Search Documents

By D. N. Nilsen

The Bureau of Mines is developing a method to recover Ni, Co, and Cu from laterites containing less than 1.2 pct Ni and 0.25 pct Co. The method consists of the following basic unit operations: (1) reduction roasting, (2) leaching, (3) solvent extraction, and (4) electrowinning. The method reflects three Bureau of Mines objectives: (1) recovery of critical minerals that are domestically in short supply from low-grade domestic laterites, (2) lower processing energy requirements, and (3) solution recycling. This report deals with the extraction of cobalt and the preparation of a suitable cobalt electrolyte by solvent extraction from liquor produced by this method. Nickel and copper are coextracted with LIX64N from an ammoniacal ammonium sulfate leach liquor containing about 1.00 g/l Ni, 0.30 g/l Co, 0.03 g/l Cu, and 0.02 g/l Zn. Cobalt (III) in the nickel-copper barren raffinate is reduced to cobalt (II) with cobalt metal. Reduction of cobalt (III) to cobalt (II) greatly aids subsequent extraction. Commercially available XI-51 extracts about 94 pct of the cobalt from the treated raffinate in one stage in a laboratory mixer-settler continuous circuit. Ammonia loaded on the solvent is removed in two washing steps. About 94 pct of the cobalt then is stripped from the XI-51 in one stage with spent cobalt electrolyte containing about 77 g/l Co and 18 g/l sulfuric acid (H2S04), Electrolytes containing less H2S04 also may be used. Preliminary data indicate that coextracted zinc may be removed from pregnant cobalt eletrolyte containing 3 g/l or less H2S04 with di-(2 ethylhexyl) phosphoric acid (D2EHPA).

Jan 1, 1980

By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938

By H. Herbert Hughes

Iceland spar is a variety of calcite ( calcium carbonate ) characterized by its purity , transparency , and perfection of crystalline structure . It takes its name from the country in which it was discovered . The actual demand for it is small , but the supplies of high - grade optical spar are so meager that the search for it has become international in its scope . Iceland spar is a scientific necessity , for without it research precision and technology would be hampered considerably . The earliest students of mineralogy were familiar with calcite , but the transparent variety was not discovered until early in the seventeenth century , when crystals of it were found in the bed of a stream in Iceland . It received little attention until 1669 , when Erasmus Bartholinus first recognized its powers of double refraction . The results of his investigation were published in a book , " Experimenta Crystalli Islandici , " which appeared in 1670. The law governing the action of the rerracted rays was discovered by Christian Huygens eight years later . The polarization of light rays in passing through Iceland spar was discovered in 1809 by Etienne Louis Malus , a French physicist , who published a paper describing the phenomenon . His work was closely followed by that of William Nicol , who in 1828 designed the Nicol prism which is still used as the source of polarized light in most optical instruments .

Jul 1, 1931

By Clyde M. Pearce

The Lake Superior iron-mining district includes parts of the States of Michigan, Minnesota, and Wisconsin. The laws of each State provide for an industrial commission and for inspection of mines. The following extract from the General Orders on Mines, effective October 25, 1937, issued by the Industrial Commission of Wisconsin, is the only reference to the use of safety catches on mine cages or skips found in the laws and regulations in the Lake Superior iron-mining district: Order 316 - Cages for Hoisting Men. (c) Sides, Gates, and Safety Catches. ***Every cage shall be provided with safety catches of sufficient strength to hold the cage with its maximum load at any point in the event the hoisting cable should break. (d) Testing Safety Catches. The safety catches of cages and skips used to hoist men shall be kept well oiled and in good working order. They shall be tested at least once each month by tying up the cage or skip with hemp rope, lowering a few feet of hoisting cable on top of cage, then cutting the hemp rope, provided that any other system of testing, which is equally effective, may be used.

