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By G. N. Carlson, C. H. Hazelroth, D. R. Dorrance

"Located on the north shore of the St. Lawrence River at Pointe Noire, Quebec are the agglomeration and ship-ping facilities of the Wabush Mines complex. Here, the specular hematite concentrate from the Scully Mine is received for further processing. Modern facilities for handling the ore, either to the 1plant or to stockpile, provide quick and efficient operation of the ore receiving station. Physical preparation of the ore for balling is accomplished with regrind ball mills, filters, bentonite crushing and drying facilities, pumps and related conveying circuits. Rotating table feeders deliver the reground and de-watered ore from storage bins to balling drums, where green ball or green pellet formation is achieved. The green balls are then conveyed to the indurating section. Three Dravo-Lurgi travelling grates, producing a total of 6,000,000 long dry tons of pellets per year, are used in the indurating phase of the operation. These grates, having 38 windboxes and firing at a temperature of 2,500°F, harden the pellets for shipment to various blast furnaces throughout the world."

Jan 1, 1969

By M-A. Thibault, C. Gauthierand, J-P. Gagné, J-Y. Carrier, P. Rochette, G. Dufour

"Anodes consumed in the electrolytic process for the production of primary aluminium are considered consumables. They need to be replaced at regular intervals of approximately one month. The so-called anode butts which are removed from the cells contain the metal supports (rods), cast iron thimbles, crust and residual carbon material. Cleaning is required to remove the waste material before the rods are fitted with new anodes. An inspection is required to ascertain if repairs to the rods are necessary. Presently, this inspection is carried out visually. ST AS, in 2004 in collaboration with Alcoa Deschambault, initiated a project to develop an automated inspection system. The objectives were to find a technical solution to perform these functions with a very simple system. Such a system was designed around ""artificial vision"". The inspection system developed uses only one fixed camera and does not require a separate step in the process for the anode rod assembly to perform the inspection. This paper presents the initial steps of the work performed to develop the equipment and software as well as a summary of the results obtained."

Jan 1, 2006

By Jerry Danni

In order to remain viable today, corporations must view the environment as a strategic issue, and integrate environmental management throughout the organization. Corporate programs that used to be based primarily on regulatory compliance now must emphasize strategic environmental management systems, and must integrate these environmental systems with basic business functions. The mining industry today is global, and must have an organizational structure that can embrace different cultures, physical settings, and regulatory regimes. Sound environmental management practices are not different from good management principles. An effective environmental management system should be a complementary system to an organization?s overall management framework, integrated and aligned with the existing management structure. Integrating environmental management into core business functions is just good business. An effective environmental management system is a critical component of a company?s commitment to environmental, social and economic accountability. This paper presents the elements of the Kinross Gold Corporation strategic environmental management system and discusses the integration of the environmental management system into the core business functions throughout the Company

May 1, 2003

By MKS Vel, S. Mukhopadhyay, R. Mishra

Off late, the criteria of selecting the refractory have acquired a trend line aiming to a cleaner environment and the utmost importance is given to the eco-friendly approach. The stainless steel making furnaces normally use mag-chrome refractories for the obvious reasons of changing slag basicity from acidic to basic. Such refractories generate toxic fumes and compounds with hexavalent chrome, which is unhygienic if inhaled. The present paper describes the development of a chrome free alumina magnesia carbon refractory, it's different test properties, simulative testing and microstructures. The optimum quantity and distribution of carbon in the brick restricts the carbon pick-up by the steel. Bricks with the same composition were manufactured in the commercial scale and used in a stainless steel making furnaces in USA. The performance of same refractory in this furnace was quite encouraging and at present the same quality brick has become a normal practice in this furnace. Since no chromite is used in making this brick, so no toxic compounds are generated environment remains pollution free.

