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By R. C. Wallace

In the early explorations of the Northwest, the search for minerals played a not inconsiderable part. The first episode had its disillusioning sequel. Sir Martin Frobisher, in 1576, sailed up that bay in Baffin land now known as Frobisher bay, thinking that he had the coast of Asia on his right hand. He brought back from this expedition a piece of 'black earth' from Hall island, from which an alchemist by coaxing nature, or his own conscience, obtained gold. A second expedition of three ships was fitted out in 1577, and a third of fifteen ships in 1578. The ships were loaded with this 'black earth', which on subsequent investigation was found to be worthless, and interest in minerals for the time being ceased. In 1612 Hall and Baffin went in search of a gold mine near the Arctic circle on the west coast of Greenland, reported to be worked by the Danes. They found old workings, but no ore. To come nearer the Hudson Bay area, it is noteworthy that the charter granted by Charles II to the Hudson Bay Company in 1670, as a result of the explorations of Radisson and Groseillers, was given "-in consideration for their having at their own cost and charges undertaken an expedition to Hudson bay in the northeast parts of America, for the discovery of a new passage to the South sea, and for the finding of some trade for furs, minerals and other considerable commodities, and of their already having made by their undertakings such discoveries as did encourage them to proceed farther in pursuance of the said design, by means whereof there might probably arise great advantage to the King and his Kingdom - ".

Jan 1, 1925

By Chris M. Healey

"Perhaps the single most significant variable in the evaluation of a mining project is the reserve estimate. Many parameters are considered when estimating reserves, among them geology. This paper examines the link between the quality of a reserve estimate and a good understanding of the geological controls for the deposit. A clear understanding of the geometry is essential to the accurate definition of the shape and size of the deposit. This includes the definition of any structural controls as well as the proper interpretation of the stratigraphy. Further when the distribution of grades is erratic and there is consequently a high nugget effect, there are significant problems in estimating the true grade of the deposit.Two Saskatchewan examples are presented, one with good knowledge of the controls and therefore good estimates of reserves, and the other with a poor understanding of the geology and resultant problems in deriving good estimates. In both cases the reserve estimates at various stages in the project development are compared to actual results from underground work. The first example is the Star Lake Mine where just about all the estimates were within 10070 of the actual on both tonnage and grade. The Laurel Lake deposit is discussed to show how problems in interpreting the geological data make reserve estimation very difficult. Laurel Lake has the additional problem of erratic grade distribution."

Jan 1, 1992

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By Roger V. Pierce

"WITHOUT mineral wealth, modern man would not exist. True, man could survive on a stone-age basis with an average life expectancy of, say, 25 to 30 years -once he got past infancy.However, no metal would tip his arrow in a hunt for protein; no steel plough would break the soil for the organized planting of seed; and no coal, nor oil, nor natural gas nor uranium fuels would pro-vide him with light or beat or safety from either beasts, or other men, or an unkind nature that threatened him and his family.Modern agriculture, fishing and forestry represent the other three wealth-producing industries. With-out metals, non-metallics and energy minerals, however, it would be impossible to fit any of these to man's modern needs."

Jan 1, 1967

By S. Banisi, A. R. Hasankhoei, Gh. Parsapour, A. R. Ghasemi

At the Gol-E-Gohar mining and industrial Company, a pelletizing plant, which includes two parallel dry closed grinding circuits and a pellet production circuit, produces 600 t/h. Each grinding circuit consists of a burner, a dry ball mill (6 m×13 m) and an air separator. Each ball mill consists of a 2 m-long dryer chamber and an 11 m-long grinding chamber. Iron ore concentrate is fed to the drying chamber to decrease its moisture from 2.5% to below 0.2%. The drying chamber consists of 56 flights in two rows. It was found when the feed moisture content decreased from 1.3 to 3.5%, the throughput decreased by 14% (40 t/h) indicating a low performance of the dryer. In order to improve the efficiency of the drying section, a scale down version of the dryer was constructed in a 1m diameter mill with a transparent end to make image analysis possible. It was found that because of the inappropriate veiling profile in the drying section, most of materials are not subjected to the hot gas tunnel. To overcome this problem, various flights with different geometries were physically tested and also simulated by the KMPCDEM © software. With the aim of arriving at a proper veiling profile which maximizes the particles contact with hot air, a new flight design was obtained and tested. The installation of the rectangular tooth type flights in one of the mills in the plant made the comparison of the old and new designs possible. The evaluation of the designs in a period of three months indicated 15 t/h increase in the throughput in the case of the new flight design.

