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By William F. Stowasser

The United States has traditionally been the world's largest producer and net exporter of phosphate rock and related fertilizer products with the exception of rock exports from Morocco. In recent years, however, U.S. producers have faced increasing competition from operations in foreign countries, leaving the future position of the U.S. phosphate .industry as a leader in the world markets somewhat less certain. This paper will review the U.S. phosphate rock industry in relation to its known demonstrated reserves, its historical and present production and export levels, and its future mining potential. The paper will include an analysis of the availability of phosphate rock in the United States represented by cost-tonnage relationships. The U.S. phosphate rock industry has for decades provided raw materials at reasonable costs to the phosphate fertilizer industry, and the fertilizer products have been made available to both domestic and international markets. Natural soils normally contain low quantities of phosphorus, and cultivation exhausts the available phosphorus through the removal of harvested products. Yields diminish, and it becomes necessary to apply phosphorus to the soil in an amount at least sufficient to compensate for removal. Raising the level of phosphorus also permits nitrogen and potash fertilizer nutrients to be effective and sustain the high crop yields necessary to support increasing food demands. In only a few areas of the world are soils, climate, rainfall, and low-cost phosphate fertilizer available to assure high agricultural yields in successive years. One of these areas is the central United States and south central Canada. By contrast, in the Soviet Union, the weather conditions in farming areas frequently cause crops to either bake or drown in the field. To attempt to counter the effect of weather on production, the U.S.S.R. has increased use of fertilizer and equipment in recent years. The effect of fertilizer on various crops has been documented, and in all cases, improvements in yield and plant development were noted, as was the ability of fertilizer to mitigate the effects of unfavorable climatic conditions. Phosphate resources can be classified as either identified or undiscovered. In the identified classification, we are principally concerned with demonstrated phosphate resources, or those that have been measured or indicated. In the southeastern United States, the phosphate mining areas of Florida and the Carolinas have been explored and drilled extensively in attempts to locate new deposits. The exploration programs indicate that another Florida Bone Valley Formation or North Carolina Pamlico River Deposit is unlikely to be discovered in the southeastern U.S. coastal plain. Phosphate rock deposits of commercial interest in the western United States are located in Montana, western Wyoming, northern Utah, and southeastern Idaho. The deposits are in the Permian Phosphoria Formation with most of the mining activity occurring in Idaho. Although substantial demonstrated resources have been identified, recovery costs and the field's isolation from markets have restricted growth of the industry in the west. The phosphate rock deposits in Tennessee are well known, and it is estimated that about 29 million metric tons1 are potentially recoverable. Undiscovered deposits of brown rock in Tennessee would likely be quite small.

Jan 1, 1985

By Nopadon Mantajit, Dallas W. Davis, Somsak Potisat, Prasert Kumalachan

For centuries Thailand has been a significant, though primarily unofficial, producer of gold. Panning has been the traditional way of making a living for innumerable villagers during the December to May dry season following the harvest. During this period groups can be seen working the streams, rivers, fields and dry valleys at as many as 90 localities in 28 provinces. Attesting to their efforts are the five and a half ton solid gold Buddha at Wat Trimit and much of the gold jewelry sold in Bangkok. This traditional panning will continue, and probably become more extensive, in harmony with commercial endeavors using modern technology suitable for extraction of gold from types of deposits for which gravity separation would give very low recoveries. Several such deposits have been discovered in the course of geochemical and geological surveys conducted by the Royal Thai Department of Mineral Resources with the object of contributing to early interpretation of the results of a country-wide airborne survey.