Jan 1, 2004

By Kostas Fytas

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (ex. pyrite) contained in rock are exposed to air and water and subsequently oxidize to produce low pH water. This acid effluent has the potential to mobilize any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pyrite is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidizes a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

May 1, 2001

By Marcel Vallée

"This text consists of two parts, comments on "Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits," by S.C. Dominy, P.R. Stephenson and A.E. Annels, Volume 10, No. 3, pp. 215-233, and related comments on some features of the JORC Code.This paper is, in many respects, a very elaborate and valuable account of the problems encountered in the estimation and classification of high-nugget gold deposits. However, in some key areas, it appears to fall short of its objective to help "resolve satisfactorily most issues" and "contribute to improved estimation and classification" (abstract). One must realize that high-nugget effect gold deposits constitute a very narrow field, despite the occasional bonanzas. This is a field of mostly smaller sized deposits, where limited success and a significantly higher rate of failure occur relative to larger deposits of mostly lower grade. This is shown by the six deposits described in the paper. Thanks for contributing to greater understanding of these complex and nevertheless challenging deposits."

Jan 1, 2002

By T. Cutard, E. Yeugo Fogaing, C. Gault, H. Marzagui, N. Prompt, M. Huger, C. Deteuf

This paper deals with studies made in the field of the French research network PROMETHEREF. Several refractory castables are considered in this program. In the present paper, one of these materials is considered, it is a low cement castable based on andalusite aggregates. A particular attention is paid to microstructural changes during the first heating and on their effects on the high temperature mechanical behavior. Microstructural evolutions have been characterized by the way of dilatometry, scanning electron microcopy and X-ray diffraction. In-situ observations by environmental scanning electron microscopy gave complementary results on these high temperature microstructural changes. They deal with microcrack formation, phase changes, crystallization, liquid phase formation and sintering. By propagation of ultrasonic waves, high temperature continuous measurements of the Young's modulus have been made. Results confirm the existence of microstructural changes and allow to quantify the Young's modulus variations all along specific thermal cycles. High temperature four point bending tests and room temperature tensile tests were made in the same temperature range. Behavior evolutions could be found and interpreted with the help of previously mentioned results.

Jan 1, 2004

By Mary Jean Buchanan

The last twenty years have seen the advent of environmental concerns and sustainable development, and the industry has witnessed the rise of Environmental Management Systems and their registration through several international standardization systems such as EMAS and ISO 14001. Beyond EMS and ISO 14001, which new goal the mining industry should aim at. Life-cycle assessment (LCA), another tool from the Environmental Management System series, is also on the rise and currently the object of an international standard (ISO 14040:1997). Through LCA, it is possible to assess the environmental aspects and potential impacts associated with products and services, taking into account all the activities required for its fabrication, its use, its transportation and its disposal. How could LCA be applied to the mining industry ? Is the international market pressurizing on mining companies to supply an ?environmental ore?? What about the automobile industry and its use of LCA ? Will it influence the ferrous and non-ferrous metal industry, suppliers of raw materials ? This paper presents a review of possible applications of LCA for the mining industry as well as world trends.

May 1, 2001

By K. Matsuura, M. Ohno, T. Tokunaga

"Recently, weight saving of automobiles has been strongly required to solve the global environmental problems. Mg alloys are one of the promising candidates as a new material for automobile components. However, the application of the Mg alloys is limited due to their poor corrosion resistance. In the authors’ preliminary study, an Al/Mg/Al clad sheet was fabricated by hot extrusion and subsequent hot forging. The clad sheet exhibited a high corrosion resistance and excellent super plasticity. More specifically, the elongation of the clad sheet was as high as 550%.Importantly, despite that the elongation of Al itself was only 40%without cladding with Mg, the ductility of Al was greatly improved in the form of the clad sheet. In the present study, in order to clarify the mechanism of the superplastic deformation of the Al part in the clad sheet, the microstructure evolution of the Al during the tensile de formation is investigated. The tensile tests were conducted at a temperature of 573 K and at a strain rateof1.0×10-3s-1. The Al exhibited fiber-type texture at the beginning of the tensile deformation, and brass-type texture after the elongation of 50%.INTRODUCTIONMg alloys have been gaining attention because of their excellent properties e.g. light weight, good recyclability and high electromagnetic shielding. However, their practical applications have been limited due to their poor corrosion resistance. In the authors’ previous study, in order to solve this problem, Al coating on Mg alloy by hot extrusion has been proposed, and the Al-coated Mg alloy plate was fabricated(Tokunaga, Matsuura, &Ohno,2012). The plate was hot-rolled and an Al/Mg/Al clad sheet was fabricated. No cracks or debondings were observed at the Al/Mg interface. The sheet exhibited a high corrosion resistance in a comparable level as pure Al. Also, the sheet exhibited a large and uniform elongation of 550%in a tensile test at a temperature of 573 K and at a strain rate of 1.0×10-3s-1without any breakings or debondings of the Al part(Tokunaga, Matsuura, &Ohno,2014).Mg alloys have been known to exhibit a superplastic characteristic when the grain size is small. However, it is known that the pure Al does not generally exhibit the super plasticity. As mentioned above, the Al-coated Mg alloy sheet exhibited 550% of elongation in the authors’ previous study (Tokunagaet al., 2014). However, the pure Al itself showed only 40% of elongation, while the Mg alloy itself exhibited 800% of elongation. Thus, it has been demonstrated that the pure Al was super plastically elongated when it was bonded with the Mg alloy. Generally, deformation mechanism of the super plasticity of the Mg alloy is known as a grain boundary sliding. On the other hand, the mechanism of the superplastic elongation of the pure Al is still unclear. The purpose of the present study is investigation of the deformation behavior of the Al part in the Al/Mg/Al clad sheet during tensile de formation."

