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YEAR 1943-1944 Vol. 44 Page A major change-over in the ventilation of a deep level mine, by F. G. Hill and E. C. Ranson, 27; Discussion 56, 62, 67, 71, 72, 79, 123, 129 131 A note on the quarrying of surface limestone in the Sinai Desert, by V. L. Bosazza.. .. 59 Mining with diamond drills at the Nkana Mine of the Rhokana Corporation, Limited, Northern Rhodesia, by W. A. Odgers and A. G. Stirling, 95; Discussion 117, 121, 122 123 On silicates and dusts from the Witwatersrand gold mines (some preliminary notes), by J. J. Frankel, 169; Discussion .. 178 Presidential Address-Review of the rock pressure problem, by C. Biccard Jeppe, 3; Discussion 11,15 17 The chemistry, production and application of plastics, by P. N. Lategan, 138; Discussion 151 153 YEAR 1944-1945 Vol. 45 Page A microtechnique for the size-grading of mine dust, by S. R. Rabson, 34; Discussion 49, 50, 52 55 Activated carbon for regenerating used lubricating oil, by F. J. Tromp and J. J. Matthee 90 A contribution to the study of the production of zeolites, by C. C. le Grange and A. J. Petrick 235 A laboratory method for the determination of the suitability of South African coal and coal blends for the manufacture of metallurgical coke, by R. F. J. Teichmann .. .. 202 Copper containing cements for self-sanitising surfaces, by R. S. Young and H. L. Talbot 156 Notes on some sulphide minerals from the Far East Rand, by E. Mendelssohn, 84; Discussion, 88 89 Presidential Address-A review of underground support on the Witwatersrand with its Bearing on the Problem of ultradeep mining, by P. J. Louis Bok, 3; Discussion, 24, 25 27 Scientific management with particular application to a Witwatersrand gold mine, by J. S. Ford, 63; Discussion, 77, 80, 82 83 Some aspects of rock-drilling practice (the Witwatersrand gold field), by C. J. Irving, 163; Discussion, 185, 190 *197 Temperature measurements in a mine on the Witwatersrand with an electrical resistance thermometer, by O. Weiss, 127; Discussion, 136 137 The measurement of the geo-thermic gradient by means of the clinical thermometer, by R. A. H. Flugge-de Smidt, 105; Discussion, 136 137 The micro-chemical determination of free and combined silica in mine dust, by S. R. Rabson, 43; Discussion, 49, 50, 52 55 The oxidation of pyrites associated with South African coals, by R. F. J. Teichmann 141 YEAR 1945-1946 Vol. 46 Page Air cooling plant, No. 4 Shaft, City Deep, Limited. A review of layout and results achieved, by H. W. Unwin, A. Malcolm and R. E. Campbell Pitt, 66; Discussion, 100, 102, 103, 106, 110 115 A preliminary note on the Waterberg coal field as a possible source of coking coal, by P. E. Hall 124

By R. C. W. Webber-Youngman

The mining industry in South Africa faces real challenges with regard to the reduction of safety-related incidents. The purpose of this paper is to highlight the need for alternative interventions in addition to other safety improvement strategies already employed on mines. It furthermore supports an existing paradigm: incident investigations. An investigation into fatalities in the South African mining industry shows that although great progress has been achieved through the reduction in fatalities in all sectors of the industry over the last few years, more can and should be done to achieve status of ?zero harm?. Fatalities and lost time injuries on mines result not only in large financial losses, but also in disruptions of mining operations in general through Section 54 stoppages to resolve the situation. The approach of the paper is therefore not to try and prove whether there is high fatality rate and/or lost time injuries, but in what way incident reconstruction simulations (IRS) can have an impact in the future prevention of such incidents. The challenge therefore lies in the utilization of pro-active systems that would show employees the possible outcomes of being exposed to certain hazards. In real life, these incidents cannot be re-enacted and in most cases we can only learn through the previous mistakes of others. A virtual reality (VR) education and training system will enable employees to be ?exposed? to different hazards in a safe environment, and simulation, in a ?forgiving? environment, of the possible consequences of unsafe acts. According to the Occupational Safety and Health Act (OSHA), unsafe acts and unsafe conditions are indirect causes of safety-related incidents, but there are also direct causes; for example, unplanned release of energy and/or hazardous material, and basic causes, for example, management safety policies, personal factors, and environmental factors. The administrative workload associated with any incident investigation places a large burden on the investigation team, and in most cases other employees are informed through vague administrative processes what the ?real cause? for the incident/accident was. New preventative strategies are often put in place without showing the employees what the real causes of the incident/accident were. This can be mitigated through the use of interactive VR simulations/animations of the hazards that they are exposed to and how to deal with them. If VR interventions are not used as proposed by this paper, the real causes and consequences of almost all fatalities and lost time injuries may never be fully understood. This paper also emphasizes what potential impact IRS could have on the prevention of future mine incidents as part and parcel of a pro-active risk prevention strategy. The intention is therefore not to replace any other risk prevention strategies, but to visually enhance the reality of the incident. Keywords virtual reality, risk management, incident reconstruction simulations, interactive safety training, usability context analysis, mine safety.

