of fluid-bed gasification of the coal, followed by the gas treatment steps of gas purification and methanation. Advantages of the system are that caking coals can be used directly, and more than half of the ultimate methane is made in the gasifier.

Jan 1, 1970

By David K. Denton

There are no active mines in the Mt. Eddy RARE II area. Chromite, gold, and stone prospects were examined. The RARE II area contains no identified mineral resources; however, a sample of a 260 ton occurrence contained 38.1 percent chromium oxide (Cr203) at the Ratero Prospect (fig. 1, no. 3), which has low potential for chromium resources. The Johnson Mine (fig. 1, no. 6) produced a small unrecorded amount of chromite during World War IT, but only a low potential exists for chromium resources. A low potential exists for gold resources at the Half Century Prospect (fig. 1, no. 2). At a borrow pit northwest of the study area (fig. 1, no. 1), sheared serpentinite is quarried for road metal; similar rock occurs in the RARE II area, but better material is more readily available elsewhere. Sand and gravel occurrences are too inaccessible and distant from markets to be considered resources. Mineral fuels and geothermal resources were not evaluated during this Bureau of Mines study. There currently are three unpatented lode mining claims in the study area. INTRODUCTION The Mt. Eddy RARE II area is 7 air-mi west of Mt. Shasta City, California, and straddles the Siskiyou-Trinity county line. The roadless area includes 7,200 acres of rugged, glacially carved, ridges and drainages which comprise Mt. Eddy. Elevations vary from 6,000 ft along the North Fork Sacramento River to 9,025 ft at the summit of Mt. Eddy. The area is covered with conifer forest below 8,000 ft elevation.

Jan 1, 1983

By Fredrick L. Johnson

No mineral resources were delineated during our investigation of the Antelope Wilderness Study Area (WSA). Only a few claims have been located in the area and only four workings were found. There has been, however, considerable exploration and mining activity in and near the south end of the study area. The Morey mining district, just southeast of the WSA, produced silver, and lesser amounts of gold and lead, sporadically from the mid-1860's through the mid-1960's. Long Lac Mineral Exploration (Texas), Inc. is actively exploring a large block of claims for hot-spring type, low-grade, large-tonnage gold deposits. Their claim block extends into the study area. The WSA, located midway between Tonopah and Eureka, encompasses approximately 87,400 acres. It is underlain by Tertiary rhyolitic and latitic volcanic rocks and by Paleozoic sedimentary rocks. At least three areas in the Paleozoic rocks have many of the favorable criterion for hot-spring type gold deposits; they have been faulted, silicified, brecciated, and hydrothermally altered, and have anomalous concentrations of precious metals and pathfinder elements. With additional exploration in the south part of the Antelope WSA, gold resources may be discovered.

Jan 1, 1986

By J. W. Faul

[The Bureau of Mines initiated an extensive research on coal-mine ventilation factors in 1922, large- scale tests being conducted in its experimental nine near Bruceton, Pa., over a period of two years. A comprehensive report an this work is in course of preparation, but in order to place the practical results before the mining fraternity immediately and in condenses form, the more important features will be presented in a number of short papers. The present report is the first of a series dealing with the resistance of coal-mine entries to the flow of air and considers only entries in which there are no obstructions other than the natural roughness of the ribs, roof, and floor.]

Jan 1, 1924

By L. R. Burdick

The Smokescope is an instrument recently developed for determining the density of smoke by shade comparison. The instrument is designed so that the smoke is seen adjacent to two shades of gray corresponding to Nos. 2 and 3 on the Ringelmann chart. Data on smoke density are important in the smoke-abatement field. The method that is specified and accepted as standard for smoke-density determination by the majority of city smoke regulations involves comparing the smoke shade with the four shades on the Ringelmann chart as published by the Bureau of Mines.2/ This investigation was made to determine the accuracy and convenience of the Smokescope. It was conducted as a part of the Bureau I s air-pollution work, which includes the study of techniques that will promote smoke abatement. The accuracy of the Smokescope was arbitrarily defined as the difference between the Smokescope determinations and the determinations by the accepted, standard method and was expressed as Smokescope correction. Although the corrections obtained were strictly correct only for the two observers and the Smokescope of the investigation, they indicate what might be expected from any observer who uses a Smokescope with reference shades that duplicate those of the test instrument. The report is devoted largely to the data on Smokescope correction, which were taken from a single stack under controlled smoke conditions. Field work, which was done at various locations with different stacks, is mentioned briefly in connection with the comparison of the convenience of the two methods. The data for estimating Smokescope correction were taken for the three variables that were expected to affect the results, namely, the density of the smoke, the amount of light, and the color of the sky behind the smoke.

