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By Dana Reinke, William Wiehagen, Launa Mallett, Charles Vaught, Kathleen M. Kowalski, Michael J. Brnich, Lynn Rethi, Lisa Steiner

Safety and health professionals from all sectors of industry recognize that training is a critical element of an effective safety and health program. A major concern in the mining industry today is how to train the present aging workforce plus the expected influx of new and less experienced miners and mine operators as the cohort of older workers retire. This paper defines the problem, offers a model to structure the inquiry, and presents the key issues a multi-disciplinary team of NIOSH researchers identified, based on an extensive review of the current literature in relevant areas. Issues include differences between cohorts, such as the newer workers (Generation M), and present workers (Boomers) with respect to their physical, social, psychological, and cultural characteristics, their learning styles and work expectations. Specific issues for an aging workforce are discussed. Some preliminary recommendations are offered on the type of training needed.

By R. Karl Zipf

MULSIM/NL (multiple seams, nonlinear) is a new U.S. Bureau of Mines boundary-element-method (BEM) program for calculating stresses and displacements (is., convergence) in coal mines or thin, tabular rnetalliferous veins. This manual gives detailed operating instructions for MULSIM/NL and illustrates its use with several practical examples. While this manual concentrates on the practical aspects of actually running and using MULSIM/NL, another companion report titled "MULSIM/NL- Theoretical and Programmer's Manual" provides mathematical and programming details to those engineers and programmers who need to fully understand the FORTRAN program or desire to alter and enhance it. MULSIMINL analyzes one to four parallel seams that have any orientation with respect to the Earth's surface. Three main features distinguish MULSIM/NL from its predecessors: (1) nonlinear material models, (2) multiple mining steps, and (3) comprehensive energy release and strain energy computations. MULSIM/NL has six material models for the in-seam material including (1) linear elastic for coal, (2) strain softening, (3) elastic plastic, (4) bilinear hardening, (5) strain hardening, and (6) linear elastic for gob. The multiple mining step capability enables the user to simulate a changing mine geometry. Finally, MULSIM/NL performs comprehensive energy release rate calculations.

Jan 1, 1992

Studies on coal mine drainage sludge densification have led to the following conclusions: 1. Coal mine waters containing iron principally in the ferrous (Fea+) state can be treated by a modification of the commonly practiced lime neutralization process to yield a ferromagnetic sludge. The sludge, presumably composed in large part of a hydrated ferrosoferric oxide (Fe304.xH20), is much denser and faster settling than the ordinary "yellowboy" sludge obtained by lime neutralization and aeration at ambient temperatures. 2. The magnetic sludge preparation technique involves (quantitative) precipitation of iron (largely as Fe(OH)2) by the addition of hydrated lime to a pH of 8.5, separation of the resulting sludge from the aqueous phase, and heating of the sludge concentrate to at least 80 C (176 F), preferably higher, followed by mild aeration. 3. Magnesium, present as Mg2 in most coal mine drainage waters, inhibits the formation of the magnetic sludge. This inhibition can be adequately minimized by keeping the pH below 9.6 during lime addition (thus avoiding the coprecipitation of Mg(OH)2) and by separating the sludge from the bulk of the aqueous phase before the heating step, as indicated in (2) above. 4. Aluminum, commonly present in coal mine drainage waters, also inhibits the formation of the magnetic sludge. This inhibition is of practical significance when the molar ratio of aluminum/total iron is greater than 0.18. Below this value, sludges are still appreciably magnetic, but are bulkier and slower settling than those obtained when aluminum is absent. Unlike magnesium inhibition, aluminum inhibition cannot be minimized by the scheme indicated above, since aluminum precipitates as Al(OH)3 near pH 4 and remains dispersed within the sludge. 5. The limitation on aluminum content is probably the most serious restriction affecting the feasibility of the magnetic sludge process as presently conceived. Nevertheless, a limited review of available water quality data has indicated that, in terms of relative acid and iron loadings, a significant number of major coal mine discharges in the eastern Ohio River basin may be amenable to treatment by a magnetic sludge process. 6. Data from tests on the use of magnetic seeding materials indicate that seeding did not enhance the formation of a magnetic sludge under the experimental conditions employed.

