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By Edward Keller

(New York meeting, February, 1912.) IN a paper, entitled A Uniform Method for the Assay of Copper Material for Gold and Silver,1 A. R. Ledoux invited the assayers of this country to contribute to a symposium, in which the results of their assays of given samples of copper-matte and metallic copper would be made comparable. This symposium 2 appeared about one year thereafter; and through it and its discussion, first became generally known the fact that the ,gold-yield by the all-fire method of assaying is usually higher than by the so-called combination (wet and dry) method, in which nitric acid is employed as a solvent for the copper. In the publication alluded to, the supposed cause of gold-losses in the latter method was declared to be the solvent action of copper nitrate, or of the reduction-products of the nitric acid, upon the gold. Up to a very recent date, gold has been held to be insoluble in pure nitric acid. (The solvent action of any chlorine present in the nitric acid must here properly be disregarded as belonging in the realm of carelessness. Among later allusions to this topic, W. R. Tan Liew 3 ascribes the solution of the gold in the combination-assay entirely to the action of nitrous acid at the high reaction-temperature of copper and nitric acid ; F. B. Flinn 4 a believes the low result in gold to be due exclusively to mechanical losses-finely-divided gold penetrating through the filter-paper-but presents no experimental data confirmative of this belief; and 0. Pufahl 5 attributes the solubility of the gold in some coppers to the presence of selenium-a view which appears to be shared by many as- 1 Trans., xxiv., 575 (1894). 2 Trans., xxv., 250 (1895). 3 Engineering and Mining Journal, vol. lxix., No. 16, p. 469 (Apr. 21, 1900). 4 Engineering and Mining Journal, vol. lxxxvii., No.11, p. 569 (Mar. 13, 1909). 5 Lunge, Chemische Technische Untersuchungs Methoden, vol. ii., p. 229 (1900).

Jul 1, 1912

By R. H. Smith, A. C. Polk

The physical properties of the materials are listed, together with a short explanation of how this material binds the sand grains together without materially reducing the effective permeability of the sand. The chemical can be used in wells with bottom-hole temperatures ranging from 105°F to more than 350°F A description of the equipment required and the techniques used for applying these plastics to the wells is included. Introduction Recovering oil and gas from unconsoli-dated sand formations offers one of the most troublesome of all production problems. These sands generally present no particular trouble while drilling is in progress, but after the well has been completed and a pressure differential has been established across the face of the producing zone, the formation begins to L'slough," resulting in "sanding up" of the well. The term "sanding up" means that sufficient volumes of sand have moved into the well bore or casing to cause a serious reduction or complete halt of all flow of oil, water or gas. In rare cases a well may produce only a small amount of sand and still continue to flow or pump, the sand being carried to the surface in the fluid stream. However, in such instances, the result may be a costly repair bill due to the effect of the sand on surface and pumping equipment. The difficulty of producing petroleum from sands that are loosely cemented has long been recognized by petroleum engineers but only within the last few years has any new approach to the problem been undertaken. This involves the use of plastics that are capable of bonding the individual sand grains in place without materially reducing the effective permeability of a formation. The successful application of plastics for the consolidation of poorly cemented sands is relatively recent but now it is widely used in many of the more difficult areas on the Gulf Coast of Texas and Louisiana. This relatively new use of plastics1 in the oil fields has been preceded by much laboratory and field research on the use of various chemicals2,3 for solving numerous well-completion and work-over problems. Plastics now are being used successfully to control gas-oil and water-oil ratios,4'6 in zone isolation, the repair of casing leaks, the elimination of caving in cable-tool drilling wells6'7 and in the setting of linerss and casing.9 Sand-consolidating plastics, however, are basically different from all others in that they must not form an impervious seal. Field Practices The approach to the sanding-up problem usually has been the mechanical obstruction of the movement of the sand grains.

