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By D. Lemieux

A gold bearing pyrite concentrate was treated at the pilot scale for the extraction of gold. Mineralogical analysis of the concentrate identified gold to be mainly present in the form of a solid solution in pyrite. This gold distribution resulted in a poor extraction yield of 55% by direct cyanidation. A piloting campaign including an oxidative pre-treatment by roasting in a fluid bed was followed by treatment with halogens for gold extraction has led to a gold extraction yield of 96.5%. Sulphur removal during the oxidation was very efficient at >99.5% and gold extraction by the halogens was completed within a 1 hour contact time. The piloting was performed on a 300 kg sample and uses a diluted solution of hypohalites as the oxidizing agent for gold extraction. Sulphuric acid was injected in the reactor during the halogens treatment to lower pH to 2. The diluted solution of hypohalites (1-3%) was generated by electrolysis during the piloting campaign in a membrane-less electrolysis cell. The extracted gold was recovered over activated carbon in column and the gold depleted brine was treated for impurities removal and recycled for further gold extraction. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable, the Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.

Aug 1, 2013

By S. Y. Mostowy, P. W. M. Shibley

"When Texas Gulf Sulphur Company discovered the Kidd Creek ore body in 1964, a crash program began almost immediately for the design and construction of a modern concentrator. It was necessary to mill two distinct ore types; one containing copper and zinc, the other lead, silver and zinc minerals. The final concentrator design was to handle 9,000 tons of ore daily in three circuits. One circuit was to treat copper-zinc and another lead-zinc ore exclusively on a permanent basis. A central circuit was designed with adequate flexibility to treat either of the above ore types in accordance with planned mining schedules. Ecstall Mining Limited, a wholly owned subsidiary, now operates the mine and concentrator complexes for Texas Gulf. The mine is located 15 miles north of Timmins and the concentrator 15 miles to the north-east along Highway 101. The ore is hauled from the mine to the concentrator over a 17-mile railroad. Initial milling operations began in November, 1966.1 - ABSTRACTThis paper deals with bulk reagent handling at the Kidd Creek concentrator. The reagent section at Kidd Creek has operated excellently since milling began in 1966. The bulk handling techniques are satisfactory. They have contributed substantially to good working conditions, economical practices and metallurgical efficiencies. The bulk handling features described should be considered in existing and proposed concentrators."

Jan 1, 1970

By M. Bertrand

Oxalic precipitation is usually applied to process radioactive wastes or to recover actinides from a multicomponent solution. Precipitation reactions being highly sensitive to many operation parameters, the computer simulation appears to be a very effective tool to forecast the evolutions of the system subjected to various operating conditions. This study focuses on the tetravalent uranium oxalate precipitation modelling which combines population balance and hydrodynamics. Both experimental and numerical studies are carried out in order to analyse the reactor design influence on the precipitate characteristics. The simulations taking into account primary nucleation and crystal growth are in agreement with experiments.

Aug 1, 2010

By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By Ajit K. Sinha

"Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentaryhosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3070 to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By F. W. Crossland

Losses of metal are often traced to incorrect pH/ORP signals in flotation, leaching, extraction, electrolysis, and precipitation processes, aggravated by pressure changes. IC Controls, a Canadian mining sensor manufacturer, developed a new superior pH/ORP sensor that stops metal losses, reduces environmental footprint and contributes to sustainability. The cause of incorrect pH/ORP signal is rooted in the reference. Reference junctions are designed to allow diffusion of reference chloride ions into the process but also allow process ions to diffuse into the reference. This development is important to mines and hydrometallurgists where sulphide, cyanide, ammonia and other poisoning ions are present in the process. These ions react with reference electrolyte components causing the signal to change, drifting from the correct process value. With fluctuating process pressure, ion in migration dilutes the electrolyte producing similar signal drifts. If process ion in-diffusion could be stopped, the pH/ORP signal would be accurate. IC Controls new pH/ORP sensor stops process ion in-diffusion, and remains accurate over long periods. New processes using higher pressure and fluctuating pressurized reactors will greatly benefit from stable pH readings. Similar to IC Controls' proven model 642 Mining pH sensor, our new model 647 contributes to sustainability through reducing disposal costs from waste reagents, lost metal and fewer used sensors.

