Search Documents

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By Niels Verbaan, Ron Molnar, David Dreisinger

"An acidic chloride leach solution was generated from the treatment of an ore containing the following value elements: silver, gold, indium, gallium, copper, zinc and lead. Iron was also co-extracted into solution as a ferric chloride species. Iron extraction was a significant component of the overall acid consumption of the leaching process. The recovery of iron by solvent extraction and water stripping was investigated. Tri-butyl-phosphate (TBP) was very effective at recovering iron from the leachate. The water strip solution could be decomposed to produce ferric oxide (hematite) and hydrochloric acid for recycle via hydrothermal hydrolysis or pyrohydrolysis.INTRODUCTION The Malku Khota deposit is situated in the eastern part of the Bolivian Altiplano at elevations between approximately 3,800 and 4,580 meters above sea level (Figure 1). The project is located 98 km east-southeast of Oruro, and 85 km south of Cochabamba in a relatively remote area."

Jan 1, 2016

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By Rufus L. Chaney

A new technology is available to the Ni mining and remediation community to “phytomine” Ni from mineralized or contaminated soils using rare plants which hyperaccumulate Ni to over 1% of shoot dry matter. Research has identified useful plant species, and even bred improved cultivars of Alyssum murale and Alyssum corsicum for commercial phytomining in temperate regions. All agronomic practices (fertilization, soil amendments, planting and harvest methods) needed for economic phytomining were identified to attain high yields and high Ni concentration in the biomass. In tropical regions, other species are available such as Phyllanthus which accumulate over 1% Ni in dry shoots. These species are perennial so they regrow after annual cutting to harvest biomass. Expiration of our patents on the technology opens the opportunity for other organizations which control Ni rich natural soils or contaminated soils requiring remediation to commercialize the technologies. Inexpensive methods to remediate/revitalize Ni contaminated phytotoxic soils using agronomic approaches have also been developed and demonstrated at Port Colborne, Ontario, but adoption is delayed until formal agreements with government are completed. These new simple remediation and profitable phytomining technologies can obtain Ni from soils which contain Ni well below levels considered economic for current mining technologies, and the plants biopurify the Ni so it is easy to recover Ni metal from plant ash by pyrometallurgical or hydrometallurgical technologies. Although increasing pH decreases the solubility of Ni in all soils, raising pH increases Ni accumulation by Alyssum species. Hence usual chemical extraction methods for phytoavailable soil metals such as the DTPA- or NH4-OAc-extraction cannot predict Ni accumulation by Alyssum species.

Jan 1, 2016

By Hammenm R., J. Hammen, C. Hammen

"The production of salable Rare Earth Element (REE) products necessitates a sequence of chemical separation steps between the mine and market commodities. The effectiveness of the chemical separations that purify REE salts is critical to the success of the producer, as the purity of REE salt products affects their market price. This is due to the fact that impurities in REE salts, even at low levels, can be deleterious to the function and usability of the end product. The purification of REE by removal of low levels of contaminant has been referred to as "product polishing". The technologies commonly in use for product polishing, solvent extraction (SX) and ion exchange (IEX) are challenged by the availability of separation chemistries to separate the contaminant from the desired REE salt. In simple terms, if a product specification is 99.9% purity, the SX or IEX separation reagents need to have at least a 999:1 selectivity ratio. Significant testing has been carried out on the use of solid phase extraction (SPE) columns to extract low-level impurities such as aluminum or zinc from REE product streams. The SPE columns are nano-composite materials that have rapid equilibration kinetics with the solutes being processed by the columns. The SPE matrices have been modified with chelating ion exchange ligands that bind the contaminating ion with great selectivity in residence times of a few seconds. Thus, REE streams with 1 to 2% of contaminating aluminum ions, have been polished to >99.99% purity. In this paper, results are presented on the removal of aluminum impurity from a didymium (neodymium+praseodymium) product stream using SPE technology. The selection of the SPE medium and the process steps to treat the feed solution for aluminum removal and ultimate stripping and recycle of the solid phase extractant are discussed."

Jan 1, 2014

By D. L. Millar

The hydraulic air compressor (HAC) is driven only by water, held up by a dam, to create relatively low head (typically 10-20 metres), such that the developed hydropower is used to cause flow in openings deeper underground. Air is entrained in the water at the inlet to the sub-surface openings (an air to water volume ratio of 1:1 is reported to be optimal) and is compressed as it is carried along by the deepening water flow. At depth, and with lower water velocities arising from larger cross sectional area tunnels, air bubbles separate out of the water flow and are collected in a receiver space above the flowing water. Water, free of air, then passes back up a return shaft (up-pipe) and rejoins the river or stream flow. In principle, an HAC can produce any pressure and flow rate required, given large enough shafts and enough water supply with head sufficient to overcome frictional resistance in the sub-surface tunnels. Practically, as air solubility in water increases with pressure, HAC installations with depths greater than 100 metres may lead to higher rates of compressed air loss, without special separation measures. A modern HAC application for mine refrigeration and cooling is presented.

