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By Elisabeth Schmidt

The conventional Canadian oil sand processing, the Clark Rowe process, is associated with many risks for the environment and high energy costs. To recover the bitumen from the oil sand (tar sand), large quantities of water have to be heated up and mixed with caustic soda and the oil sand. During this process, tailings with stabilized clay colloids are formed and dumped in tailings ponds. To avoid these disadvantages, a new, non-aqueous extraction process is to be established. Organic solvents are used instead of water and caustic soda to mobilize the bitumen from the sand-clay mixture. Pressure filtration, washing and steam pressure filtration are part of the new concept. A mixture of organic solvents and the oil sand is first pressure filtrated in a nutsch filter until a saturation level of one is obtained. After the cake has been formed, the filter cake is washed with organic solvent to flush the bitumen loaded solvent out of the cake. The following steam pressure filtration mechanically and thermally removes the remaining volatile components of the solvents from the filter cake. The filtrates from the pressure filtration, the washing phase and partly from steam pressure filtration are subsequently thermally treated to recover the organic solvents and obtain a higher bitumen concentration in the mixture. This mixture is then lead to an upgrader to win synthetic crude oil (SCO). The recovery of bitumen in the conventional hot water extraction process based on the Clark Rowe process can, in highly optimized plants, achieve between 88 and 92 %. Variation of oil sand properties leads to an actual range of between 80 and 90 % of bitumen recovery. With the alternative process based on organic solvents, the bitumen recovery exceeds the recovery of the conventional process by up to 16 percentage points. The composition of the two organic solvents in the first step of forming a suspension with the oil sand is important. The aromatic component is crucial for liberating and solving the asphaltenes, which tend to flocculate. The order of the two components of organic solvents is also important in the washing step. The paraffinic component is essential to achieve successful steam pressure filtration with respect to fast steam breakthrough and a filter cake free from organic compounds, as a result of its lower boiling point. Keywords: oil sand, filtration, organic solvents, pressure filtration, steam pressure filtration, filter cake washing

Sep 1, 2012

By U. A. Peuker

"Steam Pressure Filtration (SPF) is a modified cake filtration process and is characterized by both washing and excellent de-watering of the filter cake. Compared to conventional gas differential pressure filtration, the filter cake is treated with saturated or superheated steam replacing pressurized air. Invented in the early last century, Steam Pressure Filtration has reached technical maturity in the 1990ies for inorganic particle systems, fine chemicals and coal. Especially the de-watering performance for fine particles systems below 50 µm make Steam Pressure Filtration an excellent option for the processing of fine tailings streams, to produce a stable material, which can be described by the methods of solids mechanics instead of paste rheology. The washing, which is due to the condensing steam, is able to reduce the ion load of the solid. This additional effect is able to generate a dry tailings material, which shows a reduced leaching potential of mobile ions, which originally derive from the process water. INTRODUCTION Steam Pressure Filtration is a process concept especially of hyperbaric filtration, which started its market entry in the 1990ies (Bott 1996, Bott 2002). Even though there have been many attempts to apply steam on filters before, the success story began with the combination of hyperbaric filtration and steam application and the technical solution to limit the steam treatment to a defined zone on the filter. This resulted from the scientific findings that steam mainly enhances the de-watering during the mechanical filtration (Gerl 1999). There are no or minor positive effects of steam application to a filtration process during cake filtration and after the steam breakthrough has occurred. Furthermore that time a sufficient control technology to regulate the steam consumption as well as suitable filter cloths became available. There is a growing need for de-watering technology in the mining industry, not only for the concentrate but also for the tailings streams. Several reasons argue against the established solution of damping the tails as suspension or paste into tailings ponds. There are ecological, political, societal and economic reasons, which question the tailings ponds more and more. Due to the increasing costs in the building and monitoring of tailings dams, which contain the tailing ponds, the concept of dry stocking using filtration technology comes into the game (Jansson 2016). Dry stocking converts the tailings stream form the suspension or paste state, into a material, which can be stockpiled. The latter typically is a moist flowable disperse particle system. The conversion involves a de-watering step, in which different types of filter equipment can be used, e.g. filter presses, membrane filter presses, automatic press filters or hyperbaric filters. For coarse products also vacuum filter can be applied. Due to its excellent de-watering performance and the easy scale-up properties Steam Pressure Filtration is further option for dry tailings stacking."