Jan 1, 2014

By E. Marcotte

"Technology developments and improvements are imperative to maintain a viable mineral processing industry. In order to achieve optimum implementation of technology in processing plants, safety conscious and efficient work forces are required. Effective management methods are required to prevent employee injuries, equipment or environmental damage and process losses. Good leadership also provides for employees to perform their work in the safest and most efficient manners to attain optimum recoveries of the valuable minerals and produce high quality mill products. Equipment and processes must be designed, operated and maintained as required to assure safe and efficient mineral processing.INTRODUCTIONThe Canadian mining industry must contend with many challenges to attain and maintain a competitive position in today's global market. Canadian Mineral Processors play a vital role in meeting the challenges and achieving optimum mineral productivity.Ongoing technology developments and improvements continue to be imperative to maintain a viable mineral processing industry. The efficient implementation of technology developments requires a safety conscious, skillful and productive work force.In addition to technical and human resources, challenges may also include governments, labour unions or environmental advocates who at times may appear to be misguided or unrealistic. Canadian Mineral Processors must not allow themselves to be overwhelmed by these apparent obstacles but must use their demonstrated ingenuity to achieve successful solutions.It should be recognized that the majority of the Canadian work force are, in fact, a potentially talented and skillful people with ambitions to excel. As leaders of people, we must provide the methodology, incentive and direction that will allow our work forces to realize their ambitions. If the potentials of our work forces are not recognized and leadership is not properly exercised much loss will occur. That is, safe effective and efficient work will not be achieved."

Jan 1, 1993

By Angeles Mendoza Sammet

Based on the analysis of issues associated to conflicts between communities and mining companies in Mexico, this paper suggests actions to make mining more sustainable in Mexico. Interviews with key informants and a revision of documental information available on the internet provided information on 15 cases of conflicts in various parts of the country. The issues varied from incompliance with environmental law to assassination of community members opposing mining. The analysis concludes that mining is not sustainable in Mexico. Both mining companies and the Government of Mexico can make changes to improve sustainability. Mining companies could take a proactive approach and engage in consultation with communities before starting operations. Sharing information with communities on environmental management programs and monitoring results can be a way to start building trust and demonstrate environmental commitments. Companies can implement and evaluate CSR policies to ensure that all staff and contractors are trained on them to reduce and/or prevent corruption and violations of human and indigenous rights. Only 3 of the 15 companies had clear social responsibility policies or sustainability targets, but no reports evaluating them. Complying with the law does not make a project sustainable because of corruption, deficient enforcement, and gaps in legislation. The Government of Mexico should address the following points to make mining more consistent with sustainable development. Update the mining legislation to introduce sustainable development principles and consultation. Incorporate the notion of Free, Prior, Informed Consent (FPIC) for Indigenous People (IP) on all applicable Mexican laws or regulations. The government should not grant concessions on protected areas or indigenous lands without extensive meaningful consultation with the public, IP and land owners. Finally, it is vital to increase SEMARNAT?s capacity to review impact assessment reports and inspect and monitor environmental compliance along the life cycle of projects.

Aug 1, 2013

By M. Timberlake, A. J. Jonaitis

"The DENVER Tube Press is a simple, high pressure (1500 PSI (100 bar)) filtration unit, developed for processing difficult-to-dewater materials and to produce a handleable filter cake and clear filtrate product.Lab and Pilot testwork conducted in Australia on coal fines (55-70% -35 micron (400 mesh)) have shown that total moisture contents of less than 20% are consistently achieved in the final cake products from the Tube Press.currently, these coal super fines are sent to waste due to uneconomical mechanical dewatering methods, which were only able to reduce total moisture levels in excess of 30%. Calculated, throughput rates for the 500 series Tube Press exceeded 1700 kg/hr (3750 lbs/hr). Feed solids concentration requirements are between 45 and 50% to achieve these results.INTRODUCTIONThe DENVER Tube Press is an automatic membrane high pressure filter press, which operates at hydraulic water pressures up to 1500 PSI (100 bar). The Tube Press was developed in the late 1960's by Charlestown Engineering, st. Austell, Cornwall, England, formerly a division of English China Clays, Ltd., to address more effective methods of moisture reduction of micron-size china clays. The Tube Press reduced moisture sufficiently to produce a hard surface-dry, handleable cake and clear filtrate discharge, which was recycled into the process. This development work was conducted using a 200 Series Tube Press (200 mm diameter x 2500 mm long filter surface)."

