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By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By K. Thuro, S. Schneider, H. Kasling, P. Ellecosta

"One of the most important methods for material testing is the characterization of the hardness, which is defined as the resistance of a material to the penetration of another one. The methods according to Brinell, Vickers, Rockwell and Knoop are today the most common and standardized tests for metal. As they are developed for predominantly ductile materials like steel, they can’t easily be applied to rocks which react much more brittle under indentation. But just as steel, rock is composed of different minerals and has a specific microstructure. Its mechanical parameters are connected with the particular grains, their cohesion and interlocking, just like steel.The abrasivity of rocks and the accompanied wear of drilling tools today are mainly determined by simple and fast laboratory tests such as the Cerchar abrasivity test or the rubber wheel test. Such laboratory tests are good tribological tests, but there are limits. The Cerchar abrasivity test for example has weaknesses in extreme cases, that mean soft or very hard rock types. This leads to an underestimation of abrasivity, e.g. in poorly lithified sandstones or very hard, fine grained and extremely abrasive rocks. As mentioned, hardness characterizes, depending on the type of deformation, predominantly plastic (metal) or elastic properties (rubber). Rocks are in the range between these two extremes. Since the rock drilling process can be seen as a kind of penetration process on macroscopic and microscopic scales, we picked up the idea to characterize the interaction of rock materials and TBM-disc-cutters with hardness tests. In addition, this supports for a better understanding of the wear process on disc cutters. We used the hardnessdisparity concept after Cardu & Giraudi (2012) because wear can be understood as the interaction between the wear part and the material which causes the wear (tribological system). Several rock-forming minerals and some fine to coarse-grained monomineralic and polymineralic rocks were tested. In contrast to Cardu & Giraudi, we used in the first step of investigations the method after Vickers with loads up to 294.2 N (HV 30), depending on the estimated hardness to get bigger indentations and therefore as well information about the cohesion and interlocking of the minerals/grains. We also tested several associated disc cutters. First results show that with higher loads (HV 5 - 30) and at least 15 indentations, we get a structural hardness in fine-grained rock samples, which allows a good characterization of the elasticity and brittleness. Nevertheless, for the coarse-grained rock samples we need up to 40 indentations for a good characterization. Using this method, a prediction of disc cutter wear is feasible taking into account the hardness of the disc cutter steel. In this paper, we would like to present this approved method in material sciences to derive an additional parameter for the characterization of rock abrasivity and wear."

Jan 1, 2015

By G. Goodlad

This paper describes some of the main aspects involved in implementing the European “Equipment and Protective Systems for Use in Potentially Explosive Atmospheres” (ATEX) Directive (No.94/9/EC) in the British mining industry by the year 2003. It provides a brief background to the Directive and considers its main objective of removing all barriers to trade in Europe. It outlines the need for the European Standards making bodies to write new editions of the ’explosion protection concept standards’ and for manufacturers to adopt new quality management procedures and develop new versions of equipment in conformity with the ATEX categories of “M1” or “M2.” Finally, it assesses the possible future relationship between the European enforcing authorities, manufacturers and users of explosion protected equipment.

Jan 1, 1999

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

By M. Cossette, V. H. Tran

"How can the durability of asphalt pavement be doubled without increasing highway budgets? Asphalt containing asbestos can provide the desired performance with additional costs being made up by longer life. The addition of a low percentage of asbestos to an asphalt mix permits a higher asphalt content without any consequent loss in stability. It is mainly the higher asphalt content that provides improved performance and durability, although the fibrous reinforcement plays a key role in preventing the propagation of micro-fissures. As well, several international studies show that, thanks to the latest production techniques, no environmental hazards need be incurred.RésuméComment doubler la durée des chaussées d'asphalte sans augmenter les budgets de voirie? L’asphalte contenant de l'amiante peut offrir les performances souhaitées et l'augmentation des couts initiaux peut être rapidement compensée par une durée prolongée. L’addition d'une faible teneur en amiante courte il l'enrobe de bitume permet des teneurs en bitume plus élevées sans subir une perte de stabilité en conséquence. C'est principalement la teneur accrue en bitume qui assure un améliorations propriétés physiques et une augmentation des performances mécaniques, ainsi qu'on prolongement de la durée. Cependant, le renforcement fibreux joue un rôle clef en prévenant la propagation éventuelles micro-fissures. Les nouvelles techniques évitent tous risques environnementaux"