Jan 1, 2018

By L. Y. Feng

The percentage of leached zinc in massive zinc oxide ores (11.7% Zn, >2 mm) is up to 73.3 % in 120 days. Alternatively, crushed to -0.154 mm, mixed with cement 5% (wt), pelletized and solidified. The diameters of the pellets obtained are between 5 mm to 8 mm. When the pellet solidification periods are 3 days, 10 days and 45 days respectively, the alkaline leaching rates of zinc in the pellets are up to 95.8%, 89.1% and 76.4% respectively. Decreasing the solidification time can re-duce reaction time, increase dissolution of zinc in pellets and lower the effect of initial zinc concentration on leaching rate. The experiment results show that the minimum solidification time is three days, and the kinetic study indicates that alkaline leaching of the low grade zinc oxide pellets is controlled by the diffusion of the leach liquor through the gangue layer in the whole leach process, and the apparent rate constants are 3.33×10-2 day-1, 9.18×10-3 day-1, 5.82×10-3 day-1 respectively.

Jan 1, 2014

By Xiaodong Jia, Williams. Richard A.

This paper describes the recent developments, arising from research at Leeds, in the computer modelling of packing of complex shaped particles and prediction of physical properties of the structures represented by the packing. The computer model DigiPac, is capable of packing particles of any shapes and sizes in a container of arbitrary geometry. The ability to predict packing structure of real particle shapes and to compute directly some structure-dependent physical properties (such as liquid permeability, mechanical strength/ stability, compaction and sintering, dissolution and leaching, etc.) is obviously highly desirable and has significant potential in industrial applications. Examples are presented relating to the packing of granular materials.

Jan 1, 2003

By M. R. Tavakoli Mohammadi

Novel solvent extraction technologies in recent decades have made attempts to show the problems in applying this method for dilute solutions and find appropriate solutions to overcome them. Improving the equipments performance used in this method for dilute solutions, cause development of usable resources and reduction of operational costs. Furthermore, appropriate conditions provide for using dilute solutions produced in various industries as a new source of valuable elements. Thus, this proposal can be a very good solution for treatment of these solutions and reduce the environmental impacts associated with them. The purpose of this study is to introduce a new method of Column Floto Extraction (CFE), which has been invented in this regard. In this method, using spargers similar to Jameson cell downcomer in floatation process, the organic phase bubble dispersion has been used instead of its drop dispersion in aqueous phase for the two-phase mixture operation. This operation mode has caused a higher extraction percentage of solute in high aqueous to organic ratios due to enhancement of contact area. In this study, in addition to explaining the advantages and features of this method, we have dealt with its design and performance mode.

Sep 1, 2012

By D. W. Feng

Thiosulfate as an alternative lixiviant for gold has received much attention in recent years due to the growing environmental concerns over the use of cyanide. Cu(II) is used to catalyze the oxidation of gold and ammonia is to stabilize Cu(II) in alkaline solution. However, the presence of Cu(II) enhances the oxidative degradation of thiosulfate. The high consumption of reagents has made thiosulfate leaching uneconomical to date, in comparison with cyanide leaching. Therefore, further investigations are required to leaching under low reagent concentrations over extended periods where reagent consumption is low and gold leaching rate is low as well. It is thus necessary to find additives to enhance gold dissolution in the thiosulfate leaching system. Electrochemical studies using rotating gold disc showed that the oxidation of gold in ammoniacal thiosulfate solution increased significantly in the presence of a small amount of thiourea and the beneficial effect increased with an increase in the thiourea concentration up to 7.2 mM. Thiourea improved gold extraction in the thiosulfate leaching of gold from a sulfide ore under low reagent concentrations. Excessive addition of thiourea inhibited the leaching of the gold ore. The decomposition of thiosulfate was reduced with the presence of thiourea. X-ray Photoelectron Spectroscopy (XPS) results indicated that thiou-rea likely decomposed to sulfide and formed gold sulfide species at the gold surface.

