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In the leaching and recovery of gold from copper containing gold ores using cyanidation, some copper minerals also dissolve which can have a detrimental effect on the process efficiency and economics. There are also environmental concerns with current operations discharging cyanide and copper cyanide species into tailings dams, and strict regulations prohibit this for greenfield plants. Cyanide destruction however is not an economic option for new plants treating copper-gold ores. This paper evaluates a potential recovery process to overcome the copper cyanide problem. Despite gold dissolution occurring in copper cyanide solutions having no free cyanide, gold recovery from ores is lower compared to free cyanide. Thus, cyanide addition has to be optimised to maximise the gold recovery whilst endeavouring to eliminate free cyanide at the completion of leaching (CN:Cu less than 3:1). Subsequently, copper cyanide can be recovered using activated carbon. The loaded copper cyanide is easily recovered from the carbon with a cyanide soak and distilled water wash such that the eluted CN :Cu ratio is less than 4:1. The copper could be recovered efficiently by electrowinning, by decreasing the pH of the eluant to 5. The remaining cyanide solution, after electrowinning, is then neutralised to form NaCN and recycled.

Jan 1, 2005

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005

By R. J. Brailey

"A USER'S VIEW OF CONVEYOR WEIGH SCALESThe Sudbury Operations of Falconbridge Nickel Mines Limited includes seven mines, three concentrators and a smelter. The flow of ore, concentrates, fuel and fluxes between and within these plants requires measurement for accounting and control. The design, installation and maintenance .of weighing systems falls within the responsibility of the Instrumentation Department of Falconbridge Nickel Mines thus al lowing a common approach to conveyor weighing problems and the benefit of a common spares supply. This paper gives a brief overview of the recent experience with conveyor scales within the Sudbury Operations and discusses the problem areas.GeneralThe best way to establish the total amount of material going to or from a process is with a bucket and a stop watch. Unfortunately the flowrates involved in mining plants make the buckets very large, but wherever it is feasible static weighing is the preferred method of determining total quantity. This applies particularly to batch systems, where the material can be brought to rest long enough to allow a very accurate weight determination. Any form of weighing in motion is susceptible to variations in the forces of the transporting system. A belt scale is affected by its position on the belt, idler alignment, support stiffness, variations in belt tension, material spills and build-up, and a host of other factors all of which require careful consideration in any installation.As with instrumentation applied to any system the plant should be designed to ensure that the best results can be obtained from the equipment. This means getting the scale supplier together with the conveyor supplier as early as possible in the designing of a new plant. Any corners cut in scale installation will be paid for later in poor results and/or increased maintenance."

Jan 1, 1975

By W. B. Boggs

Part 1 Originally, the copper produced at the Noranda ?smelter was shipped in the form of blister bars to the Laurel Hill refinery of the Nichols Copper Co., New York. In 1930 a refinery was built at Montreal East for the purpose of refining Noranda copper and copper from the Hudson Bay Mining and Smelting Co., at Flin Flon. After investigation of the probable costs of making anodes at Noranda and at Montreal, it was decided to make them at Noranda rather than to continue to make blister bars there. Fuel is a major item of expense in making anodes: and since less fuel would be required in making anodes from molten copper than in making them from blister bars, a lower anode furnace cost could be expected at Noranda than at Montreal. Further, the expense connected with making blister bars at Noranda would be eliminated. The cost of treating anode and wire bar furnace slags is a serious item in a refinery, and it was found that the cheapest method would be to ship such slags back to Noranda. With the anode furnace at Noranda, much less anode furnace slag would be made at the refinery. Against these savings which would be effected by making anodes at Noranda must be set the high operating cost of an anode furnace at Montreal, using only tank-room scrap and the Flin Flon copper. This furnace would be handling a comparatively small tonnage and would have a high cost per ton. The usual equipment for making anodes from. liquid copper consists of either a stationary reverberatory furnace or a tilting Tacoma-type furnace together with an anode wheel of the Clark or Walker type. The reverberatory type of furnace has been developed from the furnace used in the old Welsh process of smelting and refining copper, while the tilting furnace is a development of the holding furnace, which is essentially a Peirce Smith converter without tuyeres and provided with burners.

Jan 1, 1932

By L. A. Anestiev

A method based on use of calorimetric data for the determination of solidification kinetic parameters is proposed. The method incorporates recent theories of nucleation and growth and allows modeling heat fluxes observed in calorimetric experiment. Statistically optimal estimations of the kinetic parameters, which include the activation's energies of nucleation and growth, are derived from experimental data by means of nonlinear regression analysis. The method is applicable to pure substances and alloys. The evaluation of the kinetic parameters characterizing solidification of pure Al is used for clarifying and exemplifying the method.