Jan 1, 1991

By J. R. Bradfield

THOSE familiar with the development of the Horne mine can readily appreciate that more and more accommodation bas been required for underground labour as the mine has grown. A permanent fire-proof change house, 30ft. by 75 ft., was built in 1927 to accommodate 194 men. This was extended ro 30 ft. by 92 ft. in 1928 to accommodate 296 men, and to 30ft. by 110 ft. in 1930 to accommodate 398 men. By 1933 this building was again overcrowded and tentative plans for a new change house were drawn up. However, it was realized that future operations would be centred around No. 4 shaft and a proposed new shaft, and the decision as to the location of the new change house had to be deferred until the area which seemed most suitable for the new shaft had been thoroughly explored underground. In the spring of 1934, the basic idea was accepted of drying the wet clothes in open mesh compartments or baskets located between rows of standard steel street-clothes lockers and built so that the covers or lids would serve as seats or benches.

Jan 1, 1935

By A. C. Hatton

Doped SrCoO3.8 was found to be a promising material for use as a cathode component in intermediate temperature SOFCs. In this work, strontium cobaltite ceramics doped with 10 mol% to 90 mol% samarium were synthesized using the glycine nitrate process in order to study the electrical conductivity and thermal expansion at temperatures of up to 800°C. As-synthesized powders were deagglomerated, pressed and sintered at temperatures ranging from 1100-1250°C. The effect of temperature and composition on electrical conductivity and thermal expansion are presented and discussed.

Jan 1, 2005

By D. W. Heard

Electrospark Deposition (ESD) is a low heat-input, high energy density, micro-welding process. The short pulse duration and high-pulse frequency, in combination with the small amount of material transferred during each pulse, results in the evolution of extremely rapid cooling rates, believed to approach 105-106 °C/s [1]. This rapid solidification event results in the refinement of the microstructure to the nanostructured or amorphous level [2, 3]. Figure 1 displays the resultant microstructure of an Al-17%Si alloy deposited by the ESD process. Furthermore, it was determined that the microstructure of the deposit remained unchanged after subsequent layers were welded onto the presented layer. Freeforming of materials is a rapid prototyping process in which the deposited feedstock is built-up to the desired geometry in a near-net shape manner. Figure 2 displays the automated set-up employed produce three dimensional freeformed objects via multiple deposition trials of the ESD process. The automated XYZ table is equipped with CNC software to transform CAD renderings into three dimensional tool paths. Figure 3 displays an Al-12Si freeformed gear (2" diameter, 12 teeth) produced by the ESD process, prior to removal from the substrate. An SEM analysis of the freeformed component showed that the microstructure did not coarsen during the deposition of subsequent layers during the freeforming process, as depicted in Figure 4, resulting in the production of a bulk nanostructured component. This paper represents a summary of the capabilities of ESD to fabricate advanced materials possessing refined microstructure. In particular, results on the microstructural evolution obtainable for various wear-related systems will be presented. In addition, the feasibility of using the ESD process to freeform three-dimensional objects via multiple deposition passes will be presented and accompanied by a characterization of the properties of the freeformed component. [1] R. N. Johnson, "ElectroSpark Deposition: Principles and Applications," in Society of Vacuum Coaters, 2002, pp. 87-92. [2] J. Milligan, D. W. Heard, and M. Brochu, "Formation of nanostructured weldments in the Al-Si system using electrospark welding," Applied Surface Science, vol. 256, pp. 4009-4016. [3] S. Cadney and M. Brochu, "Formation of amorphous Zr41.2Ti13.8NilOCul2.5Be22.5 coatings via the ElectroSpark Deposition process," Intermetallics, vol. 16, pp. 518-523, 2008.