Jan 1, 2014

By H. Tiefel, M. Schneider, T. Neesse, J. Regler, J. Dueck, F. Donhauser

In practice the advantages of high-quality hydrocyclone separation are often reduced due to varying feed suspension properties, solids concentrations and particle size distributions. Control systems of large hydrocyclones are usually fitted with controllable underflow nozzles, which is not practical for small hydrocyclone batteries. Therefore, a new control system for a battery of hydrocyclones with a nominal diameter of 150 mm was invented at the LUR in cooperation with AKW Apparate und Verfahren GmbH & Co. KG. This process was developed for bentonite slurry regeneration associated with tunnel excavation using bentonite slurry as a transport aid and lubricant.

Jan 1, 2003

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

Results of flotation process combined with atmospheric leaching and high pressure leaching for recovery of copper from low-grade silicate-copper ore have been presented in this study. The low-grade copper ore contains a small amount of copper (0.42 mass %), iron (4.6 mass %), and silicon (38.3 mass%) and among many other metals (Al, Ca, K, Mg, Na, Ti and S). The main mineralogical constituents of the copper ore are calcium aluminosilicate (Ca(Al2Si2O8), amesite (Mg2Al2SiO5(OH)4) and gypsum (CaSO4×H2O), and quartz (SiO2) as resulted from the alteration of an igneous rock. This study has shown that about 92 % of copper can be recovered with a maximum copper grade of 4.2 mass% in a froth after 15 minutes of flotation at pH 8.5 when used potassium amyl xanthate as a collector, MIBC and Dow-froth 250 as frothers and calcium hydroxide as a pH adjuster. The images of bubbles in the cell during flotation process were recorded using a high-speed camera. The froth concentrate with average copper grade of 2.0 mass% was further processed by atmospheric leaching with a solution of sulphuric acid and hydrochloric acid, respectively and high pressure leaching with sulphuric acid solution. As a result, leaching rate of copper reached about 60 % in an atmospheric leaching with sulphuric and hydrochloric acid respectively, whereas the rate can reach more than 70 % by autoclave leaching at high pressure under the controlled condition. A process to recover of copper from its low-grade ore can be developed by optimization of flotation combined with acid leaching.

Jan 1, 2014

By N. Nikolaeva, A. Romashev, T. Aleksandrova

Energetic characteristics identify energy consumption for destruction of prills and kinetic characteristics rate formation of finished size grade in the course of destruction and identify crushing and grinding equipment capacity. And if screen sizing or classification processes are applied in the cycle of ore preparation, then the use of characteristics of separation to size – separating characteristics – is required for theoretical description. Separating characteristics have a lower profile for ore preparation but, nevertheless, they have to be taken into account especially for balance and design calculations of crushing and grinding circuits. In most cases there are impregnations of minerals which vary widely in energy consumption and destruction kinetics and thus polyminerality must be considered as one of priority factor. Raw materials which passed through crushing and grinding processes can be assessed numerically by functions of fractional composition of two types: differential distribution function y ( €) and assay function B( c ) . A set of experiments on grinding of crushed raw materials at different time (up to various sizes) was conducted to analyze effect of grinding size of carbonaceous overburden on function y € and B ( c) as well as to justify the possibility of preconcentration of raw materials at the stage of ore preparation. Analysis of metals distribution per size grades showed that metals are concentrated in size grades of less than 0.315 mm (which is equivalent of cut point for this type of raw material), however, there is no overgrinding and oversludging of material, and enriched product for its further processing can be excluded with the help of classification. The stage of size segregation was tested as a method of preconcentration of raw materials for optimization of ore preparation and further separation.

