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By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly

"A numerical model has been developed to study macrosegregation associated with liquid feeding in the Low Pressure Die Casting of A356 aluminum alloy wheels. The model of the wheel casting process has been implemented within the commercial CFD software package, FLUENT, using a User Defined Function (subroutine) to account for Si rejection based on the Scheil approximation. The model has been validated against temperature and microstructural data taken from a commercially cast wheel. The amount of segregation in the wheel has been shown to be significant in a couple of key areas. The implications of accounting for segregation include an improved ability to predict shrinkage porosity, fatigue performance and potentially also hydrogen porosity.INTRODUCTION The aluminum alloy A356 is widely used in the automotive and aerospace industries for various components. Examples include automotive wheels, automotive suspension components and airframe castings. Focusing on automotive wheels, Low-Pressure Die Cast (LPDC) A356 wheels offer significant design freedom and are far more aesthetically appealing to consumers than conventional stamped steel wheels. A356 wheels now dominate the market, appearing in all but the entry level offerings of the OEM manufacturers. However, they are typically over-designed to allow for the various casting related defects that degrade their mechanical performance. Thus, their potential to save weight has not been fully realized. Wheel manufacturers are under constant pressure to ensure their products meet strict mechanical requirements (ductility, fatigue, vibration), tight geometric tolerances and high aesthetic quality. The mechanical properties of the final product are determined by the microstructure – e.g. SDAS – and the defect population (porosity and oxides). Depending on their size and location, both porosity and oxides, can act as crack initiation sites reducing fatigue life (Caton, 2001; Jordan, 2010; Wu, 2015). There are a number of examples appearing in the literature (Atwood, 2000; Carlson, 2007; Lee, 2001; Yao, 2011) of numerical models that have focused on hydrogen-based pore formation that have demonstrated an ability to predict porosity formation and pore size distributions in geometrically simple castings. These models assume that the local gas species diffusion through the liquid metal to the pores is the rate-controlling factor of pore growth. Another common source of porosity is liquid encapsulation (Dantzig, 2009). As the pressure within the isolated liquid drops, pores form first due to the pressure dropping below the equilibrium partial pressure of hydrogen in solution and then second grow substantially as the pressure continues to drop falling below the vapour pressure of Al. One factor that can affect both mechanisms of pore formation is species macrosegregation, which has received comparatively little attention in die-casting."

Jan 1, 2017

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By Nancy C. Mohn

?Even though the age of many existing coal units exceeds 30 years, these units continue to perform with excellent reliability and at a competitive cost with other fossil fuel units. ?NERC data shows a consistent increase in availability for all utility coal generation ?With the opening of power markets, the challenge for coal is to produce competitive electricity while meeting increasingly stringent, and costly environmental limits. ?During the 60s and 70s, subcritical steam power plants dominated the market. The emphasis was on scale-up to larger MW size units. ?In the last decade, we have seen interest in a broader set of technologies with new drivers: ?Fluidized bed technology was developed to respond to increased environmental requirements, particularly with lower quality fuels ?Supercritical pressure units have gained interest for both fuel cost savings and reduced emissions due to higher efficiency.

May 1, 2001

By C. Larsen, R. A. Walker, A. Voth, C. Daoust

"The 3000 t/d mill at Hernia Gold Mines Inc. was commissioned in March, 1985. By Canadian standards the concentrator is highly automated, however, unlike the retrofit systems in many other plants, the Hernia process control system was installed during plant construction. This paper describes the Hernia control system beginning with system development (justification, architecture, start up, etc.), proceeding to current applications (crushing, grinding, leaching, etc.) and finally discusses some of the short term objectives for system improvement.INTRODUCTIONThe Hernia Gold Mines Inc. operation is located in the Marathon area of Northwestern Ontario. Controlled by Noranda Minerals Inc. (50.1 %), the cost of bringing the mine into production was nearly $300 million. A unique feature of the mine development was the extraordinarily short elapsed time of three years from Noranda's initial involvement to the start of milling operations. Additional background information on this project can be found in the trade literature (e.g. Tinter (1986). Scales (1987).)The Hernia concentrator is designed to process 3000 tpd of ore and commenced operation in March, 1985. Figure 1 provides a general plant flowsheet indicating the major circuits. Typical annual production statistics are included on the figure and these have been extrapolated from the available 1987 year-to-date data. Larsen and Tessier (1986) have previously described the operational aspects of the mill.In a metaphorical sense, the Hernia concentrator is like the traditional bride, ""wearing something old (e.g. the cyanide leach process), something new (e.g. a plant wide digital control system installed during construction), something borrowed (e.g. crushers from Gaspe) and something blue (e.g. the cladding on the surface buildings). While the prospect of fully undressing this bride is of considerable interest, here we choose to focus on something new. In particular, we choose to examine the process control system in some detail since Hernia is one of Canada's more highly autcmated gold mills. The control system is of interest because it has received suostantial credit for maximizing metal production and minimizing operating costs. With reference to the latter, it is worthy of note that Hem lo reports recent operating costs of less than $100 U.S./oz."

