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By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By A. W. JR. Whitaker

Introduction Within the last quarter of a century the Lake St. John-Saguenay valley has been converted from a quiet agricultural district to one of the important industrial centres in the Dominion. First there was the expansion -of the pulp and paper industry, and then, starting a little over ten years, ago, the development, in large .blocks, of the enormous hydro-electric power resources of the Saguenay river. Coincident with this power development, the world aluminum industry was rapidly expanding and looking for a new source of cheap power. This was found in the Saguenay valley-and so, in 1925, Arvida was established by the Aluminum Company of Canada as a location for one of the largest aluminum plants in the world. Arvida, an incorporated city comprising an area of some ten square miles, is ideally located on a more or less level plateau about 350 feet above the Saguenay river. Seldom has industry stepped boldly forth and carved out of Nature a community with full city status. The process usually goes through the steps of camp, village, town, and city, involving improper planning or lack of planning; all of which has been avoided at Arvida by starting out in the right way. While this community has only a population of approximately 2,000 at the present time, it is carefully planned for a population many times this figure. Streets, city parks, business and residential sections, have been definitely planned, and, with a City government, proper ordinances were passed at the beginning to ensure the building and maintenance of a model industrial community. As the crow flies, Arvida is about 35 miles due east of lake St. John, and 0 miles west of the St. Lawrence river at Tadoussac. From a shipping standpoint, it is well served by the Canadian National railways, with direct lines to Quebec and Montreal, and by ocean shipping facilities at Port Alfred, which is about 15 miles to the east on the Saguenay river and is served by the Roberval & Saguenay railway. The latter has interchange connections with the Canadian National at Arivda, and also operates a branch line into the city of Chicoutimi.

Jan 1, 1933

By F. Mackay, S. A. B. da Fontoura

"The theoretical solution for a viscoelastic well was presented by Gnirk and Johnson in 1964. From this an exercise was executed to validate the numerical simulation of a cemented salt well. The exercise comprised the geomechanical behavior through time of a cemented salt well, this was achieved using a finite element commercial software. This simulation showed the accuracy of the theoretical solution for viscoelastic materials such as salt rock. The theoretical solution presented elastic and viscoelastic analytic equations for the tangential and radial stresses. The equations for the elastic material (casing and cement) and for the viscoelastic material (salt rock) are presented here: Where equations 1a & 1b are the radial and tangential stresses of the elastic material; equations 2a & 2b are the radial and tangential stresses of the viscoelastic material; and a, r and b are the geometrical parameters explained in Figure 1. These equations are function of Pb, a stress time dependent factor that comes from the Burgers model of viscoelasticity. This is well explained in Gnirk and Johnson (1964) and for the sake of simplicity is not disclosed here. Po is the stress at section A-A’ dependent of the depth h."

Jan 1, 2015

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

By J. G. Bensley, K. S. Detheridge

"Many plants use computers for process control and most have computerized Management Information Systems but few have been able to have these systems interact with one another. Developing this system interaction is not a one-step process but requires careful planning and implementation. This paper describes two projects that were implemented to provide the bridge between the process control and management information systems of Cominco Limited. Both projects include the replacement of essentially process control systems installed in the late 1960s. These original systems provided an enhanced level of control in the form of Direct Digital Control (via computer/manual analogue control stations) and a management reporting capability of process data. The experience gained from the use of these systems over a period of fifteen years formed a basis for the evaluation and planning for the new systems. The new systems were commissioned in 1985 and 1986 and operating and further developments leading to a totally integrated process information and control system are underway. INTRODUCTIONThe concept of hierarchical control involves a control structure consisting of a number of defined levels. Each level performs a defined function with information consolidated and combined as it moves up through the hierarchical structure. The commonly accepted structure of a hierarchical control system echoes the structure of the plant which is being controlled. Referring to Figure 1:Level 0 - Sensors and ActuatorsSensors and actuators, such as thermocouples and flow control valves, interface directly to the process and are generally connected directly to the controllers or multiplexers at Level I.Level 1 - Regulatory ControlThis level provides basic PID control (proportional/integral/ derivative) typically using microprocessor based controllers and programmable controllers for digital control of motors and machines. Systems at this levelare usually segregated by plant unit, e.g, crushing, flotation, drying. Control is concentrated on achieving optimum conditions for a particular feed rate."

Jan 1, 1989

By Jamel Sgaoula

During 1998 COGEMA Resources Inc. announced that operations at the Cluff Lake mine will be suspended indefinitely by the end of year 2000 as a result of deteriorating uranium market conditions. To remain profitable, Cluff Lake mine started an aggressive cost reduction program. A cost reduction team was formed to look for ways to lower production costs. The focus of this team was to screen all areas and to come up with ideas to improve the economy of the mine and ensure the viability of the operations over the remaining three years of operations. Among the areas where significant savings were achieved are: (1) replacement of portion of cement with fly ash in backfill; (2) backfill optimization; and (3) new shotcrete plant installation on site for bulk in-house shotcrete production. This paper details the research work carried out by Cluff Lake mine on these projects and results of its application.

