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By W. M. Cross

The hydrophobic character of sapphire surfaces in SDS solutions was examined with respect to the aggregative nature of the adsorbed surfactant phase. It was found that, at equilibrium, sapphire surfaces having adsorbed SDS bi-layers exhibited no contact angle. Conversely, when the adsorbed SDS was found to be mi-cellar in nature, sapphire surfaces developed significant hydrophobic character. The surface states as detected by Fr -IRIIRS conformational analysis were found to be reversible with temperature. The variation in adsorption density with temperature was studied by in situ Fr-IRIIRS. The isosteric heat of adsorption was calculated to be -1.6 kcal/mole. Although the adsorbed SDS was found to undergo a reversible phase change between 25 and 32°C, similar to SDS in solution, the extent of adsorption was not reversible with temperature.

Jan 1, 1993

By Keat Chuan Chew, Qiao Yue Tung, Teoh Yaw Poh

"1 INTRODUCTION With a land area of 718 square kilometres housing a population of slightly over 5.4 million, as of 2014 (Department of Statistics Singapore 2015), Singapore is a highly urbanised city. Transport infrastructure is critical to keep the country and economy highly connected and functional as the population in Singapore continues to grow. The importance of a robust transport infrastructure is recognised by the Ministry of Transport in Singapore, which is working towards bringing 8 in 10 households within a 10-minute walk of a train station by 2030 (Ministry of Transport 2015). This gives rise to the rapid expansion of the rail network in highly urbanised Singapore, resulting in more tunnelling work having to be carried out in closer proximity to existing buildings. Such tunnelling work is expectedly more challenging and complex, and if not managed effectively, will impose higher risk to the adjacent buildings. Hence, the Building and Construction Authority (BCA) has implemented specific control measures to mitigate such tunnelling risks and to ensure safety of the public. 2 CHALLENGES FACED BY TUNNELLING WORK IN SINGAPORE 2.1 General Challenges of Tunnelling in Singapore With the increasing densification of the rail network in a highly urbanised setting, rail projects in Singapore are faced with several key challenges. One such construction challenge is constrained construction sites brought about by network intensification. Alongside the growth of the rail network, shown in Figure 1, other infrastructure networks in Singapore are also continuously growing. Underground interchange stations between networks become increasingly common, forcing each underground interchange station to be constructed deeper and in closer proximity to existing buildings (Figure 2). Singapore is not alone in facing this issue. The same can be observed in cities like London, in which its myriad network of subway lines pushes new lines and interchange stations to be constructed deeper."

Jan 1, 2016

By John A. Meech

In many multiple-sulphide ore flotation processes, it is desirable to concentrate each of the various valuable minerals into separate products. Although there are a variety of techniques and chemicals which can be employed to produce efficient separation, two basic types of flotation circuits are used: The Differential Flotation Circuit and the Bulk/Selective Flotation Circuit. Figure I depicts these two circuits in their most simplified form for the production of two concentrates and one tailing product. If three or more valuable minerals are present in an ore, a variety of combinations or extensions of these two basic flowsheets may be used. There are many examples of the successful application of both circuit types with ores containing similar minerals. Each ore must be tested individually to decide on which circuit is best. However, the following general statements can be made: 1) The differential circuit will have higher capital and operating costs than will the bulk/selective circuit due to higher rougher capacity requirement. 2) The differential circuit will achieve better separation than will the bulk/selective circuit since it is usually easier to reactivate a depressed mineral than it is to depress an already active mineral. If the deactivation problem with the bulk/selective circuit . . in can be overcome, there is a clear economic argument for its use

Jan 1, 1977

By D. Shaver, M. N. Badonie, J. Newcomer, V. T. McLemore, E. Owen

Rare earth elements and critical minerals have recently become of great economic interest because of their necessity for many new technologies and recent geopolitical unrest affecting the supply and import of resources. The San Juan and Raton basins in northern New Mexico are two structural coal basins that contain elevated concentrations of rare earth elements and critical minerals. These two New Mexican coal basins will be assessed geochemically and petrographically to identify vectors of the rare earth element and critical mineral enrichment. Coalbeds, coal seams, overlying, and underlying rock units will be sampled and characterized to determine any economic viability. Historic data will be compiled into a new and comprehensive coal geochemical database, which will grow with new analyses, and serve as the dataset for this project; this coal resource database will be made available to the public.

