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Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain 's model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By J. Jung, W. Keller, A. Zucht

"The agitator design for nickel high pressure acid leach autoclaves (HPAL) is critical with regard to the process result, i.e., the recovery rate. Further considerations during the design phase are the avoidance of acid hot spots which reduce the lifetime, due to corrosion of the wetted parts, including components manufactured from titanium. Besides the process knowledge to design HPAL autoclaves, tools such as, Computational Fluid Dynamics (CFD) supplemented by lab testing allow the design of optimized agitation systems. This paper describes the effect that different feed point locations have on instantaneous blending of the reactants. Furthermore, experiments and CFD show where abrasion issues might occur and how to obtain information about the static and dynamic forces acting on internals. We show how simulations can be validated by lab testing to ensure that the CFD models are applied in an appropriate way.INTRODUCTIONAgitated systems in hydrometallurgical processes have to comply with multiple process tasks and in many cases have to withstand extreme operation conditions such as pressure up to 50 bar, elevated temperatures of up to 250°C and exposure to very acidic or alkaline environments and abrasive ores. The process tasks range from instantaneous mixing of reactants, homogeneous suspensions of up to 65% wt. solids with coarse and heavy particles, enhancing the solid-liquid mass transfer for leaching, dispersing large volumes of reactants (gas-liquid, liquid-liquid mass transfer) and moreover to transport generated heat e.g., from exothermic reactions through the vessel walls or internal heat exchangers if required. For economies of scale, agitator systems have reached sizes of 5000 m³ for large open leach tanks with impeller diameters of approx. 6 m, while autoclaves nowadays have exceeded 5.5 meters in diameter with a power demand for a single compartment drive between 300 - 400 kW. In parallel all process industries require a more efficient use of resources, to generate less by-products and higher yields, while ore-bodies tend to be less qualitative and new process routes (e.g. direct leach) are developed. Besides all these facts the mixing solution must be robust and economic. In this paper we want to address our approach in the development and designing of HPAL agitation equipment."

Jan 1, 2012

MR. J. F. MYERS, Consulting J3eneficiation Engineer, Greenwich, Conn.: In the written discussion contributed by Mr. F. C. Bond in item ( 2) (page 515), speaiking about the significance of the ratio of mill diameter to the make-up ball diameter, he states: "When this ratio exceeds 100 the power and capacity of the mill are de-creased"; and the paragraph ends with a reference to the 30 per cent ball volume "with some de-crease in mill capacity". I believe this broad statement is incorrect. When we are dealing with a non-cataracting mill, pre-ceded by a good rod mill, there is a slight increase in capacity, but the power does drop. The second point that I consider needs consideration is Mr. Bond's item (8), Proper Mill Speed (page 516). This paragraph should be qualified to cover single-stage mills only. It does not apply where a rod mill is followed by a non-cataracting ball mill. The statement as is, with no qualification, gives an erroneous idea of proper mill speeds.

Jan 1, 1957

By A. Zrimsek, G. Vingas, R. Wolke

IN 1952, prompted by the great demand of the Canadian drilling and foundry industries for sodium bentonite, the Geological Department of Magnet Cove Barium Corporation, Limited began an extensive search for bentonite deposits throughout western Canada. Their efforts were rewarded in 1958, when substantial deposits of high quality material were found approximately 100 miles southeast of Edmonton, Alberta. The bentonite material, a part of the Edmonton formation in the Upper Cretaceous, is located approximately nine miles south of the town of Rosalind. The land where the bentonite lies has in places .been eroded by stream and glacial action to form a wide gully, convenient for strip mining methods (see Figure 1). The bentonite bed is almost flat-lying, dipping to the southwest at approximately 12 feet per mile. The main bed is 8 to. 10 feet thick and is covered with 15 to 25 feet of overburden. Before stripping, the area is drilled and sampled to evaluate the quantity and quality of the bentonite.

Jan 1, 1962

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968

By J. C. Ingles

"A new technique is in the process of revolutionizing inorganic chemical analysis. Galled atomic absorption spectrophotometry, it combines the use of a special light source, a flame, and the equipment of conventional spectrophotometry, to provide a quick, reasonably accurate method for the determination of a large number of elements.This paper outlines the principles on which it is based, describes the commercial instrumentation"" available for exploiting it, and. summarizes current applications in process metallurgy."