May 1, 2001

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By G. A. Young

THE Geological Survey was created in 1842 to aid the development of Canada's mineral resources. Although the institution has been in existence for nearly 100 years and has accomplished an immense amount of work, the need for its services remains as great as ever and, indeed, it is difficult to imagine a time when the country will no longer require a Geological Survey. This is so because of the tremendous effort required to make an adequate geological examination of so large an area as is embraced by Canada and partly because what today may seem an adequate geological examination proves, later on, to be inadequate. The ultimate objective of the Geological Survey is to complete the study of all phases of the geology of Canada, that is, to determine how and when the physical features originated, how and when the soils and other unconsolidated deposits were formed, and how and when the solid rocks and associated deposits were produced and assumed their present conditions. When the study has been completed, any only then, will it be possible to make a reliable estimate of the country's mineral resources. This appraisal embraces more than determining the value of already discovered deposits: it also involves attempting to establish what kinds of undiscovered deposits may be present and where they may occur. The estimating of the potential mineral wealth can be clone only after the geology of the country is known. Not until then will it be possible to forecast what types of valued deposits may occur in a district and what types will almost certainly be lacking. A thorough knowledge of the geology of the country is desirable not only to permit estimating the potential mineral resources but also as an aid in locating and developing mineral deposits whether these are of the nature of a bed of limestone, a seam of coal, a reservoir of petroleum, a vein, an irregular body of sulphides, or any other type of deposit.

Jan 1, 1940

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By R. Tipman

"In 25 years, processing of tar sand progressed from two small pilot plants to two major commercial operations owned by Syncrude and Suncor. These plants mine tar sand and extract the bitumen which is then converted into a synthetic crude oil. Considerable research on extraction of bitumen from tar sand has been undertaken by these two companies as well as other major oil producing companies, private individuals, universities and the federal and provincial governments. These studies have produced a number of alternate processing schemes which have yet to be commercialized. The producing companies are focusing their efforts on achieving increased processing efficiency, which includes improved bitumen recovery, reduced unit cost, energy conservation, and equipment reliability. In this review, the Syncrude process and examples of new process developments will be briefly described. IntroductionTwenty-five years ago, tar sand processing was limited to two pilot plants owned by Cities Service Athabasca Ltd., and Great Canadian Oil Sands. Earnest Manning was Premier of Alberta and was inviting proposals for the construction of a commercial tar sands plant. The invitations called for a much larger operation than those which had been undertaken in the past. All of the previous attempts at commercial operations up to 1960's had failed, largely because of a poor technical understanding of the process requirements, lack of suitable equipment, and lack of adequate capital. The previous record was not good. The pending new large scale plant was based on improved but not proven technology and equipment, which were developed from the pilot plant studies. In addition, the surplus of conventional oil in Alberta and low world oil prices were factors reducing the need for such a plant."

Jan 1, 1987

By Arthur Laing

"IT is indeed a pleasure to have the opportunity of addressing this group today. Not only does it give me the opportunity of meeting with representatives of what is considered by many to be the most dynamic segment of industry in Canada today, but it also allows me to talk about a subject of para-mount interest to myself, the development of the North, and to explain, if even only briefly, some of our beliefs and hopes in this regard.It is inconceivable that all lands north of the 60th parallel, representing 35 per cent of Canada's total land area, which we believe contain a great natural resource potential, will remain as an undeveloped portion of Canada. The re-sources are there, although the people and private industry are as yet not there in sufficient numbers.It has been estimated that in the west and north of Canada there are 1.6 million cubic miles of sedimentary rocks. Of this figure, 342,-000 are thought to lie in Alberta, 115,000 in British Columbia and about 1 million cubic miles are thought to lie in Canada's northern regions, the bulk in the Arctic Islands. On the basis of apparent volumes of sedimentary rock, we estimate that as much as 13 billion barrels of petroleum may lie beneath the permafrost of the North-west Territories, another 3 billion barrels in the Yukon Territory and 33 billion barrels in the Arctic Islands. This is, indeed, a rich and elusive prize, and one which must be sought with a view to fulfilling demands on the production of petroleum."

Jan 1, 1966

By J. Lee

A monolithic caisson is one of the major structural components commonly used in the construction of docks, breakwaters, and container terminal quay walls. Since the structure of monolithic caissons is typical and somewhat simple, its design process is also typical and repetitive, but still time consuming. To reduce the total time and enhance productivity, we developed a parametric model in Revit to automatically generate a 3D model of a monolithic caisson. It is designed to generate the Revit model of a caisson with concrete body and reinforcing bars. The size of caisson, the number of reinforcing bars, and the space between reinforcing bars are automatically changed when users update parameters. This paper presents how we developed this parametric family in Revit for monolithic caisson design and how it would enhance its design process.

