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By M. E. Tyrrell

Despits its high melting point (2,135° C.), resistance to attack by molten metals, and its hardness (8), spinel (MgO?Al203) synthesized by the fusion of alumina (Al 2 0.) and magnesia (MgO) is not used on a large scale as a commercial furnace lining, mainly because of the prohibitive cost. This investigation by the Federal Bureau of Mines was prompted by the possibility of producing synthetic spinel from inexpensive raw materials by methods outlined in U.S. Patent 2,029,773, "Process for Obtaining Products Containing Spinets," dated February 4, 1936. In this patent Ture B. Haglund described a process for recovering crystalline spinels from melts in the system Mg0?Al203-2CaO-SiO2, a system well suited to the use of starting materials such as dolomite CaMg(C03)2, olivine [2(Mg?Fe)0.Si02], and bauxite (Al203?2H20) which are abundant in the southeastern United States. Compositions, ranging from a low content in the eutectic mixture of 35 percent spinal and 65 percent dicalcium silicate (2 CaO?SiO2) to a high of 75 percent spinel and 25 percent dicalcium silicate, were fused in electric furnaces of the arc-resistance and internal-resistance types. So long as members of the system were in proper chemical balance, "dusting" slags could be produced over the entire range of spinel concentration.

Jan 1, 1961

By A. J. Kraemer

This paper on the physical and chemical properties of crude oils from California fields is one of a series of reports on the on the districts of the United States. The paper includes a short discussion of results, tabular data, and individual analyses of eight. California crudes. Analyses of other crude oils from California have been published it Reports of Investigations 2595, 2608, and 2846. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting 65 samples was facilitated by the courtesy of representatives of oil companies in California. The methods used in testing and analyzing the samples are described in detail in Bureau of Mines Bulletin 207. A discussion of the interpretation of crude-oil analyses, as made by the Bureau of Mines, is given in Bureau of Mines Report of Investigations 2806.

Jan 1, 1931

By Murray Greyson

A number of tests were made with various methanation catalysts in fixed-bed, conventional fluidized-bed, and multiple-feed, fluidized-bed equipment to develop catalysts and processes for methanation of synthesis gas. The results show: 1. Methanation reactions may be carried out in 1-inch, bench-scale equipment at high synthesis-gas throughputs with good temperature control of the reactions if a multiple-feed type of fluidized-bed design is used. 2. Nickel is superior to iron as a catalyst for the methanation of synthesis gas, unless the process is considered in terms of a combined operation that produces both gaseous and liquid products. 3. Techniques of catalyst preparation determine, to a large extent, the process life of nickel catalysts, and these techniques must be thoroughly investigated before any conclusions can be reached. 4. Enough data are available to indicate that the sulfur concentrations in synthesis gas that is used for methanation are extremely critical, and maximum process limits should be carefully evaluated.

Jan 1, 1955

By P. G. Clites

This bulletin summarizes the results of Bureau of Mines research on the development of the inductoslag melting process. Inductoslag melting is an induction melting technique using a segmented, water-cooled, copper crucible. The process was developed as part of the Bureau's work on effective utilization of reactive metal scrap, and the process has been applied to melting Ti, Zr, Cr, Co, Fe, Ni, and V. Construction details are given for the segmented crucibles and for both an ingot furnace and a casting furnace. The melting process is described, and results of tests conducted with a variety of reactive metals are given.

Jan 1, 1982

By NIOSH NIOSH

This work explores application of a double alkaline leach method to extraction of alumina from Oregon ferruginous bauxitic materials. The process recovers a greater proportion of alumina from high-silica ores than is possible by a conventional single-leach method. This recovery is accomplished by calcining the ore, removing reactive silica in a preliminary dilute caustic soda leach, and then applying a second leach to dissolve alumina. Ores containing up to 15 percent Si~) 35 percent AI;:) Os, and 30 percent Os were examined. Under conditions of treatment established by experimentation, more than BO-percent alumina extraction was demonstrated. When and if conditions demand the use of low-grade materials, the double-leach process is capable of providing millions of tons of alumina from Oregon ferruginous bauxite.

Jan 1, 1963

By James W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed, to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke; (b) Which coals require special and more intensive treatment in preparation than is now practiced; and (c) Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation. This report is one in this county series that describes the preparation characteristics of the coals of Perry County, Ky.