Jan 1, 1945

By C. P. Lazzara, Y. Miron, A. C. Smith

This report presents a U.S. Bureau of Mines study to identify the causes of self-heating events beneath the floor of a deep underground coal mine. Mine samples from both heated and unheated areas were examined by various techniques, including visual, microscopic, thermal, chemical, and instrumental tests. The combined results led to the conclusion that pyrite (FeS2) oxidation was the prime cause of the beatings. However, adiabatic oven tests of selected samples did not indicate the effect of the pyrite on the self-heating process, probably because of the experimental conditions. A fast, simple procedure to assess the concentration of pyrite in the mine samples was developed, utilizing the reactivity of the sample with an aqueous solution of hydrogen peroxide (H2O2)

Jan 1, 1992

By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful 'Were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938

By Thomas H. Dubaniewicz

The National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, conducted a study of past mine explosions to identify the ignition locations and ignition sources responsible for the most severe explosion events resulting in death. Since the Scotia disaster of 1976, many fatalities from underground coal mine explosions have been linked to nonpermissible electrical equipment ignition sources located in intake air courses. With few exceptions, explosion protected equipment is generally not required in intake air courses of gassy underground coal mines in the US. Cigarette lighters were another prevalent ignition source for fatal explosions ignited in intake air courses. Several mine rescue/ recovery teams have encountered electrical ignition hazards. The study provides evidence that intake air courses of gassy underground coal mines fit the description of certain Hazardous (classified) locations described in the US National Electrical Code®. Class I Division 2 or Zone 2 explosion protection tech¬niques may be used to design intake air equipment so that it does not present an ignition source under normal operation, before mine power is shut down in emergency situations. Nonpermissible circuits in intake air courses that are likely to remain energized during emergencies, e.g. battery powered equipment, should be protected by more stringent Class I Division 1, Zone 1, or Zone 0 techniques, to protect rescue/recovery personnel.

Jan 1, 2009

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By F. B. Tough

An inusual job in controlling a gas well was executed on No. 1 well, Inland Oil and Refining Co., situated on the Alkali Butte structure, Freemont County, Wyoming. The work was done by the company in cooperation with the . S. Bureau of Minos, and resulted in a fuel saving of $5,000 in one season and of a repair job estimated at $15,000, or a total of $21,000. The woll had an open flow of 6,000,000 cubic feet of gas per day with a rock pressure of 560 pounds per square inch. A string of 6-1/4 inch casing with a toothed shoe was set on the cap rock above the gas sand at 2181 feet. Then the well was shut in, the gas worked out around both the 6-1/4 inch and 6-1/4 inch strings, breaking through the ground surface at several points under the derrick. Casing troubles encountered while drilling made it unsafe to attempt Coving the 6-1/4 inch string. Moreover, it was important from the standpoint of good management to make the gas from this well immediately available for fuel in other operations and, in addition, to save the gas from wasting. An ordinary mudding and cementing job would have necessitated sitting down this well for probably two months out of a very short operating season. For these rousons it was determined to mud the well, if possible, between the 6 and 8 inch strings by pumping mud fluid through the connection from the gas clamps. The gas clamps used wore of ordinary construction with a side outlet, making them equivalent to a Braden-hoad. When the mud fluid was pumped through the gas clamp into the space between the two strings, it began to appear inside the 6-1/4 inch string. It apparently entered the well either around the toothed shoe or through a "line sawed" leak in the string and was blown out of the well as fast as it was pumped in. In order to stop the leaks, about a half a gunny sack of finely chopped bull ropa was fed with the mud between the casings as before. The hemp gathered around the valves of the mud pump to some extent, and it also stuck in the casing-head fittings a few times. An obstruction in the casing- head would be removed by permitting the woll to "blow back" for a few seconds, and one in the pump valves, by removing the valves when necessary. In two days' time sufficient hemp and mud had been pumped into these strings to kill external and internal pressure. The wall was shut in and allowed to stand over night. The next day, by opening and closing the master gate at intervals,

Mar 1, 1921

By J. B. Carman

This paper, describing the mining practices and methods at the mine of the Molyb¬denum Corporation of America, is one of a series of similar papers on mining methods in the various mines of the United States being prepared by the Bureau of Mines. The mine of the Molybdenum Corporation of America is in the Red River mining dis¬trict, Taos County, northern New Mexico (fig. 1), The mill and camp are in the valley of Red River, about 7 miles east of the town of Questa; the mine is 1 ¼ miles away, in Sulphur Gulch, a tributary of Red River. The mine is about 600 feet higher than the mill, at an altitude of about 8,700 feet. The climate is cold in winter, but does not interfere serious¬ly with continuous operation. The mine normally produces about 40 tons of sulphide molybde¬num ore per day, which is concentrated at the local mill and chipped to the plant of the Molybdenum Corporation at Washington, Pa.; there it is made into either ferromelybdenum or "molyte" (calcium molybdate), for use in alloys. The ore is mined from narrow, irregular veins by the cut-and-fill method. About 65 men are normally employed underground and on the surface at the mine.