Jan 1, 1947

By A. C. Polk, R. H. Smith

The physical properties of the materials are listed, together with a short explanation of how this material binds the sand grains together without materially reducing the effective permeability of the sand. The chemical can be used in wells with bottom-hole temperatures ranging from 105°F to more than 350°F A description of the equipment required and the techniques used for applying these plastics to the wells is included. Introduction Recovering oil and gas from unconsoli-dated sand formations offers one of the most troublesome of all production problems. These sands generally present no particular trouble while drilling is in progress, but after the well has been completed and a pressure differential has been established across the face of the producing zone, the formation begins to L'slough," resulting in "sanding up" of the well. The term "sanding up" means that sufficient volumes of sand have moved into the well bore or casing to cause a serious reduction or complete halt of all flow of oil, water or gas. In rare cases a well may produce only a small amount of sand and still continue to flow or pump, the sand being carried to the surface in the fluid stream. However, in such instances, the result may be a costly repair bill due to the effect of the sand on surface and pumping equipment. The difficulty of producing petroleum from sands that are loosely cemented has long been recognized by petroleum engineers but only within the last few years has any new approach to the problem been undertaken. This involves the use of plastics that are capable of bonding the individual sand grains in place without materially reducing the effective permeability of a formation. The successful application of plastics for the consolidation of poorly cemented sands is relatively recent but now it is widely used in many of the more difficult areas on the Gulf Coast of Texas and Louisiana. This relatively new use of plastics1 in the oil fields has been preceded by much laboratory and field research on the use of various chemicals2,3 for solving numerous well-completion and work-over problems. Plastics now are being used successfully to control gas-oil and water-oil ratios,4'6 in zone isolation, the repair of casing leaks, the elimination of caving in cable-tool drilling wells6'7 and in the setting of linerss and casing.9 Sand-consolidating plastics, however, are basically different from all others in that they must not form an impervious seal. Field Practices The approach to the sanding-up problem usually has been the mechanical obstruction of the movement of the sand grains.

Jan 1, 1947

By James E. York

THE honor so fairly earned and so incompletely and tardily paid to Henry Cort, the inventor of the puddling-furnace and the, rolling-mill, has been fully set forth by Mr. Charles H. Morgan,1 and needs no further emphasis here. In view of the importance of the rolling-mill in the treatment of iron and steel, the paucity of information concerning it is surprising. With the exception of a hook, written about 35 years ago, by Peter Bitter von Tunner, an Honorary Member of this Institute, and of desultory articles on simple sections, which have appeared in technical journals, I know of no pub¬lication attempting to treat this subject, although volumes have been written on the scientific theory and technical manipulations involved in other branches of the iron- and steel-industry. This strange anomaly may be due to the fact that roll-turning cannot be called a scientific business. It does not ordinarily come within the range of an educated engineer; yet it cannot be performed by an ordinary mechanic. It demands some of the qualifications of an engineer, in designing, and those of a mechanic, in execution. The men who have followed this trade have controlled the training of their successors. In many cases the technical knowledge required bas been handed down from father to son, and there has been a motive of private interest to prevent its public dissemination. Moreover, the statement of the various principles involved in the process would require, besides manual experience, a degree of scientific knowledge which roll-turners do not usually possess; and, finally, any book on the subject, in order to possess real, practical value, would have to be so fully illustrated as to make it very costly to publish. Regarding my own experience, I may say that I served a six-

May 1, 1906

By James Boyd

In critical times such as the present, when the whole world is agitated by the aftermath of war and the road to peace is blocked by seemingly insurmountable obstacles, it is fitting that we should pause to take inventory of the material resources essential to our national security. Our status as a world power, in peace as well as in war, is intrinsically bound to the availability of minerals, for the foundation of our industrial and economic structurewhich in turn largely determines our military potential and our limits of national prosperity-rests on our ready access to economic sources of iron, copper, lead, zinc, manganese, bauxite, and at least threescore of other metals, minerals, and mineral fuels. By applying the well-known facts of mineral resources to recognized fundamental concepts of preparedness, we can obtain a- clearer picture of the essential needs of our country. Historically, the lure of minerals and other raw material resources has all too frequently led nations to policies of imperialism and war. For more than a century the staking of colonial territory for new sources of raw materials has been a primary objective of many nations. These national policies. of aggrandizement were accelerated by increasing industrialization. The nations, in their aggressive search for