Aug 1, 2013

By Randolph A. Pax

"The internal operation of a tumbling mill is a very hostile environment and precludes the sustainable operation of internal sensors to measure the mechanisms of charge motion and breakage events. Instead indirect methodologies are required to expand the current understanding developed within a framework of perfect mixing of the mill contents. A number of measurement approaches have been successfully used to explore the operation of SAG mills including strain instrumented lifter bolts, mill shell strain measurement and thermal (energy balance) of operating mills.Early acoustics measurement was developed by Hardinge using a 'microphone' located close to the expected toe location. This signal was an indicator of the mill fill. Improvements were implemented with the use of two microphones straddling the toe location to try to increase the sensitivity of the measurement and reduce ambiguities. Further improvements included a filtered signal indicative of steel interactions. Unfortunately, the mechanisms of signal generation and the complexity of the processes do not provide a consistent signal.In recent years, advanced acoustic measurement using arrays of microphones utilising signal processing techniques have been implemented as SmartNoise and validated on over 30 mills. This paper will discuss the results obtained with signals such as water holdup, mill shell steel hits and two each of the toe and shoulder angles. An estimate of the internal mill component wear rates is also accessible.Advanced acoustic measurements with wide bandwidths when combined with physics models and process understanding has achieved a step change in the understanding of the dynamic internal operation of a tumbling mills on time scales of 80 ms. These techniques have been used extensively on SAG mills, but have also been applied to FAG and ball mills. Acoustic measurement is used for the rapid diagnosis of mill conditions and holistic control for optimisation and stability."

Jan 1, 2016

By D. R. Schmitt, Q. Jia, R. Kofman

"Tests were carried out on clear glass blocks containing borehole aligned with and at an angle to applied principal stress states in order to study the growth of drilling induced tensile fractures. The samples were illuminated such that photoelastic fringes could be video recorded during the measurements; this was useful in assessing states of stress and in determining fracture initiation. Axial drilling induced fractures were observed at the azimuths of the applied uniaxial stress as would be expected from the concentrated stresses. En echelon fractures were observed from the borehole deviated at 45° to the direction of the compression. These preliminary and currently qualitative results show that glass blocks serve as a useful test medium for studies of stress concentration and drilling induced fracture creation. INTRODUCTIONWith the increasing exploitation of unconventional oil/gas reservoirs using deviated drilling in recent years, the effects of the in-situ stress on the success of energy production have become more critical than ever before. Knowledge of the state of stress in the earth enables us to determine well trajectories, well locations, hydraulic fracturing design and production rates, but knowing the crustal stress is always challenging. Strictly, it can only be obtained to varying quantitative degrees by accessing the earth through drilling. Failure of the rock at the borehole wall produces borehole breakouts (e.g., Bell & Gough, 1979; Haimson & Herrick, 1986; Zoback et al., 1985) and drilling-induced tensile fractures (DITF) (e.g., Aadnoy, 1990; Aadnoy & Bell, 1998; Barton et al., 1997; Brudy & Zoback, 1999; Davatzes & Hickman, 2010; Peska & Zoback, 1995). Thus, it is important to understand the failure mechanism of the rock in the vicinity of the borehole. A number of closed-form expressions have been developed that allow the stress concentrations to be calculated in the vicinity of a borehole including Kirsch’s (1898) 2-D plane strain solution and 3D formulae for elastically isotropic (Hiramatsu and Oka, 1962) and anisotropic (Lekhnitskii, 1981; Amadei, 1983) continua. These solutions have been applied in numerous studies (e.g., Ong, 1994; Ong & Roegiers, 1996; Vahid & Ghassemi, 2011; Jia & Schmitt, 2014; Ito et al., 2001) to analyze the failure mechanisms of drilling-induced tensile fractures (DITF) on the borehole wall."

