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By J. Ling, L. Racine, P. Cousin, A. R. Laplante

"The problem of gold recovery by gravity from high density gangues is first discussed from a fundamental perspective. Three potential difficulties are presented: poor liberation and fine gold particle size, concentrate bed erosion by coarse dense particles, and slow percolation of gold particle through the high density gangue bed. Two case studies are presented to illustrate the impact of these three problems on circuit performance and the feasibility of gravity recovery. It is concluded that careful testing can determine the scope of the first problem and feed preparation can limit the extent of the second. The third problem is clearly the most serious and results in lower gravity recoverable gold recoveries than would be achieved with the same recovery effort on a low density gangue application.IntroductionSince the commercialisation of the Knelson Concentrator in 1980, gold gravity recovery has experienced a surge in interest, in Canada and the United States first, then Australia, Zimbabwe and Russia, and finally worldwide. Table I details number of units sold in various countries, which corresponds approximately to their importance as gold producers 1. Exceptions. such as the low rank of South Africa or the importance of Zimbabwe, despite the much higher gold throughput of the former, are generally the result of differences in the effectiveness of the local marketing strategies, as well as a reflection of the ""philosophy of recovery"" prevalent in the country.The impact of the Knelson has not been felt equally in all plants. Typically, a highly successful application falls into the following categories: (a) alluvial or hard rock recovery for which gravity is the sole recovery method, (b) hard-rock free gold milling with ores which have a very high gravity-recoverable gold (GRG) content, (c) low grade sulphide copper-gold ores which include flotation ahead of cyanidation and (d) free-milling gold ores ahead of Other applications can be successful, but are not as common. The ""explosion"" of centrifuge concentration, of which the Knelson is the most successful but by no means the sole model, has created a certain euphoria which can be summarized as ""gravity recovery will improve the profitability of gold milling, no matter what."" This presentation is about applications that are not so successful, or even downright unsuccessful. The rationale is not to down-play gold gravity recovery, but to set it in its rightful position: metallurgically, it is not appropriate all of the times; it can become inappropriate if poorly designed; and it can be metallurgically possible but economically unjustifiable. In this paper, this will be illustrated and explained rather than demonstrated, with the use of both industrial plant surveys and laboratory test work. Alternate gravity approaches will be suggested."

Jan 1, 1997

By Donald Leroux, Dave Scott, Giovanni Di Prisco

"The Lady Loretta lead-zinc deposit in Northwest Queensland, Australia contains an average of 5.9% lead, 17.1% zinc and 97 g/t silver. Ore mineralization is mostly comprised of fairly complex intergrowths of pyrite, sphalerite and galena. Starting in 1998, Noranda Inc., the major joint venture partner of the project, conducted extensive metallurgical test work, which culminated in July - August 2000 in a series of Pilot Plant tests. A common thread to all the metallurgical work has been the deportment of a large portion of silver into non-payable metallurgical products. Average silver distribution from four Pilot Plants shows a distribution of silver in lead concentrate of 28%, whereas silver in zinc concentrate was 49%, and 23% in the final tails.The consistently poor silver recovery as well as the fairly unusual silver distribution, particularly in zinc concentrate, was considered an issue to be thoroughly investigated. A mineralogical plan was devised to determine if these particular metallurgical results were somewhat related to the nature and mode of occurrence of silver carriers. Work was performed to determine discrete silver-bearing minerals and/or silver contained in solid solution in a suite of commonly occurring sulphides. Ore microscopy, SEM methods, Electron Microprobe and Ion Microprobe analyses were all used to answer these questions, and to find the silver carriers, so a metallurgical plan could be devised to improve silver recovery.INTRODUCTIONPotential economic exploitation of the Lady Loretta deposit in Queensland, Australia is driven by revenue derived from zinc and lead flotation concentrates and co-product silver recovery in lead. Relatively low recoveries of payable silver to lead concentrate, and high silver distribution to zinc concentrate necessitated an investigation into the natu"