Jan 1, 2004

By P. C. Sui

Numerical investigation and parametric simulations of the coupled electrical conduction and mass diffusion in the GDL of a PEMFC are reported. The coupled transport is solved using a 2D, "under-the-rib" computational domain for the cathode GDL. The current density on the GDL/catalyst layer interface, which constitutes one of the boundary conditions for the GDL domain and reflects the activation overpotential in the catalyst layer and the ohmic loss in the membrane, is solved iteratively using a novel numerical algorithm. A parametric study is performed to investigate the effects on current density distribution of various operating conditions such as oxygen concentration and membrane resistance, and of design factors such as GDL geometry, anisotropic transport properties, and deformation under the land area. The results show that the current density distribution under the land area can be dominated by either electron transport or mass transport, depending on the operating regime.

Jan 1, 2005

By Wei Wei

Mining induced ground movement and/or stress redistribution could cause ground instability issues. This is particularly true when the extraction of large stopes is done with one or two large production blasts. Often enough, it is the nearby mine development like haulage drifts and cross cuts that are influenced the most by production blasts. Proper and timely mitigation of ground control issues due to stress redistribution is required. This is usually done by drift rehabilitation involving the installation of secondary support system in the affected areas of the mine development which include; slashing, wire mesh, and in some cases the use of shotcrete liners. It is imperative that such rehabilitation be implemented to the mine infrastructure in a timely manner in order to avoid aggravated ground control problems and production delays. If the real time performance of the support system is captured, it would be possible to determine the timing for rehabilitation job. Birchtree Mine in Thompson, at the Vale Manitoba Operation, has begun mining the 84 Deep Orebody. One of the identified risks is the stability of the crusher room under mining induced stress redistribution. It is proposed to use the U-Cell technology to monitor the primary support system performance (rebar bolts and extension bolts) and monitor the real time performances of the bolt axial loads. The U-Cell technology is a 7-inch long, coupler load cell that is screwed onto the threaded portion of a rock bolt prior to installation. Rehabilitation in the vicinity of the crusher area where U-Cells are installed is recommended when the bolts have reached 70% of their yielding capacity. Catastrophic ground failure can be avoided by adding secondary support in a timely fashion. This paper presents a case study at Birchtree Mine in Thompson Manitoba, where the performance of primary ground support system is monitored and recorded during production.

Jun 1, 2012

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

By A. Desbiens, M. Maldonado, R. del Villar, Aguilera. R.

This work details the application of a multiple model approach to estimate frother concentration in flotation processes. The methodology consists of identifying a set of linear dynamic models representing the effect of gas rate on the collection-zone gas holdup at different known frother concentrations (calibration step). An adaptive law is then obtained using Bayes' rule to evaluate the conditional probability that each model represents the observed system behavior. In this way, a frother concentration estimate is calculated as a weighted sum of model probabilities and their associated (known) frother concentrations. Experimental results conducted in a two-phase system using Dowfroth250C are promising. Modeling and analysis for MIBC frother are also provided.

Jan 1, 2009

By W. G. Schultz

"Sylvite's potash mine, which produces 8,000 tons of ore per day, probably ranks as one of the most highly mechanized and automated mining operations in the world. Employing, on a normal 10-hour production shift, one supervisor and a crew of seven operators, Sylvite is able to mine at an average rate in excess of 600 tons per hour. The ore is produced by two Marietta miners weighing 258 tons, the largest and heaviest pieces of equipment ever taken underground. The ore produced by these two Marietta miners is conveyed to the shaft area, cycled through a 15,000-ton storage system and hoisted to surface completely automatically. The operation of all equipment in the mine can be monitored and controlled from a central control panel located underground. Because Sylvite's mine is a new operation with equipment of a new design, the full potential of the operation has not yet been realized. The ultimate capability is clearly evident from the success Sylvite has had over the past year as the average mining capability has risen from 100 tons per hour to 600 tons per hour."