Feb 1, 2023

By P. Zhang, S. Al-Thyabat

"Phosphate rock contains traces of rare earth elements (REEs) and can be a secondary source of these critical materials as large tonnages of phosphate rock are mined annually. Attention has mostly focused on the extraction of REEs from phosphogypsum, which contains more than 70 percent of the REEs reporting to phosphate concentrate, with only limited work conducted on REE extraction from sand tailings and slime even though they account for 16 percent and 15 percent, respectively, of REEs mined with phosphate matrix.In this work, phosphate flotation tailings were upgraded by gravity separation and froth flotation. Gravity separation was conducted using a laboratory shaking table, while flotation was conducted in a Denver D-12 flotation cell. The concentrated tailings were then leached by nitric acid followed by REE extraction with solvent and ion-exchange resin.The sand tailings were assayed as having 2.6 percent phosphate (P2O5 ) and 198.1 µg/g REEs. It was found that the shaking table could produce tailing concentrate assayed as having 8.6 percent P2O5 and 616 µg/g REEs but with only 20 percent REE recovery, while the froth flotation produced froth concentrate assayed as having 8.1 percent P2O5 and 368.2 µg/g REEs with 63.5 percent REE recovery. Leaching the flotation concentrate with 5.2 M (25 percent) nitric acid followed by extraction with solvent and ion-exchange resin yielded precipitates with REE contents of 0.926 and 0.314 percent, respectively, compared with 0.716 and 0.213 percent when table concentrate was used.IntroductionRare earth elements (REEs) consist of a group of 17 elements: the 15 lanthanides along with yttrium (Y) and scandium (Sc). They are rare not because of their scarcity in the Earth’s crust but because they are rarely found in economic and mineable deposits. REEs are called “seeds of technology” because of their importance to some critical technological industries such as renewable energy, hybrid cars, electronics and batteries. On average, an electric car or a hybrid car contains about 10 kg of REEs (Grasso, 2012; Radhika et al., 2011).REEs are usually categorized into light (LREE) and heavy (HREE). LREEs consist of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pr), samarium (Sm), europium (Eu), gadolinium (Gd) and scandium (Sc), while HREEs consist of terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and yttrium (Y). About 200 minerals contain traces of REEs, but only three are considered economically significant: bastnasite, with the formula La,Ce(CO3)F; monazite, with the formula(Ce,La,Nd,Th)PO4; and xenotime, with the formulaYPO4 (Jordens, Cheng and Waters, 2013)."

Jan 1, 2016

By Adam Levy, Thomas Novak, Sampurna Arya, Joseph Sottile, Kozo Saito

The use of a woven wire-mesh screen as part of a flooded-bed dust-scrubbing system is popular in the underground coal mining industry. It is used in combination with a demister (mist eliminator) to remove dust from the dust-laden air. A study was conducted to measure the pressure drop across a flooded-bed, wire-mesh screen at different airflow rates in one-phase (dry) and two-phase (wet) conditions. Two empirical relationships between pressure drop and air velocity were developed for dry and wet conditions, respectively. In both cases, the form of the empirical relationships was found to be similar to relationships given by Sabri Ergun for high velocity, non-Darcy, single- and multi-phase flow through porous media. The experiments were repeated on a reduced-scale model of the wire-mesh screen, and the pressure-velocity relationships obtained from the full-scale prototype experiments were tested. The test results show validation of the full-scale empirical formulae on the small-scale model with an insignificant variation. This paper presents the empirical equations for pressure drop across the wire-mesh screen in dry and wet conditions. Researchers can use these equations as a tool to predict total pressure drops for wire-mesh screens of different scale sizes.

By Ali Behrad Vakylabad, Esmaeel Darezereshki, Babak Koohestani

As a by-product of the steelmaking industry rich in iron and zinc, electric arc furnace dust (EAFD) landfill disposal is restricted in many countries due to the metal lixiviation risks. Several approaches have been examined to recycle or reuse EAFD. Hydrometallurgical methods mainly include the preparation of pregnant acid leached solution (PLS) using inorganic acids followed by selective metal recovery using different methods. We herein proposed a hydrometallurgical process initiated by acid leaching and finalized by thermal treatment to produce nano-ZnO from EAFD. At the condition of this study, only 67% of zinc was leached by sulfuric acid from EAFD into PLS while 98% of surplus leached iron was removed through precipitation by sodium hydroxide. Additional purification of iron removed PLS was accomplished using di-2 ethylhexyl phosphoric acid to extract Zn+2. The addition of ammonium hydroxide to purified PLS provided (Zn(OH)2)3(ZnSO4)(H2O)5 as the final precursor for nano-ZnO that ultimately transformed to nano-ZnO (60 ± 6 nm particle size) at 850 °C. The achieved results were scrutinized through various tests and analyses including TEM, XRD, SEM, EDS, FTIR, and TGA.