Jan 1, 2010

By Ahmad Abdollahi

Many factors affect mechanical properties of hypoeutectic Al-Si alloys. As examples the presence of impurities such as Mn and Fe due to the formation of intermetallic phases, additions of small amounts of alkaline earth metals and cooling rate in consideration of Si formation, they all have an impact on mechanical properties of hypoeutectic Al-Si alloys. In this investigation, the effect of Fe content into the specification range of A357 alloy, the addition of different modifiers consisting of Na, Sr and Ca for the alloy of A356 and different mounting techniques for separately cast test coupons of hypoeutectic Al-Si alloys using the lost wax method were studied. The results showed that using material with lower Fe content and addition of modifiers improve mechanical properties. Also different mounting techniques resulted in different mechanical properties.

Jan 1, 2004

By L. Tong, D. Robinson

"The stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a netzsch™ lME4 stirred mill on siliceous goethitic, goethitic, and saprolitic nickel laterites. Tests on the -2,000 µm sample displayed the effects of selective comminution. The -38 µm product of grinding the -2,000/+38 µm feed confirmed the effects of selective grinding and nickel upgrading. Size classification followed by stirred milling is recommended for nickel upgrading. The energy requirement in the stirred milling was also investigated.RÉSUMÉ le broyage par billes de latérites comportant du nickel offre des possibilités d’amélioration de la libération et de la réduction sélective de la taille des minéraux nickélifères tendres dans les latérites. Des essais de broyage en vrac ont été effectués dans un broyeur à billes netzschMD lME4 sur des latérites nickélifères à goethite siliceuse, à goethite et saprolitiques. Des essais sur l’échantillon -2000 µm présentaient des effets d’une comminution sélective. le produit -38 µm de l’alimentation -2000/+38 µm confirme les effets d’un broyage sélectif et du rehaussement de la teneur en nickel. Pour améliorer la teneur en nickel, il est recommandé de classifier le minerai en fonction de sa granulométrie, puis d’effectuer un broyage à billes. l’énergie requise pour le broyage à billes a aussi été étudié."

Jan 1, 2015

By A. Kraly, M. Complojer, P. Paschen, K. Gamweger, H. Antrekowitsch

Increasing quality of aluminium alloys and continuous optimization of the production process leads to an improvement of the gas purging systems. The application of porous plugs for the treatment of liquid aluminum is nowadays not widely used in the aluminium industry especially in Europe. The Department of Nonferrous Metallurgy and the Christian Doppler Laboratory of Secondary Metallurgy of Nonferrous Metals intensified the research and development of refining and alloying processes by gas treatment during the last years. CFD-modeling supports these experiments, which should lead to lower hydrogen content, lower suspended particles and a better distribution of alloying elements in the melt. Different parameters such as temperature, bubble size, gas amount and which kind of gas is used influence the quality of the products.

Jan 1, 2006

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling's T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007

By Brian Lewis

"IntroductionThe leaching method selected for the dissolving of uranium ore depends in part on the physical characteristics of the ore, as well as the uranium mineralization. There are two main methods of leaching employed in uranium circuits in North America, one being ""Carbonate Leaching"" on sandstone, and pitchblende type ores, and ""Acid Leaching"", on quartzite type ores.This chapter deals with the acid leaching of uranium ores found in the Elliot Lake area, using sulphuric acid, for the leaching reagent, and ""pachucas"" for the contactor.The basic leaching process involves the pregrinding of the ore and the mixing of the ore with hot sulphuric acid, the mixture is air agitated, the air being used to oxidize the ore as well as produce agitation. The chemical reaction is as follows: Uranium Oxide + Sulphuric Acid = Uranyl SulphateThe following equations show the actual dissolution of the ""Hexavalent Uranium"", which show that more than one ion or complex of uranium is possible.Uranium DissolutionsI. UO, + 2H-(UOJ + H,O2. (UO,) + SO, = -UO, SO, (Uranyl Sulphate)3. UO, + SO,-(UO, (SO,),)=4. (UO, (SO,),)= -(UO, (SO,),)'Test work carried out in the laboratory as well as in the plants has determined the most efficient methods of extracting the uranium from the ore. A very important factor that has to be determined during initial test work are the amount of acid consumers in the ore. Within the Elliot Lake orebodies are minerals such as chlorite schist, diabase, and basement material, all very high acid consumers, consuming up to 1000 lbs. of acid per ton of ore. Of these minerals only the chlorite schist contain any uranium at all.The following are the operating parameters that have to be controlled in the plant:I. sulphuric acid concentration2. temperature of the mixture3. agitation4. liquid solid ratio5. reaction time6. particle size of ground ore"