Jan 1, 1948

By H. B. Pulsifier

THE following report on the structure of copper is the result of work done in the laboratory of the Rome Wire Co. early in 1925. Previous work had indicated to the author that excellent results might be expected if a suitable technique in surfacing and etching could be developed. The resources of the Rome Wire Co. enabled this metal to be studied more intensively than previously, although none of the materials were investigated exhaustively. The material presented is hardly more than a preliminary summary of the most obvious character of the metal; a much longer research would have been necessary to solve many of the pressing problems connected with the casting and working of copper. The Rome Wire Co. has generously released the paper; to Dr. E. H. Darby, technical supervisor of the company, are due particular thanks for his appreciation of the importance of metallographic study of copper and for his effective support in the prosecution of the work and in making its publication possible.

Jan 1, 1926

[Alphabetic Section (Page 689): The letter immediately following the member's name indicates grade: M-Member, A-Associate, J-Junior. The numerals following member's grade indicate year of election. The letter following year of election indicates primary Divisional affiliation: A-Mining & Exploration F-Coal B-Minerals Beneficiation G-Petroleum C-Iron and Steel H-Industrial Minerals D-Extractive Metallurgy J-Council o f Education E-Institute of Metals K-Council o f Economics]

Jan 1, 1961

By Timothy Collins

There was once a speculative period of interest in small mining companies that is commonly referred to as "the uranium boom of the 50's." In the late 60's, there was a second mining stock boom: it centered around uranium and silver, when silver had reached a new high of $3.60. In the mid 1970Js, there may be a new boom in the making, and it appears that substantial public and institutional interest in mining equities will finally result in a viable long-term capital market rather than the boom-or-bust pattern of the 50's and 60's. The reason for Wall Street's renewed interest in mining is understandable: most mineral commodities have recently gone up in price. Domestically, these price increases have come in the wake of the inflationary spiral unleashed by years of unbridled government deficit spending and erratic fiscal and monetary policies. Internationally, of course, the biggest push for higher prices has come from third-world countries whose primary income derives from indigenous natural resources. Many of these countries-whose fiscal and monetary policies haven't been models of excellence either-have attempted to cope with the worldwide economic mess by forming cartels that could control the price of commodities. What's happened to petroleum is well-known; what's happened to copper, bauxite, phosphate, and uranium is part and parcel of the same syndrome.

Jan 9, 1975

[Admissions: H. J. Gruy, Chairman Kenneth W. Robbins W. Frank West Aurel E. Smith R. F. Madera Tom G. Calhoun Kenneth F. Anderson B. M. Goltlieb Advertising: Clark R. Edgecomb, Chairman Bernard F. Klein. Henry N. Lyle R. E. Howard H. M. Krause, Jr. Education: R. L. Whiting, Chairman John M. -Campbell E. T. Guerrero Don D. Little J. C. McCarthy Frank G. Miller Douglas Ragland H. C. Slider R. L. Slobod]

Jan 1, 1961

[PRESIDENT ASD DIRECTOR LOUIS S. CATES 3 .New York, N. Y. PAST PRESIDENT AND DIRECTOR CHESTER A. FULTON1 .Baltimore, Md. HARVET S. MUDD 2I Los Angeles, Calif.]

Jan 1, 1946

NEW MEMBERS The following list comprises the names of those persons who became members during the period Nov. 9, 1918, to Dec. 10, 1918. ALBERT, EDWARD J 235 E. Upsal St., Philadelphia, Pa. BARRY, D. A Supt. of. Mines, The Big Five Min. Co., Idaho Springs, Colo. BATON, GEORGE S., Cons. Min. Engr., Baton & Elliott, 2412 First National Bank Bldg., Pittsburgh, Pa. BAXTER, HAROLD ALEXANDER, Met. Engr. & Operation Supt., Tacony Ordnance Corpn., Philadelphia, Pa. BENNETT, JOHN S., Chem. and Min. Engr Copiap6, Chile, South America. BOWDEN, MALCOLM, Min. Engr.; Efficiency Engr., Elm Orlu Min. Co., Butte, Mont. BROWN, HAROLD C 2d Lieut., A. S. A. P. BROWN, THOMAS ALBERT, Min. and Met. Engr.; Supt., The Royal Tiger Mines Co., Breckenridge, Summit Co., Colo. BROWN, WALTER S., Investigator, New Jersey Zinc Co. (of Pa.), Palmerton, Pa. BURDETTE, R.. S Capt., Ord. Dept., U. S. A. CALLANDER, IRA C., Asst. Supt., Gauley Mountain Coal Co., Jodie P. 0., Fayette Co., W. Va. COLLINS, J. W., Foundryman, The Aluminum Casting's Co., "L" Plant, Cleveland, Ohio,