Jan 1, 2002

By Moorrees C, Everson P

A detailed examination of carbonic acid leaching of crude iron-containing magnesia derived from Savage River magnesite shows that the rate and extent of magnesium and iron dissolution are affected by the slake time, leaching temperature, carbon dioxide pressure, pulp density and rate of agitation. In order to produce high-purity magnesia from the leachate by precipitation and calcination, the optimum leaching conditions, which are those that yield maximum magnesium and minimum iron dissolution, have to be a compromise in terms of the above parameters. For example, iron dissolution can be limited by leaching at an elevated temperature (-45°C), but because the maximum concentration of magnesium biearbonate decreases rapidly with an increase in temperature, it is necessary to use a low pulp density (-2 per cent solids) in order to achieve an acceptable degree of magnesium dissolution.Evidence is obtained that iron dissolution involves the formation of a soluble ferric bicarbonate complex that decomposes at elevated temperatures. The extent of iron dissolution is much higher than might be expected and it is probably because the original magnesite contains siderite in solid solution with the magnesite; on calcination, the hematite whieh is formed is in a very finely divided condition and hence more reactive.

Jan 1, 1983

By McHenry Mosier

The Bureau of Mines, United States Department of the Interior, has established a testing adit on the Government reservation at Mount Weather, Virginia, to facility to research on the fundamental tats of mining under actual metal-mining conditions. A number of sites in several Eastern States were investigated, out Mount Weather was selected because the rock seemed best suited for rock drilling and other mining tests and because the ground was already owned by the Federal Government, the site having been acquired in 1902 for use of the Weather Bureau. The testing edit has an advantage over en active metal mine for certain investigations because variable conditions affecting any particular research problem can be controlled and maintained in a fixed status, whereas in an operating mine this seldom is feasible. Operations were begin September 1935, with a crew of four laborers under a resident engineer. The laborers were recruited from, nearby farms, and. although they had no previous mining experience, they have developed into satisfactory miners.

Jan 1, 1939

By S M Richardson, A W McNeill, J B. Gemmell

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Hellyer, Fossey, Que River and Mount Charter volcanic-hosted massive sulfide (VHMS) deposits occur within the Que-Hellyer volcanics of the Mount Read volcanics, Tasmania. These deposits occur along a 6 km strike length and are hosted by the same stratigraphic unit. We use a combination of whole-rock geochemistry, short wavelength infrared (SWIR) spectrometry, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses and compiled historic whole-rock geochemical data to develop district-scale vectors towards VHMS mineralisation.Strongly sericite and K-feldspar altered rocks concentrate along a linear trend from Hellyer, through Que River, to Mount Charter. Ishikawa alteration index values and whole-rock major and trace element concentrations provide exploration vectors towards mineralisation on a regional scale as significant enrichment and depletion trends. On a deposit scale, composition variations in white mica (sericite alteration), chlorite and K-feldspar are observed and reflected in whole-rock geochemical variations. Regional SWIR data from drill core support the prevalence of phengitic mica and high-Mg chlorite within footwall alteration halos and highlight the main upflow zones of hydrothermal fluids in the VHMS district. The combined use of regional whole-rock geochemistry, SWIR and mineral chemistry is an effective way to highlight prospective areas for VHMS mineralisation in a mature exploration province.CITATION:Wu, S, Gemmell, J B, McNeill, A W and Richardson, S M, 2015. Exploration implications from variations in whole-rock and mineral chemistry around the volcanic-hosted massive sulfide deposits of the Que-Hellyer volcanics, Tasmania, Australia , in Proceedings PACRIM 2015 Congress, pp 85–90 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By John H. Fowler

