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By A. A. Goss

We investigate the relationship between corporate financial performance (CFP) and environmental and social performance (CSP) in a sample (n=165) of large, publicly traded U.S. mining and oil and gas firms. Using optimally scaled principal components analysis to generate aggregate measures of CSP strengths and concerns, we find higher concerns are related to higher volatility of unexpected earnings and discount rates. Furthermore, these earnings shocks are more likely to be negative as concerns increase. Decomposing this relationship shows that negative environmental performance dominates proactive environmental management as a driver of unexpected earnings, but proactive community efforts increase the magnitude of earnings shocks. We document some evidence of the strategic use of CSR, with those firms that have greater risk investing more proactively in CSR.

Aug 1, 2013

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By G. I. Mathieu

"An experimental study was carried out to evaluate the performance of column flotation versus conventional flotation for the recovery of molybdenite from a Newfoundland ore. The objective was to verify the claims made by the inventors of the flotation column, Messrs. Pierre Boutin and Remi Tremblay, that their apparatus reduces the entrainment of fine gangue and other mineral impurities in the froth product. The research included a factorially designed series of tests to determine satisfactory operating conditions of the column. These provided a basis for comparative flotation tests with column and Denver cells. In the course of the work, the action of a few depressants was studied. Results indicated greater selectivity in the column and reduced reagent consumption."

Jan 1, 1972

By Fr. -W. Bach

In the past years the enormous weight saving potential of magnesium sheet has been demonstrated by various research projects all over the world. It has been shown magnesium flat products can benefit automotive, aviation, machine tool and consumer electronics industries. Major material problems such as poor formability, corrosion resistance and high production cost still inhibit the application of magnesium sheets in large scale production. The present contribution outlines achievements in casting and rolling technology. The authors developed an adapted strip casting process in which near-net-shape rolling feedstock of several wrought alloys has been produced. During the rolling process, various parameters were varied in order to modify the microstructure and surface quality of sheet. Several temperature cycles, strains, lubricants, roll surface structures and roll coatings have been analyzed. The sheets were examined and tested in deep-drawing experiments. Suitable rolling schedules have been developed for standard and modified wrought alloys. The study concludes with an overview of current industrial solutions and an estimation of the potential cost savings that might result from the adaptation of the process that has been developed.

Jan 1, 2006

By V. I. Ryaboy, S. A. Kondratyev

"The paper describes influence of desorbed species (DS) of a number of xanthates and higher dialkyldithiophosphates on the collective ability of these reagents. Adsorbed on mineral DS of the reagents in the form of products of non-stoichiometric interaction between xanthates and heavy metal salts can pass to the gas–liquid interface and remove liquid from the layer between mineral particle and water surface. A high-speed video recording displays the process of spreading of DS of xanthates and dialkyldithiophosphates over water at the moment of local rupture of the water layer. Expansion of “dry” spot on the mineral surface after DS of xanthate capture and displace liquid from the layer has been proved with video images. The comparative analysis of collecting ability and dynamic surface activity of dialkyldithiophosphates shows that these characteristics are in good correlation. The forces exerted by spreading film of the reagent’s DS on liquid in the water layer are evaluated, and the water flow rate from the layer is determined. The line of the reduction in thickness of the water layer behind the front of spreading film of DS of dialkyldithiophosphates and xanthates coincides with the line of the increase in their dynamic surface activity. Their force on the liquid volume in the water layer characterizes collecting ability of the DS film of xanthates and dialkyldithiophosphates. It has been supposed that the collecting ability of DS of a reagent is a part of its overall flotation activity, conditioned by surface tension of solution and, thus, defined by the structure of hydrocarbon fragment of the reagent.INTRODUCTIONIt is believed that collecting ability and selectivity of collecting reagents is mainly governed by adsorption of a reagent at the solid–liquid interface. A few studies have shown that activity of collecting reagents at the gas–liquid interface may have deep influence on their collecting capacity and selectivity. Experimental researches have revealed correlation between surface pressure in a carboxylic acid film on liquid’s free surface and floatability of useful components (Kulkarni & Somasundaran, 1975; 1980; Quast, 2006). According to Quast (2006), it is not always that surface pressure of a reagent film influences collecting ability of carboxylic acid. For instance, pH range of adsorption of tetradecanoic acid on hematite does not coincide with pH range of high surface pressure. So, surface properties of this acid contribute little to flotation efficiency.The correlation between reagent film surface pressure and mineral floatability has been reveled for quartz and cationic reagents, too (Bleier, Goddard, & Kulkarni, 1977). Finch & Smith (1973) showed that combination of adsorption of ion–molecular amine complexes on mineral surface and high surface tension of “fresh bubbles” was favorable for flotation performance. The use of bubbles with reduced surface tension resulted in a decrease in quartz floatability."

