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By D. G. Ingram

This paper reviews the operating and maintenance practices at Bethlehem Copper from the commencement of operations in November 1962 to the present. Cost data and wear life of major components are also discussed.

Jan 1, 1979

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By A. Dolatmoradi

Nanocrystalline structure formations produced by severe plastic deformation in Fe-0.15C with initial ferritic-pearlitic and IF steel with ferritic microstructures have been studied through microstructural observation and microhardness measurements. It was found that the nanocrystalline region first forms near the surface of samples due to localized severe deformation. It was also observed that the nanocrystallization rate of Fe-0.15C and IF steels and the deformed layer thickness in these two materials are different with similar milling conditions. The crystallite size and structural evolution of the samples during milling was studied by employing XRD and SEM.

Jan 1, 2010

By Kevin C. Milne

"The solution of problems associated with development of a sour gas reserve will be of increasing importance in tl1e next few years if gas export is approved •by the National Energy Board. The purpose of this paper is to review briefly the history of the Carstairs gas field, and tCI describe in a general manner the reservoir, and the producing and processing facilities.HISTORYThe Carstairs gas field was discovered in April 1958 when the discovery well, Home Carstairs 10-17, was successfully completed as a gas well in the Elkton member of the Turner Valley formation. Geo-graphic location of the field is shown in Figure No. 1. Note that the field is about five miles west of the town of Carstairs, Alberta, which in turn is about 40 miles north of Calgary. Drilling subsequent to the discovery well resulted in three addition-al producing wells and one dry hole during I.958; two producing wells during 1959; and one producing well and one dry hole during 1960. Thus, seven producing wells and two dry holes have been drilled in the Carstairs field to date.In November 1959 a 12-section block in the Carstairs field was unitized on a surface acre basis. Mean-while, in June 1959, operators in the field executed an ""Interim Plant Agreement"" that provided the money needed to start construction of a joint venture processing plant and gathering system. Construction of the plant and gathering system was completed in February 1960."

Jan 1, 1960

By S. M. Bulataovic, D. M. Wyslouzil

"The Martison Lake phosphate-niobium deposit is composed of unconsolidated residuum containing clay and silt-size particles of phosphate, niobium, iron and clay minerals. This paper deals with the laboratory and pilot plant development of the flowsheet and the reagent scheme to treat the Martison Lake ore. The ore, in addition to the complex gangue composition, contained several phosphate minerals including fluorapatite, francolite and florencite. The detailed laboratory and pilot plant evaluation resulted in the development of an effective flowsheet and reagent scheme for the selective flotation of phosphate minerals using a fatty acid circuit, followed by niobium flotation using amine collectors at acid pH. The developed flowsheet included des liming of ore, magnetic separation, and selective P 2 O 5 -Nb 2Os flotation. The main aspects discussed include characterization of the ore, step by step development of flowsheet and evaluation of dfferent modifiers and collectors for P20s and Nb20s flotation.INTRODUCTIONMartison Lake phosphate-niobium ore deposit, located 75 km north of Hearst, Ontario was discovered in the early 70's and has been the subject of extensive technical-economic evaluation in the late 70's and early 80's.The deposit is covered completely by 30 m to 90 m of glacial overburden and is composed entirely of unconso1idated material called residuum, that lies on top of a precambrian age carbonatite intrusive from which the residuum was derived by weathering and natural leaching in situ. The residuum is and irregularly-shaped horizontal lens, 2 km by 3 km in area, and up to 100 m thick, composed mostly of unconsolidated clay and silt-size particles of phosphate, niobium, iron, mica and clay minerals."