Jan 1, 2018

The value creation with kaolin clays depends on removing the colored impurities which manifests in to higher brightnessone of the most sought after properties on applications such as paper coating, paint and others. The processes for removing impurities include magnetic separation, froth flotation and selective flocculation. While the flotation and selective flocculation processes exploit the physico-chemical differences between the surface properties, the magnetic separation uses the bulk magnetic susceptibility differences between the diamagnetic clay and ferro- and para-magnetic nature of the impurities. The major advantage with magnetic separation remains high yield and no or low reagent usage. However, the magnetic separation technology suffers from low separation efficacy when finer colored impurities (<1 µm) are encountered in the feed. Use of stronger magnetic intensities during magnetic separation showed limited success; nonetheless the adverse effect due to finer size range remains a dominant effect even at 5 Tesla magnetic field. Furthermore, the presence of diamagnetic colored impurities irrespective of their sizes can not be removed. Cytec Industries has recently developed a ?bolt-on? chemical enhancement technology for magnetic separation that essentially embraces the best product performance attributes of flotation and selective flocculation while keeping the chemical usage to a minimum level and using the readily available magnetic separation equipment. The paper will outline the technology and illustrate optimization work at pilot plant magnet on a wide variety of crude accommodating the process needs and plant limitations. The major advantages of chemical enhancement technology to magnetic separation include: 1) simple extension to existing magnetic separation technology, 2) ability to produce comparable product in quality with cost effectiveness compared to flotation and selective flocculation, 3) removal of impurity minerals over wide size range, 4) removing non-magnetic impurities, 5) providing robust process with high process yield and 6) operation-friendly nature. Furthermore, chemical enhancement technology for magnetic separation has also emerged as a platform for re-moving impurities at low levels in other mineral systems as well.

Jan 1, 2014

By T. Laxmi

This paper details the optimization of rougher Wet High Intensity Magnetic Separator (WHIMS) using response surface methodology. The optimization is in parametric form and takes account of the major operating variables in WHIMS operation such as current in ampere and grid gap, in inch. The objective is to recover ilmenite mineral from red sediment deposits of Srikakulam, India by optimizing the rougher WHIMS. We predict mineral recoveries as a function of current and grid gap. Combination of these predictions with assay data provides predictions of mineral grades and recoveries. The optimized response was validated against data derived from laboratory-scale rougher WHIMS test work, comprising (i) mineral grade, (ii) mineral recovery, and (iii) separation efficiency of the process. We observed close match between the experimental and the predicted data over most of the operational range. This paper describes how the optimization was carried out using the response surface methodology along with MATLAB. The response surface was used to closely investigate the separation of ilmenite mineral by varying ampere and grid gap. The results show that under optimum conditions, such as 3.5 amp current (0.53 Tesla) and 2 inch grid gap, the mineral grade could reach, as high as 87.9% in the concentrate with 74.3 % recovery and 74.4% yield. Keywords: red sediment, wet high intensity magnetic separator, optimization, ilmenite, placer heavy minerals

Sep 1, 2012

By Yuri Yemelianov, Stanislav Balikov, Alexander Epiforov, Andrey Boldyrev, Andrey Bogorodsky

"Test work was carried out using copper gold-bearing flotation concentrate with 6.85%Cu, 14.30%Fe, 20.70%S and 2.34%As. Gold and silver grade in the concentrate is 54.6 g/t and 92 g/t, respectively. Gold and copper are valuable components in the concentrate. Gold is partially associated with pyrite and fahlores. Copper in the concentrate can be found as tennantite (Cu12As4S13). The 71% of gold from the flotation concentrate is recoverable by cyanidation with simultaneous cyanide consumption in the amount of 96 kg/t. The major reason of refractoriness is that gold is fine encapsulated into sulfides and the presence of cyanicide-copper. The concentrate ground as much as 95% minus 10 µm was treated using low-temperature POX at the temperature of 100±5°C, L:S ratio of 5:1 and the process time of 1-5 hours. Residual sulfide sulfur in the cake is 2.28% which is 89% sulfide oxidation. The highest copper recovery to POX solution is 91%. It was found that gold recovery to cyanide solution is 85-94% during alkaline pre-treatment of POX cakes followed by cyanidation. In this case, cyanide and lime consumption is 75-90 kg/t and 120 kg/t, respectively. In order to recover precious metals from POX cakes leaching using sodium sulfite was carried out. Test work was conducted at varied reagent concentration, L:S ratio and leaching time. Gold and silver recovery achieved was 85-95% and 59-63%, respectively."