Jan 1, 2016

By David S. Wong

With air emission limits for total particulates continually tightening, management of `potroom dust' or airborne particulates from aluminium smelting potrooms is of increasing importance. To better understand how settled and airborne particulates are generated within a potroom, methodologies have been developed to sample and analyse the compositional signature of dust, in relation to its sources. During a smelter case study, these methods allowed tracking of mineralogical phases in dust across a range of potroom locations, showing that the mechanisms of dust generation do vary spatially and vertically in a potroom. Such methodologies may also be applicable to other metallurgical industries.

Jan 1, 2011

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By E. Lee Cameron

The old mine workings on four barite-fluorite veins of the Lake Ainslie district, Nova Scotia, were opened recently and channel sampled. The samples were then forwarded to the Ore Dressing Laboratories, Bureau of Mines, Ottawa, for chemical analyses. Following the analyses, the sample rejects were combined to form bulk samples, representing ore from each vein, for small-scale batch test work. Tonnage samples from the veins, for pilot mill testing, were submitted when requested by the Bureau. The results of the analyses on the channel samples showed that there are two grades of ore in the di strict, represented, for test purposes, by the Trout River vein and Johnson vein ores. Small-scale and pilot-plant test work was undertaken on both these ores. The Trout River ore is amenable co concentration but, because of the high-barite-co-fluorite-co-calcite ratio, a fluorite concentrate was not obtainable from the Johnson vein ore as received. However, Johnson ore blended in a 1 :1 ratio with Trout River ore gave a mill feed that was readily concentrated. The test work on these ores showed that the following concentrates are obtainable : (a) A barite concentrate, with a recovery of 85 to 95 per cent of the available barite, analysing 93 co 96 per cent BaS04, 4 co 6 per cent CaF,, and 0.5 co 2 per cent CaCO3. (b) A fluorite concentrate, with a recovery of 80 co 85 per cent of the available fluorite, analysing 94 to 97 per cent CaF, , 1 to 3 per cent BaSO., and 1 to 3 per cent CaCO3

Jan 1, 1945

By Mari Yamamoto

Controlled thermolysis of gold(I) complex, [Au(C13H27COO)(PPh3)], at 180 °C for 5 h under an N2 atmosphere affords the new type of monodispersed spherical gold nanoparticles capped by myristate and a small amount of PPh3 ligands (average diameter 23±1.5 nm), in spite of no use of solvent, reducing agent and stabilizer. Much attention has been paid to the preparation and structure determination of transition metal nanoparticles, because of their widespread use in technological applications.1 In general, the chemical reduction of metal salts and organometallic complexes2 by the use of reducing agent is carried out to prepare gold nanoparticles. In some cases, a large amount of solvent and stabilizers such as surfactants,3 polymers4 and ligands5 are used to prevent agglomeration of particles and control the particle size. For instance, Brust et al. reported a two-phase reduction of AuCl4 - by NaBH4 in the presence of dodecanethiol as stabilizer to prepare gold nanoparticles.6 On the other hand, O?Brien et al. recently reported an one-phase preparation of gold nanoparticles by the reduction of AuCl4 - by NaBH4 in the mixture of tri-n-octylphosphine oxide and octadecylamine which act as both solvent and stabilizer, but this procedure also needs reducing agent.7

