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By Carina Ulsen

The existing construction and demolition (C and D) waste recycling technologies and standards have been essentially focused on the production and use of coarse recycled aggregates. Very few papers focus on the production of recycled sand, although some previous results show that fine aggregates fraction represents around 40 to 60% (in mass) of the Brazilian waste and it is usually used as road sub-base or disposed in landfills. The quality of the recycled aggregate is strictly related to the content of porous and low strength phases, mainly the patches of cement remaining on recycled aggregate surface. Some technologies have already been described in the literature, even though, to the moment none of these technologies has clearly succeeded in reaching the large market available. This paper presents a summary of the main properties of the sand produced from C and D waste by tertiary crushing at vertical shaft impact crusher (VSI). Additionally mineral processing technologies were applied on the attained product, such as gravity concentration by shaking table and spirals and removal of cement paste by attrition. The main properties of recycled sand are discussed and compared to the previous C and D waste, respectively: particle size distribution, particle shape, chemical composition, cement paste content and porosity. The results demonstrates that the crushing allowed producing a VSI-sand with low porosity and water absorption due to the increasing on the content of silicates from natural rock phases and increasing liberation between these phases and porous cement paste; the particles from the attained product presented also a better shape (sphericity and aspect ratio). The attrition tests assayed on VSI recycled fine aggregates accomplished a further selective disaggregation of cement paste and other porous materials - the porosity was reduced from 10% to 7%. The concentration by shaking table at narrow sieve fractions led to a product with low porosity and reduced content of cement paste, however, concentration on spirals did not succeed since separation was performed essentially by the size of the particles. The heavy product from shaking table represented almost 75% in weight and has less than 60% recovery of CaO+LOI, and expressive reduction on porosity. The aim of producing sand from construction and demolition waste through mineral processing unit operations changes the recycling approach and contributes for up cycling the recycled sand. The exhaustion of sand deposits on Brazilian large centers, the increasing price and the construction boom encourages the development of alternative materials as construction raw material. Keywords: recycled sand, construction and demolition waste, technological characterization

Sep 1, 2012

By A. Deepatana

This study compares the use of an aminophosphonate chelating resin Purolite S950 and a sulphonic acid strong cation exchange resin Purolite C160H to recover nickel and cobalt from the synthetic bioleach solutions. Batch adsorption of metal citrate is performed as a function of metal citrate concentration (15~2000 mg/L) and solution pH (0.01M and 0.1M citric acid). The adsorption mechanism as inferred from the fit to Langmuir (LM), Freundlich (FM) and Redlich-Peterson (RP) models demonstrates that nickel citrate adsorbed onto C160H appears monolayer in comparison to that adsorbed onto S950 exists multilayer. In contrast, cobalt citrate adsorption onto both C160H and S950 agrees with the LM model. The results have shown that loading capacities of nickel and cobalt citrate onto C160H are 60 and 65 mg/g whereas those observed onto S950 are 16mg/g and 6 mg/g respectively. These are achieved in metal citrate prepared in 0.1 M citric acid. Resin regeneration is conducted in using 2 M nitric acid solution. The results show high efficiency of nickel and cobalt citrate elution from Purolite C160H. Findings from this study suggest Purolite C160H is a suitable adsorbent for recovering nickel and cobalt from bioleaching solutions.

Jan 1, 2014

By N. S. Phala

Declining gold grades, mineralogical complexity of ore bodies, increasing input costs, more stringent conditions in the licenses to operate, and uncertain gold price dynamics combine to exert significant ongoing pressure on margins of gold producers. Innovative approaches of extracting the metal from its ores are required to realize value from existing and future assets. In a conventional gold processing plant, size reduction of mined ore to produce floatable or leachable product is a significant cost contributor. A step change in cost reduction will be attained if radically energy efficient grinding approaches can be developed, replacing tumbling mills. In the path towards that goal, some quick wins are possible through waste rejection before grinding, and pre-treatment of mill feed to reduce grinding energy demands. Gold locked in complex mineralizations puts pressure on margins by increasing cost per oz (typically high $/t and low metal recoveries) in the hydrometallurgical steps. Gold miners are primarily price takers. The current narrow range of gold uses (predominantly investment and jewellery) is not an entirely desirable state. Some diversification into commercial uses would potentially be a price stabilizer. In this paper, promising research directions, some not always fully explored in the gold metallurgy research space, are highlighted to stimulate radical innovation for substantial value enhancements. The author strongly believes a shift from a traditionally conservative and incremental innovation approach to a more aggressive one, across all aspects of the gold metallurgy value stream (processes to products), is what the industry needs. Keywords: gold metallurgy value stream, thiobaccilus ferroxidants, HPGR

