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By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Tetsuya Yumoto, Toshikazu Shiratori

Information on the elements contained in E-Waste is important from the viewpoint of recycling. We analyzed several components of waste electrical and electronic equipment (WEEE) collected from citizens. The distributions of the minor metals in WEEE were determined with elemental mapping and chemical analyses. The annual change in elemental composition was investigated by analyzing equipment manufactured in different years. The information will be of use for separation techniques required for future advanced recycling.

Jan 1, 2011

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By M. J. King, D. A. Van den berg, R. Fukuzawa

"Mercury bearing ore bodies are often treated for the production of copper, lead, zinc, gold, and silver. The mercury deports either to tailings or is collected during various stages of the extraction process. This paper reviews the relationship between various mercury collection processes and the subsequent management of the mercury by-product or waste. It focuses on mercury removal sequestration including cementation, sulphide precipitation, bulk neutralization, and carbon adsorption. Long term mercury management strategies including third-party stabilization, stabilized mercury co-disposal, secure storage, and mercury recycle are also evaluated. INTRODUCTIONMercury is produced in North America as a by-product of non-ferrous metals processing and from recycling of products such as dental amalgam, fluorescent lamps, and thermometers. Its toxicity is recognized to have significant negative impacts on the environment and human health. As a result, many countries are adopting regulations limiting mercury use and its uncontrolled release.The European Union banned mercury exports in 2011 and the United States will do so in 2013. The export bans aim to prevent mercury use in developing countries for activities such as artisanal small scale gold mining. However, by-product mercury production from the non-ferrous metals industries continues.These factors contribute to an oversupply of mercury and the need to find suitable treatment methods for the long term management and storage of mercury and mercury bearing materials."

Jan 1, 2012

By A. R. MacPherson

"This paper considers four aspects of autogenous grinding. Part 1 discusses statements on power efficiency of autogenous grinding compared to conventional crushing and grinding systems. It also demonstrates how high-power efficiency can be obtained from autogenous grinding systems. Part 2 considers a simple method of testing ores to determine the type of autogenous plant which can treat these ores on a commercial basis. A comparison of testing for simple small plants vs large plants or complex ores is included. Part 3 considers important aspects which have to be considered in proper design of an autogenous grinding system. Part 4 discusses problem ores and how they can be treated in an autogenous system. INTRODUCTIONAfter about 35 years of using autogenous grinding plants in the mining industry, it is perhaps time to review where we are with this, by now, relatively old development. Autogenous grinding in this paper means grinding run-of-mine ore by fully autogenous means or by using a ball charge to assist the grinding (semi-autogenous). Also, autogenous grinding can be eitherby dry or wet.The use of autogenous grinding in the fifties was making its slow start, and it was not until the sixties that more of the mining industry would consider its use . By the seventies, most builders of new plants would have considered autogenous grinding, whether they used it or not, in the final design.In the eighties, most large plants use autogenous mills and to reduce over-all operating costs, many older conventional plants are now looking and actually retrofitting these old plants with autogenous grinding mills.It is evident that many misconceptions concerning autogenous grinding are still current. Some come from improperly designed plants which result from poor test work. There are many considerations in the proper design of autogenous plants. Some ores have been found to give problems even in a well designed plant. These ore types are beginning to be classified and recognition in the test stage allows steps to be taken in the design so that these ores can be efficiently handled in autogenous grinding plants.Therefore, this paper will address the following aspects of autogenous grinding:1. Misconceptions regarding autogenous grinding.2. Testing of ores to ensure a well designed commercial plant.3. Important considerations in mill design.4. Difficult ores, their recognition and types of design to handle such ores."

Jan 1, 1989

By S. Komar Kawatra, Youlian Zhou, Joseph A. Halt

"Bentonite clay has been the most common binder for iron ore pellets. Although bentonite increases pellet strength and durability, it has several disadvantages. For example, its use increases the cost of pellets and decreases pellet purity due to its composition and the higher levels of flux required to meet basicity limits. Several new types of binders have been proposed to replace clay. The binders include starch, modified humic acid (MHA), and dispersants. These binders were used to pelletize a magnetite concentrate from the United States. Typical doses of each binder type were 0.05-0.1 % starch, 0.5-0.75 % MHA, and 0.05 % dispersant. At these doses, the pellets exceeded the minimum recommended values for wet drop, dry compression strength, and fired compression strength. Pellets made with the MHA and dispersants had the lowest abrasion rates of the new binders, and were comparable to pellets made with bentonite clay. In this paper, we compare the new binders, considering pellet quality and the advantages and disadvantages of each binder type.INTRODUCTIONIron ore pelletizers need binders in order to make good quality iron ore pellets. The typical binder is bentonite clay, an alumino-silicate material. Bentonite increases the ballability and strength of iron ore concentrates, but reduces pellet iron grade and reducibility. As high quality bentonites can be expensive to ship, low quality bentonites are often used at significantly higher doses – this reduces iron grade and reducibility even further. Thus, several new types of binders have been proposed to replace bentonite clay.In this paper, we present several new binders for iron ore pellets: starch and modified humic acid (MHA). These have been tested alone and in mixtures with dispersants, or else with bentonite clay. Starch, MHA and their mixtures are briefly described below."