Jan 1, 1919

By H. D. Merchant

NUMEROUS publications have examined hot hardness of metals and alloys. Some have studied creep in long-time hardness tests, few of which, however, were tested under a spherical indentor. 1-3 The results of Mulhearn and Tabor' indicate a parabolic-type creep for indium and lead, whereas Moore and Tabor2 how a logarithmic-type creep for indium. Similar semilog relationships between hardness and time have been found by Goffard and wheeler3 for magnesium, aluminum, and their alloys. In this note, the elevated-temperature hardness of some complex alloys, shown in Table I, was examined to discover whether any basic information about the deformation behavior of the alloys could be obtained. One of the alloys, H-13 alloy steel, was tested for short-time creep tests to examine the hardness-time relationship at various temperatures. A standard Brinell Hardness Tester, mounted with an appropriate furnace and 99 pct A12O3 poly-crystalline indentor, was employed for the purpose. The alloys were tested at temperatures from room to 1400°F for 30 sec under 1500-kg load. The creep studies were conducted for about 8500 sec at 7l°, 500°, 1000°, and 1200°F. For constants A and B, a relationship of the type H = Aexp(-BT) [ll was obtained for all alloys between hardness, H, and temperature, T. In the semilogarithmic plot, the data points for each alloy were arranged into two groups, each group on a straight line with a specific set of A and B values. These results are in agreement with many such observations on hot hardness, notably those of Westbrook for pure metals,4 The thermal softening coefficient, B, and transition temperature, Tt, for various alloys are shown in Table I. The change in slope around the transition temperature suggests an apparent change in the mechanism of deformation, probably from the shear (below Tt) to the diffusion type of mechanism. At the temperatures above Tt, for constants A' and B, a relationship of the type was obtained between H and T, Fig. 1. The nature of the equation, where R is gas constant, suggests the possibility of a thermally activated mechanism of deformation above Tt. The constant B' may hence be defined as the apparent activation energy of indentation. The B' values of various alloys are shown in Table I. A plot of B vs B' gives a curvilinear relation shown in Fig. 2. The indentation-creep data for H-13 alloy steel is shown in Fig. 3. At 71" and 500°F, the creep initially follows the logarithmic time law. However, the indentation size stabilizes after 7 sec at 71°F, and after 10 sec at 500°F. Further increase in loading time has no effect on indentation size. The creep of 1000° and 1200°F follows the logarithmic time law for the first 1000 sec, after which the