Jan 1, 2016

By J. P. Norrie

The presence of copper-bearing rocks in the Coppermine River area of Arctic Canada has long been known. Word of this was probably circulated along the Arctic and Hudson Bay coasts by the Eskimo, who no doubt traded articles made from native copper among themselves. It is not known whether any of these ever reached the southern shores of Hudson bay. The Indians, also, knew of the occurrence of copper here, as they served as guides to Hearne when he made a successful trip over land from Hudson bay to the Coppermine river. The possible commercial importance of these copper deposits was early appreciated by the Hudson's Bay Company, who on December 7th, 1770, despatched Samuel Hearne from Fort Prince of Wales, now Fort Churchill, to investigate them. He reached the then unnamed river at a point forty miles from its mouth on July 14th, 1771, and after surveying the river to its mouth and naming it the Coppermine, he retraced his steps to Fort Churchill by an overland route. Hearne's expedition was probably the most remarkable and arduous ever attempted in Arctic exploration, but the actual value derived from the trip was entirely out of proportion with the hardships he must have suffered. He verified the occurrence of native copper, but his astronomical and other observations were of little value. Until 1912 no concerted effort was made to obtain any definite information as to the geology and economic value of the Copper-mine deposits.

Jan 1, 1931

By M. Xiao Bo

In recent years, there has been a heightened interest in the hydrometallurgical processing of sulfide ores and concentrates (especially copper sulfide ores and concentrates) mostly in the USA and Chile. Currently, hydrometallurgical operations account for about 30% of the primary copper production. In the present research, the leaching phenomena of IOCG (iron-oxide hosted copper-gold) ores and concentrates were studied. The IOCG ore, which is characterized as having a predominant amount of magnetite with fine chalcopyrite, is currently the center of attention for new copper resources. Heap leaching of IOCG ore is desirable because of its low cost. However, the leaching characteristics of the ores and concentrates and the mechanisms of copper leaching require investigation. This study defines the factors, which affect the leaching operation, such as the ORP, pH and oxidizing agents. Based on these results, the optimal leaching conditions are provided for pilot column leaching test and ultimately, commercial operations.

Jan 1, 2007

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016

By Y. -B. Kang

New databases are being developed to provide the capability to evaluate the suitability of present and potential new Mg alloys for automotive applications through cost-effective calculations. An extensive and complete thermodynamic database is being prepared for Mg alloys formed from among 25 present and potential alloying elements. The database is being developed by critical evaluation, modeling and optimization of available phase equilibrium and thermodynamic data. It contains model parameters giving the thermodynamic properties as functions of temperature and composition. Using the FactSage thermodynamic software, users can access the database to calculate the amounts and compositions of all phases at equilibrium at any temperature and composition or to calculate any phase diagram section in multicomponent alloys, to follow the course of equilibrium or non-equilibrium cooling, to calculate corresponding heat effects, etc. A database of densities and lattice parameters of Mg alloys and intermetallics (as functions of temperature and composition) is also being developed in order to permit the calculation of volume changes during cooling and phase transformations, c/a ratios of the hcp phase, etc.