Jan 1, 1987

By E. Milosavljevic, C. H. Bucknam, K. L. Gabby, T. C. Eisele

"Since mercury is chemically similar to silver, it tends to dissolve along with the silver and gold during cyanide leaching. Ultimately, mercury is recovered along with the silver as mercury/silver/gold amalgam, which requires retorting to remove the mercury prior to refining the silver and gold. A possible approach to separating mercury from silver and gold in cyanide leach solutions is to take advantage of the replacement reaction between [Hg(CN)4]2- and Ag2S, which results in precipitation of mercury as HgS while dissolving silver as [Ag(CN)2]-. Results are presented demonstrating that mercury can be removed from cyanide solutions with high effectiveness while, at the same time, recovering additional silver in solution. Initial experiments with static flasks in the laboratory showed a high degree of mercury removal could be achieved. Results using actual metallurgical plant products in bottle roll tests indicate the process works on a larger scale, but also results in significant gold losses if the solution being treated has high gold levels, such as carbon stripping pregnant eluent solution. IntroductionThe dissolution of mercury along with precious metals during cyanide leaching is a long-standing problem, which can result in significant mercury toxicity issues (Washburn, 2003). Mercury is first dissolved by the cyanide solution, and then, since it has a great deal of chemical similarity to silver, it follows silver throughout the concentration and recovery processes, ultimately being recovered as a silver/ mercury amalgam when the metal is precipitated by either the Merrill-Crowe process or by electrowinning.While it would be desirable to either prevent mercury dissolution entirely while still allowing silver dissolution, or to selectively capture mercury before the precious-metals recovery step, there is not yet an effective and economically practical approach to doing this (Grosse, 2003; Ravichandran, 2004; Misra, 1998; Pai, 2000). There are a few processes that have been proposed, such as differential adsorption. While activated carbon, as used in the carbon-in-pulp process, is not highly selective between mercury and silver (Washburn, 2003), it may be possible to achieve some separation by selective elution of the carbon to produce high-mercury and low-mercury eluates (Bunney et al., 2010). Certain synthetic resins were shown to be selective for gold but are more expensive than carbon, requiring special equipment, and have not yet been shown to be selective for mercury (Grosse, 2003). There may be potential for differential dissolution approaches, as thiosulfate leaching does not dissolve mercury sulfides as readily as it dissolves gold (Oraby et al., 2010), and it is possible that it may be similarly more selective for dissolving silver relative to mercury. Some work has also been done with selective precipitants, such as sodium polythiocarbonates (Bucknam, 2007), and 1,3-benzenediamidoethanethiol (Matlock, 2002). Common problems with these approaches include introduction of a solid:liquid separation step, reagent costs, the need to measure the mercury concentration for process control for minimizing silver losses, and regulatory requirements to retort otherwise stable mercury concentrates."

Jan 1, 2015

By G. Rinelli, Arthur F. Colombo, Donald W. Frommer

With the opening of the Tilden mine near Ishpeming, MI, a new era in iron ore beneficiation was begun. A description of a U. S. Bureau of Mines investigation is summarized to illustrate the selective flocculation-deslime-flotation process developed by the Bureau and used at the Tilden concentrator, which is also briefly described. The operating parameters for the selective flocculation-cationic flotation of an oxidized taconite from the Mesabi range are discussed. A water reclamation system using lime and a cationic flocculant was applied to reclaim the effluents from a 900-pound-per-hour flotation pilot plant. About 80 percent of water requirements were recovered, and the calcium content of the reclaimed water was found to be more important than clarity in influencing the selective flocculation and flotation processes. Although reclaimed waters with about 10 ppm calcium registered turbidities of approximately 5,000 ppm SiO2 equivalents, the concentrates produced using these waters contained 64 percent Fe and =5.0 percent SiO2 and had accompanying iron recoveries of 75 percent. Lower grade concentrates resulted from using reclaimed water with higher calcium contents and lower turbidities.

Jan 1, 1976

By Peter F. Howard

The lower Middle Cambrian phosphorite deposits of the Georgina Basin shown in Figure 1 were found in the period 1966-1968 by three companies, namely, International Minerals and Chemical Corporation, Continental Oil Corporation and Broken Hill South Limited. Of these deposits the significant ones are Duchess, Sherrin Creek, D Tree, Lady Annie, Lady Jane, and Wonarah which together aggregate several billion tons reserves of phosphate. Due to the economic factors of freight costs to the coast and softening of the world market price for rock phosphate, none of them is in production, nor is any in the development stage. This paper reviews the historical background to the discovery of these deposits and then deals principally with the discovery of non-outcropping phosphorites in the Barkly Tablelands of Northern Territory by the interpretation of gamma radiation logs of abandoned water bores.

Jan 1, 1971

By R. Hogg

Based on a simplified model for the motion of particulate materials in horizontal, rotating cylinders, approximate expressions have been derived relating the power consumption of a tumbling mill to its dimensions and speed of rotation and to the amount and nature of the charge. The basic assumptions underlying the model are that there is no slip between the charge and the mill shell, that the free surface of the charge remains essentially planar during rotation and that there is no transfer of momentum from the material flowing down the free surface back to the mill shell. The relationships formulated from this model have been shown to be in excellent agreement with experimental results taken from the literature. While the requirements of the model are most closer met at low speeds of rotation, the results appear to be valid even for speeds up to 70-80 percent of the critical speed. Poorer agreement between theory and experiment is found when the charge consists of relatively large particles (balls) and when the filling of the mill exceeds 50 percent of the available volume. Qualitative explanations of these deviations have been offered.