Jan 1, 1971

By 1928-05-01

"The carnotite ores of Colorado and Utah were the chief source of radium for many years. In the fall of 1922; news of the very rich deposits of radium ore discovered in the Belgian Congo caused almost complete cessation of domestic production. The Congo ore contains pitchblend and a number of alteration products, including the new minerals bequerelite, curite, kasolite, stasite, and dewindite. Reports indicate that a considerable amount of ore containing over 50 per cent U308 has been produced. It seemed certain that radium could be extracted from the Congo ore at a much lower cost than from the relatively low-grade carnotite; and in order to preserve their elaborate marketing organizations, the larger American producers made agreements with the Belgium syndicate to market the foreign product in this country. The price of radium has been held at $70 per milligram. Extraction of radium from carnotite by the usual methods does not appear to be profitable at that price. With one exception, all American firms ceased production after their accumulated stocks of ore had been treated. The United States Radium Co., which continued to treat carnotite for several years, has recently shut down its plant.Although there is probably a large profit derivable from the treatment of Congo ore, it is not likely that the Belgium Syndicate will meet sufficient competition to cause any reduction in the present quotations. It is not known how long the high-grade ore will last, but when exhausted the price of radium may be expected to advance. According to K. L. Kithil3 it is the opinion of interested parties that, so far as can be forseen, radium will in future years never again be obtained at the present low price.Carnotite contains the valuable element, vanadium, which is not present in the Congo ore. The recovery of-vanadium is an important factor in the cost of extracting radium from carnotite, and under favorable conditions carnotite can be profitably treated for the vanadium alone. Vanadifecous sandstones are found ranging all the way from roscoelite (vanadium mica), containing little or no uranium; to a high-uranium and low-vanadium carnotite. Ores containing 2 per cent or more U308 are classed as radium ore and are sold on the basis of the uranium content, which is proportional to the radium content. Only in exceptional cases have ores been evaluated on the basis of both the radium and vanadium contents, although the presence of vanadium has undoubtedly influenced the price of radium ore."

May 1, 1928

By William J. Campbell

The purpose of this investigation by the Federal Bureau of Mines was to design and construct a fluorescent X-ray spectrograph for dynamic rate studies of selective oxidation in molten metals and to establish basic principles for interpretation of data obtained by this method. An X-ray spectrograph was constructed in which the sample holder is a resistance wound furnace; it was operated up to 800° C. in oxidizing atmospheres. No difficulties were experienced with the cooling or heating systems nor with the protective layer of mica around the X-ray tube window, even though the oxidizing surface of the metal is only 0.5 inch from the X-ray tube window, Means are provided for heating under controlled atmospheres for selected time? temperature cycles.

Jan 1, 1961

By Yael Miron

Coal mines that undergo self-heatings, and specifically mines that sustain both floor heave and self-heatings, would benefit from the use of sealants to minimize air ingress to susceptible areas. The U.S. Bureau of Mines (USBM) evaluated three sealant systems for this purpose, bentonite-water mixtures, silicate gel, and guar gum gel. The guar gum-based gel was the only sealant that possessed the desired properties of elasticity, ease of preparation, adaptability to the mine, and a long life. In addition, since the gel consists mostly of water, it could quench or cool nearby heatings. Optimal formulations were determined in laboratory tests, and then tested in the USBM Safety Research Coal Mine. Two for-mulations resulted in stable gels that lasted for at least 12 months in the mine. Semicontinuous preparation of gel using an eductor was evaluated and appears feasible. Although guar gum gel is expensive, selective use to prevent heatings in specific areas would be cost-effective, both in terms of productivity and enhanced mine safety.

Jan 1, 2010

By Clarence O. Babcock

This Bureau of Mines report presents the initial development of a two-dimensional method of analysis for inclusions in plates in which the deformed shape of an open hole and the separate structural behavior of inclusion and plate with hole are used to obtain the stresses and strains in the inclusion only. In this report the solution for a circular inclusion is presented because a direct verification of the results with previous solutions was possible. The numerical results were in exact agreement with those obtained with the equations of Sezawa and Donnell. The equations developed are less complex than those of Sezawa and more general, for a circular inclusion, than those of Donnell. Stresses and strains in the inclusion are in terms of the elastic constants of the inclusion and the plate and the biaxial stress field applied far away. The elastic constants can be all different. An important conclusion from this work is that a difference in Poisson's ratios between inclusion and plate may be as important as a difference in Young's moduli between inclusion and plate in producing the inclusion effect. Many problems in mining and rock mechanics can be treated as inclusion problems. The understanding of inclusion behavior on a physical basis should provide the solutions to some of these problems.

