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By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013

By M. Kalin

Tailings deposits are frequently the source of ground water contamination due to the transport of contaminated tailings pore-water. If amendments to tailings covers could be made to facilitate a precipitation reaction and halt or reduce the generation of acid in pyritic tailings, the quality of pore-water quality would be improved which would in turn reduce the production of contaminants. The effects of phosphate wastes, added to base-metal mine tailings in Newfoundland, Canada, were tested. Laboratory and field experiments determined the effects of different mixing ratios of phosphate wastes to tailings volume (1:4, 1:8, 1:12 and 1:20, dry weight) for a total period of 3.2 years. The addition of phosphate at ratios of 1:4 to 1:12 substantially increased the pore water pH, and reduced both acidity and Zn concentrations. These results suggest that addition of phosphate wastes to tailings covers can reduce acidity generation and improve tailings pore-water quality.

Jan 1, 2004

By J. H. Ambrose

Introduction The copper smelter of the Hudson Bay Mining and Smelting Company, Limited was constructed to handle the concentrates produced by the concentrator, the residues from the zinc plant, concentrates from Sherritt-Gordon Mines, Limited, and other custom material that might be available. Construction work was started in 1929 and the first concentrates were smelted in November, 1930. From that time until June, 1931, the operations were more or less of an experimental or tuning-up nature. In designing the smelter, it was believed the following tonnages would be available for smelting per day: Copper Tons Content H. B. M. & S. Co. concentrates 331 14.0 per cent H. B. M. & S. Co. zinc plant residues 77 2.5 per cent Sherritt-Gordon concentrates 200 20.0+ per cent Consideration was given to wet-smelting the charge, but, in order to give greater flexibility to the operation, it was finally decided to roast the concentrates before smelting. Briefly, the smelter equipment consists of three Nichols-Herreshoff roasters, one reverberatory furnace, two Peirce-Smith converters, a Walker casting wheel, and a four-unit Cottrell plant, two units' for the roaster gases and two for the converter gases. A general plan of the smelter is shown in Figure 1. Prior to the commencement of smelter operations, a stockpile of about 9,000 tons of concentrates had been built up by the concentrator and the old pilot-mill. The zinc plant was in operation, but the equipment for drying the residues at the smelter had not been completed. Sherritt-Gordon did not commence their shipments of concentrates until April, 1931. The only flux available was barren sand from a pit ten miles south of Flin Flon, adjacent to the railway. Several small deposits of metal-bearing siliceous ore had been discovered in the district, but none of these were sufficiently large to be considered as a source of smelter flux. At the beginning of March, 1931, the entire stockpile of concentrates had been consumed, and available tonnage for smelting was limited to the daily production of the concentrator.

Jan 1, 1935

By M. Kataoka, Y. Obara

It is known that compressive strength and tensile strength of rocks vary significantly with specimen size. Rocks are composed of crystals and grains in a fabric that includes flaws such as microcracks, grain boundaries and pores. As the likelihood of including severer flaws becomes greater for a larger specimen, the strengths are small. On the other hand, the size effect in the fracture toughness of rocks has not been made clear until now because there are few studies focused on it. In this paper, Semi- Circular Bend (SCB) test was performed using Kimachi sandstone with various specimen sizes. A shape of the specimen is a semi-circular disc with an artificial notch. The specimens were prepared with various thickness t and radius r as the following two groups; t was changed from 10 to 37.5 mm with r = 37.5 mm in the specimen of group (a), and r was changed from 12.5 to 150 mm with t/r = 0.8 in the specimen of group (b). As a result, there was no significant change in the fracture toughness with different t. On the other hand, the fracture toughness increased with increasing r and converged on a certain constant value in a range larger than approximately 70 mm of r. Consequently it was clear that the size effect in the fracture toughness of the sandstone exists.

