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By Ron Hatch, M. K. Witte

"INTRODUCTIONThe proper selection of carbon for a gold carbon in pulp (CIP) circuit involves careful evaluation of several physical, chemical and economic factors. A series of evaluations are required to maximize gold recovery at the lowest capital and operating costs, whether the carbon is selected for an existing gold mill circuit or a new mill under design.Although evaluation may proceed through various stages, it is the intent of this paper to outline some of the preliminary testwork that should be carried out to screen potential carbons for a particular application.An examination of the specification sheets supplied by the various carbon manufacturers may indicate some desirable properties on which to make cursory selection. This exercise by itself will not provide the basic data needed for selecting the best carbon for a particular ore pulp and metallurgical circuit. The necessity of further metallurgical evaluation is indicated by the fact that different carbons perform differently depending on the physical and chemical nature of the leach pulp. In the case of an existing mill, actual leach slurries using mill water are available and should be used for testwork. In the case of new mills, leach pulps must be prepared to simulate the proposed circuit.Five coconut shell activated carbons were obtained from various suppliers, all reported to be 6 x 16 mesh carbons recommended for CIP circuits. A metallurgical evaluation was made utilizing two leach pulps with significantly different characteristics. This paper describes the test procedures utilized and the results obtained from the testwork."

Jan 1, 1985

By Lesley Hymers

First Nations Natural Resources Youth Employment Program PDAC Mining Matters ? Charitable organization ? Provide education to students, teachers, and the public about rocks, minerals, metals, and mining ? Provide current information and offer exceptional educational resources that meet provincial Earth science and geography curriculum expectations First Nations Natural Resources Youth Employment Program ? Provide instructional development workshops for educators who are teaching Earth science and geography ? Since 1994, reached more than 400,000 students, teachers, industry representatives, and members of the public

May 1, 2009

By Li Xibing

The In order to mine safely with reasonable cost, it is necessary to research the fracture characters of backfill and its matches with rock mass. Four kinds backfill with cement-tailing ratio of 0.250, 0.125, 0.100 and 0.083 respectively were tested, and basing on stress-strain curves tested, the deformation characters and fracture laws as well as the damage constitutive equations investigated with damage mechanics whose calculating results are coincided with experiment results well were proposed. The results of damage analysis show that there have different damage characters in different backfill, e. g. the lower the ratio of cement to tailings the lower the damage values when stresses reach to peak value; the lower the content of cement the more rapid in damage and the more abrupt in breakage process. In addition, using catastrophe theory, an energy model was proposed for backfill and rock mass acted each other in mechanics, and the unstable condition of the system was obtained. Research results show that the higher is the stiffness of rock mass the more stable the system, and the lower is the ratio of cement to tailings, the more unstable the system will be. Further more, according to the catastrophe model proposed, the reasonable matches between backfill and rock mass were researched, and a calculation formula that designs reasonable strength of backfill during mining was put forward. It has been proved by practice that the model and theory researched in this paper can guide filling design in mining. Keywords: Cemented tailings backfill, constitutive equation, catastrophe theory, match of backfill and rock mass

May 1, 2007

By Simon Houlding

"Part 1 (CIM Bulletin, August 1991) of this article identified the limitations of the traditional modelling methods and demonstrated the approximations and errors introduced by their application to complex mining situations. The objective of Part 2 is to describe the evolution of new, proven technology which eliminates these deficiencies and provides precise and practical alternatives. These promote the use of realistic geological and mining shapes and eliminate altogether the rectangular approximations of traditional methods. Limitations of the Traditional MethodsThe limitations of the traditional modelling method s (viz. simple block modelling, gridded modelling and their more recent variations) were discussed in detail in Part I . These methods are all based on the use of rectangular discretization to represent the boundaries and volumes of ore deposits and mining excavations. As a result they are unsuited to the representation of nonrectangular geological complexities such as folding, faulting and irregular surfaces . They are equally unsuited to the representation of realistic excavation limits, particularly in the case of underground mining.Recently these methods, with limited variations in technique, have been applied to increasingly more complex geological and mining situations. The resulting potentials for error and conflict within the modelling pro cess were demon strated in Part I . The effects can be summarized as follows:• volume and boundary approximations introduced by therepresentation of irregular three-dimensional boundaries andvolumes by rectangular modelling elements ; • geostatistical errors and conflicts caused by neglect of the relationships between grade estimates and the geometric/ spatial aspects of irregular volumes and associated observations (samples), including an inability to produce precise estimates with meaningful confidence limits;• a compounding of these effects by using rectangular element sizes other than the geostatistical optimum, and by using differentelement sizes within a model; and• general inefficiencies introduced throughout the modelling pro cess by the requirement to represent geology, grade distribution and excavation limits with a singular modelling method and model."