Jan 1, 1988

By V. Feldman, I. Holl, J. Zampini

"The Renard Mine, 100% owned by Stornoway Diamonds, is located approximately 250 km north of the Cree community of Mistissini and 350 km north of Chibougamau in the James Bay region of north-central Québec. The project benefits from a large and growing resource, good mining conditions, strong social acceptance, a modest environmental footprint, and the development of direct-to-mine road infrastructure. Construction began on July 10, 2014; following the completion of a 946 million CAD project financing transaction. Now completed, the mine is the first diamond mine in Québec, and one of only six in Canada, employing approximately 500 people. First ore was delivered to the plant approximately 5 months ahead of schedule on July 15, 2016. Commercial production was declared on January 1, 2017. In general, the project ramp up has been characteristic of a type 1 McNulty curve. One of the challenges during production ramp-up was a redesign of processed kimberlite dewatering (replacing the dewatering centrifuge with two stages of hydrocyclones and a dewatering screen). A processing opportunity captured by Stornoway was the design and installation of an ore sorting facility which rejected free waste rock from the valuable host rock; kimberlite. Through tackling both challenges and opportunities, Stornoway has realised and is now exceeding their original design tonnage.PROJECT DESCRIPTION Stornoway Diamond Corporation (Stornoway) was established in 2003 resulting from to a plan of arrangement between Northern Empire Minerals Ltd. and Stornoway Ventures. In 2011, Stornoway acquired 100% interest of the Renard Mine. The construction of the Renard Mine began in 2014 and achieved full production in 2017 [1, 2]."

Jan 1, 2019

By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By Y. Thibault, L. Morin, R. Cameron, D. Gould

"There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite tailings in the Sudbury area alone, with an average nickel grade ~0.8% (plus cobalt). Pyrrhotite is a highly reactive sulphide mineral that has the potential to generate acidity; consequently, it is stored in large tailings ponds that require perpetual treatment to avoid the production of acidic drainage. Re-processing this material using bioleaching technologies has the potential to recover valuable metals, while reducing the toxicity, reactivity, and acid generating potential of the remaining residues. CanmetMINING is currently developing a stirred-tank bioleaching process to recovery nickel and cobalt from pyrrhotite-rich tailings. Stirred-tank experiments have been conducted with one tailings sample over a range of pH and temperature conditions, resulting in 80 to 90% and 70 to 80% leaching of nickel and cobalt respectively in 10 days.INTRODUCTION Sulphide tailings may represent a significant financial liability for mining companies as these wastes may produce acidic drainage under some disposal conditions. As a result, the companies must post financial bonds large enough to ensure there are sufficient funds for perpetual management of these wastes. At the same time, there are billions of dollars in metals incorporated into these mining wastes waiting to become valorized. Many sulphide tailings are amendable to bacterial oxidation for metal extraction. Re-processing of tailings using bacterial leaching has the potential to recover valuable metals from waste; and reduce the toxicity, the reactivity, and the acid generating potential of the remaining residue. By reprocessing these wastes there is an opportunity to significantly reduce liabilities and financial assurance bonds, while recovering metal values. There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite-rich tailings in the Sudbury area alone with an average nickel grade ~0.8% (Peek et al., 2011) plus cobalt and copper. Pyrrhotite is separated from pentlandite concentrates by magnetic separation and flotation. It is already finely ground and has often been segregated from other tailings material, making „mining? relatively inexpensive. This represents roughly (> $100/ton) in contained value, with negligible mining costs. This paper reports on the development of a stirred-tank bioleaching process for recovering nickel and cobalt from pyrrhoitite-rich tailings, which is currently underway at Canmet MINING."

Jan 1, 2017

By H. Salamanca

HighService has developed different equipment using wireless technology and machine vision systems that were specially designed to allow 1) the online determination of the SAG mills liner&apos;s service life, 2) the automatic detection of a missing dipper tooth in mineral extraction shovels, 3) the reduction of accident risk potential in the mineral transportation within the mine, and 4) the reduction of collision risk potential between shovels and wheel dozers during mineral extraction. For the development of all these systems at HighService, extensive research has been done in radio frequency and image processing fields. The integration of both technologies with the expert knowledge of the company on the typical harsh environment conditions of the mining industry has led to the development of heavy duty equipment that tolerate the extreme mechanical requirements of SAG mills and electrical mining shovels.