Jan 1, 1955

By Eugene V. Cilento, R. Clark Lantz, Kevin A. DiGregorio

"A microscope-based spectrophotometer has been developed to measure superoxide release from single pulmonary alveolar macrophages (PAM) or other phagocytes in culture. Results indicate that PAM respond to stimulation by phorbol myristate acetate (PMA). It appears that some PAM do not release 02 upon stimulation by PMA; however, those that do release 0, show differences in: (I) the total amount of 0, released, (2) the rate of release of 02 and (3) the time delay for release of 02. The significance of measuring 02 release from single cells is two-fold. It allows the simultaneous study of 02 release and electrical potential changes across the membrane of PAM and it allows the study of differences in 02 release among cells. Thus, the function of Normal PAM and the dysfunction of PAM exposed to coal dusts can be more closely studied on single cells.Pulmonary alveolar macrophages (PAM), free cells found in the lungs, protect the lungs by removing inhaled foreign debris and bacteria. The macrophages do this by engulfing and then internalizing the foreign matter (phagocytosis). Stimulation of PAM causes the release of super-oxide radical (02) which has been shown to be the primary metabolite involved in the killing of bacteria by phagocytes (3,8,12). The super-oxide radical is highly reactive and is spontaneously or enzymatically converted to other antibacterial oxidants, including hydrogen peroxide (H202), singlette oxygen ( 02), hydroxyl radical toil'), and hypochlorous acid (HOCl) (2, 3,8,11,12).Exposure of PAM to dusts may lead to dysfunction of this cell-type and to a greater risk of lung damage or infection upon subsequent exposure to toxic dusts. To date, much of the research with this cell-type has used cytotoxicity (cell death) as a measure of dysfunction. Although this is an important end point, PAM dysfunction may occur at doses below those which lead to cell death. In addition, dysfunction has been measured using large numbers of cells. In order to obtain a clear understanding of the mechanisms involved in dysfunction, measurements should be made on single cells. As mentioned earlier, one of the major roles of this cell type is its anti-bacterial actions. Therefore, asessment of release of superoxide radical in single cells is important in determining the functional behavior of PAM before and after exposure to dusts. Since measurements of 02 production have not been made on single cells the purpose of this study is to develop the methodology needed to study release of 02 from single cells.Recent studies have suggested that a relationship exists between the release of 02 and changes in the electrical properties of phagocytes. The change in membrane potential is thought to be the initial step in superoxide production (6,9). Stimulants which cause 02 release also cause changes in the transmembrane potential of phagocytes (9) and in the permeability of the cell membrane to ions (6). For example, stimulants which cause the release of 0, from neutrophils have also been shown to increase the membrane transport of Na+ , K+ and Ca+2 and stimulation of macrophages leads to increases in Na and perhaps Ca permeability with a subsequent change in membrane potential. In some cases, phagocytic activity has been shown to depend upon the extracellular concentrations of these ions (6). Holian and Daniele (7) have shown evidence that the redistribution ofcellular Ca in alveolar macrophages is an initial step leading to 0, release. In order to provide direct evidence that 02- production is related to electrical changes across the plasma membrane of phagocytes, these two phenomena must be analyzed simultaneously on single cells. Ultimately, measurements of 0, release using the methodology developed in this study will be combined with electrophysiological tech¬niques to study both superoxide release and membrane potential changes simultaneiously on single PAM, and to examine the effects of coal and mineral dusts on their physiological fu"

Jan 1, 1988

By G. R. Hopkins

One of the largest items in the expense of operating a refinery is the cost of the fuel used in distillation and for miscellaneous purposes such as in the heating of buildings and in the generation of electricity. On a B. t. u. basis, the average refinery consumes approximately one-tenth as much fuel as it produces. Theoretically, the fuel consumption at refineries should be much smaller than this, but furnaces can not be designed to be 100 per cent efficient and, in addition, a large part of the waste heat is low-temperature heat which would not pay for the expense of recovering it. Annual surveys of fuel consumption at refineries have been made by the United States Bureau of Mines, beginning with 1925. During the 5-year period, 1925-1929, the refineries made steady progress in fuel economy. This is evidenced by the computed figures of heat requirement per carrel of crude oil refined, which show a decline from 829,000 B. t. u. in 1925 to 639,000 B. t. u. in 1929 (see fig. 1). In 1930, however, 'the trend in fuel economy was reversed and the quantity of heat utilized in refining the average barrel of crude oil rose to 672,000 B. t. u. There were undoubtedly a number of reasons for the apparent decrease in fuel economy at refineries in 1930, chief of which were the tendency to carry the distillation farther instead of merely topping the crude and a gain in the consumption of waste oils, such as acid sludge, which in actual practice yield less heat per unit consumed than has been theoretically assigned to oil.

Jan 1, 1931

By Michael R. Grubbs

The Bureau of Mines is currently developing methods for reclaiming the metal and mineral values contained in unburned urban refuse. One important phase of this research deals with recovering Mastic from shredded refuse using in electrodynamic separation process. The results of this study have indicated that mixed plastic concentrates analyzing 99.4 percent plastic can be consistently recovered from the light material fraction of shredded refuse, leaving a mixed paper traction analyzing 99.9 percent paper. Recovery of the plastic exceeds 99 percent.

Jan 1, 1972

By H. W. Wainwright

One phase of the research and development work on synthetic liquid fuels conducted by the Bureau of Mines at Morgantown, W. Va. in cooperation with West Virginia University deals with the purification of synthesis gas.2/ Most of the experimental studies on gas purification have been directed toward the removal of organic sulfur from gas, either catalytically or by adsorption with activated carbon. An important part of the purification program has been the development of suitable analytical methods for determining organic sulfur compounds. As the total sulfur content, organic and inorganic, of purified synthesis gas should not exceed 0.1 grain per 100 cubic feet, the need for accurate analytical methods is apparent. It is also apparent that such methods must be rapid if one wishes to evaluate various processes for removing sulfur from gas. The organic sulfur found in most gas produced from coal is usually present as carbon disulfide, carbon oxysulfide, methyl and ethyl mercaptans, and thiophene, with the exception of thiophene, the remaining organic sulfur compounds respond similarly to catalytic treatment and can be removed effectively. Not only does thiophene resist most catalytic treatment, but it poisons some catalysts, rendering them ineffective in removing the other forms of organic sulfur.

Jan 1, 1950