Jan 1, 2006

By F. Hassani, E. Aflaki, M. Nokken, M. Kermani

"This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill consists of tailings, different binders such as Portland cement, fly ash and blast furnace slag and an alkali activator such as sodium silicate. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. The influence of sodium silicate concentration, pulp density and mixing time on the mechanical properties of samples were evaluated using the uniaxial strength test. Mercury intrusion porosimetery (MIP) was used to analyse the microstructure of CHF and Gelfill samples.This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Mixing time strongly influences the mechanical properties of Gelfill samples but did not have any effect on CHF samples. (iv) The MIP analyses indicate that the pore size distribution and total porosity of Gelfill and CHF were different, and this did contribute to higher strength development of the Gelfill samples. INTRODUCTIONThe increased depths of mines in the Canadian Shield and the high stress associated with these depths favour a new method of mine backfill that can both meet strength requirements and help mine productivity. The mine backfill mainly consists of tailings, water and binder materials, the latter being most expensive. Gelfill is a new mine backfill material whose binder usually consists of alkali activators such as sodium silicate and other cementitious materials such as blast furnace slag and normal Portland cement. Although sodium silicate has been used in concrete manufacture, the use of this material in mine backfill is relatively new (Doucet, 2007, Razavi, 2007). Until very recently there have been only a few isolated publications, mostly out of McGill University, regarding mine Gelfill (Razavi, 2007 and Kermani et al., 2009 and 2010). These papers have investigated some of the basic mechanical properties and mechanical behaviour of Gelfill. However, the physical performance of Gelfill in various conditions has yet to be understood. Therefore, the main objective of this study was to investigate the influence of mixing time and sodium silicate concentration on the mechanical performance of Gelfill and CHF through a series of experiments. Moreover, the microstructure of the Gelfill and CHF samples was studied."

Jan 1, 2015

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By G. Stokreef, B. R. Davis, M. Kadiyski, T. LeBel, Alvear Montenegro, R. Parra, V. Montenegro

A drop tower and methodology were developed to study the impact of mineralogy on the flash combustion behaviour of copper concentrates. Reaction shaft conditions of a flash furnace were simulated using a drop tower reactor and different molar ratios of oxygen gas to sulphur in the feed. Five feeds were tested in the drop tower including pure minerals chalcopyrite and pyrite as well as two mineralogically distinct copper concentrates and a blend of the two. The behaviour of each of these five feeds were evaluated through analysis of the solid combustion products for elemental sulphur, mineralogy and particle size. Desulphurization curves for each of the feeds were produced. It is thought that the desulphurization behaviour of pure minerals can be used to estimate the behaviour of a concentrate and that a blending recipe could be developed, which can optimize the chemical and mineralogical inputs to the flash furnace and guide operations on the optimum furnace conditions. Overall, the drop tower has proven to be a useful tool for studying flash combustion processes. Experimental results suggest that mineralogy has a significant impact on the conditions required for the production of matte with consistent grade. This finding is especially significant for custom smelters, which may see several different blends in a day. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process that is used to produce copper matte from copper sulphide concentrates. Dried concentrate(s), silica flux, and secondary materials are blended to a target chemical composition, typically given by the Cu/S ratio, before processing. This fine, dried feed is dispersed throughout the heated furnace reaction shaft with an O2-enriched reaction gas. The particles heat up in the shaft of the furnace, ignite and undergo reactions that pre-oxidize the iron sulphide and some of the impurities in the feed. Oxidation reactions in the shaft of the furnace desulphurize the feed and produce an SO2-containing off gas. The reacted particles fall into the furnace settler and separate into a Cu-rich matte and an iron-silicate slag, while the SO2-containing off gas is carried out of the furnace for heat and dust recovery, as well as H2SO4 production. Some concerns during operation of the furnace are dusting, over or under oxidation of the feed, and a stable flame.