"Most of the aggregate used in Nova Scotia is produced from numerous glaciofluvial and ice-contact deposits scattered throughout the province. Production from bedrock sources is increasing, with most of the coarse aggregate used in the Halifax-Dartmouth area coming from quarries operating within the metro area.A recently completed provincial sand and gravel inventory mapping program has identified some ""resource-poor"" areas where comprehensive aggregate evaluation programs are underway. Although some areas of the province are experiencing aggregate supply problems, large volumes are exported to markets as far away as Bermuda.IntroductionThe Nova Scotia Department of Mines and Energy has been involved with aggregate resource studies for several years, although sand, gravel and crushed stone are not designated as minerals under the Mineral Resources Act of Nova Scotia. Our role has been to provide the aggregate industry with resource data as well as provide similar information to governmental agencies involved with municipal planning, water resource studies and environmental protection regulations. Several private consulting firms use the information in many of their site development studies.We became involved with aggregates in a rather roundabout way. Several years ago, an outcry from inhabitants of a small coastal community over the removal of sand and gravel from a local beach moved the provincial Department of Lands and Forests to take action to protect provincial beaches. We were asked by the Department to provide information and to suggest alternative sources here operators extracting sand and gravel from beaches could relocate. This request initiated an aggregate inventory survey in southeastern Cape Breton, which was later extended to cover the entire province. The initial provincial sand z and gravel inventory survey provided a series of 1:50,000 maps showing the distribution of sand and gravel deposits in the province."

Jan 1, 1982

The Coeur Rochester Mine is one of the largest and lowest cost primary silver mines in the United States. In January, the mine surpassed 3.1 kt (100 million oz) of historic silver production. Rochester is owned and operated by Coeur d’Alene Mines, the world’s largest primary silver producer. Rochester is the world’s seventh largest silver mine. It also produces gold — more than 31.1 t (1 million oz) in historic production. Cash operating costs have averaged 8 cents/g ($2.58/oz) of silver since operations began in 1986.

Jan 1, 2004

By Nicholas Chlumecky

One of the oldest mine supports in use today is timber cribbing. In many mining operations material, installation and maintenance costs for timber cribbings are substantial. Their performance characteristics also add to mining costs. During the 1970'6, the U.S. Bureau of Mines recognized many of the deficiencies of timber cribbing and very successfully initiated the development of steel-fiber- reinforced (SFR) concrete blocks. Since the early 1980's this SFR concrete cribbing has been manufactured as a high quality product which has found increasing acceptance by mine operators. The rapid acceptance of the SFR concrete block cribbing has proven that its use is eliminating many of the deficiencies of timber cribbing while providing superior load carrying capability. The use of SPR concrete blocks to build the cribbing is based on the same principle as wood. That is, stacking longitudinal, rectangular blocks in layers in a crisscross manner. The blocks are positioned at right angles to the blocks of the layer below. With this situation, the possibility of misalignment exists when the concrete blocks at the base are not placed exactly parallel or when the blocks of the base are subject to unequal settlement. Such misalignments creates localized, high stress areas which reduces the load capacity of the cribbing made from SFR concrete blocks. Recognizing the problem of misalignment, the Underground Supports Division of Commercial Shearing, Inc., conceived a circular, one-piece, steel-fiber-reinforced concrete cribbing which is being marketed under the name - Donut Cribbing. This concept eliminates the possibility of misalignment and provides 100% bearing between layers of stacked cribbing as well as other advantages. The purpose of this paper is to discuss the performance characteristics, installation speed and economical factors of each of the three cribbing types -- timber cribbing, SFR concrete block cribbing and SFR concrete Donut Cribbing.

Jan 1, 1986

By P Steinier

Most operations, when considering their comminution circuit, are primarily concerned with achieving the desired particle size distribution to obtain adequate liberation for the separation process, at minimum cost. Invariably, the effect the grinding media has on the subsequent separation process (ie flotation, leaching) is not taken into account when selecting the media. This choice is driven by cost rather than metallurgical outcomes. Maximising valuable mineral recovery, with optimum selectivity against gangue minerals, is about good particle preparation. And, particle preparation is strongly related to achieving adequate mineral liberation with the correct pulp chemical conditions. However, the pulp chemistry of a system is largely ignored and relies heavily on pH control and the addition of appropriate reagents (collectors, frothers, activators, depressants). The changes effected by the addition of the various reagents are obtained through conditioning the ground pulp prior to or during the concentration stage, subsequent to grinding. Frequently, reagents are added during grinding with good effect, but the impact of the grinding media on down stream processing is usually overlooked. A number of case studies examining the effect of grinding media on pulp chemistry and subsequent flotation performance were completed on several different sulfide mineral systems (for example, lead/zinc, copper, refractory gold). The evidence suggests that a change in grinding media type from forged to high chrome (ie conditioning the pulp during grinding) resulted in a shift in pulp Eh to less reducing conditions, an increase in the dissolved oxygen content of the pulp and a reduction in the iron species present. The changes have a positive impact on flotation behaviour. The results of the case studies are discussed.