Jan 1, 2015

By Li Qihou, Li Yuhu, Liu Zhihong, Liu Zhiyong, Yang Xiaofeng

Scorodite samples were synthesized, in adding or without crystal seed respectively by using Atmospheric Scorodite Process (ASP), Hydrothermal Scorodite Process (HSP), and Improved Atmospheric Scorodite Process (IASP) individually; and their crystal structure, crystallinity, morphology, particle size, specific surface area, Fe/As mole ratio, as well as the leaching stability were characterized, aimed to reveal the relationships among the synthesis methods, the compositional and structural properties, and the leaching stabilities of scorodite. The results show that synthesis methods have significant effects on the compositional and structural properties of scorodite. Scorodite samples of high crystallinity, small specific surface area, and low Fe/As mole ratio, possess high leaching stability. The order in the leaching stability of scorodite samples synthesized in this study is as follow: ASP<HSP<IASP. Scorodite particles in the sample synthesized by IASP without crystal seed are in large sizes and of pyramidal morphology enclosed mainly by crystal planes of {111}; and the sample possesses the crystallinity of 84.5%, the particle size (D50) of 28.2 m, the BET specific surface area of 3.72 m2/g, and the Fe/As mole ratio of 1.05; after leaching this sample by using acetate buffer solution of pH 4.95 for 10 days, the total arsenic concentration in the leaching solution is merely 1.14 mg/L.

Jan 1, 2015

By D. Kulchyski, R. Thibault, D. Lamoureux

"Mine tunneling applications are sensitive to the leakage and friction performance of ducting systems. Improvements in performance can help project economics through reduction in drift height, booster fan spacing, fan electrical power requirement, and deferral of ventilation raise construction. Semirigid plastic ducting has enjoyed significant adoption in mine tunneling in recent years. This paper explores technical properties and performance aspects of this relatively new material application.INTRODUCTIONUnderground mining projects are sensitive to mine development cost and schedule to meet first production—both of which are defined to a substantial extent by mine access construction. The very nature of mine access development requires driving accesses into new areas and even mechanized and automated tunneling methods require ventilation. Until underground airways are connected, allowing a flow-through circuit, ducted ventilation is required to establish ventilation within any single-access (i.e.: dead-end) heading. See Figure 1 as an example of ducted ventilation. Improving performance of ducted ventilation systems impacts project cost and schedule in several ways:For drifts whose height is defined by overhead clearance above haul trucks or tall equipment, smaller diameter ducting will decrease heading size.With higher ventilation flows, activities can be less ventilation-constricted; secondary headings can be worked without restriction, which improves schedule.Given the ability to provide more air for a given fan power, blasting gasses can clear the face and mine more quickly so crews can return to work more quickly - allowing higher advance rates.Lower electrical costs – both due to lower power consumed by fans and with the requirement for fewer electrical stations to power booster fans."

Jan 1, 2019

By L. S. Beck

"IntroductionThe Beaverlodge District is an important mineralogenic province of pitchblende and occupies about 1300 square kilometres centred on Beaverlodge Lake near the north shore of Lake Athabasca in northwest Saskatchewan (Fig. 1). Uranium City is the main settlement of the area and is serviced by scheduled aircraft from Edmonton, some 700 km to the southwest, and from Prince Albert which lies a similar distance to the south.During the summer, boats and barges supply the area from the railhead to Fort McMurray via the Athabasca River and Lake Athabasca, a distance of about 550 km. For the past few years a winter road has been maintained across Lake Athabasca to Cluff Lake to connect with Highway 155.The topography of the area is typical of the Precambrian Shield with generally low relief and a disorganized drainage of numerous lakes separated by hummocky rock ridges, muskeg and drift-covered areas. Local topography in the area is, however, extremely rugged, particularly south and east of Beaverlodge Lake, where resistant rocks form prominent hills and ridges extending as much as 180 m above lake level. Rock exposures are abundant and form over 50 per cent of the land area.History of Exploration and DevelopmentEconomic interest was first aroused by Tyrrell (1896) who described an occurrence of iron formation at Fish Hook Bay; however, subsequent evaluation of the deposit indicated it to be uneconomic."

Jan 1, 1986

By Y. Chengxian

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005

By Y. Chengxian, F. Yaorong, Xinzhe. L.