Jan 1, 2007

By D. W. Ginsberg, D. Cieplinski

"The lifetime cost of a material handling system, or any mine system, can be reduced through the application of quality engineering. Dynamic simulation is a powerful tool that can be used to enhance the experience and ingenuity of the design team. It cannot only de-bottleneck the system to improve system productivity, but also define critical design criteria to eliminate over-design and reduce capital cost. Eliminating over-design also reduces operating costs by lowering component replacement costs and by ensuring all parts of the system operate at a higher utilization and efficiency. IntroductionA mine owner’s profitability is improved when a mine is developed at the lowest lifetime cost. This cost relates not only to capital and operating costs, but also, to a great extent, on the efficiency and reliability of the operation. These factors are tied directly to the quality of the engineering which depends on the experience of the engineers involved, and their ability to apply known system information in a rational and constructive manner.It is becoming apparent that it is increasingly more difficult to deliver the quality of engineering expected and needed to provide attractive lifetime costs using traditional design methods. Historically, system information has been evaluated based on a limited amount of information to which global rules-of-thumb and the engineer’s personal experience were applied to develop design criteria. However, market forces are dictating that more system parameters be defined and that they be defined more accurately so that the most economical system can be developed. This increase in the volume of information and the need for more accurate predictions is straining, if not already exceeding, the ability of engineers to apply simple global rules of- thumb and to combine all the information in a rational, comprehensive and representative set of design criteria. Furthermore, as proposed system production rates increase beyond established industry practice, the extrapolation of the engineer’s experience becomes more difficult and increases the risk in the proposed design."

Jan 1, 1998

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

"ALTHOUGH Canadian metallurgists have long been active in research, the scope of the work was somewhat limited until the be-ginning -of World War II. The rapid industrial development of Canada during the past ten years has been accompanied by .a similar upsurge in research. However, the wide geographical distribution of the research centres has made it difficult for the individual research workers to meet together and to exchange ideas or even to learn what projects .are being investigated or the nature and extent of the facilities available for work of this kind.The purpose of the present symposium is to assemble data relating to projects under investigation and the facilities employed at the various metallurgical research laboratories in Canada, thus providing some measure of correlation so that workers in different locations may learn what kind of work •is being .done at other points throughout the country.In reporting the symposium it has not been possible to reproduce the papers in full, but excerpts have been selected that give the essentia1 data."

Jan 1, 1952

By C. Moreland

Fluidized low-temperature carbonization of coal, a recent development, offers a possibility of reducing fuel costs of coal-burning electric ?generating plants. The Research Council of Alberta have built a pilot plant and are conducting a programme to -develop a carbomzation plant for Alberta sub-bituminous coals which will produce char suitable for use as a .boiler fuel, and tar of a potentially high value as a ?chemical raw material. The economies of the process as a whole, and the value of the tar, have yet to be assessed.

Jan 1, 1958

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

By E. Eccleston, E. Gardner, F. Letarte, R. Schonewille

"In 2005, after nearly a decade of process development and feasibility work, the commercialization of the Falconbridge Nickel Smelting Technology (NST) began in earnest with the design and construction of a grassroots ferronickel plant at Koniambo Nickel in New Caledonia. The NST process was developed as an alternative to the conventional Rotary Kiln-Electric Furnace (RKEF) process for production of ferronickel from saprolitic nickel laterite ores. The NST process promised environmental and energy efficiency advantages over the conventional route. A key step of the NST process involves fluidized bed pre-reduction of calcined laterite ore using direct injection of pulverized coal as the reductant. Two parallel fluidized bed reduction roasters (FBRs) were installed at Koniambo Nickel, each designed for a maximum capacity of 4,200 MTPD of calcined nickel laterite ore. This paper describes the process development and scale-up of the fluidized bed pre-reduction process, the design challenges associated with the prototype commercial units, and the current status of the FBR operation at Konaimbo.INTRODUCTION In the mid-1990s, Falconbridge began to develop a new flowsheet for production of ferronickel from nickel laterite ores. The process that developed came to be known as the Falconbridge Nickel Smelting Technology (NST). The flowsheet, which is particularly appropriate for saprolitic ores, involves several major unit operations, including: drying in a hammer mill-flash dryer, calcination and preheating in a flash calciner, pre-reduction in a fluidized bed reactor, and smelting in a DC arc furnace to produce the ferronickel product. This paper focuses on the fluidized bed pre-reduction step of the process and provides an overview of the process chemistry, laboratory and pilot plant development work, scale-up and commercialization of the pre-reduction step, and the results obtained in the prototype commercial units."