Sep 1, 2012

By Y. M. Zhu, G. C. Gong

"The influences of citric acid (CA) on the flotation behavior of cassiterite using styrene phosphonic acid (SPA) as the collector were studied via single mineral flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations in this paper. The results of single mineral flotation tests revealed under the conditions that pH=4 and the dosage of SPA 100 mg/L, the recovery of cassiterite reached 76.78%. The addition of 20 mg/L AC decreased the recovery by 12.42% at pH=4. Contact angle measurements demonstrated the adsorption of CA prior to SPA made the cassiterite more hydrophilic. The results of zeta potential determinations and solution chemistry calculations indicated the chemisorption of C6H7O7- and C6H6O72- filled parts of the Sn site on cassiterite surface and prevented the SPA from getting adsorbed. The hydrophilic effect of AC was stronger than the hydrophobic effect of SPA and the flotation of cassiterite was crippled. INTRODUCTION Tin is an important metal which is widely used in medical instruments, marine engineering materials, electronic and electrical devices, welding, weapon manufacturing and organotin compounds industries (Angadi et al., 2015). Cassiterite is the only mineral from which the tin can be extracted, thus it is of great importance to efficiently exploit the cassiterite mineral. Flotation is an indispensable method for the recovery of cassiterite (Li et al., 2015). However, cassiterite is usually in association with many other gangue minerals which are of similar floatability, such as quartz, calcite, fluorite, iron oxide, wolframite, scheelite and tourmaline (Sreevinas, 1997). So some modifiers are necessary in the cassiterite flotation process. The amounts of the modifiers used in the flotation must be judicious and the overmuch modifiers may cripple the recovery of cassiterite (Parsonage et al., 1987). Nevertheless, the research about the effects of the modifiers on the flotation behavior of cassiterite has been rarely reported. In this paper, the influences of citric acid (CA) on the flotation of cassiterite using styrene phosphonic acid (SPA) as the collector were investigated by flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations."

Jan 1, 2018

By H. Ding

Calcium carbonate/Titanium dioxide composite, characterized by coating TiO2 on the surface of CaCO3 particles, is an important substitute for titanium dioxide. This paper studies preparation method of CaCO3/TiO2 ,composites based on mechano-chemical effects, measures its properties as a pigment, analyzes the binding form and interface reaction mechanism between CaCO3 and TiO2. Through single finely grinding of CaCO3, co-grinding of CaCO3 together with TiO2, and mecha-no-chemical effects produced in the course of grinding, CaCO3/TiO2 composites can be prepared successfully. Results indicate that grinding fineness of CaCO3, co-grinding time of CaCO3 and TiO2, the weight ratio of grinding media to mineral feeding, and the amount of TiO2 have much influence on the properties of CaCO3/TiO2 composites. CaCO3/TiO2 composites have the properties same as titanium dioxide pigment, oil adsorption and ultraviolet adsorption same as TiO2, and 90% of hiding power as that of TiO2. Wet grinding of CaCO3 causes the production of mechano-chemical effect and hydroxyl group, through which CaCO3 and TiO2 can be bonded together. Repulsion occurs between the particles of CaCO3 and the particles of TiO2, respectively, they are both in good dispersion. But attraction occurs between CaCO3 and TiO2. TiO2 particles are distributed evenly on the surface of CaCO3. Therefore, coating of TiO2 on the surface of CaCO3 particles and chemical bond between them make CaCO3/TiO2 compo-sites have pigment properties of Titanium.