Jan 1, 1986

By K. Soucek, J. Ptácek, A. Hastíková, R. Kukutsch, P. Konícek, P. Waclawik

"Cable bolts are used frequently as a secondary support system (with steel arch support) in difficult stress-strain conditions of deep coal mines. The load transfer mechanism of cable bolts depends on several factors, such as the strength, deformation and geometric properties of the bolts, resin and the surrounding rock mass so-called cable-resin-rock system (CRR system). The bonding length and bolt/borehole diameter ratio strongly influence the final bearing capacity of the CRR system.The study presents the behaviour of CRR system during a pull-out test which is usually used in the carboniferous rock mass in the Czech part of the Upper Silesian Coal Basin. A series of 28 pull out tests were performed on 3-m-long cable bolts, with various combinations of borehole diameters and bonding lengths, to understand this behaviour. Boreholes were drilled into a solid rock mass consisting of fine-grained sandstone to guarantee similar conditions during the pull-out tests. Video inspection and measurement of borehole diameters were performed to determine their quality and real diameters. Three characteristics were observed from pull-out test results: ultimate pull-out load; displacement of the end of bolt and system stiffness. Numerical modelling by FEM (Finite Element Method) was used to determine the stiffness of the CRR system for variable bolt/borehole ratios and bonding lengths each under constant load. A linear elasto-plastic model and a mohr-coulomb model were used for cable and resin-rock respectively. The results of the experiment may contribute significantly to improving of the methodology of cable bolts installation as well as the design of used cable bolts."

Jan 1, 2015

By H. J. Rowley

THERE are many varieties of limestone, but for the general purposes of the pulp and paper industry, two classifications are sufficient: (1) High-calcium stone, which should be quite free from impurities and contain not less then 90 per cent calcium carbonate. (2) High-magnesium stone, containing not less than 25 per cent of magnesium carbonate. Before proceeding with detail on the use of limestone and lime in the industry, a few words regarding the pulp products made in Canada are desirable. By far the largest tonnage is made by grinding spruce and balsam logs on rotating sandstones or on artificial abrasive stones of the Norton or Carborundum types. This mechanical or groundwood pulp finds its largest use in the production of newsprint paper, of which it comprises about 80 per cent of the total fibrous substance employed-the remaining 20 per cent being unbleached sulphite pulp. No limestone or lime is directly employed in making groundwood pulp, as contrasted with the chemically prepared pulps, all of which require one or the other form of the base for their processing. Sulphite pulps comprise the next largest tonnage group. They are produced by boiling, under pressure and at elevated temperatures, spruce and balsam wood in chip form in solutions of bisulphites and sulphurous acid. The usual bisulphites employed are those of calcium and magnesium. Sodium, potassium, and ammonium bisulphites give progressively better pulps, but to date, in the absence of efficient recovery methods, cost has precluded their use.

Jan 1, 1939

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By L Gill

The four basic types of electric motors -squirrel-cage, wound rotor, synchronous and D.C. -are de-scribed, with particular reference to speed-torque characteristics. The three classifications of squirrel-cage motors, C.E.M.A. B, C and D, are compared, and methods of selection for specific drives are outlined. Wound rotor and synchronous motors are covered from the viewpoint of construction details, methods of operation and control required. The application of these motors to crushers, conveyors and ball mills is described and reasons for their selection are given. The application of D.C. motors to haulage equipment and mine hoist drives is included, and the basic principles of a variable voltage drive are illustrated. Efforts have been made through-out to provide specific examples of motor selection, with particular reference to the mining industry. THIS paper will attempt to answer the question -"which motor should be used for a specific drive?" Although it is impossible to cover the complete subject of electric motor application here, we hope to give some idea of the types of motors available and why certain types are used on specific applications.

Jan 1, 1963

By K. R. Wood, G. W. McDonald

"The tailings disposal system at Les Mines Selbaie includes dewatering of tailings in a high-capacity thickener, followed by point discharge of the thickened solids to form a stable conical pile. Tailings water drains to ponds formed behind engineered dams, prior to either recycling f or process use or discharge to the environment. Design and economic considerations of the system are discussed. Construction, start-up and operating experiences are also presented.Introduction Les Mines Selbaie is located in the Abitibi region of northwestern Quebec, approximately 700 km north of Toronto and 150km south of James Bay. More locally, the Detour gold mine is 60 km to the west while the Noranda smelter is 220 km to the south.The deposit was discovered as a result of a Questor INPUT Mark VI geophysical survey in 1973, followed by diamond drill programs from 1974 to 1976. Three mineralized zones were delineated and underground exploration was carried out on all three. A production decision for the 'B-zone' copper-gold-silver orebody was made in July 1979. The underground operation started in July 1981, with full production of 1500 t/d being achieved in May 1982.During the planning phase, every effort was made to ensure that the operation would be environmentally sound . The design included the provisions of the then newly proposed provincial environmental guidelines. The tailings disposal system formed the most significant part of the environmental program due to the large volumes of solids and water effluent. In addition, the design allowed for future expansion of the system to accommodate mining of the other zones, thus minimizing future costs and disruptions."