Jan 1, 1931

By J. R. Bartels

Operation of underground coal mine mobile equipment is usually done in a restricted workspace with reduced visibility. This work environment puts machine operators in awkward postures for tasks that require awareness of their surroundings and fast reactions to avoid hazardous situations. Using experienced equipment operators as a source, researchers conducted an investigation that developed a method to gather data on the needs and practices of machine operators while controlling the machine and the reasons for needing particular operational cues. The method used was an interview technique including a survey questionnaire and visual aids. The data gathered defined operator cues and work positions for the cutting and tramming phases of remote controlled continuous mining machines used in underground coal mines. Analysis techniques to determine which cues an operator sees from a variety of positions utilizing a computer simulation is shown to be potentially useful to the mining industry for design of work practices and workplace layout and could impact equipment design and selection for improved worker safety. Conclusions indicate that the survey was a good research tool to collect data and helped investigators understand important visual cues. Using this information, researchers were able to analyze the visual cues an operator can see from a given work position and posture.

Jan 1, 2009

By John A. Organiscak

Enclosed cabs are a primary means of reducing equipment operators? silica dust exposure at surface mines. The National Institute of Occupational Safety and Health recently performed a laboratory study to evaluate which factors on an enclosed-cab filtration system are most significant. The various factors evaluated were intake filter efficiency, intake air leakage, intake filter loading, wind infiltration, use of a recirculation filter, and the use of an intake pressurization fan. The result of this laboratory testing has shown that the two most important factors for an effective filtration system on an enclosed cab were the efficiency of the intake filter and the use of a recirculation filter. A higher-efficiency intake filter considerably increased the quality of the intake air that was delivered into the enclosed cab. It also was determined that air leakage around the intake filter notice-ably reduced its air cleaning effectiveness. The second key factor is the use of a recirculation filter, which was shown to improve the air quality in the enclosed cab by six to 12.7 times more than the intake filter alone. The reason for the significant improvement was that the cab air was constantly drawn through the recirculation filter, thus continually filtering the dust out of the air.

Jan 1, 2010

By R. L. Stein

For the past several years, the Bureau of Mines has been actively engaged in developing two new oxygen self-rescuers through research contracts with private industry. These new oxygen self-rescuers are designed to be carried by a miner while he is at work and are used during emergency escape, supplying high-purity oxygen to the user and, at the same time, absorbing carbon dioxide (C02), The first of the two new self-rescue breathing devices is a 10-minute, self-contained apparatus developed by the Mine Safety Appliance Co, Size and weight of the unit are comparable to the currently used self-rescue devices. The second device, designed and developed by Lockheed Missiles and Space Corp., is 8. 4.5-lb package which supplies 1 hour of oxygen to the miner. Both devices have a canister which contains the oxygen-producing and CO2-absorbing potassium superoxide chemical, a breathing bag, a bite-type mouthpiece, noseclip, goggles, and hoses connecting the canister and mouthpiece. When needed in an emergency, the miner removes the outer protective cover and dons the unit. For both devices oxygen is immediately available once the mouthpiece is placed in the mouth. These two new units have received prototype approval from the National Institute for Occupation and Safety Health (NIOSH) and the Mining Enforcement and Safety Administration (MESA).

Jan 1, 1976

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By Fred N. Kissell

A parachute-type stopping intended for changing the course of mine ventilation air during mine emergencies has been designed and tested. Some production uses are also visualized for metal mines. Preliminary tests in the laboratory and underground indicate that the parachute stopping is a workable concept, but further developmental research is required.