Jan 1, 1974

By T. O. Llewellyn

The Bureau of Mines conducted laboratory batch beneficiation tests on a waste granite sludge from New Hampshire to determine the feasibility of recovering a reusable silicon carbide product. The granite sludge responded to attrition scrubbing, desliming, and flotation in either alkaline or acid circuits using fatty acid as a collector. Recovery of over 80 percent of the contained silicon carbide at grades of up to 96 percent SiC was obtained.

Jan 1, 1975

By D. B. Taliaferro

An accurate knowledge of the water content of oil-bearing sands4/ now is recognized as an important factor in calculations of the flow of oil through the sands to producing wells and in the estimation of oil reserves, To this end the Bureau of Mines laboratories are using a method that is an adaptation of the A. S. T. M. method of determining the water content of petroleum products (1).5/ However, the apparatus and technique have been altered slightly, as described in this report, to increase the precision of the method without affecting the simplicity of procedure or speed with which determinations may be made. Until recently petroleum engineers, when estimating reserves assumed that the entire pore volume of the oil-saturated parts of producing sands was filled with oil, as it was generally thought that the oil, water, and gas in any formation had separated completely during geologic time into distinct layers because of their difference in density. In 1929 Lindthrop and Nickolaeff (12) reported experimental results from which they concluded that 22 to 30 percent of the pore volume of producing sands in the Grozay district, Russia, was filled with water when the fields were discovered. Since that time numerous investigators (5, 7, 8, 10) have found evidence of water in the sands of now oil-producing fields and old fields that never produced water with the oil.

Jan 1, 1940

By John J. Henn

An evaluation is presented for an ammonium sulfate leaching process designed to extract manganese from Cuyuna, Minn., and Aroostook, Maine, deposits. In this process the manganese and iron in the ore are reduced to MnO and Fe 3 0 4 in a shaft furnace; the reduced ore is then leached with ammonium sulfate solution forming soluble manganous sulfate while leaving most of the iron undissolved. After filtration, the manganese and some impurities are precipitated from solution as carbonates which are then pelletized and calcined to form a product composed mainly of Mn3O4. The plants are designed to produce 100 tons per day of manganese contained in a product that is suitable for the production of ferromanganese. A byproduct credit, together with the extra processing cost, is included for the Cuyuna ore processing plants because Fe2O3 may be recovered for use in blast furnaces. The estimated operating costs per ton of manganese, excluding income taxes and return on investment, are: [ ] The process with or without byproduct recovery, when treating Cuyuna or Aroostook ores, is not economically competitive with ores available at $71.43 per ton of contained manganese.

Jan 1, 1968

By J. B. Gayle

The Bureau of Mines sole-heated oven has been used for studying coal expansion for some 20 years. During the period before 1940 emphasis was placed on studies of the mechanism of coal expansion and the effects of variations in operating conditions on the results. Since 1940 emphasis has shifted to a survey of the expansion properties of various coking coals. Because additional information concerning a number of unsolved problems in connection with the earlier studies appeared highly desirable, this investigation of the use of sole-heated ovens for studying coal expansion was undertaken. The principal findings, in order of their discussion in the text, may be summarized as follows. 1. Expansion results for binary blends of coking coals exhibit nonadditive behavior, both positive and negative deviations from additive behavior being noted, depending on the particular coals tested. Additive behavior can be achieved, however, either by charging the blend components in separate layers (which indicates that the observed phenomena are not characteristic of the particular expansion oven used) or by testing relatively coarse sizes of coal (which suggests that the effects of crushing on the expansion properties of coking coals may be even more complex than is generally recognized).

Jan 1, 1959

The current procedure for measuring the concentration of respirable coal mine dust is as follows. Each filter is preweighed by the filter manufacturer to ±0.1 mg. Following sampling with the Coal Mine Dust Personal Sample Unit (CPSU) at 2.0 L/min, the filter with coal mine dust is sent to MSHA for weighing. The current MSHA procedure for weighing respirable dust samples uses a Mettler Model AE163 analytical balance in conjunction with an automatic weighing system with a precision of ±0.02 mg [Tomb 19901. Each balance is calibrated twice per day. Quality control for the automatic weighing system includes the systematic weighing of one in eight filters on a second Mettler AE163 balance. Tolerance is set at ±0.1 mg between the two weighings of the same sample. Weights are truncated at the 0.1 mg level (e.g., 3.457 mg is truncated to 3.4 mg) [Bowman et al. 19851. The difference of the two truncated weights is then recorded as the weight of coal dust deposited. The respirable concentration (mg/m3) is computed by multiplying by a correction equal to 1.38 and dividing by the volume of air sampled (2.0 L/min x sampling time [min]).