Jun 1, 2013

By R. G. B. Pickering

Successful management of mining operations depend on the accurate and reliable measurement of performance as a monitoring instrument in a feedback and control loop. However, when changes are being considered, the probable effect of the change on bottom line results requires different measuring techniques incorporating an in depth understanding which can identify hot spots in the operation which exhibit strong sensitivity to change. The CSIR's Division of Mining Technology has therefore been devoting a considerable effort to the establishment of techniques which enable changes to be analysed in terms of their impact on the two key parameters describing mine performance, i.e. profitability and safety. This paper describes these techniques, outlines their application to some example situations and discusses planned enhancements. The first section of the paper addresses the profitability model, and this is followed by a section considering the mine safety model.

Jan 1, 1996

By J. H. Viljoen, J. F. Morrison, C. H. Wyndham

SYNOPSIS Heart rates, oral temperatures, shovels/min and number of 3/4 ton cars/hour trammed over distances of up to 350 ft were measured in samples of 6-10 miners, engaged in tram-shovelling, at 76°, 84°, 86°, and 89°F wet bulb temperatures in stopes in a mine. From the results it has been concluded that a man with an 'average' maximum oxygen intake capacity of about 2. 8 litres/min should be able to work: at 6 shovels/min, or 30 cars/shift per two men, at 76°-84°F; at 5 shovels/min, or 27 cars/shift per two men, at 86°F; and at 4 shovels/min, or 24 cars/shift per two men, at 89°F wet bulb air temperatures. INTRODUCTION A number of gold mines in South Africa still use tram-shovelling extensively. In this method of rock removal from the face of the stope, Bantu mine workers load rock into cars and tram the cars to a centre gulley where they are emptied. Previous studies from this Laboratory3 have shown that tram-shovelling is one of the most arduous tasks underground. The rate of energy expenditure is relatively high, being an oxygen consumption of about 1.4 litres/min over a period of some hours. In cool air conditions the upper limit to the rate of production of the well-motivated men employed on tram-shovelling has been shown1 to depend upon their capacities for physical work of an endurance nature (as measured by their maximum oxygen intakes). However, in hot conditions the factors which set the upper limit to the rate of production are different. They are primarily the ability of the body to maintain a heat balance between the rate of heat production, due to physical work, and the hot atmosphere, so that the men do not develop excessively high body temperatures8. In order to give mine managers guidance on the 'optimum' rate of production of Bantu mine workers engaged upon tram-shovelling under different temperature conditions underground a study was carried out in a mine. The number of shovels per minute and cars per hour were recorded and heart rates and oral temperatures were measured throughout the duration of the shift on samples of 6-10 Bantu mine workers in different air conditions. The results of the study are recorded in this paper and conclusions are drawn as to the number of shovels per minute and cars per hour which Bantu mine workers of 'average' maximum oxygen intake capacity should be able to produce at wet bulb air temperatures of between 76° and 89°F without either excessive fatigue or danger of heat illness.