Jan 1, 2015

By J. W. G. Hannon

FOLLOWING the experimental work of Denny, Robson, and Irwin, and the clinical investigation by Crombie and Blaisdell, an investigation of aluminium therapy was begun at Washington, Pa., which is situated in a very large industrial section of the State. Some of the men to be studied were from plants manufacturing silica brick, refractories used in steel and glass manufacturing, and semi-porcelain table-ware; others were workers in foundries, sand blasters, and men engaged in the quarrying of ganister rock. This group of workmen gave an opportunity to study the effects of aluminium on various types of silicosis which differed somewhat from that found in hard-rock miners. EXPOSURE In their occupations, the men studied were exposed to silica dust concentrations ranging from 17 to 97 per cent free silica. In the silica brick industries, the unfired product averages 96 per cent silica in the form of quartz, whereas the fired brick contains 50 to 62 per cent cristobalite plus 17 to 30 per cent tridymite, forms of silica that, on account of their higher solubility, are more toxic than quartz. The operational dust counts in the plants varied from 15 to 9,500 particles per c.c., and the median particle size from the aerial samples was 1.0 micron for the green product and 2.0 microns for the fired product. The length of exposure varied with the occupation as well as with the individual plant, but disabling silicosis could be produced in less than four years in certain exposures. The average time needed to produce radiological silicosis in those susceptible to this disease was eight years. Some of the men in our series of cases have been treated as long as fifteen years after exposure had ceased, and have improved under treatment.

Jan 1, 1944

By C. W. Eggert

"The idea for this talk came to me last year when I was attending the Canadian Gold Metallurgists Meeting. I talked about it to a friend of mine who is an authority on mineral dressing, particularly the theoretical end of the business. He remarked that this was an excellent technical note, why don't you write it up. This is what I have for presentation this morning. I hope in presenting this type of idea in this way it is in keeping with the tradition of the Canadian Gold Metallurgists which was to function on a not too sophisticated level and where operators could get together and trade ideas in an informal way.My basic thesis is that it should be possible to evaluate screen analyses by the application of the standard statistical probability theory. In any statistical analysis the sample is the first consideration. If we look at existing methods of size evaluation we find it is usually based on the fact that a given particle will pass one square aperature and not another. One system of standardizing how these aperatures will be set up is based on Rittenger' s work with the ratio of hole sizes proportional to the square root of 2. Keeping in mind the limitation we have accepted this as our method of 11 sizing"" in attempting to apply standard statistical methods to screen analysis."

Jan 1, 1968

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By Donald Leroux, Robert Grant

"Flotation is a complex and highly multivariate process. Using the conventional OFf (one-factor-at-a-time) technique, the optimization of flotation circuits through laboratory or plant testwork is difficult, time-consuming and therefore, expensive and often results in marginal improvements. The optimal operating conditions can be more efficiently estimated when a systematic approach like SDE (Statistical Design of Experiments) is taken.The concentrator of Noranda's Brunswick Mining Division (near Bathurst, New-Brunswick) is well known for the complexity of its differential copper-lead-zinc flotation circuits. One of them, the chalcopyrite-galena separation (or CuSep) circuit, is impacted by more than 20 variables.Statistical Design of Experiments (SDE) techniques were applied at the laboratory scale to improve the performance of Brunswick's CuSep circuit. Screening tests were conducted using Fractional Factorial designs while optimization tests were carried out based on Response Surface Modelling techniques like the Central Composite design. Every series of tests, without exception, revealed new information and process insights which led to significant circuit performance improvements in the plant So far, the metallurgical gain may be as high as four percentage points of copper recovery (in the CuSep circuit). Potential cost savings of expensive consumables (steam, activated carbon) have also been identified but will require additional circuit modifications before being realized.IntroductionIn spite of its apparent simplicity, flotation is a complex three-phase (solid, liquid and gas) separation process. Fundamentally, it is a highly multivariate process. Industrial flotation circuits are commonly affected by 10 or more process variables."

Jan 1, 1997

By M. Mirnezami, J. A. Finch

The McGill component of the consortium contributed detailed examination of the electrokinetic properties of the constituent minerals, primarily pentlandite and serpentine. Mineral specimens were derived from an ore sample; mineralogical examination showed the serpentine was predominantly clinochrysotile, a fibrous mineral responsible for much of the flotation separation problem. The study included design of a novel sedimentation potential measuring device to classify the surface charge of the ore and electrophoresis measurements on single and mixed minerals which progressively approached flotation conditions. The sedimentation potential measurements provided a general association between surface charge and the visual state of aggregation as a function of pH. The electrophoresis experiments started with single minerals in a background of indifferent electrolyte and progressed to mixed minerals in a background of supernatant derived from an ore sample. The single mineral tests supported the suspected electrostatic interaction, i.e., hetero-coagulation, at flotation pH 9-10. The mixed mineral tests demonstrated this interaction and also revealed hetero-coagulation with Mg(OH)2 precipitates, derived from the supernatant. This interpretation was confirmed by optical and electron beam imaging. A series of agents, CMC, polyphosphate, soda ash, EDTA, were examined to disperse the system. To accommodate the small mass of single mineral available a novel turbidity measurement using a UV/Vis spectrophotometer was introduced. Selected conditions were used in contact angle and small-scale flotation tests.

