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By R Adamian, F. T. Da Silva, D. H. Gameiro

Schytill and Geldart diagrams were developed for the TiO2-C-Cl2 system at 1 073 and 1 273 K, so as to define the hypothetical relations between particle sizes and chlorine velocity for simultaneous fluidisation of mixtures of anatase concentrate and charcoal for carbochlorination. It was concluded that the operating limits on chlorine gas velocity will be controlled by the behaviour of the reducing agent, mainly because of its lower density. An increase in temperature from 1 073 to 1 273 K will have only a small influence on the fluid-dynamic behaviour of the mixture. For bubble fluidisation, the maximum sizes 0.413-0.478 mm for anatase and 0.529-0.611 mm for charcoal will be adequate. When the particle size distribution is large, fluidisation will be feasible only if conducted in two stages, otherwise the residence time of the small particles in the reactor will be very short. New diagrams will be needed for the gaseous chlorides in the second stage

Jun 21, 1905

By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

By J. A. Finch, Zhenghe Xu, Z. A. Zhou

A particle-bubble collision model was used to investigate the minimum recovery zone height, H(r,min) required for flotation columns. The criterion used to define H(r,min) is that height which gives unit collision probability. It is shown that H(r,min) is determined by particle and bubble size, gas hold-up and bubble-bubble interaction. Under typical operating conditions, for flotation of particles less that 10 micrometres in size H(r,min) is greater than 10 m, but it reduces to less than 1 m for particles greater than 100 micrometres

Aug 1, 1995

By M. G. Fleming

The professional mineral engineer is an individual of personal integrity who has undergone rigorous intellectual instruction in the scientific disciplines fundamental to his vocation; he has learnt to apply these disciplines to the discovery, mining and treatment of mineral resources and, through practical training and experience, has acquired competence and judgment to fulfil his undertakings. In the course of this development he has recognised and accepted a threefold responsibility to society, to his employer and to his profession

Dec 1, 1971

By Mavor S.

Further discussion at the Mining Institute of Scotland's general meeting held in Edinburgh, 12 February 1916, with D.W. Mowat, president, in the chair, of a paper published in Trans. Inst. Min. Engrs., 1915, vol. L, p.625 and discussed vol. L, pp.92, 433, 468, and 704 included comments by Mowat D.W. and the author's reply

Dec 1, 1916

By A. T. Iannacchione

Underground mining of stone in the US is increasing, as is the depth of overburden above the mines. Data gathered from mine visits, maps, discussion with operators and numerical simulation have been used to investigate pillar design and recommend safe practice. Many pillars have slender shapes with relatively large adjacent mine openings: width-to-height ratios range from 0.54 to 3.13 and extraction ratios from 0.56 to 0.91. The pillar material is often very strong and average overburden only 80 m, but occasional failure due to excessive local stress has occurred where pillar size had been unintentionally reduced, overburdens were greater than 200 m, width-to-height ratios were less than 1.25 or extraction ratios were greater than 0.83. Pillars with width-to-height ratios of less than 1.5 appear more likely to fail under excessive stress. When width-to-height ratios fall below 1.0, defects such as through-running discontinuities can have a significant influence on stability. Dip, orientation and material properties are also important

Jun 21, 1905

By J. D. Appleton, J. Ridgway, K. B. Greally

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results suggest that meaningful geochemical maps can be produced from very low-density surveys, and that existing data sets could perhaps be incorporated into such a map series with the use of a system such as Uniras software. There are still many problems to be resolved, however, including the compatibility of data derived from different analytical methods, and the precise methods to be employed will necessarily require international agreement. Sampling densities should be chosen on the basis of the scale of the geochemical and geological features to be distinguished and will vary from region to region. Reanalysis of selected samples from archives to increase the range of elements determined or to unify analytical methods is only likely to be effective if the original survey was at quite a low density

Jul 1, 1991

By G. S. Pauley

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Case-based reasoning can be a catalyst for improvement). A new computer software technology known as Case Based Reasoning (CBR) can be used to produce small decision support systems that are economically viable. This is because the knowledge that they contain can be owned and maintained by their users. A CBR tool has been used to perform a pilot study with Anglesey Aluminium Metal Ltd. The results are encouraging. They suggest that a combination of CBR and participative design and implementation techniques (such as Checkland's Soft System Methodology) can achieve sustainable improvement in mineral processing functions. An explanation is presented of why traditional, rule based systems are often an ineffective way to implement support systems. It is shown that CBR may provide an appropriate technology solution. Methods of achieving sustainable benefit are indicated. The pilot study with Anglesey Aluminium Metal is used as a practical illustration of the development of a CBR application. A review of potential application areas and some observations about the implementation are presented

Apr 1, 1994

By K. C. Garner

The visit reported was made with support from the 1997 J.C. Boyle travelling scholarship. The management and control of hazardous gases released into the underground environment are an integral part of coal mining. The power-generations stations at Appin and Tower collieries, with a combined electrical output of 94 MW, have been operating for some time and have demonstrated a technology that is able to exploit the available gas fully. Contributory factors have been the development and introduction of directional drilling techniques, pre- and post-drainage of coal, relatively high seam permeability, a high gas content of the worked seam, high production rates and a willingness to embrace new ideas and technology