Jan 1, 1993

By Garth D. Kirkham, James P. Siddorn, Hendri Falck

"Abstract - As an integral part of the Geological Survey of Canada’s EXTECH III Project, a threedimensional computer model has been created of the Con and Giant gold mines in the Yellowknife Greenstone Belt. The Yellowknife Mining Camp has produced a great deal of gold (over 15 million ounces, or 400 000 kg) in the past sixty years and the prevailing assumption is that the mines are at the end of their lives. However, the potential for discovering additional resources using new ideas and technology, and maximizing use of existing data, offers an opportunity to sustain the old mining operations and maintain their contribution to the community.The objectives of this study included the compilation and creation of a three-dimensional Geographic Information System model (combining 3D subsurface data with surface information) to provide a framework for concurrent structural and alteration studies, and to encourage new exploration in the area. A secondary objective was to retain the data in digital format as a historical reference for future remediation efforts, and to document a portion of Canada’s rich mining history.The end result is a database and set of models that have been instrumental in facilitating further exploration in the area, as well as in developing targets for future exploration and mining activities. In addition, the EXTECH III 3D GIS model has made a valuable contribution toward the understanding of the arsenic remediation issues at the Giant mine, and has served as a tool in support of a variety of highly technical engineering studies and for communicating information and problems to the layman and community as a whole."

Jan 1, 2003

By Malcolm Powell

"Predicting the performance of the whole mining process is surely the holy grail of predictive simulation. This can be named ‘Integrated Process Prediction’.The objective is to be able to predict the response of the processing chain, from mining to concentration, to changes in the ore type. This can apply to greenfields design – selecting processing options to optimise the overall mine performance within the constraints and aspirations of the greater community and environment; expansion and optimisation of existing plant to deal with changes in economic drivers and ore types; and on-line control – predictive reaction to ongoing changes in ore processing types in an operation.In order to achieve this there are several broad key components that are required: ore characteristics based on in-situ rock properties; a reliable 3D map of the ore body by the key processing parameters; prediction of how the rock fragments and the energy requirement to break it; the ability to predict and track progressive mineral liberation of the rock through the reduction process; the response of rock to separation processes as a function of the rock mineralogical properties. This requires the identification of primary rock properties and associating them with the rock particles as they move along the mining process chain to a concentrate or various forms of waste.This paper looks at the value of this integrated approach; the challenges it poses; the technology and capability we require; and how as a mineral processing community we can address the challenges."

Jan 1, 2016

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to assist the mining industry in implementing continual improvement in management of major unwanted events, and so maximising health and safety performance. A comprehensive body of knowledge has been compiled from diverse mining industry experts for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This paper presents an overview of the body of knowledge captured from diverse mining industry experts for the management of unwanted strata incidents, and explosions in the underground environment. This knowledge is divided into a series of initiating events within both topics (as listed) with further degrees of classification based on design, operation, and management concerns. Strata Underground Initiating Events: Explosions Initiating Events Loss of strata control at longwall face Fire or ignition in a sealed area Loss of strata control in outbye roadways Fire or ignition in an unsealed goaf area Loss of strata control in roadways under development Fire or ignition in an extraction face Loss of control of overburden and caving behavior Fire or ignition in outbye Loss of pillar system stability Loss of control of goaf edge in pillar extraction Fire or ignition in a development panel or first working Loss of strata control in shafts The system guides the user in generating substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry.