Jan 1, 1956

This paper on. the physical and chemical properties of crude oils from California fields is one of a series of reports on the oil-producing districts of the United States., The paper includes a short discussion of results, tabular data, and individual analyses of eight California crudes. Analyses of other crude oils from California have been published in Reports, of Investigations 2595,3/ 2608,4/ and 28465/. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1931

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By C. C. Anderson, H. H. Hinson, H. J. Snhroeder

"INTRODUCTION The Eunice field is one of a group in southeastern New Mexico producing oil and gas from so-called limestone-type reservoirs in which the productive strata are dolomite or dolomitic limestone ordinarily, wells in reservoirs of this type show wide differences in their productive characteristics, indicating erratic variations in porosity and permeability. Often there is a large difference in total footage of actual ""pay"" penetrated in neighboring wells and the vertical distribution of the ""pay"" within the productive strata varies. In the Eunice field there are few easily recognizable geologic markers to indicate true structural conditions of the oil-productive section, due to horizontal and vertical gradation in chemical compositions and lithologic characteristics of the strata. Geologic markers are found some distance above the oil-producing zones in this field and consequently they indicate only the general structure. Furthermore, no direct relation has been found between the general structure and the accumulation of oil within the reservoir.Many problems in well-completion and production practice have been met in the Eunice field because of erratic variations in porosity, permeability, in vertical distribution of ""pays,"" and the apparent departure from ordinarily accepted relations of oil accumulation to structure. A detailed study of the position and characteristics of the oil- and gas-producing zones aids production procedure. The methods employed in studying the Eunice field, discussed in this paper, may be applicable to other limestone-type reservoirs."

Jul 1, 1939

By M. H. Chetrick

Since 1945, a commercial-scale pilot plant for the gasification of lignite has been operated by the Bureau of Mines at Grand Forks, N. Dak. The description, operation, and objectives of this pilot plant have already been described in previous reports (6, 7, 8). Although the experimental data obtained from the operation of the externally heated retort have been tabulated and summarized (1, 7), few studies have been made in the correlation of these data. The purpose of the present investigation was to review the data taken in tests of the lignite-gasification pilot plant and to correlate the gas-composition data in terms of their basic factors.

Jan 1, 1950

By Richard L. Rains

During this study in 1983, the U.S. Bureau of Mines examined one mine and five prospects in the Greenwater Valley Wilderness Study Area (WSA). No mineral resources were identified within the WSA. Principal mineral commodities in the WSA are gold and silver with minor lead, and zinc. Two properties have significance; sample analyses indicate the Salsberry Prospect may have gold-silver-lead-zinc resources, and the Graham Jem Mine may have gold resources. The likelihood for development is greatest at the Salsberry Prospect, although the only recorded production from the study area was from the Graham Jem Mine; in 1908 less than 1 ton of gold-bearing ore valued at $25,000 per ton was produced. Gold, silver, lead, zinc, and copper minerals in the WSA are associated with rhyolite dikes and quartz veins in Precambrian gneissic rocks, commonly concentrated in sheared zones along the dikes and veins. Although known to contain silver-lead deposits elsewhere, Precambrian Noonday Dolomite sampled inside the WSA contained no significant mineral values. Much of the WSA is covered by relatively unmineralized Tertiary and Quaternary volcanic rocks. The Bureau collected 140 rock samples at four adits, nine shafts, four trenches, and 33 prospect pits in the WSA. In 1983, 14 lone claims and one millsite within the study area were current. No patented claims, placer claims, or coal, mineral, oil and gas, or geothermal leases were in the WSA.

Jan 1, 1985

By E. J. Lintner, J. R. Thoenen

During the period 1937-40 and until peacetime research was superseded in 1941 by wartime activities , the junior author was engaged in studies regarding the relative efficiency of operating methods in quarries producing crushed stone for mineral aggregates . The results of some of these studies were published as reports of investigations in 1939 and 1940 ; / others were discontinued due to war demands on personnel and time . The published reports discussed the efficiency of particular quarry operations with respect to the time consumed and without reference to costs or mechanical factors . • At the time , the field data were collected for the published reports other data were collected relative to the relationship of the numerous variable factors inherent in the operation of a churn drill to the ability of the drill to produce blast holes . The churn drill is essentially a crusher and depends. for its performance upon the foot-pounds of energy it can impart to the cutting edge of its bit . The gravity stamp mill , so well-known in western gold mines , is essentially the same type of crusher . The ratio of foot- pounds necessary to crush the rock , to the total theoretical energy developed by the falling churn- drill tools , affords a good means of evaluating the efficiency of the tool . This does not include to tal over-all efficiency involving the mechanical equipment of the drill itself or its power unit .

Jan 1, 1947

By John Soule

The Torpedo copper mine in the Organ Mining, District, Dona Ana County, N. Mex., was discovered in 1899, and production of copper from oxidized-ore deposits was begun in 1900. Production continued through 1907, but operations were only intermittent frown 1907 through 1921. The production of copper during these periods amounted to about 3,500,000 pounds. Reserves primary sulfide copper ore were believed to occur below the old workings, and after a detailed examination of accessible workings and a study of drilling records of several private companies by an engineer of the Bureau of Mines, a development program of diamond core drilling was initiated. This investigation was started October 3, 1949; and completed April 30, 1950. Four holes totaling 2,122.3 feet wore diamond-drilled, and 70 samples were analyzed. All drilling was done with a Government-owned hydraulic-feet drill having special rods and core barrels to increase the recovery of core in critical zones. This report describes the location, history, ore deposits, and factual data obtained by the Bureau of Mines from the drilling.