Jan 1, 1997

By Charles D. Litton

Experiments were conducted to determine the optical scattering properties of diesel particulate matter (DPM) and various combustion aerosols from both flaming and smoldering combustion sources at discrete angles of 151 and 301 in the forward direction and at a light source wave length of 635 nm using a simple light scattering module. In addition to the scattering data, simultaneous measurements were made of the total aerosol mass concentration; light extinction at an average wave length of 546nm; and the response of a common bipolar ion chamber typical of residential smoke detectors modified to allow the aerosols to flow through the chamber. The results of these experiments indicate, for DPM and combustion aerosols, the intensities per unit mass concentration depend not only upon whether the aerosolis DPM or combustion aerosol but also upon the type of combustion aerosol. The results also indicate that the ion chamber responses are greatest for DPM, followed by the response to flaming combustion aerosols (FCA)and lowest for smoldering combustion aerosols (SCA). For light scattering, the greatest intensities are found for SCA, followed by the intensities from FCA, and lowest for DPM. This report describes the experiments, their results, and the use of these results to developed sign criteria for early warning fire sensor capable of the rapid and reliable detection of fires in atmospheres that may or may not be contaminated by the products produced from diesel engines. © 2002 Elsevier Science Ltd. All rights reserved.

By R. Karl Zipf

MULSIM/NL (multiple scams, nonlinear) is a three-dimensional boundary-element method (BEM) program developed at the U.S. Bureau of Mines for stress and displacement analysis of coal mines and thin metalliferous veins. It can analyze one to four parallel seams that can have any orientation with respect to the Earth's surface. Three main new features distinguish MULSIM/NL from its predecessors: (1) nonlinear material models, (2) multiple mining steps, and (3) energy release and strain energy computations. MULSIM/NL has six material models for the in-seam material: (1) linear elastic for coal, (2) strain softening, (3) elastic plastic, (4) bilinear hardening, (5) strain hardening, and (6) linear elastic for gob. Detailed checks show that numerical stress and displacement calculations compare well to known analytic solutions for simple problems. The total energy release calculated by MULSIM/NL is comprised of three basic terms: (1) strain energy release from the mined-out material, (2) linear kinetic energy release due to change in gravitational potential over the mined-out area, and (3) nonlinear kinetic energy release due to nonlinear materials in the total backfill and gob area. The strain energy release term is modified to account for nonlinear stress-strain behavior in the unmined materials. Comparisons of these numerical energy release rate calculations with known analytic solutions show excellent agreement.

Jan 1, 1992

By Sidney Katell

An estimated capital investment of $76,499,800 will be required for a plant designed and built to produce 90 million standard cubic feet per day (std.c.f.d.) of synthetic pipeline gas through Lurgi gasification of bituminous char. This investment figure does not include the pretreatment plant, the cost of which is assumed to be reflected in the cost of the char fed to the gasification system. Shift conversion, C02 removal, and methanation are required after gasification in the Lurgi unit to make a gas suitable for pipeline transmission. Capital investment data are based upon equipment costs, January 1959. Based on a 90-percent or 330-day operating year, the operating cost before profit and Federal taxes with the char price as a variable will amount to the following: [ ]

Jan 1, 1959

Determine the appropriate spacing and alarm levels for carbon monoxide and smoke sensors used for fire detection in underground coal mine conveyor belt entries. Background Fire represents one of the most severe hazards in underground coal mines. Early-warning fire detection in underground coal mines is essential to successfully implement and execute evacuation and control measures. Both carbon monoxide (CO) and smoke sensors have the ability to provide reliable early-warning capability, provided that they are spaced properly and set at the appropriate alarm levels. The U.S. Bureau of Mines conducted a series of large-scale experiments where a small coal fire was used to ignite a conveyor belt at air velocities of 0.76 to 6.1 m/s. The test configuration was purposely designed to model a worst-case fire scenario for fires that develop within conveyor belt entries in underground coal mines. During the tests, CO and smoke levels were continuously measured to determine alarm times and alarm levels as the fire intensity progressed. The data from these tests indicated that for a given sensor spacing, the time to reach a preset alarm threshold depends upon the belt entry air velocity and cross-sectional area. Analysis of this data resulted in the equations and nomographs for CO and smoke sensor spacing, and alarm levels contained in Bureau of Mines RI 9380, "Fire Detection for Conveyor Belt Entries."