Jan 1, 1991

By T. McCallum, B. Wellbrook, T. Ratnaweera

Leaching of copper (Cu) concentrates produces elevated concentrations of Cu and acid, which makes solvent extraction (SX) processing more challenging. Maintaining extraction targets can be more difficult with higher pregnant leach solution (PLS) grades, and variability of PLS Cu and acid can lead to increased chemical iron transfer. Diluting concentrate leach feeds with an existing heap leach inventory makes SX processing easier. However, considerations about how much to dilute and where to distribute the flow into the SX configuration must be carefully evaluated, given their impact on metallurgical performance. In this paper, characteristics of a concentrate leach feed are discussed, along with considerations for processing by SX. Also reviewed are pilot plant results of concentrate leach distribution into SX and plans for commercial testing. INTRODUCTION Hydrometallurgical processing of copper concentrates continues to gain interest from the industry. Treatment by smelting and electrorefining continues to dominate, accounting for ~80% of global copper production, but is faced with its own challenges (Li et al, 2017). The case for increased hydrometallurgical processing has been discussed as high grade ore deposits are diminishing, capital costs for smelting are high, and the environmental aspects present challenges for sustainable practice. The hydromet copper industry is also turning a corner as easily leachable copper oxide deposits are depleting, and excess SX-EW capacity exists in certain regions. The transition to hydrometallurgical processing of copper concentrates will take a bit of effort as leaching of copper sulfides is difficult and byproduct credits must be considered. Various POX leaching processes have been studied and proposed to the industry as viable practices. Of the many processes, commercial use has been practiced with the Mount Gordon Copper Process, total and partial pressure oxidation by Freeport-McMoRan at their Bagdad and Morenci, Arizona complexes, the Sepon Copper Process in Laos, and the bioleach BIOCOP™ process in Chile (Dreisinger, 2016).

Jan 1, 2019

By A. S. H. Kabir, I-H. Jung, J. Su, S. Yue, M. Sanjari

The final mechanical properties of wrought magnesium alloys are mostly controlled by microstructure and crystallographic orientation or texture. In common magnesium alloys, grain coarsening occurs during annealing process and formation of undesirable basal texture cannot be changed markedly. The aim of this work is to investigate the effect of static precipitation on microstructure and texture evolution during annealing at 250 °C after warm rolling of Mg-Al-Sn alloy. Mg-3Al-3Sn (wt. %) alloy has been designed using thermodynamic modeling software, FactSageTM, based on forming target stable and incoherent Mg2Sn precipitate within the industrial deformation temperature range. Microstructures and precipitation were investigated by optical and scanning electron microscopes and macro-texture was measured by X-ray diffraction (XRD) techniques. It was found that static precipitates form in a large scale at the recrystallized grain boundaries and retards the grain growth during annealing. Slight weakening in basal texture was also observed during annealing.

Jan 1, 2014

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016

By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Mike Anderson

The annual budget for the repair and maintenance of equipment at Syncrude Canada Ltd is in excess of 450 million dollars. Of this amount, a significant portion can be attributed to the loss of material on various pieces of equipment throughout the operation. In order to effectively battle the different wear and corrosion mechanisms that lead to material loss, it is important to understand how materials behave in the environments in which they are used. Through the work carried out at Syncrude, and work conducted with various external collaborators, significant improvements in both equipment reliability and productivity have been achieved. This paper will review some recent field trails where materials research has demonstrated the potential for significant improvements in equipment run life and reduced maintenance costs. These field trails will demonstrate the need for understanding the interaction between various damage mechanisms and the materials used in different services. The paper will also discuss current areas of focus along with future directions for further work.

May 1, 2003

By Ken McClure, Alex Day

Located North of Williams Lake British Columbia, Gibraltar Mine is the fourth largest open pit Copper mine in North America. Gibraltar commenced Copper concentrate production in 1972 with a mill throughput rate of 30,000 tons per day. A series of expansion projects, including installation of a second SAG mill with variable speed drives in 2013, has increased mill throughput to 85,000 tons per day. Over the past 24 months, Gibraltar Mine in partnership with Spartan Controls has executed several advanced process control programming projects culminating in the implementation of a Continuous Speed Controller (CSC) for the most recently installed SAG mill. This paper covers development and results for the SAG mill speed controller. INTRODUCTION In January 2016, the price of Copper fell below $2.00 USD per pound, the lowest price in 7 years. Gibraltar Mine faced a significant challenge; how to maximize profit in an environment where capital spending was not an option. An opportunity was quickly identified to improve performance through increased automation and advanced control of the grinding processes. Beginning in March 2016, Gibraltar Mine partnered with Spartan Controls to introduce Advanced Process Control (APC) to the grinding circuits. The collaboration between metallurgical and process control engineering disciplines proved to be effective for achieving gains in throughput, reliability and productivity for the mill process. The Gibraltar milling facilities include 2 grinding-flotation plants for concentration of chalcopyrite ore with throughput rates of 58,000 tons per day (Concentrator 1) and 38,000 tons per day (Concentrator 2). Each of the two concentrators has a 34’ diameter SAG mill powered by 2 GE 4800 kW synchronous electric motors. For SAG 1 (in concentrator 1), power is transmitted through 2 Eaton Airflex clutches. For SAG 2 (in concentrator 2), the motors are driven by 2 TMEIC Variable Frequency Drives (VFDs). All programming is done using DeltaV, which Gibraltar uses as its Distributed Control System (DCS) and Human Machine Interface (HMI).