Jan 1, 1989

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By A. A. Brant

Self-potential methods are based ?on measurements on the surface of voltage distributions caused by natural sub-surface oxidation phenomena. The attempt is made to. correlate voltage minima or maxima with the location of mineral materials or geological conditions which may give rise to such naturally produced spontaneous potentials. Any orebody undergoing oxidation is a source of electric current. Ground waters carrying free oxygen attack the upper surface of the body, rendering this the positive pole of a galvanic cell, with the lower portion of the body the negative pole and the surrounding weak acidic waters the electrolyte. Current flow is from positive to negative through the orebody and negative to positive through the electrolyte, i.e., through the surrounding rock. The upper end of a steeply dipping, tabular orebody is hence indicated as lying below the point on the surface where the largest negative potential is observed(l). From its basis, it is apparent that the self-potential method was developed primarily for ore exploration.

Jan 1, 1942

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

By H. Staton, V. Suontaka, E. Sharifi

"Flotation circuits are typically controlled using on-line elemental assays obtained from the slurry lines. In base metal applications, X-ray fluorescence (XRF) analyzers are the most common instruments for elemental analysis of the slurries. Eagle Mine has been utilizing a Courier XRF Analyzer since 2014. Typically, in XRF analysis, the sampling rate is 10-25 minutes which is good enough for manual process control. In 2018, Eagle Mine upgraded the Courier XRF analyzer with the Rapid Measurement module that is based on reflectance spectroscopy. This option reduces the sampling rate to 10-15 seconds, while maintaining the superior accuracy of the XRF analyzer. This paper presents the results from implementation of Rapid Measurement at Eagle Mine.INTRODUCTION Eagle mine is an underground mine producing nickel and copper concentrates. Eagle Mine is owned by Lundin mining and located in the Upper Peninsula of Michigan, USA. The Humboldt Mill, previously an iron ore processing facility, was refurbished in 2014 and is used to process the ore and produce separate nickel and copper concentrates. Approximately 2,000 metric tonnes of ore is milled per day. Ore is processed using a conventional crushing followed by single stage ball mill and flotation. Nickel and copper concentrate are transported to facilities in North America via rail car. A bulk copper-nickel concentrate is produced by separating the copper and nickel minerals from gangue material by flotation. The copper-nickel bulk concentrate is reground, followed by one stage of cleaning to reject further gangue minerals. The bulk cleaner concentrate is then subjected to a final flotation stage where the copper and nickel minerals are separated from one another through the addition of lime. Final concentrate grades are 14% Ni and 2% Cu in the nickel concentrate and 31% Cu and 0.8% Ni in copper concentrate."

Jan 1, 2019

By R. Bonifaz

The Chagres Smelter, part of the Anglo American plc group situated 80 Km north of Santiago in Chile, completed a series of operational improvement in 2005 resulting in an optimum capacity in its operational units. At present the Chagres Smelter has developed an operational strategy which seeks to reduce bottle-necks in the production process. In this way we have managed to lower operational cost, decrease energy consumption and maximize the capacity of the Acid, Oxygen, and Smelting, Converting, Refining and Casting units. A constant application of international benchmarks together with continuous staff improvement and the latest smelter technology have combined to place Chagres among the finest smelting works in the world. In response to environmental challenges, we have studying various options for investment suitable for a profitable business of benefits to both Anglo American and Chile as a whole. The most relevant technical indicators are the figures : Energy consumption less than 6,3 GJ/ton fine copper, Intensity of smelting rate in Flash Smelting unit of 6900 ton of copper concentrate/m2 settler of furnace area and be one of the top five smelter in direct cash cost .

Jan 1, 2007