Jan 1, 2018

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By D. Xia

Pt-Bi intermetallic Nanoparticles was prepared by the polymer-anchor method. The electron micrographs shows that the dimensions of particles sharply distribute in the range of about 3-6 nm. The elemental ratio of Pt/Bi in the bimetallic particles is estimated by the electron probe microanalysis method. Pt-Bi intermetallic Nanoparticles shows a higher activity for the ORR than pure Pt. No significant dependence of the oxidation currents on the rotating speed of the electrode could be observed in the presence of methanol. This clearly indicates that the Pt-Bi is inactive to methanol.

Jan 1, 2005

By Andreea Catalina Gluhoi

The oxidation of propylene and methane has been investigated over two series of Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 catalysts (M, MI, MII =Li, Rb, Mg, Mn, Ce, Zr). Whereas the effect of the presence of MOx or MOI x/MOII x on the oxidation of methane is relatively small, a large enhancement in activity is observed for propylene oxidation. Synergistic effects have been observed by combining ceria or a transition metal oxide (high oxygen storage capacity) with an (earth) alkali metal oxide.

Oct 1, 2003

By J. Zinck

The management of mine wastes generated by both active and inactive mining is an ever more challenging issue. The cost to manage and treat mine wastes, including tailings, waste rock, treatment sludge and slag, is estimated at over $50B in Canada and the United States alone. Cost-effective technologies are required to meet both short and long term challenges and increasing environmental standards. This paper will provide an overview of novel and conventional technologies to manage mine waste particularly in the areas of waste stabilization, treatment and disposal technologies.

Jan 1, 2004

By S. Z. R. Pinkney

Positron Emission Tomography (PET) is a medical technique that produces three dimensional images of the body, commonly to aid diagnosis and treatment of tumours. PET has been developed by the University of Birmingham in order to track particles in an opaque system which is known as Positron Emission Particle Tracking (PEPT). The object to be tracked is irradiated. As the radionuclide decays positrons are produced; when these collide with electrons a pair of concurrent parallel back-to-back gamma waves are emitted and detected, from which the position of the object can be calculated. Stirred media mills are used for particle size reduction. The mill is usually operated at high solids loading with grinding media and has a polyurethane or polyurethane-lined steel pot and is thus opaque. For this study grinding media has been directly irradiated and tracked using the PET camera during the grind. The stirred media mill can be divided into cells of equal volume known as voxels. The fraction of the total time the irradiated media spend in each voxel can be shown in an occupancy diagram. The mean velocity and kinetic energy of the media for each voxel are calculated and also plotted. In occupancy and kinetic energy plots colour indicates the value of the voxel, in dimensionless time and Joules respectively. The arrow in velocity plots shows direction and length of arrow indicates magnitude of the mean velocity for the voxel. From these diagrams and further data analysis a detailed understanding of the flow patterns, media behaviour and high energy areas of the mill can be developed. Variables considered were the tip speed of the impeller and density of the grinding media. It was found that the grinder has three distinct regions: above, at and below the impeller with each region having its own flow patterns and velocity and kinetic energy profiles. These are different for each variable and so are used to characterise the grind. Tip speed and density of the grinding media were shown to both affect the velocity of the media and the proportion of time spent in the each region of the grinder.