Jun 21, 1905

By S. G. Tsimas, A. K. Moutsatsou, G. K. Parissakis, M. A. Komiotou

For Greek kaolin producers, a considerable proportion of whose output is from deposits containing more than 4 wt% Fe2O3, the colouring resulting from iron oxide impurity represents a serious problem that necessitates upgrading of the ore to meet commercial specifications. Autoclave leaching with oxalic acid for 1 h at 120 degrees C and 5-6 bar was shown to reduce Fe2O3 by up to 90% without affecting the structure of the kaolin, which maintained its physicochemical properties. The iron oxalate product can either be removed from solution or precipitated as iron hydroxide with recycling of the oxalic acid

Aug 1, 1995

By T. J. Serenko

The epithermal deposit is hosted by Tertiary volcanic rocks that lie between mid-Miocene normal faults of the Northern Nevada Rift. Petrographic, laser-ablation and metallurgical observations suggested that the gold occurs in two principal forms: native (and electrum) and disseminated in arsenopyrite. It was proposed that gold is distributed between two parageneses with distinct mineralogical associations. Detailed downhole geochemical study supported the observations. Concentrations of Au, Ag, As, Sb and Se were determined from drill core and reverse-circulation cutting composites and contoured on cross-sections. Gold was indeed shown to have a bimodal distribution with the two parts separated spatially and perhaps temporally, implying that two separate genetic processes acted to concentrate gold at Mule Canyon

Aug 1, 1995

By R. Sweennen, A. Vervoort, J. Caers

A case study is presented of the mechanical behaviour of fractures in the Westphalian A and B siliciclastic succession of mud-, silt- and sandstones with intercalating coal layers in the Campine basin of northeast Belgium. Mining ceased in the area in 1992 and a pilot well was drilled to assess the feasibility of methane extraction by hydraulic fracturing. Work was carried out to study the influence of types of cement fill in fractures on the shear behaviour of the rocks by comparison with that of the coal seams. X-ray computerised tomography was used for visual appraisal and selection of jointed rocks before destructive shear testing was carried out. Two major type of veins were found to be present, one cemented with carbonate and the other with kaolinite or kaolinite/carbonate. Uniaxial compressive strength and shear tests showed that differentiation of the two types of veins was vital in evaluating the strength of the sandstones, as cementing of the fractures by rigid carbonate minerals can reinstate the strength of the rock masses to that of the intact material. Kaolinite was more susceptible to plastic deformation than carbonates

Jun 19, 1905

By T. G. Carter, R. I. Miller

First, the influence of variation in the

Apr 1, 1995

By J. A. Finch, D. Lin

The robustness of the large-sections correction procedure, Hill's fast approximation, Barbery's correction and the PARGEN correction was examined by comparing their ability to reconstruct the true liberation distribution using sectioning data from computer-generated spheres. The results indicate that the flexibility of a correction procedure is related to the assumptions it makes about the continuity of the liberation distribution, locked-particle characteristics and ore texture. Overall, the large-sections procedure appeared to be the most generally applicable. The Hill fast approximation performed well, but this was probably because it partially incorporates the sphere model; the performance of the PARGEN and Barbery corrections varied from case to case.

Dec 1, 1995

By R. M. Cooper, H. K. Herbert, D. N. Phillips

A study was carried out to determine the effects of adding CaCO3, Fe, Al and CaSi2 to the ladle, rather than to the raw materials, in order to increase the concentration of Ca, Fe and Al in the final product to meet customer specifications at Simcoa's Kemerton plant in Western Australia. LA-ICP-MS, SEM-EDXRA and ICP-AES analysis of samples and controls showed that the technique is suitable for controlling minor element concentrations. Iron was successfully added, while calcium silicide with aluminium proved better than limestone with aluminium for controlling Ca and Al concentrations in the silicon

Jun 19, 1905

By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

By C. J. A. Mcewan, C. M. Rice

The Rosita Hills contain rich, vein- and breccia pipe-hosted precious metal deposits. Volcanic activity occurred in two cycles - an early, mainly andesitic cone-building phase that terminated in the formation of a caldera and breccia pipes and a later phase characterised by trachytic lavas and dykes, rhyolite domes and lamprophyre dykes. Alteration consists of weak propylitic and argillic and, locally, intense advanced argillic, K-feldspar sericitic and silicic types. Marked trace-element depletions (Rb, Sr, Zn, Mn) are associated with K-feldspar-sericitic alteration and with advanced argillic alterations, whereas enrichments (Pb, Ag) are associated with K-feldspar-sericitic alteration. Gold distribution is highly localised and is controlled by breccia pipes and a caldera ring fault; it is not related to district scale alteration. In general, the geochemical and alteration patterns are complex, but they are clearly influenced by linear structures, the caldera ring fault and breccia pipes. Pipe-hosted Au-Ag and vein-hosted Ag mineralisation are associated, respectively, with early andesitic and late, post-caldera rhyolitic activity. The pipe-hosted and, especially, the vein-hosted mineralisation show affinities with adularia-sericite-type epithermal deposits

Jan 1, 1991

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905