Jan 1, 2004

By Michael J. Atwood

Many buildings in Boston are founded on untreated wood piles, which can deteriorate and lose their structural capacity if groundwater levels are lowered below the tops of the piles, exposing the wood to air in the unsaturated soils that surround the piles. The problem of wood pile deterioration due to lowered groundwater levels in Boston first became evident in 1929 following discovery of rotten piles beneath walls of the Boston Public Library building. Repairs to reconstruct the library building?s wood pile foundations were made in 1930 using pit underpinning methods. Today, more than 80 years later, the subsurface conditions beneath several of Boston?s historic neighborhood areas continue to be plagued with low groundwater levels - regrettably resulting in ongoing deterioration to the wood piles that support some of Boston?s oldest and most beautiful buildings. Pit underpinning is still recognized as the preferred approach to repair wood piles and restore uniform foundation support beneath the impacted buildings. This paper provides a brief historical review of the land filling in Boston through the early 1900s that led to the use of wood piles as building foundations. Also discussed is the impact that groundwater level can have on the long term performance of wood pile foundations and the pit underpinning procedures used to reconstruct decayed wood pile foundations in 1930 beneath the Boston Public Library, and today beneath some of Boston?s oldest buildings. Also included are discussions on engineering controls and permitting requirements that help ensure safety and protection to the workers and buildings during underpinning, and some procedures being used to supplement and improve the loading capacity of the reconstructed foundations and facilitate construction of new useable below-grade space.

Jan 1, 2011

By Derek. C. Arnold

In order to meet increasing demands for water supply in the next millennium, the Government of the Hong Kong Special Administrative Region have identified the need for a major new water treatment and transfer scheme. The project now under construction will comprise a 1.2 km long raw water aqueduct, a major new 0.25million cubic metres per day water treatment works (with space for upgrading to 1.2Mm³/d), a 12.1 km long treated water aqueduct and a primary service reservoir. In order to meet increasing demands for water supply in the next millennium, the Government of the Hong Kong Special Administrative Region have identified the need for a major new water treatment and transfer scheme. The project now under construction will comprise a 1.2 km long raw water aqueduct, a major new 0.25million cubic metres per day water treatment works (with space for upgrading to 1.2Mm³/d), a 12.1 km long treated water aqueduct and a primary service reservoir.

Jan 1, 1999

By Qingwei Wang

This study focused on acidic wastewater from producing sulfuric acid system in zinc smelter containing mercury 21.48mg/L, zinc 55.85mg/L, lead 38.50mg/L, copper 1.68mg/L, cadmium 10.25mg/L, As 29.86mg/L treated by biologics. The factors of pH value, the ratio of biologics to mercury, complexing time, hydrolytic time and temperature were studied in this paper. Experimental results indicated that at pH value 10, quantity of biologics to mercury ratio was 16, complexing time 30min, hydrolyzation time 20min, temperature at 40?, concentration of mercury in treated water was removed to 22.15µg/L. At same time heavy metals such as Zn, Pb, Cu, Cd, As was removed by biologics, the remained concentration in treated water was Zn 0.53mg/L, Pb 0.12mg/L, Cu 0.01mg/L, Cd low to 0.01mg/L and As 0.023mg/L. According to EDAX analysis, mercury content in complexing sediment reached 28.49% easily to recycle as raw material and low concentration of heavy metals in hydrolytic sediment easily to dispose and treat.

Jan 1, 2009

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

By Lon Santis, Dale Ramsey

The use of aircraft to support blasting operations in mines, quarries and construction sites goes back to the early days of aviation. Invaluable at times, aircraft use has been limited by cost, the unpredictability of weather impacts and other factors. Recently several technologies have matured to open up a new way to acquire aerial data with unmanned aircraft systems (UAS), commonly called drones. Equally important, the U.S. Federal Aviation Administration has recently implemented an exemption process and rulemaking to implement the commercial use of UAS into the United States’ National Airspace. The skies are opening for many applications of UAS. The most notable may be photogrammetry, which is the science of making measurements from photographs, especially for determining the exact positions of surface points.