Jan 1, 2014

By Avinash Tripathi

It is now well known that the size distribution of the particulate solid has a significant effect on the breakage behavior of particles in the wet as well as dry modes of ball milling operation. In the context of the size discretized batch grinding kinetic model, grinding behavior of particles is characterized by the breakage rate parameters, k, and breakage distribution parameters, B. Understanding the nature of variation of these two sets of parameters with particle size distribution is important for simulation and control of operation of production mills. However, so far it has not been possible to track the variation of both the set of parameters with grinding time simultaneously. In this paper an attempt has been made in this direction by using a modified functional form approach with time dependent constants. Keywords: dry and wet ball milling, breakage rate and distribution parameters, effect of particle size distribution

Sep 1, 2012

By O. A. Bascur

"In recent years, metal producing companies have increased their investment in automation and technological innovation, embracing new opportunities to enable transformational change. Internet of Things (IoT) is one of many transformational initiatives, which can fundamentally revolutionize how industrial complexes operate. Whatever the issue, the answer is in the abundant and growing quantity of real time data and events collected in the grinding and flotation circuits in a mineral processing plant. Based on earlier work, today a grade recovery model permits identifying the best operating conditions in real time. We will review the strategy for increasing the value of the abundance instrumentation in current plants. An optimal Gaudin size distribution model provides augmented information from traditional sensors to find the optimal grind cut to reduce metal losses in the flotation circuits. The large amount of sensors in a flotation circuits permits to estimate the recovery and to find the optimal froth depth and aeration using an air holdup flotation model. The paper will describe the strategy of classifying data for on line generation of insights to using operational intelligence tools. We will discuss the implementation Recovery/Grind strategy with industrial examples in non-ferrous mineral processing and iron beneficiation.INTRODUCTIONThe declining supplies of high grade ores and increasing consumption of mineral and metal products have demanded higher operational efficiencies with minimum capital investments. The objective of copper flotation objectives are based on maximizing the dollars return on the concentrate produced. The economic efficiency is maximized by manipulating the circuit along the grade/recovery curve relationship. To achieve such objective improved stabilization of the grinding and flotation circuits are required (Oosthuizen, Craig, and Jamsa-Jounela, 2017)."

Jan 1, 2018

By Leming Ou, Qiming Feng, Yiping Lu, Pengyu Zhang, Qing Shi, Kun Liu, Guofan Zhang