Jan 1, 1966

By D. C. McKechnie

To the examining engineer, the ever-recurring problem involving the valuation of ore in a prospect presents at different times highly divergent aspects- some entirely physical or mathematical, others essentially personal. The majority of the problems discussed in this paper are obvious to the engineer, and need little elaboration. By the prospector and the general public, however, a number of these questions are often and completely over-looked, or else approached in such a way as to produce final results which are, to say the least, misleading and at times decidedly erroneous. While the purpose of this paper is to deal with prospects or potential mines, many of the problems considered apply equally well to mines with developed ore reserves. As the usual showings on a prospect consist chiefly of a few open-cuts and a limited amount of underground development work, an estimation of the actual ore reserves is a question of minor import, and seldom enters appreciably into an estimation of the probable value of the particular property. The physical valuation of a prospect mainly involves the consideration of such subjects as the general geological features exposed, the strength and type of mineralization, the width and persistence of any associated veins, shear zones, fractures or contact zones, together with the possible grade, size, and continuity of any ore-bodies that may there occur.

Jan 1, 1930

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By M. Sugamata

Creep tests were carried out for friction welded joints of AZ31 magnesium alloy rods under an ambient atmosphere at temperatures between 423 and 573K. Tensile tests were also performed at temperature from room to 573K. The obtained results were compared with those of the base metal. AZ31 extruded rods of 19 mm in diameter were joined by brake type friction welding machine. Creep and tensile specimens were machined out of the welded rods. The tensile strength of the joints was almost the same as that of the base metal at room temperature. However, joint efficiencies of welded joints were about 92% at above 373K. The elongation of welded joints was lower than those of base metal. The welded joints showed appreciably higher minimum creep rate and shorter rupture time than the base metal at all the tested temperatures and initial creep stresses. Creep and tensile rupture of the joints always occurred at near the weld interface. Thus, friction welded joints of AZ31 alloy showed lower creep and tensile strength than the base metal at elevated temperature.

Jan 1, 2006

By Z. D. Hora

Traditionally, industrial minerals in British Columbia comprise about 10 per cent of the combined value of mineral, coal, petroleum and natural gas production. Over the years a wide variety of industrial minerals have been produced in British Columbia, often with a different level of marketing success. For some products such as building stone, common brick or expanded shale, once strong demand gradually disappeared; for others such as asbestos and barite, new discoveries or new industrial activities created demand and new markets. For yet other minerals such as fluorite, talc and perlite, wider use has been prevented by the small size, poor quality or remote locations of the deposits. Bentonite (1926 to 1944-as a by-product from coal mines) Building stone (intermittently since the mid-1800s) Chromite (1918 and 1929) Over the past years, the list of industrial minerals produced has been expanded to include several new commodities: glassgrade silica sand, magnesite, pumice and silica for ferrosilicon and silicon carbide manufacture.

Jan 1, 1984

By A. K. Debnath

The water resource is key to survival of the mankind and this resource is now becoming critical in many parts of globe including India. As per an assessment of Central Ground Water Board (CGWB) of India, a huge shortfall of about 58 billion m3 of water is anticipated by the year 2050. In order to counter this shortfall, there is thrust from Government of India to adopt water conservation measures. National Environment Policy, 2006 of Government of India also stresses upon the need to take up water conservation measures for water security of the country. The coal mines in India provide an excellent opportunity to take up water conservations measures therein. The mine water is not acidic unlike western countries and it conforms to the prescribed regulatory standards. This nature?s gift is utilized in Coal India Limited by allowing mine voids to get filled with mine water. The net recharge potential of the opencast mining area is found to be about 5% in comparison to 2% in non-mining area offering good prospects for ground water recharge. The seasonal rainwater is also diverted into mine voids left at the end of mining operations which act as huge reservoirs/ pit lakes for storage of the water. They also serve as surface water bodies for recharging of water table in the surrounding areas. The area and space left from where coal has been extracted completely in underground mines and will not be entered by any man or machinery after the extraction, called goaf, are also potential source of water conservation. These additional water resources created are being utilized for meeting the industrial, domestic, irrigation and other requirements of the projects and local communities eliminating the need to tap other fresh water resources including ground water. Presently, 75% of the water demand of the coal mining project is being met from the water stored in the mine pits. In future, CIL is likely to create about 3.3 billion m3 of water resource, on an average, in its opencast mines alone. In the mine closure plan of opencast mines, the last cut is proposed to be developed into water body for recharge of ground water and creating additional water resources. A clean potential source of potable water is thus developed after mine closure. This will ensure water security of the country.