Oct 1, 2003

By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By V. Chatain

The environmental assessment of historical mining sites contaminated with various inorganic species, as also the determination of remediation targets require a better knowledge of pollutant-bearing phases. The objective of this paper was to investigate the operational fractionation of arsenic (As) in an As contaminated (ca. 3 wt%) soil collected from a gold mining site in France, where mining activities and smelting processes of gold ores took place until 2004. Single and sequential chemical extraction procedures were performed to evaluate the potential mobility of As according to the fractions to which it was associated in the contaminated soil, and also the part of As sorbed onto soil particles. These procedures used provided information on the nature of As fixation processes in the mining soil studied. Results showed that As appeared mainly sorbed (ca. 72%) with iron on the soil particles, in particular amorphous iron oxyhydroxides. These results confirmed a potential risk of arsenic mobilization under acidic and/or reducing conditions, which frequently occur in mining environment. This research evidenced the importance of the knowledge of As-bearing phases to better predict the mobility of this pollutant and in turn improve the management of As contaminated sites.

Aug 1, 2013

By Xiang-dong and Zhu, Xia-jie Hao, Yi-lin Fan, Quan Jiang, Lian-xing Hu, Xia-Ting Feng, Shao-jun Li

"Columnar jointed basalt (CJB), which typically originates from lava flows, is characterized by a special geological structure. The joint network inside the CJB is self-organized into a rough hexagonal arrangement. The field test and measurement during the unloading excavation showed that the columnar joint sets and other internal joint sets not only are important for determining the mechanical properties of the CJB, but also induced its asymmetric unloading deformation and failure. A constitutive model, which considered mechanical deterioration of both the joint sets and rock blocks, was also developed to simulate the unloading behaviour of the CJB. The crack-confinement supporting method for surrounding CJB was developed to overcome the failure of columnar jointed rock mass in the diversion tunnel. Application to the CJB segments of the diversion tunnels in the Baihetan project indicated that this supporting method was reasonable and efficient. INTRODUCTIONColumnar jointed basalt (CJB) rock mass, which typically originates from lava flow, is characterized by a special joint structure. The joint network of the CJB is self-organized into a roughly hexagonal arrangement and leaves behind an ordered colonnade. The widely accepted current view regarding the formation of columnar jointing involves a thermally induced contraction–cooling mechanism (Peck and Minakami, 1968; Degraff and Aydin, 1987; Budkewitsch and Robin, 1994; Lore et al., 2000; Goehring et al., 2006). Although the columnar basalt formation mechanism is fairly understood, the geotechnical characteristics of such rock mass are not well established. In practice, joint sets always induce the multi- failure modes of surrounding rock in the tunneling space (Ibarra et al., 1996; Waltham and Swift, 2004; Mahendra and Bhawani, 2008).According to conventional wisdom in rock mechanics, structural joints affect the mechanical response of rock mass by introducing strong anisotropic effects (Barton and Bandis, 1980; Hudson and Priest, 1983; Brady and Brown, 1985). The columnar jointed rock mass should be considered an anisotropic material given that the joint sets are distributed with some principal directions and characteristic spacing distributions (Cundall and Fairhurst, 1987; Hoek et al., 1998; Wu and Wang, 2001; Budetta and Nappi, 2011; Fortsakis et al.,2012). Columnar jointed rock mass would result in structurally controlled failure patterns, even serious disasters during underground excavation because of the low shear and tensile strengths of intensely joints (Gencer,1985 ;Ishida and Uchita, 2000; Jia and Tang, 2008). The CJB rock mass in the Baihetan hydropower station has exhibited serious stability issues, including sliding, fracturing and even collapse (Shi et al.,2008). Therefore, the geotechnical and geomechanical characteristics of such rock mass should be assessed through in situ investigation and numerical analysis to minimize future accidents during underground unloading excavation."