Jan 1, 2011

By Miguel A. Cuba

Trends in the mean and/or variance are a longstanding challenge in mineral resource modeling. Geologic modeling and/or grade domaining are often employed to account for heterogeneities in mineral grades; however, this is only practical up to a certain point since the number of data available for reliable model construction can be severely reduced. In such cases, trends remain present in certain geologic/grade domains and directly impact the modeling methodology; the trend must either be handled explicitly or a suitable approach is adopted to implicitly account for it. This is highly dependent on understanding the source of the trend. We propose an approach that detects the source of non-stationarity, which is based on quantifying the impact of non-stationarity in the mean and the variance via the semivariogram. By expanding the methodof- moments approximation of the semivariogram, we decompose the experimental semivariogram is into three terms: 1) trend in mean component, 2) trend in variance component and 3) stationary component. We can then assess the source of trend by calculating the contribution of each component at every lag. Two cases are presented to illustrate this tool. Firstly, a synthetic reference model is simulated and different trend patterns are added; the influence of these patterns in the experimental semivariogram calculation are analyzed and discussed. Secondly, a real dataset is considered where the impact due to the presence of trends in the mean and variance are assessed. The results of this paper reveal the semivariogram to be a tremendously powerful tool in determining the source of the trend. This insight may be useful in the selection of a suitable modeling approach for resource estimation.

Oct 1, 2009

By Robert E. McIvor

"Use of the Bond Work Index to size industrial grinding equipment was widely known. Bond also described its application for measuring grinding circuit efficiency. Bond Work Index efficiency also has been used extensively by industry, but until now without concise standard methods, or a formal guideline, for doing so. The Bond Efficiency Sub-Committee of the Industrial Comminution Efficiency work group of GMSG has produced such a guideline, which is appended hereto. It covers the methods and provides examples of how to calculate the Bond Work Index Efficiency of most industrial grinding circuits. Bond Work Index testing equipment and methods are also provided.Comminution is responsible for a major portion of mineral processing plant energy consumption and operating costs. Bond Work Index efficiency provides valuable means, first, for benchmarking one’s plant performance against others in the broad industry, and hence defining the extent of the opportunity for improvement. Secondly, improvements in circuit efficiency with implemented changes can be quantified and monitored as part of continuous improvement efforts. These two important business activities are thus facilitated, and, in the absence of any other accepted method, otherwise would be lacking without the existence and application of this standard for comparison. While often loosely applied in the past by plant metallurgical staffs, the increased precision offered by this guideline provides much clearer definition of both the conceptual and statistical meaning of these measurements. Even a small improvement can be enormously financially important, but only if differentiated by measurement. This guideline was thus intended to provide industry improved means to differentiate comminution circuit efficiencies. Carbon footprint reduction is coincidental, but nevertheless can be substantial.The next steps are: (1) to establish standard reference testing materials and one or more laboratories to serve as bases for reference testing; (2) to establish the accuracy of relative circuit Work Index Efficiency determinations; and (3), to develop and provide a public data base of industrial comminution circuit Bond Work Index Efficiencies."

Jan 1, 2016

By Miguel A. Cuba

Resource models are generally constructed using data of different types and/or from different sources. A common issue is the consistency of scale in the information that often leads to a requirement to composite the data prior to model construction. For the purposes of mine planning, development and/or resource assessment, this model may then be upscaled to a relevant selective mining unit. It is well established that the geostatistical parameters for resource model construction is scale dependent. In particular, the volume variance of integrating these various scales has a direct impact on the variogram that should be used in model construction and/or the assessment of volume variance relations as it affects resource estimation. The scaling laws are a set of guidelines that detail how the variogram should change as a result of a change in the volume; these laws are empirically derived and involve some simplifying assumptions, not the least of which is an assumption of shape invariance in the variogram structure. An alternative approach was proposed to directly upscale the variogram via numerical integration, which demonstrates that the assumption of shape invariance is not required and we can directly access the new variogram shape given any volume of interest. This paper compares these two different approaches to variogram upscaling by considering two applications: the first corresponds to a 2D synthetic case and the second looks at a 3D case with data from a porphyry copper deposit. The simulation studies in these cases show that the direct upscaling approach performs better than the scaling laws in fitting the average experimental variogram values at any block size. This is based on a mean absolute error criterion. Moreover, it is also shown that with an increase in the block size, direct variogram upscaling significantly outperforms the scaling laws approach.