Aug 1, 2013

By Robert P. Dufresne

Electrolytic cells are used in electrowinning (EW) and electrorefining (ER) of non-ferrous metals such as zinc and copper, and are a critical part of the purification process. The cell is a large basin and has an electrolyte or aqueous solution, an anode and a cathode, an insulator, and incoming high amperage. Cells are exposed to unfavourable internal and external factors that have a direct impact on their lifespan. Their deterioration can be caused by incorrect polarity, insufficient magnitude, their construction, tension stress, thermal shock, corrosion and other, and their maintenance and replacement can be time-consuming, costly, difficult and environmentally unsafe. Occupational health hazards and dangers posed by the maintenance and removal of the cell should also be taken into consideration. Modifying the design and fabrication method of the cell, using chemical-resistant reinforcement, and increasing tensile and mechanical strength will defer maintenance for a very long time. This can be achieved by a double hull system that comprises full-length composite reinforcement, polymer concrete reinforced with fiberglass pultruded rods and rebars, fiberglass structural layers, and special resin matrices. This will provide protection against thermal shocks, corrosion, leakage, cracks. The design of this cell incorporates a lifting system that will afford quick and easy install without having to move a great number of cells in close proximity, since it is strong enough to stand on its own and not have to be bonded to adjacent cells. As well, the cell can be anchored with ease as it remains stable. This is especially important because space is limited to lift and manoeuver between the cell and the double-girder overhead travelling cranes. The lifting system can also prevent electrocution and loss in product quality, while increasing efficiency and safety in the workplace. Considerable savings in terms of production downtime are also part of the equation. INTRODUCTION Maintenance and replacement of electrolytic cells in electrowinning and electrorefining are operations that pose many challenges, health and safety concerns, and give rise to substantial operational costs. These problems have existed since time immemorial. Electrolytic cells are made of conventional concrete or polymer concrete, and because of the very nature of their composition and their exposure to severe and environmental conditions, their lifespan is short. Although polymer concrete is composed of high-quality materials, and has good thermal stability and resistance to chemicals, nonetheless, maintenance is frequently required in order to maintain the integrity of the cell and to ensure the quality of refined metals. Repairing concrete is a non-permanent solution as cracks will reappear, and every repair weakens the integrity of the cell a bit more, until it reaches a knock- down point and the structure is compromised. The cell needs to be replaced, otherwise the cell will collapse.

Jan 1, 2019

By L. M. Lowe, D. B. Chambers, D. G. Feasby

"Potentially economic deposits of rare earth elements (REE) often contain elevated levels of naturally occurring radioactive materials (NORM), primarily thorium and uranium and their associated radioactive decay products. The concentrations of NORM usually exceed typical background levels of natural radioactivity, sometimes by factors of ten or more, and can be of concern relative to occupational radiation protection and the management and disposal of REE mineral processing and metallurgical wastes. This paper provides a summary of the radiological issues normally encountered in the REE concentrate production industry. In addition to an introduction to background radiation and radioactivity, including the thorium and uranium radioactive decay series, radiation levels expected to be encountered in REE concentrate production are outlined. The occupational, environmental and regulatory aspects of REE production related to NORM, including radiation dose limits, radioactive waste disposal guidelines, and threshold VALUES (for the application of transport regulations, are presented.INTRODUCTIONConcurrent with the increasing demand for new sources of rare earth elements (REE) to meet modern industrial needs, there is also an increasing awareness of the radioactivity associated with the REE ores and resources. This is an especially important consideration in addressing questions from the public and local communities who are often concerned about “radiation” and “radioactivity”. Public concern is heightened by reference to legacy issues that arose during times of less regulatory oversight; as well, the benefits of modern technologies, practices and regulation are overlooked. Such concerns are also often inflamed by unfounded claims by non-governmental organizations (NGO’s). Thus, it is important that all concerned have a full understanding of just what the potential risks from radiation associated with REE are, or are not. This paper provides an overview of the sources of radioactivity, the potential implications of radiation and radioactivity in the REE industry, and a brief discussion of established and reliable methods of managing exposure to radiation and radioactivity."

Jan 1, 2012

By Kati Tschöpe

Cathode wear has become an increasing challenge in the aluminum industry due to the use of more graphitized materials. Today, there exist no standard laboratory methods for measuring cathode wear where different commercial materials can be ranked. The typical average wear rate in an electrolysis cell is quite small. The aim of this work was to design a test method where the wear could be accelerated compared to industrial cells. It was focused on polarized tests where the cathode is exposed to electrolyte, which gives higher aluminium carbide solubility. The cathode materials were characterized by microscopy and image analysis.