Jan 1, 2016

By Abdurrahman Tosun

It is very important for after blasting processes that muck pile fragmentation is predicted and controlled during blasting. Therefore, a significant research effort has been devoted to the development of mathematical equations that predict the value of average muck pile fragmentation. The specific charge parameter used in all of these equations is determined as the ratio of the total mass of explosives used to break a volume of rock. The length of blast surface and the row number of the blasthole are ignored in the calculation of the specific charge. However, in a blasting operation, blasthole geometry may result in additional material being impacted by a blasthole. This is due to effect shares of in both end sides of blastholes and the back region of blasting surface. In this study, a total of 14 blast tests, 8 at the first quarry and 6 at the second quarry of the Bati Anadolu (Western Anatolia) Cement Factory, were performed. In each study area blast tests were designed in the same direction continuously to provide stable structural properties of the rock. Therefore muck pile fragmentation depended on only specific charge values for each blast tests. Specific charge values were calculated according to both an average blasthole and also the total volume of material occurred as a result of blasting for each blast tests. During loading until the end of blasted material the front, the back, the arm off and the bucket off pump hydraulic pressure values occurred in hydraulic pistons of the loader were determined with a lot of data received for each blast tests. After that the relationships between specific charges values obtained according to two different methods and hydraulic pressure values of the loader were established with two correlations. The relationships between specific charges values obtained according to the total volume of material occurred as a result of blasting and hydraulic pressure values of the loader occurred as the best results especially the blasting operations that have the total length of blasting surfaces are short.

Aug 1, 2013

By E. F. Evoy

"The Gunnar uranium deposit was within metasedimentary rocks of the late Archaen Tazin Group. These rocks were intensely altered by albitization so that the immediate host to the ore consisted dominantly of albite, and by the subsequent introduction of calcite. The ore consisted of disseminated pitchblende and uranophane in a pipe-shaped breccia zone. Oxidation of the ore was more intense near surface than at depth, but there was no near-surface enrichment.IntroductionThe Gunnar Mine site is on the tip of Crackingstone Peninsula, on the north shore of Lake Athabasca, Province of Saskatchewan, Canada. The peninsula forms the southern part of the Beaverlodge mining area. The ore consisted of disseminated pitchblende and uranophane in brecciated metasedimentary rocks of the Tazin Group, and the deposit was characterized by extreme albitization and subsequent carbonatization of the host environment.Production from the mine began in 1954 and the ore was depleted by 1963. In that interval the deposit yielded about 5 million tonnes of ore containing about I. 75 kg/tonne U3O8. It was mined initially from an open-pit and subsequently from underground; the open-pit contributed about 55% of total tonnage. Uranium was recovered by atmospheric leaching in sulphuric acid, ion exchange concentration, and precipitation with magnesia.This paper is based on studies made during the productive life of the mine and is concerned primarily with pre-ore alteration of the rocks containing the deposit, and with the ore mineralogy."

Jan 1, 1986

Unplanned open stope hanging wall dilution is a significant cost for many open stope mining operations. Significant advances in empirical and analytical approaches for estimating stope dilution have been made, however, many important factors are still either ignored or assessed in purely subjective terms. There are many hard to quantify factors that simultaneously influence opening stability and dilution. This creates a significant difficulty for determining the influence of a single variable, such as exposure time, on opening stability. Open stope exposure time has been found to be one of the important factors that influences overall stope stability and dilution. A study is currently being conducted to quantify many of the factors influencing open stope dilution. The assessment of a large comprehensive case history database of Hudson Bay Mining and Smelting Co. Ltd. (HBMS) operations forms the basis of this study. This paper presents the findings of a study on the influence of stope exposure time on open stope dilution. The study is based on applying existing empirical stope dilution prediction methods to the extensive HBMS database. Minimising stope mucking time has been recognised as a method to significantly reduce stope dilution. Factors which influence hanging wall dilution, such as drill and blasting methods as well as undercutting the hanging wall, have been applied to reduce the scatter in the database. Empirical design techniques based on rock classification attempt to relate opening stability to ?stand-up time?, however, these approaches have not frequently been applied to the mining industry. Data from a ?stand-up time? graph have been interpreted in terms of an equivalent average depth of hanging wall slough and compared to the HBMS database findings. To add to the existing HBMS database, several stope case histories have been taken from Geco mine. These cases include data from very large open stopes with long exposure times. Data from all three sources suggest that hanging wall slough increases between .14 and 0.3 metres per month for a rock mass Q? value between about 4 and 13.