Jan 1, 1951

By J. M. Stuve

Thermodynamic properties were determined by the Bureau of Mines for the intermetallic compound, TiA13. Heat capacities were obtained from 5 to 303 K by adiabatic calorimetry. The derived value of S2 1s is 22.08±0.07 cal/deg¬mole. Enthalpies relative to 298 K were obtained from 298 to 1,413 K by copper-block drop calorimetry. No anomalous thermal behavior was noted in the temperature ranges investigated. Low- and high-temperature data were combined with a known enthalpy of formation at 298 K to give values of enthalpy of formation and Gibbs energy formation, 0 to 1,400 K.

Jan 1, 1974

By E. W. Newman

The Bureau of Mines, in cooperation with the U. S. Geological Survey, developed the property of the Tungsten Metals Corp. by surface trenching and diamond drilling from November 1940 to June 1941 and from August 1943 to December 1943. The purpose of the work was to determine possible reserves of tungsten in the downward extension and lateral eastern extension of three major tungsten-bearing quartz veins. The property is 50 miles south of Ely, White Pine County, Nev., in the Minerva Mining District. Tungsten ore was discovered in the district in 1915, and mining started in 1916. The tungsten ore bodies occur as shoots in quartz veins that occur along faults in limestone. With the exception of a small-scale leasing operation in 1932, the property was idle from 1919 until 1936, when Tungsten Metals Corp. was organized to acquire the mines. Production ceased in May 1945, and the mines were idle until leased in 1947. Development by the Bureau of Mines during 1940 and 1941 consisted of surface trenching, sampling, and diamond drilling 37 holes for a total of 6,959 feet. Subsequent drilling of eight holes, totaling 3,067 feet, in 1943 disclosed additional reserves. This report sets forth in considerable detail the exploration work completed by the Bureau and briefly describes the mining and milling methods employed. Diamond-drill halo logs and sample analyses are shown graphically in the illustrations that accompany the report.

Jan 1, 1950

By E. G. King

In continuation of the study of thermodynamic properties of the common interoxidic compounds of ferroalloy elements, this report gives the results of low-termperature heat-capacity measurements and entropy evaluations of the monotungstates of sodium, magnesium, and calcium. Previous reports4 5/ of this laboratory dealt with low-temperature heat capacities, entropies, and heats of formation of the sodium vanadates. Heat-capacity measurements of the monotungstates of sodium, magnesium, and calcium (Na2W04, MgW04, and CaW04) were conducted throughout the temperature range 51° to 298° K. The entropies at 298° K. were evaluated and then combined with entropy data for the elements and oxides to obtain entropies of formation. This information is an essential part of the data needed for thermodynamic appraisals of chemical reactions of these substances. No similar data for any tungstate are to be found in the literature.

Jan 1, 1961

By John R. Reeves

The data presented in this paper form the chief part of a general survey of the oil-shale resources of Indiana. Other papers* have already been published which contain data an various aspects of this resource. In combination, these papers present data with reference to the following points; (1) distribution of the New Albany shale; (2) amount of shale available; (3) homogeneity and thickness of the formation; (4) amount and quality of the oil obtained from the shale; (5) nitrogen content of the shale; (6) extractibility of the shale and its amenity to breaking; (7) some economic factors bearing upon the utilization of the shale; and (3) other miscellaneous factors and data. In the future, technical work on other phases of the general problem is expected to be done with the object of making a complete survey of this resource which is of much potential importance to the state and nation.

Jan 1, 1923

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content (method 520.11) copper-dish evaporation residue (method 520.11),7 and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and try will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation.

Jan 1, 1930

By A. B. Hooker

A list of permissible mine equipment, tested and approved by the Bureau r. Mines previous to January l, i-)4, , was published in Bureau c Moines In ornation Circular 7207.3/ The l ,.t c -. that dote was complete as to equipmentthen available and in current Information Circular 7210,?+/ published as a supplement thereto, listed equipment approved during; the calendar 1942. Information Circular72x'3,_/ published as a second supplement thereto, ! listed equipment approved during the calendar year 1943. The present listis. Another supplement covering approvals issued during the calendar year 1c)44. The items are numbered crud to indicate the consecutive order in which each typo of machine or device was approved _.c?. in its particular classification. Thus Information Circular 7207 gave 1,t drills and drilling much fines on the Bureau'sactive.. d active list Ih: additional anal approval: were given in 1942 the three issued in 19 and one issued :n 1944- bring the total to `3. Item 111, under. Loading Machines and conveying appeared in lnformation Circular 7207. It is repeated ',tore to _how that on j,,l was granted Curia 1the optional of this loader when modified .'or 2 0. alt ciruits .]

Jan 1, 1945