Jan 1, 1975

By Eugene T. Sheridan

The annual survey of the fuel-briquet industry by the Bureau of Mines, United States Department of the Interior, revealed that 21 fuel-briquet plants in 11 States were in operation and reported production in 1956. The demand for fuel briquets in the United States has gradually declined since 1948, and the number of operating plants has decreased from 36 to 21. Also, the annual productive capacity of the industry has decreased, although not a proportionate amount because most of the plants that were abandoned were small and in most instances had a designed capacity of less than 25,000 tons per year. In 1956 the 21 active plants had an annual capacity of 3.7 million tons (table 2), which was only 20 percent less than the total capacity of the 36 plants in 1948. This indicates that most of the larger plants have remained active, even though operating at reduced rates, and the average capacity of the industry has increased from 130,000 tons per plant in 1948 to 177,000 tons in 1956. Since 1948 operating rates have decreased from 67 percent to 41 percent of annual capacity.

Jan 1, 1958

By A. W. Ambrose

"A need exists for men in oil-field production work who correspond to the mining engineer of a large mining property. Some oil companies prefer to call such an employee a resident geologist, resident engineer, or a petroleum technologist. He should perhaps be more correctly termed a petroleum production engineer. The duty of such a man is to apply his scientific and geologic training practically to oil-field development work.He should be, by education, a mining, civil, or mechanical engineer, with a knowledge of geology and chemistry. Upon completion of his education, such a man should spend several years in the oil-fields. There are two means of gaining proper experience. The first method is to work for an oil company in making a detailed study of each well, collecting data on the history and production, followed by a preparation of good records, from which well logs can be prepared. From the well logs, the geologic cross-sections, peg-models, and structure contour maps can be made. These allow a comparable, detailed study of each well, which is necessary to solve many of the problems. Along with this the engineer should visit drilling wells daily for collection of samples of formations and for a proper study of how they drill. He should form friendly relations with the drillers and production foremen. The second method of gaining proper experience is to start work as a roustabout, pumper, or on the pipe¬line gang, finally working up to a tool-dresser. After three or four years of such work, the engineer may be classed as a petroleum production engineer."

Jan 1, 1920

By W. Hermanson

This report, which covers the period from January 16 to October 21, 1974, describes the work performed in compliance with the requirements of contract no. H0242028 and modifications 1 and 2 thereto. The purpose of the contract was to further reline and modify three of the canopies (shuttle car, loader, and roof drill) which were developed under contract no. H0220031, and to conduct further testing and demonstration of the relined designs. Modifications I and 2 involved conducting further in-mine evaluations of the face. drill and cutter canopies, also developed under contract no. H0220031. In addition to the canopy modifications, the contract involved an evaluation of an operator's seat concept for a shuttle car which was developed for the USBM by another contractor.

Jan 1, 1974

To develop effective noise controls for continuous min-ing machines (CMMs) to reduce worker noise exposure. Background Noise-induced hearing loss (NIHL) is an occupational illness caused by chronic exposure to excessive sound levels. For underground coal mine workers, NIHL continues to be a serious health issue. Analysis of hearing loss data suggests that by retirement age, 70%?90% of U.S. coal mine workers will have a hearing impairment. Operated in the confined spaces of underground mines, large industrial mining equipment often produces sound levels that can be harmful to workers. Of all equipment used in underground coal mining operations, CMMs account for the most noise overexposures. To reduce the occurrence of noise over-exposures, engineering noise controls must be developed for the CMM.

Sep 1, 2008

By E. L. Garton

An active list of permissible explosives was published in July, 1931, as part of United States Bureau of Mines Report of Investigations 3134, under the title of "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1931." Changes in that list were authorized in August, September, October, November, and December, 1931, and January and March, 1932, as published in Reports of Investigations 3140, 3147, 3150, 3155, 3158, 3161, and 3163, respectively. By these changes the following explosives were added to the active Permissible list: Austin Red Diamond No. 1, L. F. Gel-Coalite W, L. F;" Austin Red Diamond No: 5. Gen-Gel No. 2. Black Diamond Nu-Gel No. 1 Genite C-1 Burton 1, L. F. Liberty No 4 Burton 2, L. F. Liberty No. 5 Burton 10, L. F. Peerless D Burton 12, L. F. Permigel 1, L. F. Burton F, L. F.

Jan 1, 1932