Jan 1, 1971

Refractory gold concentrates often contain sub-microscopic gold that is encapsulated within the crystal matrix of iron sulphide minerals such as pyrite, pyrrhotite and arsenopyrite. To recover the gold, the host mineral must generally be broken down chemically, by oxidative processes such as roasting, pressure oxidation or bacterial leaching, which expose the gold for subsequent recovery by leaching in cyanide solution. The focus of attention in these pre-treatment processes is usually the oxidation of the sulphides to elemental sulphur, sulphur dioxide gas or sulphate ions. Less attention is paid to the deportment of iron and the changes in its oxidation state, although this can have a profound effect on gold and silver liberation, as well as down stream operating costs. Iron sulphide minerals break down completely during pressure oxidation, and dissolve in the sulphuric acid solution that is generated from oxidation of the sulphides. This liberates the tiny gold particles that were originally trapped in the sulphide crystals, and gold recovery during subsequent cyanidation is usually very high (>95%). Iron goes into solution in the oxidation process, initially as ferrous sulphate, but this is rapidly oxidized to ferric sulphate, which then hydrolyzes and re-precipitates. The form of the precipitate varies depending on the operating conditions in the autoclave and the presence of certain metal cations. When the acidity in the autoclave is quite low (<20 g/L H2SO4) and the temperature is high (>200OC) the formation of hematite is favoured. When the acidity is high (>20 g/L H2SO4) and the temperature is relatively low (160 to 200OC), the formation of basic iron sulphate is favoured. If the ore or the leach solution contain significant levels of certain cations (such as Na+, K+, NH4+, Ag+ or Pb2+) and the acidity is high (>20 g/L H2SO4), jarosite compounds are favoured. Hematite is the desired iron product in the autoclave discharge, for both metallurgical and environmental reasons, but it is difficult to operate an autoclave under the conditions required for effective liberation of gold without converting some of the iron to basic iron sulphate and/or jarosite. These compounds fall into a category of iron compounds known generically as iron hydroxy sulphates, all of which can cause significant processing and environmental problems in the downstream gold process. This paper deals specifically with basic iron sulphate; the conditions under which it is formed in an autoclave, the problems that are caused by its presence in the feed to a cyanidation plant, and possible remedial strategies that can be adopted, both in the autoclave and downstream.

Jan 1, 2010

By C. L. Karr

Researchers at the University of Alabama are investigating artificial intelligence based computer models of mineral processing systems. Two approaches have been found to be particularly effective in developing data-driven computer models. The first approach employs neural networks which are computational paradigms based on the mechanics of the human brain. They are able to extract the basic relationships between input and output variables from large data sets. The second approach combines fuzzy mathematics with genetic algorithms to produce an adaptive modeling system. Fuzzy mathematics provide computers with the capability of manipulating abstract concepts like those which humans use so effectively in decision making. Genetic algorithms are search algorithms that mimic evolutionary processes apparent in nature. Together, these two techniques can be used to produce an effective modeling system. In this paper, the two approaches to modeling are compared and contrasted with respect to accuracy and computational time while used to model three mineral processing systems: (1) a grinding circuit, (2) a hydrocyclone separator, and (3) a flotation circuit.

Jan 1, 1997

By L. B. Hales

December 3, 1972, James Wm. White presented the results of an instrumentation and process control survey which was sponsored by the Anaconda Company at the annual Tucson Subsection AIME meeting.(1) Twenty-six responses were obtained from questionnaires sent to 48 operating plants throughout the world. The survey results were discouraging in that there were more failures and problems than examples of success. The following quotes are taken from the text of the paper. "We run our mill by the seat of our pants." &apos;If these blue sky Ph.D.&apos;s (in the instruments and controls area within research) had some operating experience they wouldn&apos;t make a lot of the suggestions they do."

Jan 1, 1981

By LaPoint D. J.

Copper deposits in sandstones are excellent targets for open pit mines using SX-EW extraction and processing methods. The mineralogy consists of chalcocite as the primary sulfide and copper carbonates and sulfates in the zone of oxidation. Two general deposit types are recognized: early diagenetic copper deposits that are associated with the reddening of the surrounding sediments, and epigenetic deposits that are associated with the migration of copper-rich basinal fluids along faults into permeable reservoir beds with a source of reductant. Epigenetic copper deposits are more likely to contain enough tonnage to be economic.