May 1, 2003

By T. H. Patching, M. W. Mikhail

"The gas sorption and emission characteristic of coals are important to the planning and conduct of mining operations. Methane drainage from coal strata can also provide a supply of fuel in certain circumstances. Gas emissions have also created hazards during the handling and transport of coals and the release of gas also appears to be related to the yield of fine sizes during mining and processing operations.This paper summarizes studies at the University of Alberta on the permeability and gas emission of certain bituminous coals. Permeability of 'solid' samples was found to be drastically reduced by confining pressure. An emission index, .P, which has been related to outbursting behaviour of coals, has also been related to the proportion of fine s in cleaning plants. Gas sorption isotherms are dependent on temperature, moisture content, the gas involved and the type of coal and can be approximately expressed by the Langmuir or the Freundlich equations. Sorption values in sections taken across a given seam were similar but considerable differences were found in . P indices in the different coal layers of a seam.IntroductionThe emission of gases, especially of methane, from coal has been a subject of great interest (and sometimes a matter of life and death), to those who dig and handle coal since it was first mined from underground pit s. Many studies and investigations have been carried out on gas occurrences and emissions but our knowledge of the precise mechanisms of gas sorption, desorption and flow from coal is still incomplete. It is the purpose of this paper to review the principal factors involved in these processes and to briefly rep ort some of the results that have been obtained by studies in the laboratories of the Department of Mineral Engineering, University of Alberta, and Coal Research Laboratory, Edmonton, CANMET"

Jan 1, 1986

By Frank Ebbutt

In this paper it is proposed to point out certain structural factors that; have an important bearing on gold deposition. The subject will be treated; more or less generally. Although the writer has had access to a great many; of Canada's gold mines he does not wish to take the liberty of discussing; details of any particular mine or mines; the aim will be to discuss controls; that are evident in many places.

Jan 1, 1954

By W. A. Crosby, W. K. Smith, K. L. McDonald

"IntroductionThis paper describes how the introduction of two blasting techniques and the resuItant development of new dragline digging methods have increased the productivity of single- and double-seam dragline operations at the Rietspruit opencast mine.LocationRietspruit , one of South Africa's largest opencast strip mines, is situated some 11 5 kilometres east of Johannesburg in the Witbank coal field.BusinessRietspruit is a joint venture between Transvaal Consolidate d Land and Exploration Company (T.C.L.) and Shell, South Africa. Rietspruit is administered and managed by Rand Mines, the Mining division of Barlow Rand, transportation and marketing being the responsibility of Shell. The total saleable coal product, approximately 5,5 million tons per annum, is exported via Richards Bay.Presplitting and Throw BlastingPresplitting was initially introduced in September 1980, as a means of dewatering t he overburden and mid burden to facilitate the use of dry-mix explosives a s opposed to slurry explosives.The utilization of the throw blasting technique arose as a direct result of observed ground movement after the successful introduction of presplitting. The first trials commenced in March 1981 on the double-seam operation. The methods, economics and resulting advantages are fully described elsewhere. A brief description follows.Method of PresplittingAfter determining the desired presplit line, 250-mm holes are drilled to top of coal at 4-m to 6-m intervals, dependent on the competency of the rock overlying the coal. A single 60-kg charge of slurry explosives is located at the bottom of each hole, no tamping is used and all the holes are detonated simultaneously. The results are a competent, straight, vertical highwall. This enables accurate control of the first row of blast holes closest to the highwall, which is a prime requisite for successful throw blasting."