Jan 1, 2017

Despite the fact that mined minerals and gemstones have allowed human beings to continuously improve their standard of living throughout the ages, mining has also been implicated in violent conflict for two principle reasons. The first is that mineral resources have been used or traded to conduct or finance violent conflict from small to large scales. The second is the substantial social, economic and environmental changes that occur in a community or a region as a result of mining activity which can either precipitate or re-awaken latent conflict. A modern complication of mining-related violent conflict is the trend for activists, international NGOs and intergovernmental organisations (e.g. the United Nations) to regard any human consequences of resource extraction in terms of Human Rights violations. Acknowledging but not labouring the Human Rights implications of mining-related violent conflict, this paper explores whether or not there is a relationship between the actual or perceived value of mineral resources and the level of violence that occurs in mining-related conflicts. Key to the investigation is a mapping exercise of mining related conflict from 2005 ? 2012: to see where mining related conflict is happening; to identify precipitant causes of mining related conflict; and, to discover what correlation ? if any ? there might be in the degree of violence and the value of the mineral(s) implicated. Findings of the analysis are presented in this conference paper.

Aug 1, 2013

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By Y. Nishida, Y. Nara, T. Ishida

Understanding time-dependent deformation and fracturing in rock is essential, because the information of the long-term stability of rock is required for many sub-surface structures excavated in a rock mass. Time-dependent fracture propagation has been invoked as a potential key mechanism responsible for the increase in seismicity preceding earthquake ruptures. In engineering projects and in preventing natural hazards, the study of time-dependent fracturing is necessary. Subcritical crack growth is one of the main causes of time-dependent fracturing in rock. For silicate rocks, subcritical crack growth has been investigated by various researchers. It has been clarified that surrounding environmental conditions (temperature, humidity, and existence of water) have strong influence on subcritical crack growth in silicate rocks. Therefore, the information of subcritical crack growth in silicate rocks has already been enough. On the other hand, information of subcritical crack growth in carbonate rocks is not enough. Especially, the influence of surrounding environment on subcritical crack growth in carbonate rock has not been clarified yet. In this study, we investigate subcritical crack growth in carbonate rock experimentally using a fracture mechanics testing method. Marble obtained in Skopje in Macedonia is used as a carbonate rock sample. The Double Torsion method is used to measure the crack velocity and stress intensity factor. Especially, influence of water on subcritical crack growth in Macedonian marble is investigated. It was shown that the crack velocity in water is much higher than that in air at the same temperature. Based on the results of subcritical crack growth measurements, the long-term strength is evaluated for marble. It was clarified that the long-term strength in water is lower than that in air in marble. It is concluded that water has a remarkable influence on subcritical crack growth in marble. It is also considered that the long-term stability of carbonate rock masses should be ensured in a dry environment.

Jan 1, 2015

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By Sarah Belair, Gauthier Deblonde, Valerie Weigel, Alexandre Chagnes, Gerard Cote

"Niobium and tantalum are strategic metals for electronic and alloys industries. They are produced by pyrometallurgy and hydrometallurgy but most of the niobium and tantalum production processes are not environmentally friendly. For instance, in the hydrometallurgical route, niobium and tantalum separation can only be achieved by liquid-liquid extraction in the presence of hydrofluoric acid by taking advantage of the difference in niobium(V) and tantalum(V) speciation in fluoride-based media. Therefore, the environmental footprint of hydrometallurgical processes for the production of niobium and tantalum could be clearly lowered by replacing HF or NH4F by greener media such as alkaline solutions in which high solubility of niobium(V) and tantalum(V) can be achieved.The development of such new efficient and environmentally friendly hydrometallurgical processes requires a fine description of the physicochemistry of niobium(V) and tantalum(V) in alkaline solutions. Unfortunately, literature data show a huge discrepancy on niobium(V) and tantalum(V) speciation in such media. This paper gives a brief overview of the niobium(V)-tantalum(V) production processes and paves the way to the development of alternative processes in alkaline media by presenting and discussing recent advances in the physicochemistry of niobium(V) and tantalum(V) in these media.INTRODUCTIONNiobium and tantalum are strategic metals since they are used for the production of alloys and super alloys, capacitors and magnets in strategic industries such as electronic, aeronautics and automobile. The main sources of niobium and tantalum are given in Table 1."

Jan 1, 2016