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005

By C. P. Jenney

"Exploration for copper, in a region of 7,000 square miles on the Arctic coast between longitudes 114 and 118 degrees west, has covered a period of nearly 200 years. Occurrences of native copper, used by the natives for tools and weapons, have been reported since the early part of the eighteenth century. In J 771 Samuel Hearne of the Hudson's Bay Company, in the course of his classic 3-year journey from Fort Churchill, became the first white man to see the deposits, and incidentally the first to reach the Canadian Arctic coast by land. During the next 140 years the deposits were mentioned by every explorer and traveller who passed through the area. A good historical summary of this literature has been presented by Tyrrell (1912).In 1911-12 the Douglas-Sandberg party did the first geological mapping along the Coppermine River and Dismal Lakes (Douglas, J., 1913; Douglas, G. M., 1914), and described the copper occurrences there. In 1914 J. J. O'Neill (1924) of the Canadian Arctic Expedition investigated the showings on Bathurst Inlet. In 1929-31 two Canadian exploration companies sent prospectors and geologists to the area (Gilbert, 1931; Norrie, 1931; Duncan, 1931). Since that time only brief references have been published (Kidd, 1931; Stockwell and Kidd, 1931; Lord, 1941, 1951; Washburn, 1947). In 1943-45 an area of more than 1,500 square miles was prospected by American Metal Co. of Canada, Ltd., under the direction of the writer. Forty-nine showings were examined; seven of these were mapped in detail by plane-table and two were sampled by 27 short diamond drill holes totalling 3,061 feet. All holes were in permanently frozen rock, and the deepest vertical distance reached was 206 feet. Five groups of claims were staked. These later lapsed, but one of the groups was restaked in 1951, and assessment drilling and some trenching were carried out in 1952-53. Results were disappointing, and the claims have been allowed to lapse.The area is within the Arctic Circle, northeast of Great Bear Lake and 360 miles north of Yellowknife on Great Slave Lake. For exploration purposes, access is by aircraft from Yellowknife. During the short open season heavy freight can be brought by sea to Coppermine at the mouth of the river, either from Aklavik at the mouth of the Mackenzie or around Alaska. Concentrates would have to be moved by these routes.Although none of the deposits so far found is mineable under present conditions, the total volume of copper in the numerous showings marks the district as a major area of copper mineralization, which may some day be of economic importance."

Jan 1, 1949

By R. E. Ray

"As real estate for new development in urban settings becomes scarce, commercial high rises are being constructed above open passenger rail tracks and vehicular roadways. Rail and roadway overbuilds are treated as tunnels requiring emergency ventilation systems for train or automobile and truck fires. The value of floor space in residential and office towers poses challenges to engineers responsible for designing fan rooms and shafts for tunnel ventilation systems within the towers. This paper describes a case study of the unique incorporation of tunnel ventilation fan plants in the overbuild structure of a passenger railyard and an adjacent roadway.INTRODUCTIONTunnel ventilation systems are required for passenger rail and transit (subway) tunnels by the NFPA 130 Standard for Fixed Guideway Transit and Passenger Rail Systems, and the NFPA 502 Standard for Road Tunnels, Bridges, and Other Limited Access Highways requires tunnel ventilation systems for vehicular (road) tunnels. Passenger rail and transit (subway) tunnels are typically ventilated with a series of shafts placed longitudinally along the tunnels to provide piston relief for normal train operations and emergency ventilation of train fires utilizing reversible axial flow fans. The shafts are incorporated in dedicated ventilation buildings that house the tunnel ventilation fans and starters, switchgear to power the fans and other equipment and systems in the building, Programmable Logic Controllers (PLCs) to control fan operation with Supervisory Control and Data Acquisition (SCADA) software, and HVAC fans and ductwork to ventilate the spaces in the building. These ventilation buildings may also provide access to the tunnels below with ingress/egress stairs for use by first responders and firefighters entering the tunnels and train or transit system passengers exiting the tunnels in an emergency. A photograph of a passenger rail ventilation building that encompasses four tunnels is shown in Figure 1."