Aug 1, 2013

By M. P. Amsden

"Ecstall Mining Limited, a subsidiary of Texasgulf, Inc., Operates the Kidd Creek Mine, Concentrator and Zinc Plant at Timmins, Ontario. Two different ore types are mined and milled to produce concentrates of copper, zinc, lead and tin. The ores are processed at the Concentrator in three separate individual milling circuits, each with the capacity to treat up to 3500 tons per day. Two circuits treat copper-zinc ore 1t an average combined rate of 6500 tons per day and the third circuit treats 3500 tons per day of silver-lead zinc ore. Conventional crushing, grinding and flotation procedures are followed. The purpose of this paper is to describe Ecstall's experience with rubber mill linings in the grinding circuits.CrushingBoth ores are crushed to minus 6 inches at the Mine and delivered by rail to the Concentrator where they are reduced by secondary and tertiary crushing to minus 5/8 inch.GrindingThe crushed ores are prepared for selective flotation by grinding with rod mills and two stages of ball milling. flotation circuit middling products are reground in regrind mills prior to further treatment. A typical flowsheet of one of the grinding circuits is shown in Figure 1.All the grinding units are Allis-Chalmers Mills. The rod mills are 10 1/2 feet diameter by 16 feet long. Both the primary and secondary ball mills are 12 feet diameter by 18 feet long and all regrind mills are 6 feet diameter by 12 feet long. The primary mills are charged with 1 13/16 inch forged balls. Secondary mills are charged with 1 1/2 inch forged balls and the regrind mills are charged with 1 inch forged balls. All cyclones are Kreb units. The primary cyclones are Dl5B hydrocyclones, the secondary cyclones are D6B hydrocyclones and all regrind cyclones are D6B hydrocyclones."

Jan 1, 1974

By H. E. Frimmel

Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morphological characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively, estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry. Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infJ.1tration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in tum, was determined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

"In today’s world of complex projects, where engineering and execution are supported by a high level of project management and systems, how critical is the human factor in design engineering. Based on his involvement on a variety of projects, Tony Lipiec will relate his experiences as the impact of 4 factors: the ‘team’ involved in the design and execution of the project; the project and information systems supporting the project; the impact of scope, time, and budget; and finally the selection of the proper success criteria to judge the project and the people who have enacted the project.The discussion of the team will relate to the quality of people and the impact of their knowledge, attitude and experience. It will also look at the relationships and interests of the various stakeholders. Decision making and taking responsibility will be discussed.Supporting the team are the management, document and information systems. The value that these systems bring to the project as a whole will be examined. How project size impacts the applicability of the systems will be discussed.Scope, time and budget are recognized as critical. Reference will be made to the interplay between these components which are vital to project success. The issue of iterative design and whether it is necessary will be considered together with the development of supporting technical information.Finally the selection of the proper success criteria and the awards provided to the team can have a big impact on the final, production success of the project. The author will discuss his views on the impacts of these on EPCM projects."

Jan 1, 2016

By T. Negeri, M. Boisclair, A. Bouajila

CanmetMINING has been working on process development for separation and concentration of rare earth bearing minerals from various ores. Among others, the flowsheet development for the Montviel Rare Earths/Nb deposit, located at the north end of the Abitibi region in Quebec and owned by GeoMegA Resources Inc. (GeoMegA) is now at an advanced stage. The concentrate produced by a flotation-only process at the early stage of the project accounted for higher than 90% TREO and Nb recovery in 40% mass. This concentrate was submitted to SGS Lakefield for hydrometallurgical processing. Lixiviation of the concentrate using hydrochloric acid yielded approximately 99 % REE. An overall (from ore in ground to final precipitate) REE recovery of 80% was obtained through a series of selective precipitation steps. Recently significant additional developments have been made. CanmetMINING is steadily improving the quality of concentrate produced through a simplified, more efficient flowsheet which consists of flotation, magnetic separation, and a thermal treatment procedure. The paper discusses aspects of the process that allowed obtaining 82% recovery of TREO and Nb in 16% of mass, the best result to-date.

Jan 1, 2014

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By B. Garitte, O. K. Mahabadi, P. Marschall, A. Lisjak, H. R. Müller, T. Vietor, G. Grasselli

Numerous research studies have shown that clay rock formations exhibit favourable characteristics for the deep geological disposal of radioactive waste. However, one main concern is that the favourable long-term isolation properties of the intact rock mass could be negatively affected by the formation of an excavation damaged zone (EDZ) around the underground openings. The goal of this paper is to present new rock mechanics insights into the phenomena involved in the EDZ formation and evolution processes in Opalinus Clay, a clay shale currently being assessed as a potential host rock for an underground repository in Northern Switzerland. More specifically, discontinuum-based computer simulations, using a hybrid finite-discrete element method (FDEM) approach, were applied to two case studies considering circular excavations in an anisotropic Opalinus Clay formation. In the first case study, numerical modelling was applied to the HG-A experiment, a long-term in-situ test carried out at the Mont Terri underground rock laboratory to investigate the hydro-mechanical response of a backfilled and sealed microtunnel. A mechanistic analysis of the fracturing processes involved in the EDZ formation was carried out. In the second case study, the long-term effect of the bentonite backfill swelling on the EDZ around an emplacement was numerically analyzed. Overall, the simulation results highlight short-term distinctive rock failure kinematics due to the bedded rock structure, as well as a long-term reduction of the excavation-induced fracture porosity in response to mechanical loading.