Aug 1, 2013

By Y. Jin, H. You, H. Pang, B. Lin

Successful application of steam assisted gravity drainage (SAGD) on the recovery of land facies ultra-heavy oil in Xinjiang oilfield depends largely on shortening the preheating period with the aid of the micro-fracturing technology, which is conducted through controlled water injection to a pair of horizontal wells to create homogenously distributed microcracks in the zone between the two wells. The numerical simulation of this mechanical process is yet to be investigated. Up to date, there has been research work on rock mechanics during the SAGD production period of marine deposited ultra-heavy oilsands, but the counterpart research on land facies ultra-heavy oilsands of Xinjiang oilfield is left undone. In this regard, this study is attempted to perform numerical simulation of the fracturing process on land facies unconsolidated oilsands. With this objective, the study first investigates geological and physical identification of the field collected cores, then carries out mechanical analysis on laboratory triaixal test results, based on which numerical simulation of the fractured zone is performed. The simulation is applied through a finite element platform adopting extended Drucker-Prager constitutive model, with the parameters determined by experimental work. It is verified that hydraulic fracturing of unconsolidated oilsands generates a microcrack feature in terms of a dilative zone instead of linear apertures. The extent to which the fractured zone propagates is visually demonstrated based on the magnitude distribution of equivalent plastic strain or volumetric dilation. Evaluation of the connection of injection and production wells can possibly be determined by the expansion of the saturated region around each well. Finally, the implications on the efficiency of hydraulic fracturing in stimulation of the pay zone are investigated.

Jan 1, 2015

By Chris D. Veldhoen

If you ask most diamond drillers if they have ever encountered methane gas, the answer would probably be yes. This paper explores a serious methane gas explosion that the author experienced while diamond drilling at a northerly Ontario mine. It is hoped that by documenting this event, people may be alerted to the hidden danger posed by confined methane in underground workings. Methane gas tends to be a problem the deeper you get in any Canadian gold mine. Common procedure when encountering methane is to take readings at the collar of the hole and at different lengths from the source. Monitoring continues until the readings drop below 0.25 ppm. Methane is a tasteless odorless gas that is usually locked up in the seams of the rock or is a product of decaying organic material. Occasionally, the gas is released abruptly over a short period of time. Sometimes the gas can continue to vent for months or even years. In small concentrations, methane is relatively safe. In concentrations under 0.25 ppm methane gas is considered safe to work around. Concentrations over 0.25 ppm can become dangerous. During the summer of 2001, Chris Veldhoen was drilling at a gold mine in Ontario. There were three electric hydraulic diamond drills on the 39 meter level, approximately 5200 feet deep. Two Longyear LM 55 drills were about 40 feet apart and another LM 75 was about 2000 feet away. The two LM 55?s were set up to drill holes no deeper than 350 meters. All three drills had been set up on the same spot for more than a month. None of the three drills had ever encountered methane gas in the entire time they had been drilling on the level. On the day shift of July 13 2001, the driller on Chris? cross shift hit a small pocket of gas. He tested the hole and got a reading above 0.25 ppm. He proceeded to rope off the area with a ?DO NOT ENTER - METHANE GAS? sign and a rope denying access beyond the sign. On Saturday, July 14, Chris was instructed to install a Margo plug in the hole that was emitting methane gas. Methane is usually odorless, but occasionally when encountered underground, is accompanied by a rotten egg smell. As he walked to the drill, he could not smell methane gas. He proceeded to test the hole and got a reading of 0.22 ppm methane. This number was in the acceptable range for drilling, but he plugged the hole anyway.

May 1, 2004

By K. Shikaze

"For the last three years (1967-9) the value of the output of mineral resources in the Province of Ontario exceeded one billion dollars per year. To produce this great wealth, it was necessary for the mining industry in Ontario to dispose of an estimated 80 million tons of waste mill tailings. Some of these tailings were returned underground but the greater proportion was disposed of above ground in lakes, watercourses, marshy areas and in engineered impoundment basins. This volume of tailings, if accumulated in one location would cover an area of 1000 acres to a height of almost thirty feet. The provision of proper disposal of the waste mill tailings in a manner such that they will not create problems in the environment is one of the costs which must be borne from the extraction of such a wealth from our mineral resources. It is principally the potential water pollution which may occur as a result of the indiscriminate discharges of waste mill tailings which is of concern to the Ontario Water Resources Commission.ONTARIO WATER RESOURCES COMMISSIONThe Ontario Water Resources Commission was formed in 1956 and operates under the Ontario Water Resources Commission Act. The Act has been broadened and amended many times by amendments."