Jan 1, 2019

By D. G. Ingram

This paper reviews the operating and maintenance practices at Bethlehem Copper from the commencement of operations in November 1962 to the present. Cost data and wear life of major components are also discussed.

Jan 1, 1979

By E. Yalçin, A. Ünal

In transitional mineralization, the sill of the underlying variogram is relatively easily estimated, but the estimation of the nugget effect may be more difficult. This study aims to determine for massive copper deposits just how sensitive the estimations of ore reserve, economic copper content, total net value, and ultimate pit limits are to the errors of estimation in the nugget effect of the spherical variogram model. A massive copper deposit which has a log-normal distribution and a spherical variogram was simulated on a rectangular grid using the turning bands method. By using the three dimensional random kriging method, the mean block grades were estimated at four different sampling densities. The ultimate pit-limits were determined by using the two-dimensional dynamic programming algorithm. To calculate the estimation errors, the values obtained by using the actual nugget effect and structured component values were deducted from the estimations obtained using the incorrect nugget effect and structured component values. For isotropic massive copper deposits, it was found that the ratio of the nugget effect to the structured component of the spherical variogram has no significant effect on either the block grades estimated by the kriging method or on the ultimate pit limits.

Jan 1, 1992

By X. Cao, B. S. Naik, D. L. Chen, P. Wanjara

AZ31B-H24 Mg alloy sheets with a thickness of 2 mm were friction stir lap welded (FSLWed) at two tool rotational rates of 1000 and 1500 rpm and two welding speeds of 10 and 20 mm/s. The tensile behavior of the FSLWed AZ31B-H24 Mg alloy was then evaluated at low (-40°C), room (25°C), and high (180°C) temperatures. It was observed that the failure load increased with decreasing tool rotational rate and increasing welding speed. The maximum failure load occurred at a tool rotational speed of 1000 rpm and a welding speed of 20 mm/s at all temperatures tested. It was also noticed that at the high test temperature, the samples failed along the sheet interface, i.e. shear fracture. At the low and room temperatures, the samples failed on the advancing side (AS) of the top sheet near the interface between thermo-mechanically affected zone (TMAZ) and stir zone (SZ). The different modes of fracture observed are associated with the hooking defect.

Jan 1, 2014

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By A. J. W. Law

"This paper deals with the organization of the central office technical areas and the role played during the feasibility studies, construction and operating phases of Les Mines Selbaie.HistoryThe Engineering Department was originally formed as a part of the Exploration Department, to examine the feasibility of advanced exploration prospects being brought to the company. In 1968, with the discovery of the South Bay property in northwestern Ontario, the department became part of a Mining Division and was expanded, so that it could provide more advanced mine feasibility studies, control of construction engineering and procurement and initial mine design. As is generally the case, the mine design function was handled with in-house capability, while plant, mill and const ruction functions used outside consultants.The 1974 discovery of the Selbaie deposits, started a period o f growth in the capabilities o f the department. The complex nature of these deposits, required that skills were added in the mining, metallurgical and plant areas. During the early feasibility study period these skills were provided by the engineering company of the parent group, but when it was realized that production from the deposits was likely, permanent staff was added."

Jan 1, 1990

By H. A. Gorrell

Preliminary studies of the potential for the production of warm water (up to perhaps 150°C) have been carried out in the Plains region of Western Canada. Production might be from depths as great as about 5 km . Natural waters in this temperature range are currently being used for space heating in other parts of the world. The geography and stratigraphy of the Prairie Provinces are reviewed in terms of their apparent potential for warm-water production. Temperature, salinity and other data provided by wells drilled by the oil and gas industry are reviewed and problem areas are outlined.

Jan 1, 1979

By I. A. Cameron

In 1979, John Peacey and William (Bill) Davenport published The Iron Blast Furnace Theory and Practice billed as "An up to date and comprehensive treatment of blast furnaces from fundamental principles to modern operations" (back cover). As a 1979 graduate of McGill University’s Metallurgical Engineering program, I belonged to the last "beta" student group which completed the prescribed blast furnace course work before The Iron Blast Furnace Theory and Practice was published. As my career developed, I become an international blast furnace consultant and have worked with blast furnace operators and raw material suppliers on 5 continents. The blast furnace is the dominate iron making process responsible for 70% of global steel production. Blast furnace engineers have implemented many improvements by manipulating the blast furnace process metallurgy using the principles presented by Peacey and Davenport to reduce coke consumption and increase oxygen usage and blast furnace productivity. This paper briefly summarizes some key principles presented by Peacey and Davenport (1979), describes process improvements made by blast furnace operators over the 35 years since The Iron Blast Furnace Theory and Practice was published and outlines important future developments in blast furnace technology.

Jan 1, 2014

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract—Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O signature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995