Mar 10, 2021

By Richard E. Gray

Virtually all structures show some signs of distress due to deterioration of the building components, to changed loads, or to changed support conditions. Changed support conditions result from ground movements. In mining regions many cases of structural distress are attributed to mining without considering alternative causes. This is particularly true of coal mining since it occurs under extensive areas. Coal mining is estimated to have already undermined more than eight million acres and may eventually undermine 40 million acres in the United States (HRB Singer, Inc., 1977). Other nonmetal and metal underground mines impact much smaller areas. Although it is sometimes difficult, even with careful study, to identify the actual cause of damage, persons responsible for underground coal mining should at least be aware of possible causes of building stress other than mine subsidence. This paper presents information on distress to structures and briefly reviews a number of causes of ground movements other than subsidence: Mass movements, dissolution, erosion, frost action, shrinking and swelling, yield into excavations and compressibility

Jan 1, 1986

By B. W. Cavender

Capital investments are made for a variety of purposes, from providing incremental capacity at existing operations to developing and implementing new technologies intended to radically improve a company's capabilities. These projects generate very different business opportunities and create value in distinctive ways. For incremental improvements, the capital budgeting process assures at least a loose fit between short-term goals and readily available resources. However, the criteria used to evaluate capital projects often prevent a company from committing to more aggressive goals that lie beyond the firm's current abilities or resources. Such projects may not have clearly identifiable future cash flows, and the degree of interaction with other projects and the nature of the risk incurred may be difficult to estimate. Additionally, by focusing only on quantifiable benefits, the budgeting process often fails to recognize "soft" improvements such as increased operating flexibility or new knowledge generated by such projects. By rejecting these projects, the capital budgeting process may actually harm the company's future competitive position.

Jan 1, 1998

By Virginia T. McLemore, Devlon R. Shaver

Clinkers are the result of a seam of coal catching fire and burning the surrounding rocks. The fires caused the surrounding rocks to be baked at high temperatures, removing organic material and partially forming glass. These rocks become hard, orange, and brick like, forming clinker. The purpose of the study is to determine their potential to contain economic levels of critical minerals, including Rare Earth Elements. Some clinkers contain over 200 ppm total REE.

Feb 1, 2024

By Charles R. Boardman

Recent underground nuclear tests in tuff, alluvium, salt, and granite have yielded data essential to the evaluation of mining applications of contained nuclear detonations. The data indicate that for these media the cavity radius is predictable within ±20% without regard to the properties of the rock in the immediate shot environment. Properties of the chimney of broken rock resulting from collapse of the cavity, on the other hand, are found to be related to the properties of the rock and its preshot structural weaknesses. Seismic effects and radioactivity distribution are sufficiently documented to serve as a basis for predicting the safety conditions associated with detonations for a variety of yields.

Jan 1, 1964

By C. RAMADINI, F. NURJAMAN, A. SHOFI, B. SUHARNO

In this work, the selective reduction of lateritic nickel ore was carried out using sodium sulfate, sodium carbonate, and sodium chloride as additives. The 5 wt% of anthracite coal, which contains 60.35% of fixed carbon and 1.9% of sulfur, was used as a reductant. All raw materials were mixed homogenously prior to the pelletization process into 10–15 mm of diameter. The reduction process was carried out to 50 g of pellets at 950 °C, 1050 °C, and 1150 °C for 60 min in a muffle furnace at atmospheric pressure. It continued with a wet magnetic separation process to separate ferronickel (concentrates) and impurities (tailings). Iron and nickel grade analysis was performed using XRF, while phase transformation and microstructure were analyzed with XRD and SEM–EDS. The results showed that the sodium sulfate was superior, resulting in the highest nickel grade in concentrate, i.e., 15.06%. The sulfidation mechanism, which could inhibit the metallization of iron, effectively increased the nickel grade in concentrate than decomposition of carbonate and chloridization process. The sulfur content in the reductant also influenced the selective reduction process. It promotes more sulfidation of iron, thus increasing the nickel grade in concentrate.