Jan 1, 2014

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By S. M. Javad Koleini

Processing of phosphate ore sample was investigated for increasing phosphate content and reduction of its gangue minerals such as carbonates and silicates. Experimental designs were per-formed using Taguchi method. Different flotation methods were investigated for Moundon phosphate ore sample and three methods were used as follow: direct cellophane flotation, reverse calcite flotation and reverse quartz flotation. Because of the sensitivity of cellophane flotation to slime content, prior desliming was carried out before the experiments. Direct flotation experiments carried out and a concentrate contained 23.80% P2O5, 6.88% SiO2 and 72.33% recovery were produced. The achieved P2O5 content in the produced concentrate from reverse flotation of calcite was 26.44% and the recovery was 82.56%. The concentrate products obtained at optimum conditions by direct flotation of phosphate and indirect flotation of calcite were subjected to indirect flotation of calcite and direct flotation of appetite and final concentrates with P2O5 grade of the order of 24.19% and 26.96% were obtained, respectively. It was concluded that one stage direct flotation is unavoidable to achieve a product with low SiO2 content.

Jan 1, 2014

By Y. X. Yang

Porous silica was obtained by acid leaching of chrysotile. The porous silica had been characterized by chemical analysis, powder X-ray diffraction (XRD), Fourier transform infrared spectros-copy (FT-IR), and N2 adsorption-desorption techniques. It is shown in this study that the porous silica retains the nanofibrous morphology of the original chrysotile, and produces a high specific surface area (SBET) of 391. 8 m2/g and total pore volume of 1. 05 mL/g. The increase in SBET and the total pore volume of the porous silica reflect the formation of micropores of 1.2~1.5nm and meso-pores of 3.2~3.8nm in diameter inside the porous structure. The hysteresis loop of N2 adsorption-desorption curve indicates mainly slit-shaped pores. The porous silica is amorphous, but its structure is regular to some extent. The structural unit of silica from chrysotile is a SiO4 tetrahedron and six-member silicon-oxygen rings with the tetrahedral positioned alternately up and down in the six-member rings.

Jan 1, 2014

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By M. Brozek

The constant of flotation velocity is the value characterizing the kinetics of cyclic flotation. In the statistical theory of flotation its value is the function of probabilities of collision, adhesion and tearing off the grain from the air bubble. The grain ? air bubble collision plays a key role since there must be a prior collision before the grain ? air bubble adhesion happens. The probability of such an event to occur is proportional to the relation of the grain diameter to the bubble diameter. When the grain sizes are given, it is possible to control the value of collision probability by means of the size of air bubbles. Consequently, it is significant to find the effect of physical and physicochemical factors upon the diameter of air bubbles in the form of a mathematical dependence. In the pneumo-mechanical flotation machine the air bubbles are generated by the blades of the rotor. The dispergation rate is affected by, among others, the rotor rotational speed, the amount of air transported to the flotation chamber an time and the liquid surface tension, depending on the type and number of applied flotation reagents. In the proposed paper the authors will present the distribution of air bubble diameters on the grounds of the above factors, according to the laws of thermodynamics. The correctness of the de-rived dependences will be verified empirically.

Jan 1, 2014

By R. Marandi

The effective removal of heavy metals from aqueous wastes is among the most important issues for many industrialized countries, How ever biosorption, i.e. the uptake of heavy metals by non- living biomass, has gained increased credibility during recent years. Biosorption of Cr(VI) from aqueous solution, on pretreated and immobilized Aspergillus niger was investigated in a batch and countinuous reactors. A.niger biomass pretreated by boiling in 0.5 N NaOH solution for 15 min, exhibited higher Cr(VI) removal capacity than autoclaved biomass. The optimum adsorption pH value observed for Cr(VI) ions was 2. The Cr(VI)removal rate increased with a decrease in pH. The influence of contact time, pH, Cr(VI) concentration, biomass concentration and temperature on Cr(VI) removal were also evaluated. Biosorption of Cr(VI) on pretreated biomass followed the Freundlich and Langmuir adsorption models.In this study A.niger biomass was immobilized in Na-alginate matrix. The biomass beads packed in a column were able to remove metal ions.In this study we used two different flow rate in a column, 1.5 mL/min and 3 mL/min.The breakthrough data obtained for Cr(VI) was adequately by the Thomas and Yan models and the adsorption capacity of the biomass was found to less than the adsorption capacity obtaind in the batch study. When the beads containing biomass become saturated with metal ions, the adsorbed metals were eluted using 0.5 N NaOH solution. Therefor nearly 90% of Cr(VI) was desorbed by NaOH solution.