Jan 1, 2019

By Ki-Bok Min, Bona Park

"In spite of the applications of DEM models to emulate the elastic modulus, Poisson’s ratio and strengths of isotropic rock in laboratory scale, extensions to anisotropic rock and larger engineering scale still have many challenges to overcome such as robust verification and validation against observed field case. In this study, a discrete element modeling was performed in order to represent a transversely isotropic rock such as shale, and the upscaled model was applied to foundation and borehole problems using PFC2D. The applicability of the upscaled rock mass model was verified by an analytical solution. The DEM modeling of stress redistribution induced by an applied surface line load compares well with Boussinesq’s isotropic solution and anisotropic solution given by Bray. The borehole model with a circular opening under biaxial stress was compared with both isotropic and anisotropic solutions resulting in good agreement. The abilities of DEM model to investigate the micromechanisms accounting for complex macroscopic behaviors and to predict the macroscopic behavior are discussed.The results demonstrate that DEM modeling has the potential to be applied to anisotropic rock mechanics problems on larger engineering scales such as wellbore stability problems especially in shale formations. Furthermore, the effect of anisotropy modeled through this study may be able to explain failure behavior of anisotropic rock encountered frequently in real cases.INTRODUCTIONAnisotropy is prevalent in various types of rocks, especially in shale that contain a set of parallel bedding planes. These weak planes in various forms are sources of large deformation and low shear strength and contribute significantly to the anisotropic behavior of rocks (Amadei, 1996; Cho et al., 2012; Kim et al., 2012). As elastic and strength behavior of anisotropic rock is substantially different from that of isotropic rock, proper consideration of anisotropy is of great importance. There is extensive of experimental evidence showing the anisotropy of shale. Niandou et al. (Niandou et al., 1997) analyzed the plastic deformation and failure mechanisms of Tournemire shale were highly dependent on the orientation of bedding planes. Cho et al. (Cho et al., 2012) presented various deformations and strengths of Boryeong shale obtained from laboratory experiments. Fjaer and Nes (Fjaer and Nes, 2013) performed uniaxial and triaxial compressive strength tests using Mancos shale, and they observed that the shear sliding along the planes of weakness before the occurrence of a major failure can reduce the strength of anisotropic rock. The recent research has demonstrated that the anisotropy of rock is an important consideration in rock engineering."

Jan 1, 2015

By I. Silin, M. Stapelmann, H. Wotruba, K. M. Hahn, C. Gerold, J. Katzmarzyk

New deposits are often characterized as low-grade and complex ore bodies. To date, processing of fine grained ore deposits implies complex processing routes with high energy consumption. For that reason, the investigation of dry grinding, e.g. with vertical roller mills (VRM), is an approach to save energy reserves. It is already proven that dry grinding can influence subsequent processing steps. In terms of flotation, the surface characteristics of the minerals are crucial for a successful flotation process, e.g. the sufficient adhesion of mineral particles and air bubbles. Wet grinding results in different surface properties of the product entering the conditioning stage than dry grinding, which has direct influences on the subsequent flotation process. To investigate the consequences for flotation, processing of a copper sulfide ore containing chalcopyrite and bornite was investigated, including grinding and rougher flotation. The effects of wet tumbling mill and dry VRM grinding on the degree of liberation of valuable minerals are characterized using mineral liberation analysis by scanning electron microscopy. The obtained flotation results, as well as the recorded flotation parameters such as dissolved oxygen, oxidation reduction potential and conductivity are presented and discussed. INTRODUCTION Copper production is mainly connected to porphyry copper deposits as main source for copper sulfides such as chalcopyrite and bornite. State-of-the-art processing of these deposits is already established worldwide for decades, combining crushing, fine grinding and subsequent flotation with rougher, cleaner and scavenger stages (del Villar, Desbiens, & Maldonado, Bouchard, 2010). While the demand for copper is increasing, copper grades of the deposits are decreasing and the remaining ore bodies have more complex mineralogy and finer particle size distribution. This implies processing routes with high water and – due to the liberation of fine grained valuable minerals – high energy consumption by fine grinding. One of the main energy consumers in processing plants is the grinding section, which accounts for more than 50% of the energy consumption in processing plants and even 4% of the worldwide energy consumption (Jeswiet, & Szekeres, 2016). Therefore, dry fine grinding alternatives are applied to enhance the overall energy consumption of mineral processing plants: high pressure grinding rolls (HPGR) and vertical roller mills (VRM).