Jan 1, 2015

By François Robert, Rex Brommecker, Don S. Bubar

"The Orenada Zone 4 deposit is a small vein-type gold deposit occurring directly within the Cadillac Break southeast of Val d' Or in southeastern Abitibi Sub province. Mineralization is hosted by the Piche Group which, on the Orenada property, consists of talcchlorite- carbonate, chlorite-carbonate, and sericite-chlorite schists, derived from ultramafic volcanic, mafic igneous, and intermediate to felsic volcaniclastic rocks, respectively. All these rocks have been carbonatized.Rocks of the Pichi Group display a strong east-west, subvertical S1foliation, which is superimposed by asymmetric, intrafolial F2folds with shallow to moderate plunge to the east and to the west. F2folds are accompanied by an S2, subvertical axial planar cleavage, and are interpreted to result from dextral transcurrent shearing along sr.The Zone 4 deposit occurs within a large F2 fold, 60 m wide and plunging at 45 to the east, down to a depth of at least 300m. The auriferous zones consist essentially of zones of closely spaced, parallel quartz-tourmaline-albite-carbonate-arsenopyrite veins concordant to Sr these veins have been folded by the large F2fold and may pre-date the folding. A few discordant quartz-tourmaline-arsenopyrite veins, post- dating the F2 folding, also contain gold. Wallrocks adjacent to concordant veins have been carbonatized, albitized and contain significant amounts of tourmaline and arsenopyrite, with which gold is intimately associated.The Orenada Zone 4 deposit is a unique example of a deformed vein- type gold deposit, and exemplifies one of several types of association of lode gold deposits with folds."

Jan 1, 1990

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By Sylvie Lévesque, Cory Hennessey, Daniel Amariei

"In the iron ore industry, fine particles recovery is an important concern in terms of process performance and production costs. Continuous efforts are thus devoted to increase the efficiency in handling these fines.The Reflux Classifier (RC) is a relatively new technology that is mainly used in the coal and industrial minerals industries. The operating principle of this system is based on three mechanisms: hindered settling, autogenous dense medium and lamella settling. A preliminary evaluation of the Reflux Classifier technology for the beneficiation of iron ore fines was formerly done at the pilot scale using a RCTM300 unit. The good results obtained, using iron ore fines from screened spiral stream, made this technology very attractive for the iron industry. However, the high capacity of the RCTM300 unit (1–3 t/h), makes it unsuitable for R&D purposes. Thus, a smaller unit, the RCTM100, was assessed to validate the performances obtained with the RCTM300.This paper summarizes the performances obtained with the RCTM100. The challenges of the scale-down related to the adaptability of this technology to the iron ore industry are also presented. The results are compared to the RCTM300 performances, as well as benchmarked against sink-float tests. The metallurgical results on feed and products issued after the test work with the RCTM100 unit are supported by mineralogical characterization using a Mineral Liberation Analyzer.INTRODUCTIONFine particles recovery by physical separation means is a historical concern (Holland-Batt, 1992; Peukert and Wadenpohl, 2001; Srivastavaa et al., 2001; Majumder et al., 2003). Attempts to improve fine particle recovery at the laboratory, pilot and industrial scales adopting different strategies with traditional equipment or assessing new promising devices such as the MGS (multi-gravity separator), the Kelsey jig, the Yang jig, etc. (Kim, 2002; Goudreau, 2008; Kerr, 2012) have yielded variable success."