Jan 1, 1986

By W. A. Bell

The Carboniferous system of rocks in the Maritime Provinces include as workable mineral and organic substances, gypsum, anhydrite, salt, coal, building stones, grindstones, limestones, brick-clay shales, fire-clay shales, oil shales, etc. The system is, therefore, pre-eminently of economic value to the provinces in which it occurs, and the more knowledge we may gain concerning it, the more we may be prepared to aid in the development of these useful substances. For this purpose it is not sufficient to state that the ground upon which we stand is underlain by Carboniferous rocks. In-discriminate digging or drilling will not open many new mines of wealth, however difficult it may be to dampen the optimism of gamblers. For mineral wealth has not been scattered in the rocks haphazard, now here, now there, but its distribution has been the result of natural earth forces acting at intervals throughout the countless millions of years that have elapsed since our planet was born. As regards the majority of metalliferous deposits, the earth forces involved have resulted in the penetration of surface or sub-surface rocks by molten rock-matter and associated mineral solutions from deep-seated sources. But the economic Carboniferous deposits that have been mentioned are themselves types of bedded surface rocks rather than immigrant deposits, and their formation and geological history is closely related to that of the rocks with which they are interbedded.

Jan 1, 1924

By E. H. Kranck

Introduction Baffin Island is still too in-accessible to be of interest to the mining industry. However, twenty years ago few people dreamed of mining iron ?ore in Labrador. A journey by air to the most remote places in the Arctic is today no more remarkable than a trip to Europe, and the technical difficulties of mining minerals of high value are not insurmountable. Some ?observations concerning the geology and mineral possibilities of Baffin Island, the largest of the Arctic islands, may therefore interest the members of the Institute, in spite of problematic practical value of the subject. The following short account is mainly based on observations made during the Baird Expedition of the Arctic Institute of North America last summer 1950), and on information available from earlier expeditions. Early Work Baffin Island was one of the first parts of Canada to attract prospectors. Frobisher sent a shipload of rocks, which he believed contained precious metals, from Baffin Island to England. This attempt, however, was a failure and no further serious prospecting work has, so far as I know, been done. During the past few years geological mapping has been carried out by the Geological Survey of Canada (Fortier. Davison, 1949-1950) in the southern parts ?of the island, along the coast of Hudson strait. In 1942, Weeks mapped the coast from Pangnirtung to the head of Cumberland fiord, and Netteling river up to Netteling lake. In the northern parts of the island, only scattered observations have been made ?by Bell, Watkins, Baird, and others.

Jan 1, 1951

By G. A. Sutton

This paper, describes a case example from San Manuel mine, where in situ copper leaching of the supergene zone was done over a 14 year period (1986–1999) in conjunction with underground and open-pit mining operations of a copper porphyry deposit. In 1993–1994, testing of well fields was done to determine the amount of copper that would be recovered from in situ leaching of the supergene zone, which was composed primarily of chrysocolla and copper-clay minerals. It was determined that the leach fluid would reach 70% (‘sweep efficiency’) of the copper minerals and that 75% of them would be leached for a recovery of 52% of the acid soluble copper. However, the final results from Zone 6, which had the longest leach history, showed that approximately 42% of the acid soluble copper was recovered, indicating that the `sweep efficiency’ was closer to 55%. Comparison of drill-core assay data from two holes, one drilled before (ARM158) and the other after (SMO9607) leaching, also indicate that approximately 42% of the acid soluble copper was recovered. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to a combination of factors, including difficulty in maintaining fluid saturation, channeling effects and gypsum precipitation. INTRODUCTION In situ copper leaching at the San Manuel mine, Arizona, was initiated in 1986. It was recognized that some of the copper oxide resource was not going to be economically recoverable by conventional open pit and heap leach methods using solvent extraction and electrowinning (SXEW). A high stripping ratio would be required to access part of the resource. At the time, in situ leaching was becoming popular in the uranium industry but the approach was virtually unknown in the copper industry, especially not at a large scale.