Jan 1, 2019

By J. F. Nie

Mechanical properties of precipitation hardenable magnesium alloys depend critically on the chemistry, structure, morphology, orientation and distribution of strengthening precipitates. It is therefore important to gain an improved understanding of these information and their correlations with mechanical properties. Our recent studies indicate that additions of 1-2 wt% of Zn to a Mg-6wt%Gd alloy result in a substantial enhancement in precipitation hardening and in creep resistance. If the strength and creep resistance of the resulting ternary alloy are to be further enhanced for commercial applications, then a detailed characterisation of the strengthening precipitates in these alloys is required. In the present study, the precipitates formed in a Mg-6Gd-1Zn-0.6Zr (wt%) alloy, peaked aged at 250°C, have been characterised in detail using transmission electron microscopy and 3-dimensional atom probe field-ion microscopy. It is found the peak-aged microstructure contains a dense and uniform distribution of precipitate plates that form on the basal plane of the matrix phase and are typically less than 1 nm in thickness. Detailed analyses of the structure and composition of these basal precipitate plates will be presented and discussed in the context of previous work on other Mg-RE¬Zn alloys of similar compositions.

Jan 1, 2006

By A. L. Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium and rare earth deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The effectiveness of bio-mining in Elliot Lake depends on the success of bacterially-influenced dissolution of metals of economic importance. The determination of both the dissolution efficiency and rate controls for uranium and rare earth elements from bio-extraction processes is critical to assess the potential for success of bio-mining along the Quirke Syncline. This poster provides an overview of proton-mediated biogeochemical dissolution of more than 50 elements, including uranium and rare earth elements from samples of the low grade uraniferous ore collected as drill core from the Elliot Lake area. The elemental data is quantified using advanced spectroscopic tools (ICP-MS and ICP-AES) to analyze solutions obtained from a series of environmentally controlled biologically-mediated uranium ore extraction experiments. The findings are being to guide design of larger scale bio-leaching experiments to further assess the potential for success of bio-mining along the Quirke Syncline.

Aug 1, 2010

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005

By Bonnie Cooper

3D printing by fused deposition can be used on lunar soil. The soil can be precisely size-separated to make the 3D printing process work efficiently. Using a MASER instead of a LASER would allow us to use the finest fraction of lunar soil, AS-IS, to manufacture things on the Moon.

May 1, 2013

By J. Bouchard, R. del Villar, A. Vazirizadeh

"Industrial flotation is a continuous and often multistage process, where particles of a given mineral species (usually the targeted one), present in different sizes, encounter a large amount of gas bubbles (normally air) to produce mineral–bubble aggregates, which are removed from the flotation device (cell or column) as a valuable product (concentrate). The bubble content inside the cell is characterized by the prevailing hydrodynamic conditions (known as gas dispersion variables), which in turn are known to influence the flotation performance. Although most researchers and practitioners agree that the relationship between the hydrodynamic variables and flotation performance exists, the lack of an adequate method foronline measuring the average bubble diameter has prevented such studies.The aim of this study is to apply appropriate hydrodynamic variables for flotation kinetic modeling (as a key feature of flotation performance) for a given introduced particle size distribution (PSD). In this regard, experiments were conducted in a laboratory flotation column (5.6 cm internal diameter for a total height of 650 cm), and mixtures of quartz (hydrophilic gangue) and talc (naturally hydrophobic mineral), classified in four different size fractions. The correlation between the flotation rate constant and given hydrodynamic variables were analyzed. Results suggest that the relative importance of hydrodynamic variables for flotation rate modeling depends on the PSD. Finally the suggested hydrodynamic variables for each of the various particle size-classes considered were used to produce single variable models for the flotation rate constant. INTRODUCTIONIndependently of the prevailing flotation conditions, the mechanisms for bubble-particle aggregation and the residence time of the phases inside the device must also be considered. In this regard, one of the most used approaches to represent the overall flotation process is as a pseudo-chemical reaction between a particle and a bubble, whose rate (at a given time) is proportional to the amount of remaining floatable species. The proportionating constant is called the kinetic constant or the flotation rate constant."

Jan 1, 2016