Jan 1, 1983

By C. L. Lewis

"The development of computer process control at the Lake Dufault concentrator is reviewed and the on-stream X-ray analysis -computer system is described briefly. Some applications of the computer in metallurgical process control are described.The computer sequences slurry sample streams to the analyzer and translates the analytical results from voltage signals to elemental percentages. The required flotation reagent flow rates are calculated from analyses and mill-feed tonnage rates and the reagent feeders are set automatically to provide such flow rates. X-ray calibration time has been reduced from about 45 minutes to 15 minutes by the use of a computer program. Metallurgical and operating personnel have acquired the ability to program the computer and have extended the system capability to allow the calculation of recoveries, averaging of mill data, application of ore specific gravity in grinding control, control of oxidized ore flotation and the development of an economic recovery program."

Jan 1, 1971

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By Peter Harben

"This paper discusses the benefits of industrial minerals, their sources of supply, price and marketing trends, and their increasing use as substitute materials and ""strategic"" minerals. IntroductionKaolin finds have yet to spark the kind of frenzy associated with the 1849 California gold rush; no dolomite deposit has ever gained the notoriety of the Comstock Lode; and few industrial minerals are counted among the currently fashionable list of "" strategic mineral s"". Nevertheless, the glamorous zhine associated with metals may be somewhat superficial; further digging provides perhaps the real foundation of modern society - industrial minerals.They are often tagged as common, everyday materials that are simply dug out of the ground, crushed and hauled to a local point of consumption. Although this description is accurate in the case of road aggregates, sand and gravel, and the like, there are many exceptions to this rule. The term industrial minerals is rather nebulous, covering as it does the mundane and esoteric, the chemically active and the refractory, the $2 and the $10m-a-ton product. All of these minerals influence every facet of modern life from fertilizers to fire retardants, ceramics to cars, construction to clothes, and toothpaste to tennis courts. Their usefulness is well illustrated by the variety of industries they serve; the main ones are listed in Table 1. It is now time to dismiss the notion of non-metallics as the ""third world"" of natural resources business after the metallic and energy products by dispelling some of the myths regarding abundance, variety and value of the group's sixty-plus products."

Jan 1, 1982

By J. D. Stewart

One of the first important questions that should be settled on the opening of a mine or the development of a new deep is the system of haulage to be used, since the layout of the haulage-ways at the pit bottom, or, in case of a slope mine, the arrangement of the surface works, depends largely upon the type selected. Should it later become desirable to install a system of haulage of a type other than that for which the mine roadways were originally laid out, considerable difficulty would likely be encountered in its installation and with the result that it would in all probability be most unsatisfactory and expensive in its operations. It therefore becomes very necessary that full consideration be given the haulage problem at an early date in order that the type best suited to the mine conditions and the required outputs can be intelligently planned for. It is sometimes found, however, that no matter how well the mining engineer explores the seam to be developed, or how accurately he anticipates its eccentricities, there will still remain some unrevealed or unsuspected conditions, or shall we say obstacles, placed by Nature to prevent the too easy winning of her treasures and incidentally to frustrate or modify the application of the plan so painstakingly laid down on paper, and to adversely affect the cost estimate.

Jan 1, 1928

By Michel Gauthier, Pierre Marcoux, Gaétan Morin

"The recent opening of Muscocho's gold mine at Montauban, as weil as the discovery of several new copper-gold showings of a similar nature near the confluence of the Saguenay and St , Lawrence has revealed the existence of a new metallogenic gold province which is located within supercrustal units of Helikian age within the Grenville Province. Three metalliferous belts have been identified, each one of which is related to a series of SW-NE trending faults. The first is located in southeastern Ontario and southwestern Quebec. The second extends from the Balmat-Pierrepont mining district of New York State up to the Lac St. Jean region of Quebec, and includes the Montauban camp. The third follows the St. Lawrence river in Charlevoix County and along the north shore of the Gulf of St. Lawrence.The gold mineralization which is present in the central portion of the Grenville Province is of two types: either stratiform or vein. Deposits of the first type, of which the Muscocho is the type locality, are economically the more interesting of the two. Not only is this mineralization stratiform, but also shows a distinct affinity to AI-rich, Mg-rich or calc-silicate-rich bands. As is the case with the Bousquet and Hemlo regions of the Superior Province, they are associated with layers which are rich in sillimanite and occasionally staurolite. A second parallel between the Bousquet and Montauban deposits might be the presence of manganesian gamets, which have been recognized at the two localities. Some of the mineralization in the central Grenville Province is located within thin bands of iron formation which are rich in arsenic.The stratiform gold deposits of the central Grenville Province are of exhalative origin and are located within a volcano-sedimentary terrane. It is probable that a part of the gold present in these Helikian deposits have been derived by remobilization of Archean mineralization. The vein showings form as a consequence of the remobilization of the Helikian strata during the Grenville metamorphism,"

Jan 1, 1985

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977