Jan 1, 2019

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge's Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge's Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

By W. J. Witte, M. K. Witte

"INTRODUCTION A pilot heap leach project was conducted on the B. P. Selco Hope Brook ore located in southwestern Newfoundland. The pilot heap leach was undertaken to assess and confirm the following:1) To confirm that heap leach technology now currently used in the United States could be applicable to Canadian sites.2) To confirm gold recovery by the Heap Leach technology3) To assess and study potential heap leach environmental concerns in cold and wet climate.PROJECT LOCATIONThe Hope Brook Project is located near the southern coast of the island of Newfoundland, approximately 100 kilometers southeast from Stephenville, approximately 25 kilometers west of Burgeo, Newfoundland. Access to the property is limited to helicopter, float plane or by sea through Couteau Bay. The property was covered with muskeg and very few trees. Surface relief was moderate with many poorly drained boggy sections confined to small areas. Many small unnamed lakes were located on the property which provided water to small brooks and streams flowing to Couteau Bay.Several locations were reviewed for the installation of the pilot heap leach facility. Important parameters used to select a suitable location included sufficient land area, close proximity to but not on the ore body, reasonable protection from wind, sufficient supply of fresh water, close to a suitable location for a portable crushing plant, reasonable access to aggregate material for preparation of the test pad and ponds and suitable contours to minimize site preparation."

Jan 1, 1987

By P. M. Hedley

GOLD mining in Nova Scotia, as in any other gold district, has its own peculiar problems. Being in close proximity to excellent roads and to railways, and being blessed with good labour, the majority of gold mines in the Province find their paramount trouble is geological, namely, ore finding. After six years of continuous mining at Goldenville, the staff of Guysborough Mines, Limited, has collected many facts, has come to some definite conclusions, and has made a lot of guesses, some good and some bad. It is the purpose of this paper to set down such information as we have been able to gain in the hope that it may prove useful to other operators, present and future, faced with similar problems. What may be true of one Nova Scotian mine will not necessarily be true of another, so that the observations that follow should be considered as primarily applicable to Goldenville. Stated facts, conclusions, and theories are the result of the combined thought and effort of Head Office officials, of members of the Provincial and Federal Departments of Mines, and of members of the mine staff, past and present. Grateful acknowledgment is made to all.

Jan 1, 1941

By J. Karonen, M. Tiihonen, J. Guentner, L. Haavanlammi, Outotec GmbH, E. Kolehmainen

"Rare earth elements have obtained significant attention during the last few years due to predicted increase in their demand. Several projects worldwide are at pre-feasibility or feasibility stage aiming to commence production. Deposits of rare earth elements are typically complex and multi-metallic of nature. This means that production processes are often also complex and therefore, various metallurgical unit processes are needed. Outotec’s equipment and technology portfolio is very comprehensive and includes hydrometallurgical and pyrometallurgical apparatus and processes applicable to the efficient exploitation of rare earth deposits. Outotec has gained useful experience relevant to the processing of rare earths through several assignments including those for Alkane Resources Ltd. (Dubbo Zirconia Project), Greenland Minerals and Energy Ltd (Kvanefjeld Project), Frontier Rare Earths Limited (Zandkopsdrift project), Tantalus Rare Earths AG (Madagascar), Quest Rare Metals (Strange Lake project) and Orbite Aluminae Inc. (HPA project). The hydrometallurgical test work of two process flowsheets is presented in the paper. A roasting or acid baking step is common to several proposed rare earth projects. In the past, rotary kilns have been used, but Outotec has developed a new process concept to handle the rare earth material in fluid bed reactors. The basis for this development is long experience in fluid bed technology of Outotec in Germany. One advantage of fluid bed roasting is the higher throughput per unit. In combination with the roasting and baking, Outotec offers the gas cleaning and acid plant and provides a complete and closed concept.INTRODUCTIONRecovery of rare earth elements (REE) has obtained significant attention during recent years. It has been estimated that their demand will be boosted because of their need in many technology areas. REE can be utilized in magnets, batteries, displays, catalysts, optical devices etc. (Jordens, Cheng, & Waters, 2013; Zhang & Edwards, 2013). The production of REE is focused in China, which means that production outside of China is very scarce. However, there are multiple active development projects worldwide working towards production of REE containing products outside of China (Chen, 2011)."