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

By G. Sahasrabudh, G. DeIulii, K. P. Galvin

A novel agglomeration process has been developed, utilising a concentrated water in oil emulsion as a binder. The binder is typically 95 wt% water, the remainder being an organic phase containing kerosene and the emulsifier— sorbitan mono oleate (SMO) in equal mass portions. The binder can selectively agglomerate hydrophobic particles in less than 7 seconds. The agglomeration has proven to be highly effective in recovering any particle of virtually any size, provided the particle is hydrophobic. The approach has previously been applied to coal, magnetite and silica. In the paper, sodium isobutyl xanthate (SIBX) and its much longer chain version, potassium tetradecyl xanthate (C14X), were used separately as collectors to selectively agglomerate chalcopyrite from the ore. Xanthates attach to metal sulphides, thus hydrophobising sulphide mineral particles. Chalcopyrite is a sulphide mineral; however, it hydrolyses quickly in the presence of water. Ethylenediaminetetraacetic acid (EDTA) was used to remove the oxide layer formed at the surface of the mineral particles after wet grinding, leaving behind a freshly generated metal sulphide surface. After the EDTA treatment, the ore particles were quickly conditioned at an optimised pH as well as collector concentration and agglomerated. The agglomeration achieved a copper recovery of 75% within 7 seconds, consistent with the recovery achieved by flotation over much longer time scales. Keywords: Chalcopyrite, agglomeration, froth flotation, interfacial chemistry, X-ray fluorescence, selective hydrophobisation

Jan 1, 2020

By J. Stacey

There are four components to this guideline 1. Guidance on the socio-economic aspects of closure policy 2. Socio-economic closure activities mapped against the mining project life-cycle (a ?check status? tool) 3. A process guide for mine closure planning and implementation 4. Tools in support of mine closure planning and implementation How to use this guideline The four components are part of a hierarchy with: ?Overarching policy as the starting point ?The mine life cycle model as a quick process check tool ?The process guide for detailed practical planning and implementation as practical guidance ?Supportive tools as resources to address specific planning and implementation steps.

Jan 1, 2010

By J. K. Williams, M. P. Wells

"As part of the planning system at each division of Nchanga Consolidated Copper Mines, Limited, the Mine Planning Department is required to produce a detailed production schedule for each shaft.Because of the difficulties in producing a schedule which satisfies all the mining constraints, and because of the large clerical effort involved, the full range of possible schedules can never be considered.It has been found possible to produce a schedule using linear programming which satisfies the majority of the many varied mining constraints. Computer programs have been written to enable the mine planning department to use this mathematical system without assistance.The system has a large degree of flexibility to enable the planner to include conditions which cannot be incorporated readily in the linear program. This system permits the more efficient production and evaluation of schedules and reduces the amount of clerical effort."

Jan 1, 2014

By G. T. G. Emere

With the assistance and encouragement of Mr B.C. Alberts, the Institute's immediate Past President and Iscor's Senior General Manager: Mining, the Committee of the Johannesburg Branch recently organized a two day excursion for members to the northern Transvaal. The itinerary included visits to the Grootegeluk colliery, the Matimba power-generation utility, and the Thabazimbi iron-ore mine.