Jan 1, 2016

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present investigation flotation was used as a diagnostic to understand the effects of changes to the media during the grinding stage. The observations from flotation for different media are discussed in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. The chemical parameters; pH, redox potential (Eh) and dissolved oxygen (DO) levels were measured. A Base Metal Sulphide (BMS) ore was ground under media of different shapes and compositions to determine the effect of different rod/ball material on the flotation performance of the ore. For a given grind (D80 = 75 µm), media shape had no effect on flotation performance of a BMS ore. Different grinding media had significant effect on slurry chemical properties and flotation performance. Mild steel rods (RMMS) produced the highest solids recovery, nickel and pyrrhotite (Po) recovery, with the highest ethylenediaminetetraacetic acid (EDTA) extractable iron and the lowest DO level. Chrome steel balls and stainless steel rods produced the lowest metal recovery, EDTA extractable iron and the highest DO level. A complementary study was conducted to investigate the effect of using different grinding media compositions, viz, ceramic, forged steel, 15% chrome steel, stainless steel and a mixture of stainless steel and 15% chrome steel (50:50) balls were investigated using a Platinum Group Mineral (PGM), UG2 ore. Grinding products of five different media produced the same solids and water recovery, but the grades and recoveries of Platinum Group Elements (PGE) and chromite were different. Grinding products of ceramic media showed the best flotation performance, with the highest PGE recovery and the lowest Cr2O3 recovery. While grinding products of stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery in the concentrates.

Jan 1, 2016

By F. Barriga-Ordonez, J. A. Finch, L. Calzado, S. R. (Ram) Rao

Sludge, formed by lime treatment of acidic drainage and stored in tailing ponds of the Sudbury region, contains 5-7% Ni, mostly in a mix of hydroxides with Fe (~ 10%), Mg (~ 10%) and Cu (-0.5%), and Ca (-3.5%) as sulphate. Investigations were conducted to recover nickel by a 2-stage process. In the first stage, the sludge was leached with sulphuric acid at pH 3.2. About 90% of the nickel was extracted, producing a solution, which contained mainly nickel (2 g/L) and magnesium (3.7 g/L). In the second stage, nickel was separated by treating with ozone which recovered 99% of the nickel in the Ni(III) oxidation state as -85% pure nickel oxide-hydroxide (NiOOH) precipitate. The oxide settled and filtered readily. A potential use of the product in battery making is suggested. The leach residue contained 0.5% Ni making it less toxic for disposal. Some physical properties of nickel oxy-hydroxide and process parameters including ozone consumption will be discussed.

Jan 1, 2005

By Rod Maclean, George Stewart

"This paper covers the planning, development, and mining of an underground pillar complex using a bulk mining method. To achieve the long-term goal of continually improving our operating processes, all cut-and-fill and undercut-and-fill workplaces at Thompson Mine have been evaluated for their conversion potential to the bulk method referred to as VerticalBlock Mining (V.B.M.).Since December 1979, conversion has occurred to the extent where 80% of the ore hoisted is mined using Vertical Block Mining (V.B.M.).Productivity and profitability have been substantially improved by converting to this bulk method, especially in pillar areas.IntroductionThompson Mine is a 6000 ton per day underground nickel mine located 3 miles outside the City of Thompson, 400 air miles north of Winnipeg . The mine has two shafts, T-l and T-3 (Fig. 1). The T-l shaft is 4427 feet deep with the deepest mining taking place on 4000 level. The T-3 shaft, which is the area of this presentation, extends to a depth of 2607 ft with the deepest operating level at 2400 ft. The two shafts, some 10 000 ft apart, are connected underground on numerous levels. The ore mined at T-3 is trammed on 2400 level to the T-I main ore pass and hoisted through the T-l shaft. Eight hundred and fifty thousand cubic feet of fresh air per minute ventilates the mine.The 1400 level 310 pillar complex is located in the T-3 mine area. There are six rib pillars, two crown pillars and one main pillar (boundary pillar between cut-and-fill stopes) within the complex (Fig. 2). The majority of the ore in this area has been mined using mechanized cut-and-fill techniques .Undercut-and-fill mining was the method originally planned to recover these pillars. It is slow, labour-intensive, and requires extensive use of timber during the mining cycle. The extraction drifts in the area are heavily timbered due to their proximity to the ore and the age of the facilities. Increasing drift maintenance costs and the successful mining of two main pillars with V.8.M. techniques provided the stimulus to review the mining plans for this area."

Jan 1, 1988

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016