Jul 7, 2021

By Roy H. Paddon

This paper describes the 6, 000 tpd, three stage haulage system at the Ozark Lead Company's mine in southeastern Missouri. It details the methods and problems pertinent to the loading, hauling, sorting, crushing, storing and hoisting of waste rock and ores obtained from underground development headings and production areas. The Ozark Lead Company is a wholly owned subsidiary of the Kennecott Copper Corporation. Its mine is located nine miles south of Bunker in Reynolds County at the south end of the "New Lead Belt" mining district. Development started in May, 1964, by drilling a seven foot diameter (six foot cased), 1, 250 foot development-ventilation shaft. Drifting began in August, 1965, to obtain a bulk ore sample, to test ore continuity, and to drive two mine levels while the pre-grouted production shaft was being sunk. Over 7, 900 feet of 12 by 24 foot drifting was done from this small shaft. In March, 1966, a 20 foot diameter, three compartment, concrete lined production shaft was collared. It intersected existing development headings at a depth of 1, 195 feet in April, 1967, and was completed along with a concentrator and other facilities in June, 1968. Mine production began that month, with 5, 000 tpd reached in 1970.\

Jan 1, 1971

"One of the major issues that the Rare Earth Elements Mining Industry has to deal with is the legislation vacuum that exists in many countries around the world. Among these, are countries which have long history and tradition in mining. In many cases the lack of direct legislation for REE mine management as well as for other potentially polluting industries can be a barrier to sustainable development. Moreover, the case of lax legislation in China has led to environmental pollution problems and extended smuggling of rare earth elements. This paper looks into the current regulatory status on the mining of REEs, identifies the loopholes and suggests some elements for a new global legislation framework for sustainable development in the REE mining industry. The setting of this regulatory framework will be in line with the present and future challenges of the rare earths market as well as with the policy strategies that are defined internationally. The aim of such a legislative framework will be to strengthen the global rare earth elements supply chain, appease social concerns and ensure the preservation and conservation of the environment. INTRODUCTION The general public received their first introduction to rare earth elements (REEs) in 2010, when the previously inconspicuous commodities became the subjects of front-page headlines. It was when China created a furore in global high-tech markets after imposing an embargo on Japan following a minor marine dispute (Barakos et al. 2015b). Soon enough the Chinese embargo was extended on REE export restrictions all over the world and thus aroused concerns to many countries over potential supply disruptions. The world had suddenly realized that these wonder materials underpin products that they care about. Governmental and industry executives, policymakers and material scientists voiced concerns and conducted numerous reports stating the situation and the risks of a supply crisis. The price spike of 2011 intensified the crisis and the public turmoil, yet the drama did not last for long as the prices declined significantly in 2012. Nevertheless, the world was nonplussed by the fact that China has the total control of the market with more or less the 90% of the global production. More potential entrants became interested, thus initiating an exploration boom during the recent years that has resulted in a significant increase in known global REE reserves that could have potentials for exploitation."

Jan 1, 2016

By Edward C. Dowling

Froth flotation has been used industrially for many years to separate valuable minerals from their associated gangue constituents. Notwithstanding the significance of this process to the mineral industry, many of the engineering tools needed for the evaluation of the flotation process are still in a developmental stage. Traditionally, the evaluation of a flotation test on both the laboratory and industrial scale has been based largely on a rougher recovery value achieved at a sufficiently long time to give a "final" or "equilibrium" recovery value. The assumption of a time equivalency for a given recovery value between various flotation tests or between laboratory tests and industrial operation underlies this method of evaluation. Such an assumption implies that flotation is an "equilibrium engineering process" and that the time-rate recovery of material from the flotation cell is not affected by changes in the flotation system. It has been shown by Bushell (1) and by Klimpel (2) that the assumption of time equivalency between various flotation tests is unjustified. Consequently, better tools are needed for evaluating flotation test results, Because mathematical flotation models which incorporate both a recovery and a rate function can completely describe flotation time-recovery profiles, they can provide an excellent tool to evaluate flotation tests.

Jan 1, 1984

In this paper, the logic and the capabilities of a long term production planning method for open pit mining are presented. The method is the first attempt in obtaining simultaneous solutions to the four interrelated parameters of open pit mining; 1) the mine life, 2) the specific blocks to be mined each year, 3) the amount of ore and waste to be mined each year, and 4) the ultimate pit limits. An efficient cutoff grade can also be obtained through a sensitivity analysis. None of the existing methods can bring such a comprehensive solution to the problem. A production plan for a real life gold deposit is given to illustrate the logic and the capabilities of the method.