Jan 1, 1964

By J. S. Dodge, I. M. Krieger

The laminarturbulent transition was studied for monodisperse rigid polymer latices as functions of particle diameter and concentration at several tube diameters. Breaks in the graph of friction factor US Reynolds number were used to characterize the transition; rates of shear were sufficiently high so that Newtonian behavior at the high shear limiting viscosity could be assumed. No abnormal behavior was noted at concentrations below 30 volume percent. At higher concentrations, suppression of turbulence was observed with critical Reynolds numbers rising to as high as 5,500 at 50 volume percent. No definite effect on the transition was noted due to variation of particle size or tube diameter. The type of surfactant used to stabilize the latex was found to have an important influence on the critical Reynolds number. INTRODUCTION For some polymer solutions and solid-in-liquid suspensions, the transition from laminar behavior to turbulence in pipeline flow has been reported to take place at unusually low1-5 and in some cases at higher than normal6,7 critical Reynolds numbers. Extreme values of critical Reynolds numbers (NRe*) have been found to range from 1 to 6,000, as opposed to the values of 2,000 to 3,500 which are obtained for ordinary liquids. Observations have also been reported of drag reduction in fully developed turbulent flow, i.e., a decreased value of the friction factor in the Reynolds number-friction factor plot6*10-14 in colloidal and polymeric fluids. In some cases, turbulence suppression (unusually large values of Nre*) was noted to occur preceding the drag reduction,6 while a normal transition was noted in other cases of drag reduction.14 To relate the occurrence of turbulence suppression and drag reduction to the molecular or particulate structure of the fluid, it is desirable to characterize the structural variables with some precision. For most colloidal dispersions and polymeric fluids, this is very difficult; particle sizes, shapes and stiffnesses may vary over wide ranges in the same sample. Recently, however, a colloidal fluid has become available which consists of rigid spherical particles of highly uniform diameter dispersed in a simple Newtonian liquid. These are monodisperse polymer latices, prepared by carefully controlled emulsion polymerization reactions. The purpose of this research was to study the transition to turbulence in these well-characterized colloidal fluids as a function of concentration, particle diameter and tube diameter. Typical flow curves of latices of high solids content are shown in Fig. 1. While these curves were obtained with monodisperse latices, the general shape of the curve is also typical of a polydisperse latex. It is observed that a shear-thinning region occurs for low to moderate rates of shear. At sufficiently high shearing rates a limiting Newtonian viscosity is reached. The viscosity µ diminishes with decreasing volume fraction 4 at all shear rates. For 4 less than 0.25, latices are Newtonian at all rates of shear.15 An increase in average particle size (at a given extends the Newtonian viscosity region to lower rates of shear. A third factor which influences the

By S. A. Bradford

Internal-oxide precipitates in decarburized a iron alloys were studied by microscopic and X-ray methods. Diffusion of oxygen is primarily trans-granular, although large amounts of manganese or PhosPhorus cause preferred grain boundary dimsion at temperatures below 1450OF. Transgvanular internal oxidation follows the parabolic rate law with an apparent activation energy of 60 kcal per g-atom for decarburized rimmed steel and around 50 kcal per g-atom for higher alloy contents. The internal oxide is (Fe,Mn)0. Evidence was found for a miscibility gap in the FeO-MnO system. UNTIL very recently, the internal oxidation of metals was studied primarily as a scientific curiosity or, in a few cases, as a means of strengthening alloys by precipitation hardening. However, with the recent development of low-carbon enameling sheet steel, internal oxidation has become a problem of practical importance to the steel industry. For example, in 1961 it was reported1 that internal oxidation of steel can occur during decar-burization by open-coil annealing and will reduce the notch ductility of the sheet unless the process is carefully controlled. The present study was therefore undertaken to learn more about the rates and mechanism of oxygen diffusion and oxide formation in iron alloys. BACKGROUND The process of internal oxidation has been well-defined in the literature:',' oxygen dissolves in an alloy, diffuses inward from the surface of the metal, and reacts to form a precipitate with the alloying element that will provide the most stable oxide. he growth of the finely divided so-called subscale, i.e., the internal-oxidation zone, depends on the diffusion rates of both the oxygen and the reactive element.4 Investigators have generally found that increasing the temperature increases the size of the oxide particles, the rate of subscale growth, and the tendency to transgranular diffusion. With very few exceptions, the square of the thickness of the internal oxide layer is directly proportional to the reaction time. Given two conditions easily satisfied for iron systems— a) an oxygen solubility much less than the concentration of the alloying metal and b) an oxygen-diffusion rate to the oxide boundary much faster than that of the alloying element—then the general expression developed by Rhines and co-workers5 for the parabolic growth rate of the internal-oxide zone can be simplified to the following form: where Co and CM are, respectively, the solubility of oxygen and the concentration of the alloying element, DO is the diffusion coefficient of oxygen, O/M is the weight ratio of oxygen to metal in the precipitated oxide, and x is the thickness of the internal-oxide zone after an annealing time t. Both the oxygen solubility and diffusion coefficient can be approximately expressed as functions of temperature by Arrhenius-type equations: in which H and Q are, respectively, the heat of solution and the activation energy of diffusion. Consequently, the apparent activation energies calculated from Arrhenius plots are the sum of the heat of solution of oxygen in iron and the activation energy for diffusion of oxygen. The data, if not the interpretation, of Schenck et al.8 bear out the fact that oxygen diffuses in the atomic form. The general rate law for atomic diffusion is: the reaction rate being proportional to the square root of the pressure at low pressures. Benard and Moreau8 studied both the surface oxidation of Fe-Ni alloys and the gradual penetration of oxygen into the metal. They observed that oxide particles first form along grain boundaries and then grow to form continuous films that eventually envelop the grains. The parabolic rate law does not usually apply in these cases, especially at the higher temperatures. The oxide formed is wustite which gradually transforms into Fe3O4 and finally into Kennedy and coauthors8 examined Fe-Ni alloys with 26, 75, and 84 pct Ni oxidized at 800°C and