Jan 1, 2019

By Shamia Hoque, Charles Q. Jia

Smelter slags contain valuable metals such as Co, Ni and Cu in proportions of less than 1 wt% along with about 40 wt% of Fe and 15 wt% of Si. Although aqueous SO2 is a versatile lixiviant for transition metals, dissolving the slag in aqueous SO2 produces solutions in which Co and Ni concentrations are lower than that of Fe due to the low metal/ Fe ratio in the slag. To develop the options for increasing Co and Ni concentrations the solubility of slag in aqueous SO2 was studied experimentally and theoretically using OLI, a software package for simulating electrolytes chemistry. The modeling results correlated well with experimental results. The model suggested that the species dominating the system was FeSO3, which would precipitate out as FeSO3.3H2O when the concentration of Fe+2 reached 1.22 molal and the concentration of S032- was beyond 1.4 molal. In the experiments the influence of pH and solids loading were studied. The leach solution obtained after dissolution of slag at 50% solids loading had a pH of 1.85. On raising the pH to 3, precipitation occurred. Analysis of the solution collected after the addition of alkali showed over 50% reduction of Fe, Co and Ni. XRD analysis revealed the precipitate to be of amorphous nature due to the silica present. The analysis confirmed that the precipitate was mainly FeSO3.3H2O. The paper also discusses the potential impact of the slag on the environment.

Jan 1, 2004

By Kr. N. Karparov

Measurements made with high precision GPS landmarks and geotechnical radar Reutech MSR- 300 associated with the observed movements in the north face of Assarel Mine, where on a horizontal distance of 50 m, 2 groups of landmarks indicated different deformation behavior. Measurements are made in order to confirm the applicability of the radar system in regions of complex geotechnical conditions. The standard deviation of each landmark is used as an accuracy standard between the separate measurements of the deformation vectors made by the high-precision GPS system for each landmark. A very good correlation between the displacement vectors can be seen based on the measurements made with the high-precision GPS system and the measurements made by the radar system MSR-300. Geological, engineering geological and hydro-geological conditions of the area of concern are discussed in this paper. The measured deformations and the FLAC/SLOPE analysis show similar results. In the paper is discussed their local character and their sensitivity to other geotechnical and hydro geological conditions.

Aug 1, 2013

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp&apos; s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By R. Burns, A. I. A. Salama, M. W. Mikhail

"Large amounts of oil sand tailings are produced in the Fort McMurray area, including sand, clays, and misplaced bitumen. The objective of the present study (as part of the overall engineered tailings program) is to select and evaluate the role of hydrocyclones in removing most of the solids from the tailings slurry and producing an underflow product containing about 75% solids.Multistage cyclones were evaluated in pilot plant tests. Slurry feeds with different percents solids and increasing ratios of superfines (–44 µm) were used in testing multistage cyclone circuits. A two-stage Linatex separator circuit gave high recovery to the underflow of 98.8% to 99.6% by mass with the desired high solids content in the underflow of 73% to 75% by mass. Changes in feed solids content (20% to 50%) had little or no influence on cyclone underflow recovery and solids content. The keys to achieving such results were the apex control mechanism and operation at relatively low feed pressure (<60 kPa for 23 cm F cyclone) when the feed solids content was high. Increasing superfines above 7% by mass in the feed resulted in a significant reduction in the recovery to the underflow, probably due to the heavy medium generated by excessive amounts of clays in the cyclone. Pilot plant results were better than those predicted by available cyclone simulation models in terms of recovery and solids concentration in the underflow.Increasing cyclone diameter from 23 cm for the Linatex separator to 51 cm for the Krebs cyclone appears to have little or no effect on size cutpoint."

Jan 1, 1997

By Rafic Moubarac

FRP (Fiberglass Reinforced Polyester) equipment has been used in different and several applications during metals processing and extraction, and the hydrometallurgical process. Case histories of such equipment will be shown of major projects worldwide.