Oct 1, 2009

By J. Bardinas

"The use of autogenous mills has become widespread, owing to their capacity and favorable capital and operating costs. Optimal operation of these systems is critical, given their high energy consumption and effect on downstream processing. A considerable effort has been spent over the years in the development of advanced control systems to achieve a better performance in this regard. However, despite significant advances, the problem still remains challenging, owing to the nonlinear behaviour of the system with respect to the mill variables, and, the unmeasured ore variability come from the mine.The mill load, in particular, can be seen as a state variable of the mill, which could be important for; modelling and control, and, important insights into the mill behaviour. In this investigation, time series cluster analysis was performed using online mill load measurements in order to identify the different control states of the mill. More specifically, this time series was divided into short non-overlapping segments. A distance matrix was set up for each segment and the information was captured by means of textural features, similar to that used in multivariate image analysis. These wavelet and grey level cooccurrence matrix features could subsequently be used to rapidly identify the normal operating conditions from the feed disturbances in the mill.In principle, the methods and models presented here, once suitably validated and calibrated, could be used in online process monitoring of autogenous mills. They also could serve as a foundation for developing more advanced process control models."

Jan 1, 2016

By D. K. Sarkar, Ying Huang

"Superhydrophobic thin films were fabricated on aluminum alloy substrates by chemical etching followed by passivation with organic acid molecules; (ii) electrophoretic deposition (EPD) of functionalized ZnO nanoparticles and (iii) electrodeposition of organic-inorganic composite materials. The physical and compositional analyses of the deposited thin films were characterized by SEM, FTIR, XRD as well as contact angle goniometer. The contact angle and surface roughness of the superhydrophobic surfaces prepared by the chemical etching process were found to be 156° and 2.29 µm, (ii) by the EPD process were found to be 155° and 4.54 µm and (iii) by the electrodeposition process were found to be 159° and 7.11 µm, respectively.The corrosion properties were analyzed with both polarization and electrochemical impedance spectroscopy (EIS) in NaCl aqueous solutions. The results demonstrate that the superhydrophobic thin films on aluminum alloy substrates display better anti-corrosion behavior than the as-received aluminum substrate. The comparison of results pertaining to the compositional and corrosion properties of these thin films on aluminum will be discussed in this work.INTRODUCTIONSuperhydrophobicity is defined as a surface property which provides non-wetting characteristics with a water contact angle larger than 150°. It is observed that the creation of certain micro-nanoroughness structures promotes the entrapment of air in the spaces of the rough surface morphology. In addition, lowering the surface energy helps to reduce the affinity of water drops to the surface, thereby weakening the water-surface interaction. Recently, various fabrication methods for superhydrophobic surfaces have been explored (Sarkar, 2010, Huang, 2010, 2011, 2013, 2015a, 2015b), such as the sol-gel process (Brassard, 2011), plasma treatment (Marchand, 2013), chemical vapor deposition (Zheng, 2009), chemical etching (Saleema, 2011), electrodeposition (Ying, 2011) and electrophoretic deposition (EPD; Huang et al., 2015b)."

Jan 1, 2016

By R. B. Harkness

Many of us are familiar with the history of oil in the Province of Ontario, but for the benefit of those who have never heard the story I will repeat it. In 185 7 J. H. Williams, of Hamilton, an old-country Scotchman, who had the advantage of experience gained from the primitive methods used for refining the oil collected at seepages in Roumania, heard of the "gum beds" along Black creek in Enniskillen township, Lambton county. He erected a small plant in the bush and refined illuminating oil, where the village of Old Springs now stands. The labor of collecting this thick ?gummy substance from the sluggish water of the creek, prompted him to dig a well, the next year ( 1858), in the hope of obtaining a greater quantity. When his excavation reached a gravel bed on top of the rock, oil, resembling "lubricating oil of commerce", rose several feet. Several of these wells were dug and his refining business flourished. The following year the Drake well, in Pennsylvania, was drilled into rock, resulting in an oil find which encouraged one James Shaw to make a similar attempt on Black creek. With a spring-pole drill he completed his well in the spring of 1861 to a depth of 160 feet, and at that depth struck a gusher that flowed uncontrolled for several days. Great excitement followed and the village of Oil Springs had a mushroom growth. The Petrolia field was discovered in 1865. Lick followed up the Thames with a spring-pole rig testing the formations along that river and discovered the original Bothwell field in 1865. During the sixties wells were drilled in many counties in southwestern Ontario.

Jan 1, 1924