Jan 1, 2016

By P G. Gaylard

The minerals Industry carries out over US$ 2 billion of R&D annually. The R&D is performed at three levels ? in house research facilities; on a one-on-one basis with a research provider; as syndicated (collaborative) research. The key to a successful R&D programme is project selection. It is suggested that at this time of ?bounty? for the minerals industry the research portfolio should contain some ?blue sky? but potentially long term significantly beneficial projects. This said, the projects should align the technical concepts with the business imperatives. AMIRA has found the ?Road Map? concept has assisted in defining areas for R&D. Examples of this methodology using a Copper Road Map developed by AMIRA for the copper producers operating in South America is presented. The benefits derived from syndicated research are also discussed.

Jan 1, 2007

By AMIRA P588 Research Team

This contribution summarises new knowledge and data, obtained during a three year ARCAMIRA funded research project, on the mineralogical and geochemical characteristics of hydrothermal alteration associated with low sulfidation, gold-silver epithermal deposits. These data are used to develop exploration vectors for use at both deposit and district scales, plus techniques have been established to distinguish ore grade epithermal systems from barren or low grade systems. Deposits investigated were Ladolam, Papua New Guinea, Gosowong and Mt Muro, Indonesia, Cerro Vaguardia, Argentina and Bimurra and Twin Hills, Australia.

Jan 1, 2005

By Wylie A. W, Mathew PJ

Bulk density and grade were determined on a variety of ore samples from the Mount Tom Price iron ore mine and the interrelationship between these properties and porosity deduced.Variable porosity is responsible for the wide scatter of data points and low accuracy of prediction in the grade of a single sample from grade/bulk density relationships.However, with a sufficient number of such data points, as from a nuclear geophysical borehole logging operation, the mean ore grade in an exploration-type drill hole (~63 per cent Fe) could be determined by regressionanal~sis with 95 per cent confidence intervals of approximately ± 1 per cent Fe. From the same logging operation, utilizing core data for calibration of the probe, the -mean fractional porosity for the drill hole (0·19 ± 0·016 at 95 per cent confidence interval) was deduced. This is less accurate than the corresponding result obtained on core material in the laboratory (0·20 ± 0·005).The range of porosity was from 0·08 for dense, high grade sectIOns of the ore, to 0·28 for friable ore of high grade or goethitic ore of lower grade. Shale band porosity ranged from 0·15 to anomalously high values of 0·48 believed to be caused by leaching of iron minerals from the shale. Porosity values for the iron ore component of the deposit are comparable to those found for the Cockatoo Island (W.A.) mine, and for sections of the Krivoy Rog (Ukraine) iron ore deposit of the Soviet Union.