Jan 1, 1964

By George A. Roche

Investment in growth stocks is the most assured way of achieving superior, long term investment accomplishment. There are many criteria used to select growth companies but the most important is a combination of superior management operating in an industry with above average growth potential. This growth stock approach is the cornerstone of investment strategy for two of the three mutual funds sponsored by the Price organization and for its private clients. However, during the past five years inflation has accelerated due to a variety of factors including the inability of government to meet seemingly unlimited needs with limited revenue sources.

Jan 4, 1972

[ ] (14) SCREENS: Description of Allis-Chalmers' complete line of vibrating screens for the mining industry is contained in a new 8-page bulletin. Primary scalping, secondary scalping, and conventional screens for wet or dry sizing and screens for heavy media separation are included. Also given is a typical fiowsheet showing how horizontally operated Low-Head screens are used in the sink and float process. (15) MILLS: Forty-six years of experience and 4000 installations throughout the world lie behind the seven basic types of mills illustrated in a recent bulletin from the Hardinge Co. Fields of application and materials handled in various installations are listed. (16) BLOWERS & COMPRESSORS: A brochure describing the manufacturing facilities and the axial and centrifugal blowers and compressors made by the Sawyer Bailey Corp. is now available. (17) LINATEX: The first catalog of the Linatex Corp. of America has been issued, outlining the advantages claimed for this special form of natural rubber, when used in corrosion, abrasion, and vibration resisting applications. (18) WIRE ROPE: Twenty-four pages packed with concentrated wire rope data is the way E. H. Edwards Co. describes a booklet which they are now making available. It was condensed from the Edwards general catalog to provide users with a concise guide to every important phase of wire rope production, maintenance, and use.

Jan 1, 1952

By Benjamin C. Craft

Oil and gas development in Louisiana during 1935 brought this state at the close of the year up to fourth place in the nation as a producing area. A review of development in North Louisiana centers around Rodessa, the most important reserve discovered in this area in many years. While the producing limits have not been defined, this discovery is one of the major developments of the year. New gas fields were discovered in Lincoln, De Soto and Bossier parishes. The Lincoln Parish discovery, completed flowing a highly saturated gas from the Glen Rose, further indicates the importance of deep-seated prospects in the interior salt-dome area. Minor extensions were made at Sligo and Pine Island. During the year, 126 oil wells and 103 gas wells were completed in North Louisiana as compared with 144 oil wells and 68 gas wells during 1934. The North Louisiana oil production was 9,617,405 bbl. as com-pared with 9,274,050 bbl. during 1934, an increase of 343,355 bbl., while the gas production increased 18 billion cu. ft. in 1935 over its 1934 figure. The Louisiana Department of Conservation gage of Nov. 1, 1935, shows an open-flow capacity of 4,563,725,000 cu. ft. per day from 941 wells in the Monroe field and 682,770,000 cu. ft. from 159 wells in the Rich-land field. A great deal of leasing continues in North Louisiana as a result of the Lincoln Parish discovery and development in the Rodessa field, especially in Bossier, De Soto, Winn, Lincoln, Bienville, Webster, Ouachita and Richland parishes. South Louisiana's position as an area of important reserves was further proved during the past year. Increased drilling resulted in the discovery of seven new fields: Lafitte, Garden Island Bay, Tepetate, Bunkie, St. Martinsville, Jeanerette and Big Lake. New sands or producing horizons proved productive in 15 of the proven fields. The total oil production for South Louisiana during 1935 was 40,731,-056 bbl. as compared with 23,255,437 bbl. during 1934. There were 222 oil and gas wells completed in South Louisiana during 1935 as compared with 214 oil wells during the previous period. Drilling during