Jan 1, 2011

By W. H. De Blois

Introduction In the contact process for ?the manufacture of sulphuric acid, sulphur dioxide gas - produced by the burning of sulphur or of sulphur-bearing ores, or as a by-product in the treatment of sulphide ores - is made to combine with the oxygen of the air to form sulphur trioxide, which then only requires the addition of water to form sulphuric acid. The substance, as for example platinum, causing this combination is usually referred to as a catalyst, a convenient term, in the definition and explanation of which many pages have been written. Catalysis is now a comparatively common means of effecting chemical combination, but if the question were raised here tonight as to what actually goes on when this apparently innocent third party unites the parties of the first and second . part, without itself being altered in any way, I am afraid even our most learned members would have to confess their inability to entirely explain the phenomenon; for although the subject is under investigation, there is still much to learn. The contact process, however, is one of the outstanding achievements in chemical engineering. ? From the standpoint of the difficulties involved and the time absorbed in their solution, it probably stands alone in the field of technical chemistry. In fact, the manufacture of sulphuric acid has, from the earliest days, been surrounded with problems which have interested the ablest chemists. The Chamber System Although this paper has particularly to deal with the contact process, it may not be amiss to refer briefly to the chamber system, which was, and still is, a most important factor in the sulphuric acid industry.

Jan 1, 1927

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By R. R. Irrinki

Abstract -The Key Anacon deposit consists of four sulfide zones called, from south to north : Key Anacon No. 1, Key Anacon No. 2, Key Anacon No. 3, and Key Anacon Copper Zone. Massive sulfides of zones 1, 2, and 3 are underlain by rocks correlated with the Nepisiguit Falls Formation and are overlain by matie volcanic rocks correlative with the Boucher Brook Formation. In contrast to zones 1, 2, and 3, narrow northwesterly-trend.ing, copper-rich fracture zones occur within the Patrick Brook Formation. Sulfides in zone 2 occur as three mineralogical associations, namely: pyrite-chalcopyrite, pyrite-sphalerite-galerta, and pyrrhotite-sphalerite-galerta. The distribution of lithologies and en-echelon patterns of the three sulfide lenses of Key Anacon No. 2 zone are the result of F1 and F2 folding. Zone 2 is the most promising economically, with proven reserves of 1.11 million tonnes grading 0.2207o Cu, 3.47% Pb, 8.41% Zn, and 96 g/t Ag; the zone is open below a depth of 427 m.

Jan 1, 1992

By R. Frank Chiappetta, E. B. Wilson

"The maintenance records for AL-60 airlegs at Falconbridge Ltd. are used to demonstrate some of the procedures for the analysis of such data.The data are not representative of pure failure s of one type or another. In fact, the records are for the undefined pseudo-failures which are usually found in industrial operations. However, because the machines are brought to the shop only when inoperative, the individual recorded components are treated as failures. Manual calculations are conducted to show the analysis of variance (ANO VA) approach to determine whether certain data can be combined; only a limited number of the 206 machines being considered. The manual procedures continue with the weighting of the suspensions; i.e. terminations f or reasons other than the failure of the given component. After the data are sequenced in the proper order, the nature or pattern of the data is determined using the Kolmogorov-Smirnov (KS) test.It is recognized that these manual examples must be replaced by compute r methods 10 process voluminous data of this nature. Such programs are developed and available. However, a program called RELCODE is used in this case to correspond to the manual examples and to take into account the suspensions. These analytical procedures form the basis for those studies required for good maintenance management."

Jan 1, 1985

By V. Taylor

"THE petroleum industry in Canada has been experiencing considerable difficulty in filling its manpower requirements during the last few years, and because of the rapidly expanding nature of the industry it is concerned about the supply that will be available to fill the needs of the future. As the oil industry is one of the more technically oriented industries, the most acute problem exists primarily in the field of profession-al/technical personnel. This is particularly true in the production and exploration side of the business, because it employs the highest percentage of this type of personnel. Let me illustrate this by giving you some figures reported by the Alberta Bureau of Statistics as of December, 1965 -out of a total of 9,641 male employees engaged in oil producing and geological and geophysical operations in Alberta, 3,021, or 31 per cent, were classified as engineers, geologists, geophysicists, managers and other professional personnel. No figures are available for 1946 to make a direct comparison of the expansion of the industry over the past twenty 466 years, but it is doubtful whether more than 100 professional/technical people were engaged in producing in Alberta at that time"

Jan 1, 1967