Aug 1, 2013

"In the UK, Ireland, and Western Europe, the mineral resource and reserve reporting standard is the PERC Code, developed and maintained by the Pan-European Reserves and Resources Reporting Committee, which is a standing committee set up under the auspices of a number of professional organisations which include the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI) to develop a Pan-European reporting code. The PERC Code supercedes the old IMMM Reporting Code 2001 and is recognised by the UK securities regulators and stock exchanges.""FOREWORD1 The Pan European Reserves and Resources Reporting Committee (PERC) Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (further referred to as 'the Code') sets out minimum standards, recommendations and guidelines for Public Reporting of Exploration Results, Mineral Resources and Mineral Reserves in the United Kingdom, Ireland and Europe. The history of development of this code is summarised in Appendix 4.This 2008 edition supersedes all previous editions of The Reporting Code and the IMM Reporting Code.INTRODUCTION2 In this edition of the PERC Code, important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Code clauses using indented italics. They are intended to provide assistance and guidance to users in interpreting the application of the clauses in the Code. The same indented italics typeface formatting has been applied to Table 1, and to Appendices 1 and 2 which form part of the Guidelines.3 The Code has been adopted by the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI), and is therefore binding on their individual members.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that should be considered in addition to the Codes of Ethics normally applying to members of professional institutions."

Jan 1, 2003

By Simon P. Fricker

Gold drugs have been used for the treatment of rheumatoid arthritis since the mid 20th century as disease-modifying antirheumatic drugs (DMARD) class. Methotrexate is often the preferred DMARD, and with the advent of new therapies gold drugs are now used infrequently. Since the introduction of auranofin in 1985 there has been no new clinically approved gold drug. In spite of this apparent lack of progress there has been a great deal of interest in the use of gold compounds for cancer therapy and early promising indications were achieved with a gold phosphine complex [Au(dppe)2]Cl. This compound was not entered for clinical trials, however, due to problems with cardiotoxicity highlighted during pre-clinical toxicology studies. Gold(III) is isoelectronic (d8) with platinum(II) and likewise forms square planar complexes. It is therefore tempting to speculate that such complexes would have similar antitumor activity to cisplatin. In order to stabilise the gold(III) oxidation cycloaurated complexes were synthesised with a single mononegative bidentate ligand, damp, (2-[(dimethylamino)methyl]phenyl), and two monodentate anionic ligands e.g. Cl or acetate. The damp ligand forms part of a five-membered chelate ring. The monodentate ligands are readily hydrolysed and are available for substitution. These compounds had limited anti-tumor activity in in vivo against human tumor xenografts. Mechanistic studies indicated that these compounds had a different mechanism of action to cisplatin. An alternative molecular target for these compounds is biologically important thiol-containing molecules such as the cysteine protease cathepsin B. Modifications were made to the Au(III) damp structure to give compounds with a six-membered chelate ring. These compounds were shown to be inhibitors of cathepsin B. Compounds were also tested for cytotoxicity against a panel of human tumor cell lines. Three compounds were selected for further evaluation against a human colon tumor xenograft. The compounds showed modest anti-tumor activity but with no marked improvement over the parent Au(III)damp complexes. Initial indications are that Au(III) compounds targeted against disease-specific thiol-containing biological molecules have potential as drugs, particularly for cancer. However, further work is required to produce a target-specific drug with a suitable pharmacological activity and toxicity profile.