Jan 1, 1936

By J. B. Newkirk, W. G. Martin

Oxidized cobalt powder is known to have a magnetic hysteresis loop which is asymmetric with respect to the magnetization axis. The experiment described herein shows that the orientation relationship between the basal plane of hexagonal cobalt and the oxide which forms upon it at 400°C is {111}ux//{100.1 }co <110>ux//<11.O> This orientation relationship allows a magnetic interaction between the antiferromagnetic oxide and the ferromagnetic substrate which could account for the offset hysteresis loop. Oxidized nickel powder has a symmetrical hysteresis loop and so is apparently not influenced by any magnetic interaction between metal and oxide. The orientation of the oxide (cubic) was found to be identical with that of the nickel substrate when the oxide forms on a polished surface parallel with {111} Ni. IN 1956 W. H. Meiklejohn and C. P. Bean discovered that fine particles of cobalt which had been prepared in a certain way have a magnetic hysteresis loop which in a strong field is asymmetric relative to the magnetization axis.&apos; The cobalt powder exhibited this unusual magnetic property only after it had been oxidized in air or oxygen; it lost the shifted hysteresis loop when the oxide was reduced in hydrogen. X-ray and neutron diffraction&apos; experiments showed the presence of cobaltous oxide (COO) and hexagonal cobalt in samples exhibiting the biased hysteresis loop and specifically showed no indication of any other compound with the exception of mercuric oxide.* The magnetic hysteresis loop becomes symmetrical above the Nee1 temperature (paramagnetic state) of COO. Therefore, it was concluded that the anomalous magnetic behavior is associated with the influence of cobaltous oxide upon the metallic cobalt. It has been proposed that crystallographic coherency may exist between the cobalt and a plane of some antiferromagnetic material which has unbalanced spin distribution and sufficient magnetic anisotropy to hold its spin in the direction which existed when the specimen was cooled. COO has these properties. Therefore, Roth&apos; has suggested that cobaltous oxide may form with a {111} plane parallel and coherent with the basal plane of the hexagonal cobalt metal and proposed that, as consequence of the antiferromagnetic interaction between COO and the underlying cobalt, the magnetization direction in oxidized fine Co particles may be ro-lated from the easy c-direction.2 Such a relationship, he proposed, would explain the observed magnetic effect in oxidized cobalt powder. The main purpose of this study was to determine the orientation relationship, if any, between the basal plane of cobalt and the oxide which forms upon it. Attempts to produce a film of COO which was strong enough to be handled were not successful. However we did succeed in making a film of CoCo2O, which was strong enough to be removed from the cobalt substrate and mounted on an electron-microscope grid. Because of the close structural similarity of COO and CoCo2O, we believe the orientation relation found for CoCo2O, on cobalt probably also holds for COO on cobalt. The epitaxial relationship of NiO and Ni also was investigated. To date no shifted hysteresis loop has been observed with nickel powder. However, the similarity of atomic array in cobalt and nickel leads to the prediction that a {111} of NiO may be parallel with a (111} of nickel. Experimental Method Cobalt-Cobalt Oxide—A coarse-grained specimen of a (hexagonal) cobalt was prepared by allowing a large crystal of fee cobalt to transform slowly at 400°C. The crystal was then cut to expose a surface parallel with the basal plane. A back reflection Laue X-ray photograph showed that the 00.1 plane was within 2" of the cut surface. The surface was mechanically polished and then electro polished in 85 pet orthophosphoric acid after which the crystal was held for 30 min at 400°C in air. During this heat-treatment the surface darkened slightly due to the oxide film which formed. The film was not thick enough to give an X-ray diffraction pattern, even by a glancing-angle technique. Glancing-angle electron diffraction was not possible either, owing to the interference of the electron beam with the high magnetic fields which exist at the 00.1 surface of the cobalt. However, it was possible to make an electron-diffraction photograph of the oxide film by stripping it from the cobalt substrate using the method described later. By maintaining reference marks carefully, it was possible to preserve the orientation relationship between the stripped film and the substrate on which it was formed. The oxidized surface of the crystal was first covered with a 1 pet solution of collodion (cellulose nitrate) in amyl acetate. When the film was dry, small rectangles were scored on the surface with a needle point. The specimen was then repolished