Jan 1, 1973

By William C. Browning

An economic drilling programme is one which costs the !east in chemicals, equipment, and time. The basis for such a programme with rotary drilling techniques is a drilling fluid in which bentonites do not swell. This is recognized in the growing trend toward gyp and other inhibited mud systems. Therefore, even though the mechanism of thinner action is a subject of applied colloid ,chemistry, the understanding of this mechanism is of economic importance in controlling the flow properties of inhibited muds. In phosphate, or sodium tannate, conditioned muds that are relative-!y free of contaminating-electrolytes, the thinner, or dispersing agent, is adsor.bed, ?creating an electrical double layer about the clay particles. The mutual repulsion of these charged particles effects colloidal stabilization, or deflocculation of the suspended clays, as discussed by Norton and others. In inhibited muds, however, the electrolyte concentration in the filtrate is sufficient to collapse the double layer and flocculation of the mud solids occurs, as evidenced by increased viscosity and gel values. Chemicals to control the flow properties of inhibited muds, therefore, are vital to the successful use of these systems as it is not always economical to adjust flow properties by watering back. Flocculation of suspended particles, as indicated in the work of Vervey, Overbeek, and others, is due primarily to gravity-like, long-range Van der Waals forces. Prevention of flocculation may, therefore, be secured by the interposition of any barrier between the particles, the thickness of which approximates the extension of the Van der Waals at-traction. Organic polyelectrolytes, such as Kembreak, Rayf!o, and Q-Broxin, may act to increase the double layer charge when used in small amounts in fresh-water muds. More important, however, is the fact that in inhibited muds an increase in concentration of the polyelecholyte permits the formation of a condensed film adsorption layer of the polyelectrolyte about the clay particle. When this occurs, the extremely viscous condensed adsorption layer creates a mechanical. barrier that prevents flocculation of clays, even in the presence of inhibiting concentrations of elecholytes. Rheological evaluation of the degree of deflocculation, or colloidal stability, may be made by utilizing the known effects of particle inter-action and volume concentration on the flow properties of suspensions. Rheological evaluation should be supplemented by direct microscopic or ultra-microscopic observation.

Jan 1, 1958

By P. Chollet, A Constant

THE RESULTS of a previous investigation ( 1) on the work-softening of some heat-treated steels have led to the conclusion that the occurrence and intensity of the phenomenon is possibly governed by the work-hardening capacity of the material, and the relative amount of retained austenite. The first assumption is compatible with Polakowski's theory (2) that the absence of work-softening, in steels quenched and tempered at relatively low temperatures, may be attributed to the high rate of work-hardening which compensates for, and even out-weighs, the loss of internal energy associated with the simultaneous rearrangement of the original system of internal stresses. Indeed, Polakowski first considered the work-softening as a manifestation of a partial release (by cold-working) of the latent strain energy stored in

Jan 1, 1962

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By C. M. Trigg

"PEC uranium deposit, 100 km southwest of Coppermine, was discovered by diamond drilling in 1976 following ground and airborne geophysical surveys, geological mapping, geochemical surveys and boulder prospecting that were initiated as the result of the discovery of uraniferous sandstone outcrops in 1969 by geologists of Aquitaine Company of Canada Ltd.The deposit is within gently northeasterly dipping medium to coarse-grained Unit 11 quartzitic sandstone of Neohelikian Dismal Lakes Group. The deposit is from 10 m to 70 m above the base of the sandstone which, beneath the deposit, non-conformably overlies weathered and altered Aphebian granite of Great Bear Batholith or unconformably overlies rubble breccia, conglomerate and medium-grained Unit 8 sandstone of Paleohelikian Hornby Bay Group.A northeasterly trending, 500 m wide graben, bounded by the steeply dipping northeasterly striking Imperial and Aquitaine faults, contains the deposit which is 1.1 km long by up to 340 m wide. The deposit overlies a post-Hornby Bay Group, pre-Dismal Lakes Group topographic high. Uranium principally occurs as stratabound, often peneconcordant bands; a lesser amount of uranium is fracture controlled.Stratabound uranium exists in gently easterly dipping, subparallel bands ranging in thickness from 1.5 m to 6.0 m. Pitchblende, coffinite and sooty black uranium oxides occur as interstitial disseminations and grain coatings subparallel to bedding; they also replace pyrite and form narrow veinlets.Small amounts of torbernite, carnotite and cuprosklodowskite coat pitchblende and are disseminated within mineralized bands. Pyrite, marcasite, chalcopyrite, chalcocite, cove/lite, digenite, azurite, malachite, arsenopyrite, glaucodot, niccolite, bravoite (? ), goethite, hematite and magnetite as well as quartz, barite, calcite, biotite, chlorite and clay minerals exist within the mineralized bands. Uranium grades of 0.1 % to 0.3 % U3O8 over thicknesses of 1 m to 2 m are typical.A steeply dipping fracture zone near the Imperial fault contains sooty black uranium oxides, torbernite, carnotite and cuprosklowdowskite as well as sulphides, cobalt arsenides, quartz and carbonate. The zone may reach 70 m long; its true width is about 1.9 m. Uranium grades range up to 5.18% up, over0.9m.Pitchblende and coffinite from PEC deposit have been dated at 1.08 ± .10 Ga with possible remobilization at .45 Ga. The deposit contains an inferred 3,150 tonnes of U3O8."