Jan 1, 1996

By Terry W. Engelhart

"A computer-based approach to online supervisory control and operations management of bulk materials handling terminals". This paper describes an integrated computer facility supporting the functions and responsibilities of shift operations, scheduling, maintenance and management using real-time interactive techniques. The functions and responsibilities as related to coal export terminals are specifically addressed, although these functions would be equally applicable to other terminal configurations and other commodities. A discussion of the resulting benefits are presented: - throughput efficiency - long-term planning and scheduling, using simulation - operations monitoring and protection - demurrage/despatch optimization - preventative maintenance - operational productivity

Jan 1, 1982

By Drummond Earley III

The hydrology of in situ leach mining operations is being studied by the U.S. Bureau of Mines using a variety of techniques, and the Bureau has made significant advances in tracking and modeling the flow of leach solutions in rock formations. However, the influence that leach solution composition has on the hydrology of these systems is poorly understood, and geochemically-controlled changes in the hydrologic characteristic of ore deposits during in situ leach mining of porphyry-hosted, copper oxide ores have not been previously studied. The Cyprus Casa Grande in situ leach mining operation mines fracture-hosted and disseminated copper oxides (predominantly chrysocolla) hosted by granodiorite porphyry using a pattern of underground wells. The injection solution consists of sulfuric acid raffinate from a solvent extraction-electrowinning plant. Chemical analysis of representative injection and recovery solutions reveals that gangue cation concentrations in these solutions are high, and geochemical modeling shows that the solutions are saturated or nearly saturated with respect to gypsum, jarosite, and various amorphous oxides. Precipitation of these solids is evoked by calcium-exchange reactions, rising pH, and perhaps locally rising redox potential, as the leach solution reacts with the ore minerals, host rocks, and the atmosphere. Mass and volume balance calculations show that approximately 25 cm of precipitates are formed per gram of copper recovered at Cyprus Casa Grande. The results of geochemical modeling agree with petrologic examination of pre-and post-leach core samples from the leached horizon. Moreover, hydrochemical modeling and hydrologic field data suggests that chemical precipitation causes significant decreases in porosity and permeability during in situ leach mining of porphyry-hosted, copper oxide ore.

Jan 1, 1992

By Steve Kral

When discussing stock market investments, a company&apos;s performance is important. But so is the financial community&apos;s perception of that performance. To be sure, a good product or service, coupled with sound manage¬ment, remains important but is no longer enough. How stock analysts view a company&apos;s performance has become equally important. A major task of a mining company&apos;s investor relations officer, then, is to build and maintain a positive perception of the company to mining analysts throughout the world. That&apos;s a tough assignment in any market. The subject here, though, is gold. And, with its weakened price, gold companies must work harder to convince analysts their company is still a good investment. The analyst, on the other hand, must see through the corporate hype and decide whether it&apos;s worth recommending to clients as an investment. No simple task, either. Annual reports, 10-K forms, and quarterly reports only tell part of the mining company&apos;s story. Site visits, complete with discussions (sometimes interrogations) with a mine&apos;s principals, oftentimes tell an analyst more about a company&apos;s investment potential than the annual or quarterly report. So it was that three of the nation&apos;s major gold companies arranged a three-day tour of their gold operations in Nevada for a group of 22 analysts and a pair of mining industry scribes. The analysts represented investment houses the US, Canada, and England. The host companies and mines visited included FMC Gold&apos;s Paradise Peak mine, Amax Gold&apos;s Sleeper and Wind Mountain mines, and Battle Mountain Gold&apos;s Surprise and Fortitude mines.

Jan 1, 1989

By Paul Soros

There has been a steady increase in shiploading capacities in the last 20 years. One of the reasons has been the general increase in ship sizes, with the largest vessels currently around 280,000 DWT in the bulk trades. Obviously, the large vessels can accept loads faster and their economic utilization justifies higher loading rates, up to a point. The high capacity facilities have loading rates far beyond this point. The economic logic of these facilities is based on the fact that for a given annual throughput the capital and operating cost of a single high capacity system is less than that of two smaller systems. Thus, where the projected throughputs are large, there is a great incentive to reduce capital costs by maximizing capacity. Tubarao, in Brazil, designed for a 100 million ton per year throughput with one finger pier and one high capacity berth is a successful demonstration of this approach. In the current state of the art, the high capacity systems have shiploading capacities in the range of 10,000 - 16,000 TPH, for annual throughputs of 20 million tons and larger per loading berth.

Jan 1, 1982

Over the years, numerous studies have been conducted to characterize the floatability of coal pyrite. Unfortunately, many of the results obtained using isolated samples of coal pyrite are not directly applicable to actual coal flotation systems where liberation and entrainment may be the major factors affecting pyrite rejection. In this paper, the association of pyrite with other coal constituents is investigated, and the data are presented for feed and product streams obtained from release analysis tests. Release analysis is used to minimize the effects of entrainment. Particle distributions for each stream are presented as functions of size and composition in order to discern the behavior of free and composite particles.