Jan 1, 1959

By Benjamin C. Craft

Oil and gas development in Louisiana during 1935 brought this state at the close of the year up to fourth place in the nation as a producing area. A review of development in North Louisiana centers around Rodessa, the most important reserve discovered in this area in many years. While the producing limits have not been defined, this discovery is one of the major developments of the year. New gas fields were discovered in Lincoln, De Soto and Bossier parishes. The Lincoln Parish discovery, completed flowing a highly saturated gas from the Glen Rose, further indicates the importance of deep-seated prospects in the interior salt-dome area. Minor extensions were made at Sligo and Pine Island. During the year, 126 oil wells and 103 gas wells were completed in North Louisiana as compared with 144 oil wells and 68 gas wells during 1934. The North Louisiana oil production was 9,617,405 bbl. as com-pared with 9,274,050 bbl. during 1934, an increase of 343,355 bbl., while the gas production increased 18 billion cu. ft. in 1935 over its 1934 figure. The Louisiana Department of Conservation gage of Nov. 1, 1935, shows an open-flow capacity of 4,563,725,000 cu. ft. per day from 941 wells in the Monroe field and 682,770,000 cu. ft. from 159 wells in the Rich-land field. A great deal of leasing continues in North Louisiana as a result of the Lincoln Parish discovery and development in the Rodessa field, especially in Bossier, De Soto, Winn, Lincoln, Bienville, Webster, Ouachita and Richland parishes. South Louisiana&apos;s position as an area of important reserves was further proved during the past year. Increased drilling resulted in the discovery of seven new fields: Lafitte, Garden Island Bay, Tepetate, Bunkie, St. Martinsville, Jeanerette and Big Lake. New sands or producing horizons proved productive in 15 of the proven fields. The total oil production for South Louisiana during 1935 was 40,731,-056 bbl. as compared with 23,255,437 bbl. during 1934. There were 222 oil and gas wells completed in South Louisiana during 1935 as compared with 214 oil wells during the previous period. Drilling during

Jan 1, 1936

By C. W. MacGregor

THE observation of the flow layers, or Lüders&apos; lines, produced in mild steel when it is stressed into the plastic range often provides considerable useful information for the study of the fundamental mechanism of the plastic flow of metals. It is a commonly observed fact that as soon as the upper yield point in a mild-steel tensile-test bar is passed, an unstable condition develops in the equilibrium, the load on the testing machine drops and if the surface of the bar contains a thin mill scale, the latter begins to flake off rapidly along certain "lines." These "lines" are in reality traces of wedge-shaped flow layers and are formed by the intersection of the surface of slip and the surface of the bar. The average plane of the flow layer itself has been found by various experimenters to be inclined at an angle of approximately 45° to the axis of the test bar. In a body of more complicated shape stressed in possibly a different man-ner, the tangent planes to the flow layers at each point seem in many cases to be inclined at an angle of about 45° to the principal stress direc-tions at the point. As examples of the latter may be mentioned the logarithmic spirals obtained when a rivet hole is punched in a thin plate, or when a tube is subjected to internal pressure only, etc. Hence if the flow layers are observed from an experiment, the shear-stress trajectories -the curves indicating the directions of the maximum shearing stresses in the body-may then be approximately determined. Since the latter curves form an orthogonal family inclined at 45° to the principal stress directions, the family of principal stress trajectories, or the curves indicating the directions of the principal stresses, may be thus obtained. Although the discontinuous type of stress-strain curve at the yield point is commonly observed with test bars of mild steel, more recent experiments have shown that this is by no means the only material exhibiting this interesting phenomenon. A similar effect has been observed in zinc and cadmium crystals, by Becker and Orowan;1 in duralumin and other aluminum alloys, by Dawidenkow,2 Elam,3 Fell, and others; in copper and copper-alloy crystals, by Elam;5 in brass by Elam;5 in brass wires by deForest;6 in higher carbon steels, tungsten steel, and

Jan 1, 1939