Jan 1, 1986

By L. Voisin, K. Itagaki

In the reductive smelting of the copper concentrate like a blast furnace operation using coke as fuel and reductant or in processing the copper concentrate which contains coal in the bulk, a sulfur-deficient matte phase often coexists with an iron base alloy in the bottom of the smelting furnace. This alloy is generally called furnace residue or speiss when considerable amount of arsenic or antimony is contained in the alloy and in the extreme case of reducing condition the alloy is saturated with carbon. As a fundamental study to know the behavior of some precious metals such as silver, gold and platinum between the sulfur-deficient matte and the furnace residue or the speiss which are in equilibrium under reducing condition, the phase relations and distribution of precious elements in the Cu-Fe-S-As and Cu-Fe-S-Sb systems saturated with carbon were determined at 1473 K by a quenching method.

Jan 1, 2007

By W. A. Jones

"The Hollinger gold mine is in the Porcupine area, Cochrane district, in northern Ontario. The adjacent town of Timmins, which has a population of 25,856, lies 490 miles by railway north of the city of Toronto.The property was staked in the late summer of 1909. The original four claims were staked by Benjamin Hollinger, after whom the mine was named. Development commenced in the autumn of 1909 and mill construction in the winter of 1910. A catastrophic forest fire swept the district in 19ll, destroying the surface plant, so that the original 300-ton mill was not completed until June 1912. From that date up to December 31, 1945, 44,280,750 tons of ore have yielded 13,636,796 oz. gold and 2,613,354 oz. silver. The total value of the production has been $363,638,315.0REBODIES AND MINERALIZATIONThe orebodies consist of quartz veins, stringer lodes, and scockworks, with associated pyritized wall-rocks. The width of individual orebodies, as exposed by mining operations, ranges from 1 to 70 feet and averaged approximately 10 feet in 1942. The vein system forms a complex pattern in a favourable zone, which in places is 6,000 feet long and 4,000 feet wide. The deepest level being developed is 5,150 feet below the surface. Few veins are persistent for long distances, although some are continuous for more than 1,000 feet longitudinally and vertically.The host rocks consist of a closely folded series of Precambrian lava flows of Keewatin age. These are schistose and hydrothermally altered, but are believed to have originally been of intermediate to basic composition. The schistosity strikes N.70°E. and dips to the south at 75° to 80°. The structure of the formations is complex, but in the principal ore-bearing zone the general dip of the flows is to the south at a slightly flatter attitude than the schistosity."

Jan 1, 1954

By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By D. A. Beattie

Talc is a commonly encountered gangue mineral in metal sulfide flotation. Talc is naturally hydrophobic, resulting in high recoveries if polymeric depressants are not used to specifically reject this MgO containing mineral. We have studied the adsorption of a selection of polymers onto talc using a variety of techniques. Adsorption isotherms have been determined using ex situ depletion techniques and in situ ATR-FTIR spectroscopy has been used to determine adsorption kinetics. Adsorbed layer thicknesses have been determined for the polymers on cleaved talc surfaces using the AFM. The effect of the adsorbed polymer layer on the properties of the talc surface has been quantified through contact angle measurements and single mineral flotation tests. Distinct correlations are observed between the adsorbed layer properties and the flotation performance of the polymers. These observations are discussed with reference to the bubble-particle attachment process and the molecular structure of the polymers.

Jan 1, 2006

By A. G. Roach

IT IS generally stated that the gold ores of Nova Scotia are free-milling, and for the most part this is true. However, there is a certain proportion of the gold finely disseminated throughout the sulphides, notably arsenopyrite, and this gold is definitely not recoverable as 'free-milling' gold by amalgamation. The proportion of free-milling gold to total gold seems to vary widely in different localities in the Province and is lowest in deposits of the fissure-vein type. The problem of recovery of these relatively recalcitrant values is usually one of economics, in some plac.es a simple gravity concentrate being of such low tenor that its extraction and subsequent disposal will not bear the costs involved. In other cases, such a high percentage of values escapes from the mortars and plates that concentration is definitely indicated. The size of the mining operation is also an important factor. In the large majority of cases, however, some concentrating step is warranted, even if the resulting concentrate is stock-piled until sufficient has accumulated to justify further treatment.

Jan 1, 1940