Jan 1, 1970

By T. Sakai

Present authors have succeeded in single pass large draught rolling of AZ31 and ZK60A magnesium alloy sheets below 200 °C without heating rolls by raising rolling speed above 1000 m/min. Heavy reduction larger than 60% can be applied by single pass high speed rolling even at room temperature. The rolled sheets showed fine recrystallized microstructure by dynamic recrystallization. The improvement of workability at lower rolling temperature is due to temperature rise by plastic working. In high speed rolling, almost all of the work done by plastic deformation is converted into the heat that raises the temperature of the sheet during rolling because the heat did not flow out of the sheet by conduction and radiation within very short time.

Jan 1, 2006

By J. D. Stinnette

Traditionally, airflow requirements for diesel equipment operating in underground environments such as mines and tunnels were determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations(s) or determined empirically from known quantities. In some cases, utilization factors were further used to adjust (reduce) the total airflow calculations for a diesel equipment fleet. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is currently a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. Tier IV engine standards mandate a reduction of DPM and NOx of approximately 95%, but can ventilation rates at mines with Tier IV equipment (or equivalent) really be reduced by a factor of twenty? This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and examines how they can be applied in determining a reasonable ventilation rate for Tier IV compliant equipment operating in subterranean environments.

Aug 1, 2013

By Benoît Valley

Optimization of the mining sequence in terms of economics (maximizing net present value) often leads to multi-front mining methods generating pillars. Significant resources are tied up in these pillars, but mining them is often challenging. In order to improve our understanding of rock mass behaviour while extracting these pillars, an extensive monitoring program has been designed and implemented at Vale?s Coleman mine (Sudbury, Canada). The program focuses on existing and new technologies that have potential for monitoring deformation and rock mass property changes. It includes both active and passive methods: gravimeters, multi-point borehole extensometers, fiber optic strain meters, fixed and portable three-component seismic arrays, borehole imaging and sonic logging, and, repeated LiDAR surveys. This paper reports results from an initial project phase, when only a small amount of mining has taken place. The goal was to test and compare technologies in order to assess their sensitivity, accuracy, repeatability and suitability for underground mining conditions. Value is gained by having a broad range of monitoring devices running side by side, enabling comparisons and benchmarking.

Jun 1, 2012

By Randolph A. Pax, Brian Cornish

The operation of grinding mills in an ore processing circuit is supported by monitoring the input and output variables. These can include the feed ore size distributions, ore feed and water addition rates. The outputs can include the discharge undersize density, oversize tonnage rate and the P80 of the discharge. The grinding mill performance is judged by the power draw, recycle rates and discharge grind size. Conditions inside the mill are inferred from loads cells or bearing pressures and past histories. An overall noise value is sometimes used to evaluate the load as well as the occurrence of excessive impacting of steel balls onto the liners/lifters of the mill. This paper presents results of the internal behaviour of a mill using non-contact stationary microphones located close to the mill outer shell (Pax, 2012). The noise generated by a mill can be attributed to a number of events that occur inside these mills and suitably analysed can provide real-time determinations of in-mill behaviour and can provide powerful insights into the operation of the primary comminution tumbling mills. The acoustically determined signals including a specific 'steel' signal, water hold-up, integrated area together with a classification of impact events. Specific results from case studies will show information of the trajectories inside a mill, steel to rock ratio as well as rheology effects. By incorporating a self-consistent understanding methodology for the in-mill processes from an array of microphones, the information can be used to diagnose the dynamic conditions inside a mill.

Jan 1, 2016

By J. A. Muñoz

In this work, short and long-term tests were performed using different massive mineral sulfide specimens (chalcopyrite, pyrite, sphalerite, galena, covellite and chalcocite) of museum grade and quartz of analytical grade in an acid medium containing silver ions. After attack, the samples were observed by SEM and products characterized by EDS. Parallel, massive specimens of pyrite (FeS2) and chalcopyrite (CuFeS2) were embedded in an epoxy resin, either electrically isolated or in electrical contact, and treated with silver ions in the presence of bacteria. Finally, massive chalcopyrite and pyrite electrodes were subjected to electrochemical measurements in an acid medium under different experimental conditions (addition of silver ions and inoculation). The results showed that silver deposition takes place preferentially on specific mineral surfaces: chalcopyrite, galena, covellite and chalcocite. The chemical reaction of silver ions with pyrite and sphalerite was negligible at low silver concentration (8 ppm). But sphalerite reacted with silver ions at higher silver concentration (100 ppm). In a mixture of chalcopyrite and pyrite, silver was deposited on the former surface creating new cathodic sites which sped up the electrochemical reactions of chalcopyrite dissolution.

Jan 1, 2007