Jan 1, 2014

By Xiong Dahe

In recent years many creative technologies are applied to SLon vertical ring and pulsating high gradient magnetic separators. SLon-2500 and SLon-3000 vertical ring and pulsating high gradient magnetic separators are created towards larger scale. Through optimizing the magnetic system and lowering the electric current density, their energy consumption is obviously dropped. New magnetic matrixes are developed to raise the beneficial efficiency of valuable minerals. Special SLon vertical ring and pulsating high gradient magnetic separators are developed which can treat coarser particles of 0-5 mm. Through these technology creations, the mineral processing efficiency of SLon magnetic separators is further raised and their processing cost dropped. Therefore, they have been found wider applications. SLon-2500 applied in Essar Steel of India. In 2007, Essar Steel did a test on its Kirandul hematite ore with SLon magnetic separator and got very good results. The feed grade is 59.77%Fe, after SLon one roughing and one scavenging, the total iron concentrate grade is 65.00%Fe and iron recovery 93.86%. In 2008-2010, the company bought 10 SLon-2500 magnetic separators to treat such iron ores. In 2010 the first SLon-3000 was applied to processing ilmenite. The magnetite-ilmenite deposit is located in Pan Zhi Hua, Si Chuan Province of China. The ore processing flow sheet is: Drum low intensity magnetic separator is used to take out magnetite, and then the SLon-3000 is used to recover ilmenite for roughing. The mags of the SLon-3000 are further cleaned by flotation. The SLon-3000 average operational results are: feed grade 9.52%TiO2, mags grade 17.43%TiO2, mags mass ratio 41.01%, TiO2 recovery 75.09%, non-mags grade 4.02% TiO2, non-mags mass ratio 58.99%. SLon magnetic separators Applied to treat 0-5mm limonite: The feed of SLon magnetic separator is usually 0-2 mm which needs to be ground by ball mill. As many Chinese iron ores are poor grades, if we can throw part of tails before grinding, the grinding cost will be greatly reduced. In 2010, a SLon-1500 and a SLon-2000 were specially built to treat 0-5 mm limonite. The feed grade is 26.51%Fe, mags grade 53.20%Fe, iron recovery 64.26, and tails grade 13.66% Fe. SLon-2500 applied to purify quartz. In 2009, a SLon-2500 magnetic separator was applied to purify quartz in Shan Xi province. Its feed is 0-1mm quartz which contains 0.15%-0.25%Fe2O3, the designed non-mags grade need to be less 0.08% Fe2O3. The production results of SLon-2500 non-mags are 0.05-0.06% Fe2O3, much better than the designed data. SLon applied in Si Jia Ying Iron Mine to recover hematite. Si Jia Ying is a big oxidized iron mine located in He Bei Province of China. In 2005-2010, a plant annually treating 10 million tons of oxidized iron ore was built in which 39 SLon magnetic separators are applied. The total flow sheet results are: Feed grade 30.44%Fe, iron concentrate grade 66%Fe, iron recovery 80%Fe, tails grade 9.65Fe%. SLon applied to recover specularite. Li Lou Iron Mine in An Hui Province of China built a plant annually processing 5 million tons of iron ore in 2010-2011. 25 SLon-2000 magnetic separators are applied to recover specularite. The total flow sheet results are: Feed grade 31.65%Fe, iron concentrate grade 65%Fe, iron recovery 80%Fe, tails grade 10.37%Fe. SLon applied in Da Hong Shan Iron Mine. Da Hong Shan Iron Mine is located in Yun Nan province of China. It treats 4.5 million tons of oxidized iron ore annually. 15 SLon-2000 magnetic separators are applied to recover hematite. The total flow sheet results are: Feed grade 35.61%Fe, iron concentrate grade 64.95%Fe, iron recovery 74.08%Fe, tails grade 15.55%. Keywords: SLon magnetic separator, iron ore, ilmenite, quartz, beneficiation