Jan 1, 1992

By A. A. Densmore

Telluric Current is that portion of the electric field observed at the surface of the earth which is of an alternating nature, and which is related to solar activity and events in the ionosphere. The primary electromotance which drives the telluric current is the result of the induction process associated with time variations in the earth&apos;s magnetic field. The relationship between the electric and magnetic components of this electromagnetic field depend upon the conductor. For our purposes, we are dealing with frequencies f in the range

Jan 1, 1972

By J. R. Cobble

The Bureau of Mines has developed a process to improve the leaching kinetics of diffusion controlled systems. The system features the Bureau-developed turbomill, an attrition grinder which scrubs the reaction product coating away from the unreacted mineral grains during leaching. The system can be continuously operated at any temperature up to the boiling point of the leaching agent. This paper describes the research on the dissolution of chalcopyrite with acidified ferric sulfate which forms a sulfur product on the unreacted chalcopyrite surface. This method is a hydrometallurgical alternative to chalcopyrite smelter technology which eliminates S)2 emission problems with its associated costs. Batch testing at 90? C with the chalcopyrite/ferric sulfate system resulted in better than 99-pct extraction of copper. At an optimal energy consumption of 1,520 kW h/st, 95 pct of the copper was extracted. Recent work has been directed to development of a continuous system and SX/EW treatment of the resulting pregnant liquor from the chalcopyrite/ferric sulfate leach.

Jan 1, 1991

By J. Swensen, R. Brandon, A. Wallstein, S. Bessinger, J. Pile

It is generally agreed that C.C. White was the first to describe and market coal mine roof trusses beginning as early as 1967. White was issued a patent in 1969 1. Coal mine roof trusses were extensively used in the 1970’s, and their use has proven valuable in many difficult conditions. Beginning in the mid 1990’s, several types of bar/cable trusses have been introduced. A new and innovative bar/cable truss recently introduced offers several advantages. By eliminating many small parts, and simplifying the installation, these new trusses are much easier and faster to install, thereby increasing operator safety.

Jan 1, 2004

By D. Bristow, D. Baker, K. Awuah-Offei, A. ur Rehman

While a body of work exists on intelligent systems for guiding occupants out of buildings during an emergency, the problem of guiding miners out of a mine during an underground emergency has not been explored. Underground evacuation fundamentally differs from building evacuation because of differences in the regulatory regime and uncertainty regarding the number of occupants. The potential for implementing an intelligent miner guidance system is buttressed by the fact that miner tracking systems, along with communication and sensor networks, already exist in underground mines. This work presents a method based on a local positioning system, in the form of a network of “nodes” at major “intersections,” which can then be used to guide miners to safety. We have developed a path-planning algorithm, based on Dijkstra’s algorithm and the local positioning system that can provide miners with the optimal escape path in an emergency. The algorithm is validated with scenarios at the Missouri University of Science & Technology Experimental Mine demonstrating the potential to include smart technology in mine emergency management and response planning. INTRODUCTION Underground mines are hazardous environments with a higher than usual risk of safety emergencies where miners have to evacuate the mine to save their lives. Mines have always trained miners to evacuate or shelter-in-place in minimum time. Jalali and Norrozi (2009) opined that the three major components that help miners in case of emergency are pre-planned optimal escape routes, decreasing delays, and improving the education of miners. In fact, Goodman and Kissel (1990) suggested that fatalities arising from mine accidents could be reduced by 50% just by decreasing delays in finding the pathways in case of emergency. The proposed work can assist miners in finding escapeways quickly in case of emergency. It is very important to have a pre-planned evacuation strategy that is clearly communicated to miners to ensure the safety of all (Conti, Chasko & Wiehagen, 2005).

Jan 1, 2019

By F. J. Murrell

No other region of the world is enjoying the tremendous growth of power use that is currently being experienced in Asia. Fortunately for those of us in the coal industry -particularly in Asia -the preponderance of the power plants being planned or under construction designed to use coal as the power plant fuel. This has produced a significant increase in the demand for steam coal, which has in turn encouraged many of us in the industry to develop new coal mines. One country that has enjoyed very substantial growth in coal production is Indonesia. This developing country of 195,000,000 people who live on the nearly 13,000 islands of Indonesia have emerged very quickly to become the third largest exporter of steam coal, following only Australia and South Africa. Almost all coal in Indonesia is mined by surface mining methods. This paper will examine the surface mining of coal in Indonesia, as it continues to be an important part of the supply equation for coal in Asia.

Jan 1, 1996