Jan 1, 1989

By A. F. Lee

Dr E. C. Hanekom (Visitor): Two years ago we used the bubble pick-up technique as developed at Anglo American Corporation for screening candidate flotation agents prepared in our laboratories. It was obviously necessary to know to what extent the technique gave reproducible results and a statistical evaluation of the test method was made using a mineral sample provided by Anglo American Corporation. A bubble of 2.0 mm diameter was used and the measuring graticule was divided into squares (units) with sides of 5.0 mm at 25 X magnification. The mineral granules had diameters from 53 to 74 mm. The bubble was loaded by depressing it against a layer of mineral grains to give an arbitrary but constant compression of 0.4-0.5 mm. It was rolled five times through 2 mm horizontal displacement. The bubble was then lifted, its load compacted by gently stirring and the projected area measured in squares (units) on the grid. Each substance was tested at 5 ppm concentration in distilled water at five points in the pH range 3-6. With these standardized conditions of operation the reproducibility of the test was studied. Four materials were tested and at each pH value the procedure of forming a bubble, picking up granules and counting the units was repeated ten times. From these results the standard deviation for a single count at any pH value was calculated for each material (Table 1. The coefficient of variation of approximately 3 per cent was relatively low and it was decided that further refinements in the counting procedure would be of doubtful benefit with the present apparatus. Similar experiments were carried out with 12 sample materials. In this case the bubble formation and pick-up were repeated four times at each pH value, the mean value was calculated for each set of four observations and final pick-up values for the materials were obtained by selecting the highest mean count. Each test was completely repeated a number of times as indicated in Table 2 and the standard deviation calculated. The results allowed the selection of the more promising materials and the rejection of poor performers at the 95 per cent confidence level. All tests were carried out by one operator. Some evidence was obtained that the method is sensitive to operator bias. In conclusion it can be said that from all the results analyzed it would appear that once operation conditions are fixed (viz operator, pH control) the precision of the method is adequate. The author wishes to thank Messrs African Explosives and Chemical Industries Limited for permission to publish these data. G. S. Stander and C. J. Kooij (Visitors): We must congratulate Mr Lee for this most interesting and useful development of the pick-up experimental method. It certainly provides research workers with an instrument which makes flotation more of a science and less of an art. We visited Mr Lee at his laboratory where he gave us a demonstration of the bubble pick-up instrument and technique as developed and improved by him.

Jan 12, 1969

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N'-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014

Ninth International Symposium TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of 14th to 19th June, 1970, follows the Computer Symposium held in Salt Lake City in September, 1969. The purpose of the Symposium is to define the role of decision-making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-have permitted us to structure it in such a way that a complete picture of the mineral industry in its public policy, corporate, financial and technological environment emerges. Topics for the sessions are: . The Public Policy Environment;. The role of Decision Making Techniques in the Mining Company; . Information Storage and Retrieval; . Markets-Forecasting, Patterns and Strategies;. Search for Mineral Deposits;. Quantification of Geological Variables;. The Mine Development Decision; Production Systems;. Planning, Scheduling and Control Systems. The sessions will be directed energetically by chairmen who have been in continuous contact with the authors, providing them with information about related papers and sessions. This symposium is sponsored by the Canadian Institute of Mining and Metallurgy, McGill University and Ecole Polytechnique. Further information may be obtained from: The 9th International Symposium. W. H. Gauvin, General Chairman, J. Elbrond, Programme Chairman. Department of Mining Engineering, Ecole Poly technique, P.O. Box 501, Snowdon, Montreal 248, Quebec, Canada. ACHEMA 1970 The European meeting of Chemical Engineering and the Achema Congress 1970 is being held at Frankfurt/Maine, from 17th to 24th June, 1970. The programme includes some 110 plenary and specialised lectures, numerous technical films, excursions, and technical discussions in front of the exhibits which form the central feature of the Achema-Exhibition Congress. Further information may be obtained from the honorary representative of Achema in South Africa, Mr F. Schilling, P.O. Box 31274, Braamfontein, Johannesburg. NINTH COMMONWEALTH CONGRESS PROCEEDINGS Publication of the proceedings of the Ninth Commonwealth Mining and Metallurgical Congress, 1969, is being undertaken by the Institution of Mining and Metallurgy, London. There will be four volumes covering papers presented at the Congress together with the discussion and author's replies, and the addresses by Sir Duncan and Sir Ronald Prain. These will be available April-June 1970. Special pre-publication prices apply to orders received before 1st April, 1970. Order forms may be obtained from Secretary S.A.I.M.M., P.O. Box 1183, Johannesburg. 6th World Congress on the Prevention of Occupational Risks This Congress, dealing with industrial accidents and occupational diseases, will be held in Vienna from 10th to 15th May, 1971. Further information may be obtained from: VI Weltkongress für Unfallverhütung, Postfach 745, A-1015 Wien, ÖSTERREICH. International Vacuum Metallurgy Conference 1970 The Vacuum Metallurgy Division of the American Vacuum Society is organizing an international meeting that will be held at the Convention Center in Aanaheim, California from 15th to 19th June, 1970. Enquiries should be directed to the Arrangement's Chairman, L. M. Bianchi, TRW Inc., 23555 Euclid Avenue, Cleveland, Ohio 44117, Tel. No. (216) 383-2111. AIME WORLD LEAD-ZINC SYMPOSIUM This symposium is being held from 21st to 23rd October, 1970, in St. Louis, Missouri, U.S.A., in conjunction with the Fall Meeting of the Society of Mining Engineers, and a Rapid Excavation Conference. In addition to local field trips to smelter and refinery operations there will be a number of extended trips of six to eight days. Information may be obtained from: Mr. John C. Fox, Secretary, Society of Mining Engineers of AI.M.E., 354 East 47th Street, New York, N.Y. 10017, U.S.A. NEW SUBSCRIPTION RATE TO THE JOURNAL As from 1st JANUARY, 1970, the subscription rate for the Journal has been increased from R12.00 to R18.00 per annum, i.e. R1.50 per issue instead of R1.00. The discount to booksellers is 15 per cent. COURSEOF THE THEORYOF THE UNIT OPERATION OF GRINDING The South African Institute of Chemical Engineers is arranging for Prof. L. G. Austen to conduct a course on the above subject in September, 1970. Interested persons should contact Dr G. S. Harrison, S.A. Institution of Chemical Engineers, A.E. & C.I., 15 Anderson Street, Johannesburg. METRICATION The S.A. Bureau of Standards has published a document entitled "Metric Scales and Units for use in the Building and Construction Industry." It has been compiled by the Metrication Committee of the National Building and Construction Advisory Council and is the first of the series of informatory documents relating to the programme for the metrication of the Building Act Construction Industry. This document is obtainable from the South African Bureau of Standards, Private Bag 191, Pretoria at 50c per copy.