Sep 1, 2012

By X. Y. Liu

A culture-independent approach based on 16S rRNA gene clone library was used to analyze the bacterial community change both associated to the solids and in the liquid phase during pyrite bioleaching process. Phylogenetic analyses of 16S rRNA fragments revealed that the retrieved se-quences mainly related to genus Leptospirillum, genus Sulfobacillus and genus Acidithiobacillus. During the bioleaching process, genus Leptospirillum trends to grow associated to the solids while major of genus Sulfobacillus were in the liquid fase, only accounting little portion in the solids. Genus Acidithiobacillus can grow both on the solids and in the liquid phase, but accounting high portion on the solids.

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By A. T. Adema

The cohesive zone, where the ore fed into the blast furnace softens and melts, is critical to the blast furnace performance and stability due to its influence on the gas and solid flow. This paper de-scribes a project for the development of a process model to predict the cohesive zone properties and the results of its first step; the solid flow model. The process model is expected to describe a realistic solid burden flow and the formation of the cohesive zone, its shape, location, structure, permeability, and in particular the mineralogical changes within the cohesive zone. This will be achieved using various simulation and computing tools: a combination of the Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD), the DEM?CFD hybrid approach, together with models for the thermodynamics and reaction kinetics. The key benefits of the hybrid approach lie in the coupling of the continuous phase and the discrete particles, and the possibility of introducing thermodynamics and reaction kinetics into the system in a more realistic manner. Two DEM simulations are presented for a small scale blast furnace to investigate the influence of non-spherical particles on the solid flow. This influence can be observed from a more even solid flow pattern and a reduced deadman size. The results indicate the requirement to include non- spherical particles in a blast furnace simulation to achieve a realistic solid flow.

Jan 1, 2014

By Graeme Lamson, Rene Dobbe, Merle Kalstrom, Janice Baron, Robert Thorpe, Chris Martin, Snezana Bajic, Amanda Palko

"This paper presents early results from a case study at the Mount Polley porphyry copper mine in British Columbia, Canada. Daily mineralogical data was acquired and reconciled with daily plant assay and recovery balances to interrogate the mineralogical controls on plant performance. After commissioning, the Minesite machine operated smoothly and reliably, creating daily data to generate mineralogical balances around the circuit for a period of several weeks. The key data, on final products were produced within 13 hours of the end of the respective operating period. The resulting information allowed for a greater understanding of the opportunities and limitations of the Mount Polley metallurgy. In this paper, how this information can be used to help long term strategic planning for the operation, as well as mine planning and production forecasting and the fine tuning of day to day mill operations is described. Early data available at the time of preparing this paper indicated that roughly 40% of the sulphide losses, or 32% of total copper losses existed as low grade inclusions in +75 micron tails. This represented the dominant form of long term copper losses, demonstrated repeatedly in the routine analytical data. However, on a day-to-day basis, the amount of copper present as chrysocolla is the major driver behind variations in total copper recovery. The degree to which this influences mill recovery is valuable to the geologist or mine planner. As they are armed with mineral speciation information for future ores, this will allow for improved mine planning, prediction of copper recoveries and production forecasting. The data was also started to find value in the mill by showing what caused sulphide losses. In the roughers, for example, the data showed poor recovery was the result of poor flotation performance and not any changes the speciation of copper sulphides or their liberation characteristics."