Jan 1, 1993

By G. T. Brow

An experimental method is described for testing diffusion of gases in crude oils at pressures and temperatures up to 3,000 psia and 200° F. A sampling technique was developed to withdraw by constant-pressure mercury displacement about 60 µl of oil from the diffusion cell through any of several 1/2-in vertically spaced capillary tubes and to trap about 4 µl of the oil in a specially designed microsampler. Oil trapped in the microsampler can be completely inserted in the sample inlet of a chromatograph. From analysis in a three-stage chromatograph (GLC), gas concentration in a sample is determined from the ratio of gas peak heights to area of peaks of reference components (hexanes or heptanes) in the oil. A diffusion coefficient is calculated from measured concentration profiles with known equations for diffusion in finite or semi-infinite systems, depending on whether the gas has or has not reached the end of the oil column. Results are given for a test of methane diffusing at 2,560 psia and 160° F in crude oil from the Weber Sandstone reservoir in the Rangely field, Colorado. A constant diffusion coefficient of 3.34 X 10-5 cm2 per sec was obtained which gives a good fit between calculated and experimental profiles determined at six times after start of diffusion. The maximum standard error of gas concentration determinations experienced with this method was ±0.88 ml per ml of gas-free oil.

Jan 1, 1970

By R. Barany

This paper reports determinations of heats of formation (from the oxides and elements) of crystalline cadmium metasilicate and crystalline lead meta-silicate by hydrofluoric acid solution calorimetry. The results, in conjunction with known entropy values, yield free energies of formation. There are no earlier data of this type for cadmium metasilicate. The results of this investigation for lead metasilicate deviate from the literature values (which are less reliable) in the direction of increased thermodynamic stability. Both cadmium and lead metasilicate are much less thermodynamically stable with respect to their constituent oxides than are the corresponding compounds of the alkaline earth metals.

Jan 1, 1959

Three -dimensional boundary value problems are difficult to solve. Indeed, while the separation of the scalar wave equation can be effected in 11 different coordinate systems, an analytic solution requires that the boundaries, both external and internal, possess the same symmetry as the coordinate system. Numerical methods are thus of great importance for the solution of such problems; however, despite the availability of high-speed, large memory digital computers , the solution to a significant three -dimensional problem is by no means trivial. It is unfortunate that the results reported here by Jones are invalid. Jones discusses a model in which a three-dimensional island lies off a linear coastline where all the interfaces lie in the coordinate planes in a Cartesian system. A downward plane em wave polarized with the electric field parallel to the linear coastline, and two of the islands coast, is incident downward. This, of course, requires that the incident electric field is perpendicular to the other faces of the idealized Cartesian island. The significant equation used by Jones for his finite difference calculations is [ ] where n2 = sµ? . is the conductivity, µ=µo is the permeability of the appropriate medium, and w is the angular frequency of a Fourier component of the incident field. We see that the displacement current term is omitted, which is an excellent approximation for the parameters of interest in this model. In the similar equation for the y- component of the diffusion equation, the same considerations which we are about to discuss are equally valid. It can be seen from the equation that the field components are related and thus any errors introduced will be propagated into all three components. The difficulty arises when Ex or E is perpendicular Y to one or other of the surfaces of discontinuity in s. The continuity of current at the air-earth interface (upper surface), e. g., jy, requires

Jan 1, 1973

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract SO122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine. Field testing was conducted during the last week of November 1972, at a coal mine operated by Inland Steel Company, near Sesser, Ill, and in the Robena No. 1 Mine, Waynesburg, Pa, on 12 March 1974. The tests included uhf propagation losses and noise (200 MHz to 1 GHz) in the Sesser, I11 mine location and vlf propagation loss and noise (1 to 200 kHz) in both of the above locations. The basic experimental parameters were frequency, polarization, antenna type/orientation, and distance. The following reports treat the various aspects of the test programs in detail. Since different antenna configurations were used in the two mines, each report contains its own experimental predictions drawn from its corresponding test activities. A test equipment list and block diagrams of typical experimental setups for the tests of section 2 are contained in appendix A.

Jan 1, 1974