Oct 1, 2003

"“Developed by the CIM Sub-Committee, these guidelines are an addition to Guidelines Specific to Particular Commodities which are appended to the CIM Estimation of Mineral Resources and Mineral Reserves Best Practice Guidelines.Rock Hosted DiamondsJennifer Burgess, Consultant, Sechelt, BCNeil Buxton, WWW International Diamond Consultants Ltd.Darren Dyck, BHP Billiton Diamonds Inc., Kelowna, BCMartinus Oosterveld, (De Beers retired), Plettenberg Bay, South AfricaRichard Routledge, Scott Wilson Roscoe Postle Associates Inc., Toronto, ONMalcom Thurston, De Beers Canada, Toronto, ONPreambleDiamonds are produced commercially from intrusive rock, consisting of kimberlite and lamproite, and from alluvial and marine placer deposits. These guidelines apply to rock deposits; the term ""diamonds"" herein refers to natural diamonds; ""diamond deposits"" refers to diamonds hosted in kimberlite and lamproite rocks; and ""diamonds"" and ""stones"" are interchangeable.The CIM Best Practices General Guidelines for other commodities are also applicable to diamond deposits, however, because of diamond's distinguishing aspects, additional guidelines are appropriate as published in the CIM Guidelines for the Reporting of Diamond Exploration Results and these Best Practice Guidelines for estimating Mineral Resources and Mineral Reserves (MRMR).Diamonds differ from other minerals. Firstly, they occur as discrete particles in concentrations as low as parts per billion. Secondly, the release of diamonds from the kimberlite or lamproite host rock is a function of the excavation and treatment process. Thirdly, the value of diamonds varies from deposit to deposit and varies with stone size within a given deposit. These aspects must be considered when sampling, evaluating the resource and establishing the reserve of a depositThe product from metallic mineral mines is generally quite liquid in terms of number of potential buyers, and the commodity prices and price structure are published daily. In contrast, most diamonds are valued in the overall market context only 10 times a year in ""sights"" and the marketing of diamonds is dominated by a small number of organizations. Diamond valuation is more akin to industrial minerals valuation in that process recovery is important at the ""assay stage"", the impact on price of new goods arriving on the market must be evaluated, and product quality must be acceptable to potential buyers."

Jan 1, 2003

By Michel Aubertin

Using mine wastes as backfilling material for underground stopes has been a common practice for more than 60 years. Waste rock and tailings are used as filling materials because they are available at a reasonable cost to support the rock walls. Backfilling is also very advantageous because it reduces the amount of mine waste disposal on the surface. In underground mines, the backfill must first ensure stability of the opening, while increasing recovery of ore and minimising dilution. It is thus critical to accurately evaluate the pressures exerted on the walls and on the barricades placed near the base of the stope. In this presentation, existing solutions for evaluating the stresses on stope walls and barricades are briefly reviewed. The authors then present recently developed analytical solutions that take into account the stress transfer from the backfill to the walls in the stope and access drift. The stress state solution, which is based on arching theory, considers the influence of the stope geometry and barricade position within the drift. The method gives the pressure generated by partly or fully submerged backfill. The solutions apply shortly after backfill deposition, when the effect of pore water pressure cannot be neglected, and also for long term conditions under a fully drained state. Experimental testing and numerical modelling results are used to validate the proposed equations. Both numerical and analytical results show that the total pressure on barricades can be significantly increased by water pressure, while the effective stress is decreased (compared to dry or drained conditions). A discussion follows on the implications of the results for backfill applications.

Nov 1, 2008

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By R. A. D. Pattrick, D. A. Polya, D. J. Marsh, J. -J. Bao

"Abstract-The utility of high-density stream sediment and stream water sampling to the exploration for silver deposits was investigated by the study of the epithermal Ag-Au base-metal prospect at Lagalochan in western Scotland. The geology of Lagalochan is dominated by a calc-alkaline Caledonian intrusive complex emplaced into Dalradian Supergroup rocks (Harris et al., 1988a). The complex consists of subvolcanic porphyrytic rocks associated with intense hydrothermal alteration and brecciation. Early Cu-Ag-Mo-rich mineralization is found in the core of the complex with later Pb-Zn-Ag-Au-As-Sb-rich mineralization toward the margins (op. cit.).Stream sediment sample analysis spatially resolved the Cu-rich and Ag-rich mineralization. Ag and Cu anomalies relative to local background values were found in all size fractions analyzed (-125 µm, +125 µm, +180 µm, +250 µm) but the more pronounced anomalies were found in the -125 µm fraction. The coarser fractions generally revealed more erratic but longer dispersion trails. The separation of Cu-rich and Ag-rich mineralization is also apparent in the distribution of relatively high dissolved Cu and Ag in stream waters, particular when expressed relative to the solute load as Cu/TDS and Ag/TDS.The mineralization at Lagalochan is indicated by Ag, Cu and Pb stream sediment and water concentrations that are anomalous with respect to local backgrounds, but are difficult to distinguish from regional backgrounds. This emphasizes the further potential of high-density stream water sampling, in particular, as a viable geochemical exploration tool on a sub-regional scale for epithermal deposits in relatively unpolluted upland terranes."

Jan 1, 1995