"This paper introduces the mineralogical analysis of certain polymetallic copper-zinc ore in China with the aim of improving the flotation process. The main valuable elements, mineral phases and compositions of run-of-mine ore were inspected by the X-ray Fluorescence (XRF) and chemical analysis. For a deep known of the old process defects, Mineral Liberation Analysis system (MLAs) was employed to investigate the minerals liberation degree of selected key slurry points. Analysis results show that the run-of-mine ore belongs to the original copper-zinc polymetallic symbiotic ore at low oxidative level, which mainly contains 0.16% Cu, 4.43% Zn and 0.88% Sn. Gangue minerals are mainly silicate minerals, and zinc mineral is sphalerite. MLAs test illustrates that about 86% sphalerite has been dissociated in zinc flotation feed. In the current flotation process, over grinding of sphalerite monomer and insufficient liberation of intergrowths are the key problems need to be solved imminently. Up to this point, a new process consisted of two steps roughing unit is submitted in this research. It contributes two positive effects on zinc flotation performance: (i) separating sphalerite monomer timely to decrease overgrinding; (ii) improving zinc minerals intergrowths liberation efficiency. Flotation results indicate that the zinc concentrate grade increased 0.90% and the recovery improved 0.96% in the new flotation processINTRODUCTION Mineralogical analysis mainly focusses on solving mineralogy problems in minerals processing, assisting in minerals behaviors prediction and control for separation engineering (Falkovich, et al., 2001; Hillier, et al., 2003; Schouwstra and Smit, 2011). Process defects searching becomes its ordinary work, and flotation optimization appears to be its targets gradually. For example, Lucky Friday mine company (Idaho America) fails to obtain qualified lead concentrate as the change of ore properties (Nadoll, et al., 2011). Mineralogical analysis ascertains that there are too many dissociated sphalerite, pyrite and gangue particles exist in lead concentrate. According to this, more cleaning units are added to solve problems effectively. Kanowna Belle mine (Australia) takes a flash circuit in operation successfully with the aim of optimize flotation process, under the helps of mineralogical analysis and industrial test (Newcombe, et al., 2013). Lotter N.O. (2011) gives a deep description on how mineralogical data assisting mineral processing engineers to design and optimize flowsheet. For decades, quantitative and automated mineralogy techniques (Andersen, et al., 2009; Gu, et al., 2012; Oghazi, et al., 2009; Yu, et al., 2007) get well developed and hugely improve the veracity and repeatability of minerals properties measurement. Among these, MLAs (Gu, 2003) provided by JKMRC (Julius Kruttschnitt Mineral Research Center) is critically acclaimed all over the world. This analysis system can measure mineral phases composition and content, particles size, minerals occurrence and liberation degree directly."

Jan 1, 2018

By A. K. Mukherjee

In this apparatus closed sized particles are placed in a container and then fluidized by passing water through the load of particles. Water flow is adjusted to deposit particles in one or more layers depending on the specific gravity of each of the particles, after which the deposited particles are separated in portions of different specific gravity. The obtained portions represent different ore content of the closed sized fraction. The process is repeated for all other size fractions to generate washability curve of the feed. Three different types of iron ores and one coal sample are tested in this equipment. The theoretical yield-grade curve generated for iron ore feed is unique in absence of any such practice for ore minerals. Similar curve is generated for coal and it is compared with washability curve, an existing practice followed worldwide. This comparison validates the performance of the process and the equipment.

Sep 1, 2012

By G. Semenchenko

Heterotrophic microorganisms Pseudomonas aureofaciens, microscopic fungi Fusarium sp. and their combinations with some chemical substances were used for gold leaching from refractory ore and flotation concentrateof Akbakaj deposit. All biological additives raised the speed of noble metals dissolution. The best results of gold extraction from ore were in the presence of bacteria or their associations with other solvents and from flotation concentrate in the presence of fungus - 30 % of additional amount of gold. The maximum extraction of gold speed value was during the first 8 hours of process. The electronic-microscopic researches of the ore samples showed almost complete decay of pyrite and arsenopyrite under bacteria influence whereas at chemical leaching most of these minerals stayed uncrushed. The presence of microscopic fungi in flotation concentrate during leaching provided full distraction of pyrite, but some crystals of antimony and arsenopyrite were undestroyed. During cyanide leaching of flotation concentrate there were accumulation of antimony and incomplete pyrite decomposition. Keywords: gold bioleaching, bacteria, fungi, complex solution

Sep 1, 2012

By Z. F. Dai

The Thompson Nickel Belt, located in Northern Manitoba, Canada, contains more than 400 million tonnes of ultramafic low-grade nickel mineralization in 9 deposits. One of these, the Pipe deposit, was mined between 1971 and 1983 producing a Ni concentrate of 9% to 11% grade at 73% recovery. The operation was terminated because the poor recovery, low Ni grade and high MgO con-tent of the concentrate made processing this ore uneconomical at the metal prices prevailing at that time. Vale Inco is now re-evaluating these deposits with the intent of providing a new source of concentrate for its Thompson integrated processing facility. It is known that serpentine slimes coating on the sulphide surfaces are responsible for the poor metallurgy. Various desliming methods were tested including settling, elutriating, tabling and hydrocycloning. Hydrocycloning has proven to be the most effective means of desliming. With a feed assaying 0.70% Ni and 33% MgO, a rougher flotation concentrate assaying 22.7% Ni and 4.8% MgO was produced at a Ni recovery of 62.5% (relative to the feed to grinding), with no utilization of slimes dispersants. Another 16.6% Ni recovery was achieved in scavenger flotation resulting in a total Ni recovery of 79.1%. Batch flotation tests using various flowsheet configurations to optimize the grinding, desliming, reagentizing and flotation conditions are in progress.