By L. von Ketelhodt

Dual energy X-ray transmission (DE-XRT) sorting is a recent development in the range of sensor-based sorting technologies available today. DE-XRT is particularly suitable for dry coarse coal beneficiation in the size range -120 mm +12 mm. In this paper, we describe the technology and show the results of a number of test runs conducted on different types of coal from the USA and South Africa. The results have shown that DE-XRT is an effective technology not only for deshaling of coal and removing pyritic sulphur but also for separating coal and torbanite. The use of dry deshaling methods will be more important as water availability becomes a greater concern. DE-XRT is one such technology which will be incorporated in future dry coal processing plants.

Jan 1, 2010

By D. Visser

This paper is based on the Townlands Ore Replacement Project whereby the concept of conventional sinking of one large diameter shaft was declined and replaced with three smaller raise bored shafts. A wire line geophysical survey was done and the results indicated that a single shaft larger then 4 m diameter unsupported would not be suitable. The shafts were placed 28 meters apart measured from centre to centre. To ensure that the skin to skin pillars between the shafts remained regular and to minimise any deflection, the pilot holes were drilled with the Rotary Vertical Drilling System. The different shaft sinking methodologies are discussed explaining the risk associated with each method.

Jan 1, 2009

By D. Visser

This paper is based on the Townlands Ore Replacement Project whereby the concept of conventional sinking of one large diameter shaft was declined and replaced with three smaller raise bored shafts. A wire line geophysical survey was done and the results indicated that a single shaft larger then 4 m diameter unsupported would not be suitable. The shafts were placed 28 meters apart measured from centre to centre. To ensure that the skin to skin pillars between the shafts remained regular and to minimise any deflection, the pilot holes were drilled with the Rotary Vertical Drilling System. The different shaft sinking methodologies are discussed explaining the risk associated with each method.