Jan 1, 2016

By Poul Hansen

"In mid-1986, a world-class mining enterprise was created in Highland Valley, British Columbia, bringing together the copper mining operations of Lomex and Cominco . In 1988, Highmont joined the new partnership.Highland Valley Copper is the largest copper mine in North America in terms of both tonnage mined and tonnage milled, and it is one of the largest in the world. Due to its relatively low ore grade its production of copper in concentrate ranks about ninth in the Western World.The current eighteen year mine plan is based on ore reserves of 761 million tonnes. The daily milling rate is 133 000 tonnes. At the end of mine life, a total area of approximately 6500 hectares will have been disturbed. At this time, vegetation has been established on about 600 hectares and while work will be done during the operating years, it will not be until the end of mine life, about 2008, that the last half of the land can be reclaimed and revegetated.Once final reclamation has been accomplished, Highland Valley Copper will have completed its "" temporary use of the land"". In the meantime, about 1250people have had employment for about 50 000 man years, at wages ranking among the best in Canada.IntroductionTo provide and sustain our way of life, we need steel, copper, aluminum, zinc and many other minerals.To sustain mining, we must have adequate ore reserves and replacement of reserves as they are mined. Each year the search becomes more difficult as more of the Earth's surface is investigated and depo sits are mined. This calls for aggressive and sustained efforts.In British Columbia, past and present mining activities have disturbed less than one-tenth of one per cent of the land.With today’s technology, mining operations can be substantially reclaimed and thus complete the cycle of ""A Temporary Use of the Land""."

Jan 1, 1992

By Yanping Xiao, Ton van Sandwijk, Gus Van Weert, Larry McHugh, Thomas Zabev

"All attempts to remove significant amounts of arsenic from enargite via neutral or reductive pyro routes have required operating temperatures between 600 and 700 º C, too high to propose an equipment development program. Operating at reduced pressures, or using hydrogen or elemental sulphur as a sweeping gas did not help to lower these temperatures. Admixing iron powder gave excellent results, but still required 700 º C. By fortuity, in recent experiments to produce tennantite from an enargite mineral sample, it was observed that enargite was completely converted to bornite, chalcopyrite with minor residual tennantite within an hour at 400-450 ºC. This is believed to be due to the presence of pyrite in the mineral sample treated. All earlier decomposition work appears to have been done on predominantly enargite (i.e. low pyrite) samples, or at high operating temperatures, ignoring possible reactions at lower temperature. The decomposition of enargite into iron substituted tennantite plus some bornite under evolution of liquid elemental sulphur, followed by further decomposition of this tennantite into bornite and volatile arsenic sulphides, appears experimentally feasible at these low temperatures and mimics described ore genesis pathways at > 250 ºC in saline solutions. We suggest two pathways to describe the observed experimental results:20 Cu3AsS4 + 12 FeS2 ???5 Cu10Fe2As4S13 + 2 Cu5FeS4 + 31 S(l)31 S(l) ???31 S(g) (evaporation)5 Cu10Fe2As4S13 ???10 Cu5FeS4 + 10 AsS(g) + 5 As2S3(g)"

Jan 1, 2014

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012