Jan 1, 1993

By S. S. Klima, H. Jiang, T. W. Beck, Y. Zheng

Researchers at NIOSH’s Pittsburgh Mining Research Division (PMRD) performed comparative testing of six different water sprays at pressures ranging from 689 kPa (100 psi) to 6,895 kPa (1,000 psi) in a 14.5-m3 (512-ft3) confined dust chamber. Testing was conducted to determine the effect of various pressures on each spray’s respirable coal dust knockdown ability. It is known that higher water pressures are typically preferred for lowering airborne dust concentrations, but it was important to determine at what pressure range the dust knockdown ability of each spray plateaus or reaches its minimum dust concentration. Results from this testing showed that several sprays saw up to 100% decrease in dust concentrations during the five-minute water spray testing period, with some occurring well below the maximum 6,895 kPa (1,000 psi) spray pressure.

Feb 1, 2023

By Christina Dahnér, Kristina Jonsson, Savka Dineva

The iron-ore underground Kiirunavaara mine (Sweden) has been seismically active since 2008. In 2021 the production is on levels 1079 and 1108 m, at the deepest. The seismic activity has changed in character over time with one step change in 2015 when the number of large (ML>2) seismic events increased, and another one when the mine experienced a seismic event with Mw 4.2 in 2020. In 2017, the mine evaluated Hydraulic Fracturing (HF) as a possible mitigation technique for larger seismic events and a one-hole trial was performed. The trial proved promising, and it was decided to go forward with a large-scale trial covering an entire production area in the mine. The large-scale trial consists of 25 fracturing holes, 50 – 100 m long, running along 500 m out of the ~4500 m long orebody and spanning between production levels 1108 m and 1252 m. The fracturing process continued for a year, resulting in ~38,000 seismic events with −3.3<ML<1.4. The breakdown pressure varied between fractures in the same hole as well as between holes in the same area. Average breakdown pressure per hole was between 12 MPa and 50 MPa. The seismic response to HF in 2021 varied greatly from hole to hole and between fractures in the same hole. The variation in response could be related to the geological conditions and the infrastructure, such as large caving ore passes. In this paper some details about the experiments and broad preliminary analysis of the effect of the HF by using seismic source parameters of the induced seismic events are presented: 1) Distribution of seismic activity, 2) the ‘equivalent’ magnitudes for each hole calculated from the cumulative seismic energy and seismic potency released during the fracturing, compared with the local geological conditions; 3) the predominant failure mechanism of the seismic events caused by HF was defined. A difference in the behaviour between larger and smaller events was noticed, as ML>0 events seem to be compression type failures and ML<0 events seem to be related to slip on pre-existing structures. No seismic events related to creation of a new fracture have been identified yet.

Apr 26, 2022

By G. S. Austin

New Mexico produced 83% of domestic potash and 27% of domestic consumption in 1992. The potash industry of New Mexico produces sylvite (KCI), langbeinite (K2SO4-2Mg(SO4)2), and artificial K2SO4. Average sylvite grade in New Mexico today is about 14%. The average grade of langbeinite is 8-10% Kp. Commercial potash occurs in the middle or McNutt Member of the Salado Formation (Upper Permian Ochoan Series). The 120-m-thick McNutt Member dips about 1° east and contains 11 of 12 potential ore zones in the Salado. The mineralogy and proportion of clay minerals, up to 7% of the ore, influence optimum milling procedures and ore grade cutoff.

Jan 1, 1994

By Peter C. Badgley

Three tectonic provinces within the Cordilleran System, are analyzed in terms of tectonic framework. (1) Precambrian terrain of North-Central Colorado; (2) The Pacific Northwest; and (3) The San Andreas-Garlock fault system and associated features. In each case a close relation- ship is seen to exist between: (I) Arcuate mountain development; (2) Precambrian basement fabric; (3) Major fault patterns; and (4) Major mineral occurrences. The arcuate trends developed when the basement was still mobile. Later competent deformation rejuvenated pre-existing lines of weakness. Because of the pre-existing arcuate framework, the rejuvenated faults frequently act as conjugate shears (strike-slip faults) flanking the old arcs. The conjugate shears intersect to form wedge- shaped plates. When such plates move forward along boundary strike-slip faults in response to post basement orogenic forces, new secondary fracture systems are generated in the country rock flanking the advancing wedge. The apex regions of the wedges are particularly favorable for detailed exploration.

Jan 1, 1959