Jan 1, 2015

By Jean-Yve Tremblay, Michel Prud'homme

"IntroductionIndustrial minerals include a group of more than fifty minerals which are marketed into almost all the sectors of industry; they are the backbone of many manufacturing industries. Table I shows major end-uses for industrial minerals in manufacturing sectors.At Energy, Mines and Resources, industrial minerals are divided in three major categories: (I) agro chemicals and chemicals, (2) construction mineral s, and (3) ceramics and specialty minerals. A listing of the major groups of minerals is shown in Table 2.Agro-chemicals and chemicals are sold on the basis of their chemical content and purity. Construction minerals or structural minerals are distinguished by their performance as low cost and bulky commodities. Ceramics and specialty minerals are performance-specific and are sold for their property on imparting functions on end-products. Industrial minerals have unique characteristics that are useful in many stages of processing; from crushed size to micronized fillers a single mineral ca n serve a broad range of industries because of its intrinsic properties.The Industrial Minerals Industry in CanadaCanada has a large industrial minerals base and is a world leader in the production of some of them. The total value of product ion of these minerals has grown by 115% over the last 10 years despite the misfortune of asbestos.Industrial minerals have shown remarkable growth in the past 20 years at an average annual rate of 9.2%, compared to 7.8% for metallic minerals. In 1986, the value of industrial minerals rose to $4.9 billion, or 14% share of the Canadian mineral production. Figure I shows the value of production of the mineral industry for the period 1966-1986.The leading segment in industrial minerals segment since 1976 is the chemicals and agro-chemicals sector which has an average annual growth rate of 5.75 % in terms of value of production. During the same period, the growth rate for the whole Canadian mining industry was 1.37% per annum. The chemicals and agro-chemical s sector increased its contribution to the total value of production of 2% to 6070 despite the growing share of fuel minerals with 59%."

Jan 1, 1988

By David J. Kerr, Robert Mason

"From1927 to1989, the Hornemineproduced53.7 Mt of ore grading 6.1 g/t Au and 2.2% Cu from two large volcanogenic massive sulphide deposits composed primarily of pyrrhotite, pyrite and chalcopyrite. The ore bodies were hosted by a package of chlorite-sericitealtered epiclastic rhyolite tuffs which were deposited in a narrow palaeo-graben located on the flank of a major felsic volcanic centre. M ineralizingfluids percolated upward through the permeable footwall rocks and were further focussed along syn-volcanic, graben-bounding faults. Sulphides were deposited by a process of sub-seafloor replacement of the rhyolite tuffs.Gold-copper-(zinc) mineralization, including ore zones mined between 1985 and 1989 as the REMNOR ore zones, is present throughout the 900 m of felsic volcanic stratigraphy at the Horne. All the deposits were formed by syn-volcanic hydrothermal processes active during felsic volcanism. There is no evidence to indicate that any economic gold mineralization was introduced by a post-volcanic hydrothermal episode.RESUMEDe 1927 a1989, /amineHorneaproduit53.7 Mt de minerai avec une teneur de 6.1 g/t Au et 2.2% Cu provenant de deux grands amas de sulfures massifs volcanogeniques comprenant esentiellement de la pyrrhotite, de la pyrite et de /a chalcopyrite. Ces gites font partie d'une séquence de tufs rhyolitiques epiclastiques chloritises et sericitises qui ont ere déposes dans un paleo-graben étroit situe sur le flanc d' unimportant centre vo/caniquefelsique.Lesfluides mineralises ont circule de bas en haut a travers /es roches perméables sous-jacentes; ils ont été également canalises par les failles syn-volcaniques en bordure du graben. Les sulfures se sont déposes par remplacement des tufs rhyolitiques immédiatement et sous /e plancher océanique.Les zones minéralisées en or et cuivre (±zinc) - y compris celles qui ont ere exploitees au cours de l’opération Remnor (1985-1989) - se retrouvent, sans discontinuité, à travers les roches volcaniques felsiques dont l' epaisseur atteint 900 m. Ces gites se sont formes par le biais d' un processus hydrothermal qui ag issait pendant le volcanisme felsique. II n'y a aucune évidence de minéralisation aurifère d'importance économique qui soit postérieure a l' activité hydrothermale syn-volcanique."

Jan 1, 1990

By Ju-hyung Ha

New automated curing system for mass concrete has been developed to improve the quality of concrete structure and to save construction time and cost. The principle of this system is the automated water circulation system of heated curing water. Applied curing water on the surface of mass concrete keeps the temperature difference between center and surface of the structure below the threshold of specification. Mock-up test and field application have been conducted to investigate the performance of this system. In the results, new automated curing system reduced the chance of thermal crack occurrence and improved quality of the concrete structure as well.

Aug 1, 2013

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019