Jan 1, 2015

By A. L. Williamson

Bio-mining, the use of micro-organisms to recover elements of interest, is potentially useful for the economic extraction and recovery of ore metals from a variety of ore deposits, including the lowergrade uranium deposits found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The metabolism of chemolithotropic bacterium Acidithiobacillus ferrooxidans depends on an ability to derive energy and reducing power from the oxidation of ferrous iron found in a varirty of iron sulphide minerals associated with base, precious metal and uraniferous ores. The characteristics of this bacterium, especially the ability to oxidize both iron and sulphur with an associated high tolerance of low acidity, allow the organism to contribute significantly to bio-mining processes. Under ideal conditions, A. ferrooxidans promotes the oxidation of ferrous iron in low sulphide ore materials, breaking the crystal structure of the ore minerals .releasing protons to the surrounding solutions, thus promoting the dissolution of uranium and rare earth elements, among others. This paper provides an overview of elemental dissolution and release of uranium, rare earth elements and investigates the acid generating potential of the final residues, from a series of environmentally controlled, biologically-mediated uranium ore extraction experiments. The findings will be used to guide in the design of larger scale bio-leaching experiments to further assess the potential for successful bio-mining operations along the Quirke Syncline.

Aug 1, 2010

By Y. M. Shneerson, I. V. Fomenko, M. A. Pleshkov, E. A. Ospanov, A. A. Shakhalov, S. S. Naboychenko

Low-grade copper concentrates (with copper content less than 20%) often contain impurities such as arsenic, zinc, lead, mercury, antimony and bismuth. The pyrometallurgical treatment of such concentrates is associated with several problems, which will ultimately affect the cost and the quality of copper cathodes as well as by-products. SRC Hydrometallurgy proposed a complex hydrometallurgical technology which allows the removal of impurities and the enrichment of low-grade copper concentrates to a quality which will be more suitable for pyrometallurgical processing. Laboratory batch tests and pilot plant results for the pressure leaching steps are shown in this paper. The key parameters of the leaching steps were determined and optimized. The quality of possible by-products were also determined. The developed flowsheet includes two pressure leaching steps: pressure oxidation (POX) and hydrothermal alteration (HTA). Both operations are carried out at 170°C with subsequent flotation of POX and HTA residues and recovery of copper, zinc and lead into separate concentrates for further processing. The development of the flowsheet was based on the Balkhash Zinc Plant (Balkhash, Kazakhstan), which had been non-operational since 2009. The developed flowsheet for processing of low-grade concentrates will utilize 80% of the existing equipment of the Balkhash Zinc Plant, thus leading to a significant reduction in required capital expenditure. INTRODUCTION As the age of copper mining operations advance, copper grades continue to diminish and impurity levels increase. Therefore, copper producers are forced to look for new innovative hydrometallurgical technologies which are able to handle low-grade raw materials and solve problems associated with impurities in an economically justifiable way. New technologies allow to extract valuable components selectively and to process low-grade concentrates which had previously been marked as non-technological and economically unviable. Hydrometallurgical technologies for processing of copper-containing materials can be divided into two main categories: chloride and sulfate (atmospheric, autoclave and bacterial) based technologies. Since the 1970s, many autoclave techniques for the processing of copper-containing materials have been developed and implemented (Naboichenko, 2002; Dreisinger, 2005; Habashi, 2009; Shneerson, 2011). The mineralogical composition of the ore (or concentrates), geographical location of the deposit, distance from industrial areas, availability of existing treatment facilities, availability of skilled labor, cost of electricity and cost of neutralization are some of the factors which are usually considered when the appropriate technology is selected (Halbe, 2002).

Jan 1, 2019