Jan 1, 2014

Domestic production of pyrite cinder reached 15.95 million tons in 2006. The pyrite cinder used in cement industry accounts for about 30% production. The remaining 70%, 11.17 million tons, was thrown away as waste, which brought serious environmental and resource problems. A new technology of composite pellet reduction-roasting and magnetic-separation (CPRM) has been developed to utilize pyrite cinder. Pyrite cinder sample, containing 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700~800 ? for 20min with 300kg/t pulverized coal injection in rotary kiln. After two stages of ball-grinding and four stages of magnetic separation, high grade magnetite concentrate with 66.23% Fe was produced, meanwhile impurities Cu and S was decreased to 0.048% and 0.053%, respectively. And iron recovery of 73.32%, desulphurization of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which can be removed during wet magnetic concentration. This new technology can be used to fully utilize pyrite cinder and produce high quality magnetite concentrates as feed for steel industry, which will help tackle the pollution problem of pyrite cinder and extend iron-bearing raw material sourcing for Chinese steel industry.

Jan 1, 2014

By W. D. Guo, Y. M. Zhu, B. B. Luo

The main chemical constituents of waste cooking oil are higher fatty acid glycerides, which can be used to produce anionic fatty acids for most non-sulfide flotation. However, using the mixed fatty acids (MFA) produced by waste cooking oil as collectors directly, the flotation effect is usually not satisfactory, especially at lower temperature or room temperature. There are very rare systematic studies about the reason for poor flotation performance of waste cooking oil. This study aims to investigate the flotation and adsorption characteristic of different types of fatty acids in waste cooking oil to find out what kind of fatty acids results in the poor flotation performance. This will provide technical supports and theoretical guidance for the waste cooking oil application in the field of mineral processing. In this study, MFA were produced from the waste cooking oil, and then separated into saturated fatty acids (SFA) as well as unsaturated fatty acids (UFA), which possessing different flotation properties. The properties of the MFA, SFA and UFA were analyzed by iodine value, melting point measurement, Fourier transform infrared (FT-IR) spectroscopy and quartz micro-flotation tests. The results showed that UFA was composed of fatty acids containing group—(CH=CH—CH2)n—, having an iodine value of up to 162.90, a melting point as low as -17.3 ? and stronger low-temperature floatability. In contrast, the SFA was made up with saturated fatty acids and a few oleic acids, with an iodine value of 48.97 and a melting point of 38.8 ?. SFA had shown poor collectability and required a flotation temperature higher than 35 ?. The results of zeta potential measurements, solution chemistry calculation and FT-IR spectra revealed that both UFA and SFA can be adsorbed on the quartz surface activated by CaCl2 via the chemical and hydrogen bonding. The reason MFA having a poor flotation performance is the SFA has an extremely high melting point which affecting the dissolution of the dispersion.

Jan 1, 2018

By Arkady Senchenko, Yury Kulikov

"Basic theoretical grounds of the methods applied for crushing and grinding parameters determination according to international standards are given in this paper. Statistical data about crushability and grindability research are shown. The potential relationship between the values of Fred Bond Work indices and John Starkey indices (Crushing index, Ball mill index, Rod mill index and AG/SAG index) are discussed in this paper. In order to establish correlation between the crushability and grindability indices the analysis of over 2 500 tests for 165 deposits located in different parts of the world was performed. The relationships among different types of energy consumed for crushing and grinding were determined. A method for preliminary estimation of energy consumption in semiautogenous + ball mill grinding circuit is suggested for its application in preliminary technological solutions development and technical-and-economic assessment."

Jan 1, 2014

By A. Vilinska

Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. Recent developments in biotechnology have not only aided hydrometallurgical leaching operations but also shown great promise in mineral beneficiation processes. The adhesion of bacteria on minerals alters the surface properties relevant to flotation and flocculation of minerals. The biomodification of mineral surfaces occurs through the attachment of microbial cells, oxidation reactions and adsorption or chemical reaction with the metabolite products. Several types of heterotrophic and chemolithotrophic bacteria have been successfully applied in flotation and flocculation processes for the last two decades. Al-though the potential of microorganisms in minerals beneficiation has been realised by several re-searchers from their laboratory investigations, the studies were mostly confined to pure mineral systems and there is hardly any sincere effort to apply the methodologies on ores. This paper presents a brief summary of the literature in bioflotation and bioflocculation, and attempts to outline new dimensions of research for a practicable application of this technology in mineral industry.

Jan 1, 2014