Jan 1, 2009

By E Matinde, M. Mnisi, I. C. Thobadi, W. Clark, J. D. Steenkamp

Pyrometallurgical smelters utilise tap-holes, through which liquid metal, matte and/or slag are tapped at regular intervals. However, tap-hole failures can have a devastating impact on smelters, which includes loss of equipment, human life and business interruptions. Contributing factors to tap-hole failures include poor and/or incorrect refractory material selection, including tap-hole clays. The functions of tap-hole clays in smelters include their ability to be extruded and drilled with ease at the end and beginning of a tap, and their ability to resist chemical wear due to molten metal and slag during tapping. Mintek is currently developing methods of evaluating properties of tap-hole clays with a specific focus on workability, and wear mechanisms of clays due to ferrochrome alloy and slag. Of particular interest to this study was the characterisation of various tap-hole clays. This paper evaluates the chemical and phase chemical properties of three different tap-hole clays. The bulk chemical composition of the tap-hole clays was determined by inductively coupled plasma optical emission spectroscopy, proximate analyses and combustion methods. The bulk phase compositions and specific phase chemical compositions were studied using quantitative X-ray diffraction, scanning electron microscope and electron probe microanalyses techniques. Keywords: Tap-hole clay, chemical analyses, phase chemical analyses, ferrochrome

Jan 1, 2020

By M. H. Dehghanpoor, M. Zivdar, M. Torabi

"A hydrometallurgical route was developed to extract metals such as gold, silver, copper, and selenium from anode slime from Sarcheshmeh Copper Complex in Iran. For the extraction of copper by leaching, the anode slime was heated and stirred with 4 M sulphuric acid in the presence of oxygen. Optimal conditions for recovery of copper were temperature 80°C, mixing time 5 hours, and oxygen flow rate 2 L/min, resulting in a copper recovery of 94.47%. Silver and selenium were dissolved by leaching anode slime from which the copper had been removed with nitric acid. For gold extraction, anode slime was heated with aqua regia at 90°, and the gold then extracted with 2-ethyl-hexanol at a concentration of 0.5 M and phase ratio of 4. The extract was then stripped with soda solution at pH=10.5 and a phase ratio of 5. Finally, gold was recovered by precipitation with oxalic acid at a ratio of mass to volume 10 g/L. Total gold recovery was 80%. IntroductionDuring the electrorefining of copper, some metals are accumulated in the byproduct anode slime, which is an important source for recycling and recovery of these metals (Petkova, 1994). In this paper, a hydrometallurgical route is described for the recovery of precious metals from copper anode slime of Sarcheshmeh Copper Complex, which is located in southeastern Iran .Copper anode slime is black or gray powder with a particle size less than 200 mesh. Approximately 2 to 20 kg of anode slime is produced per ton of copper cathode. The slime is characterized by higher amount of Ag, Se, Pb, and Cu compared to other metals and a very low Au content (Khaleghi and Ghader, 2013).The copper anode slimes are composed of 11.69% selenium, 3.93% copper, 5.26% silver, 0.13% gold, and 45% barite, plus lead, tellurium, antimony, sulphur, and silica with small amounts of nickel, iron, zinc, and bismuth. Gold is one of the most important noble metals due to its wide applications in industry and economic importance, so recovery of gold from slime is more appealing than that of other metals. According to the World Gold Council (2013), the demand for gold has increased during the last decade. This increase is due not only to the increasing demands of the jewellery market, but also to the increasing demand for gold in industrial as well as medical applications (Ranjbar et al., 2014)."

Jan 1, 2016

By P. Hand

Most coal plants must run under conditions of varying feed conditions or are asked to produce qualities different from that used in the design. This can cause overloaded conditions as the ?bottlenecks? within the plant, depending on plant operation or as the feed changes. During plant design, geological information can be used to determine washability envelopes and blends that may be expected. Historical data can also be used to develop a size distribution envelope as well as to assign reasonable models for each of the unit processes. In operation, a plant can be sampled to determine changes and to refine process models. The information obtained can then be used in an accurate simulation to define how the plant can deal with the changing environment. This paper uses Limn: The Flowsheet Processor to simulate the coal plant in detail and will produce an accurate model, in terms of equipment sizing as well as water, medium, and solids balance, for each change in feed condition. It will show examples of running the simulation through complete density and size ranges and will determine the equipment required to address each part of the performance envelope.

Jan 1, 2010

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020