Jan 1, 1978

By W. J. Young, K. B. Macneill, C. N. Smith

"A BRIEF HISTORY OF THE MURRAY BROOK MINERAL DEPOSITDuring the mid-1950's intensive exploration activity in northern New Brunswick followed the discovery of the world class Brunswick base metal deposit. Using the prototypes of modern airborne geophysical and geochemical exploration techniques many mineralized areas in the Bathurst-Newcastle area were quickly identified. This base metal - silver camp is situated within the metavolcanic - metasidementary rocks of the Tetagouche Group which forms a roughly circular caldera-chaped voloanio complex of Ordivician age.One of the early results in the exploration history in the camp was the discovery of the Murray Brook Deposit by Kennco Explorations, (Canada) Limited. During routine ground checking of geophysical anomalies, most of which turned out to be graphitic schist, the discovery of some copper bearing float was made by the exploration team. This encouraged the company sufficiently to carry out a regional stream sampling program which lead to a large anomaly associated with a hematitic gossan. Diamond drilling of a weak Slingram anomaly over the gossan zone resulted in the discovery of massive sulphide lenses. This was followed in 1956-7 with an intensive drilling program. The result was the delineation of a potential ore body containing an estimated 23 million tons with an overall grade of 0.44% copper, 0.86% lead, 1.95% zinc, 25.73 g/tonne (0.91 oz/ton) silver, 0.28 g/tonne (0.01 oz/ton) gold. Within this package were higher grade zones of copper and lead-zinc mineralization approaching ore grades.A thick blanket of gossan was present and is reported to have caused the drillers considerable trouble as they attempted to penetrate it to get to the underlying sulphides. The gossan, consisting of iron oxides and silica fragments sits on top of the massive sulphides and attains a remarkable thickness of 45.5 meters (150'). Early work had suggested that the gossan was enriched in gold and silver. If this were the case and if the precious metal could be leached out with cyanide, then mining and recovering those values might be economic.With this in mind Northumberland Mines Limited optioned the property from Kennco in 1985. Preliminary leach tests indicated that indeed the gold in particular leached readily. Subsequent drilling of the gossan (using triple core barrel technology for better recovery of the easily ground core) indicated 1,536,363 tonnes (1,690,000 tons) with an average grade of 1.05 g/tonne (0.037 oz/ton) gold and 42.13 g/tonne"

Jan 1, 1993

By Kym Runge, Emmy Manlapig

"The objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate. Regrinding and reagent addition are particle modification processes which are employed within these circuits to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process.Batch test nodal analysis, or the ability to compare floatability through mathematical combination of laboratory batch flotation test results, is a powerful technique for assessing the effectiveness of particle modification processes on ore floatability in industrial flotation circuits.In this paper, the use of nodal analysis is demonstrated within an industrial flotation circuit. It is used to show that regrinding and staged reagent addition within Teck Cominco’s Red Dog zinc retreatment circuit is beneficial to pulp flotation selectivity. Optimisation of these processes could potentially improve the zinc recovery within the circuit. Lime addition, which is periodically employed to depress pyrite in the circuit, was found to depress sphalerite in preference to pyrite and to result in poorer metallurgical performance in the circuit.INTRODUCTIONThe objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate.Different minerals can only be effectively separated using flotation if they are sufficiently liberated from each other (i.e. do not co-exist within the same particles) and have a sufficient difference in surface hydrophobicity. Size reduction processes and chemical addition are utilised before and within a flotation circuit to achieve sufficient particle liberation and to maximise differences in mineral hydrophobicity. In effect, the objective of these processes is to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process."

Jan 1, 2004

By Patrick Polk

For many years, sulfuric acid producers all over the world have been forced to meet ever more strict environmental regulations to reduce SO2 emissions. The sulfuric acid industry has implemented new solutions in order to comply with the new lower SO2 emissions target. Haldor Topsoe (Topsoe) has responded to this challenge by continuously improving the range of VK sulfuric acid catalysts and providing tailor-made catalyst solutions to meet the demands of the sulfuric acid producers for lower SO2 emissions. Reducing emissions through catalysis: requires less capital than installing a scrubber, requires no additional process chemicals, generates no waste or by-product to dispose of. In 1996 Topsoe introduced VK69, a cesium-promoted vanadium catalyst, designed for operation in the pass(es) after the intermediate absorption tower in double absorption plants. The high activity of VK69 allows for a more than 50% reduction in SO2 emissions from existing double-absorption plants. Topsoe currently has more than 110 installations of VK69. To comply with the still more stringent regulations being placed on the sulfuric acid industry to lower SO2 emissions, Topsoe has developed a new sulfuric acid catalyst designated VK-701 LEAP5™. This catalyst was introduced to the market in 2010. VK-701 LEAP5™ is based on a novel technology which circumvents the internal transport deficiencies of existing commercial sulfuric acid catalysts and thereby offers exceptionally high activity in strong, SO3 rich gases. Sulfuric acid plants have used this catalyst to meet emissions requirements lower than previously believed possible with a catalyst only solution. This paper will present examples on how to reduce emissions by implementing a tailor-made catalyst solution using VK69 and VK-701 LEAP5™.

Jan 1, 2014