Jan 1, 2014

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

Phosphorus slag is one of the most large-tonnage of yellow phosphorus production waste, which for decades stored in the slag disposal, by polluting the environment and creating environmental problems in the regions. Phosphorus slags from the processing of Karatau phosphorites are a very promising source of raw materials not only for silicon compounds but also rare earth metals (REM). Among the REM, yttrium, neodymium, europium and lutetium predominate, which are relevant to high-tech industries. The report presents technological scheme of complex processing of slags of phosphoric production with obtaining of REM concentrate and precipitated silicon dioxide ("white soot"). The regime parameters of the main operations of the technology are determined: I stage- leaching of slag with nitric acid solution; extraction of the REM-containing solution with tributyl phosphate and stripping of the REM with water; settling of solution of salts of oxalic acid, calcining the precipitate to obtain a concentrate S REM oxides and II stage of leaching silicon cake to obtain "white soot". Recovery of S REM from slags of phosphoric production on various redistribution has made, %: leaching – 95.0; extraction - 90.2; extraction on the average ~ 93.2; the production of a concentrate of REM oxide is 93.9. A concentrate containing 17.3 % of REM oxides was obtained. According to X-ray analysis it contains the following phases: calcium oxide, portlandite2, gadolinium oxide and yttrium, gadolinium oxide, gadolinium oxide and cerium, neodymium oxide, neodymium oxide and cerium. Thus, the concentrate can serve as a raw material for the production of individual rare-earth metals like gadolinium, cerium, yttrium and neodymium. After performing the II stage of leaching siliceous cake with nitric acid the samples of "white soot" were obtained. Its chemical composition corresponds to the state standard and has a specific surface area equal to 180 - 200 m2/g. The technology has been tested in a large-scale laboratory scale and will solve the problem of complex processing of phosphorus raw materials and import substitution in Kazakhstan. The end-to-end recovery of S REM oxides and silicon into concentrate and product from their initial content in slags is ~ 75.0 and 98.0 %, respectively.

Jan 1, 2018

By Peter Ay, Vincenz Mehlstaubl, Satyanarayana Narra

"This study gives an insight into non-destructive testing methods suitable for porosity analysis at a small scale, firstly summarizing relevant state-of-the-art technology and pending patents, secondly realizing and documenting the start-up of the VHX-2000 digital microscope by the manufacturer Keyence and thirdly demonstrating practical application with the extended analysis of three fundamentally different agglomerates for which important application-related parameters are determined. Various analysis procedures on the different agglomerates the efficient and timesaving operational features of the digital microscope are outlined. Firstly an analysis of flax fibre agglomerates determines the process conditions best suited to produce agglomerates with specific properties by determining sphericity, cubicity, density and porosity as well as fibre damage and alteration. Secondly the production of iron-hydroxide - hemp-fibre agglomerates serves to obtain information on porosity values as a result of a cauterization of the fibres. The third analysis provides estimations of porosity values for acid-treated lignin agglomerates. Measurements were carried out with compact dry agglomerates and with soaked, expanded agglomerates, determining factors for total water carrying capacity. Practicability of non-destructive testing by digital microscopy is demonstrated and explained concerning the applications in this study by obtaining definite structural findings about the analysed agglomerates. Information on its operation is made available by a practice-oriented manual for the VHX-2000 digital microscope. Further suggestions for more in-detail analysis results with different instruments are given."

Jan 1, 2014