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By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By C. Lorimar Colburn

"The use of helmets during the war has accentuated interest in the advisability of using stiff hats in mines to protect the miners against falling rocks. About forty per cent of the accidents in mines are due to falling rocks or roof. A large number of these accidents could be prevented if the miners wore stiff hats or helmets.The use of head protective devices in minas is not new, for they have been in use for many years in Europe and in the Lake Superior District in the United States. In practically all of the mining districts in Europe stiff hats of some kind are required by the mine management. George S. Rice, chief mining engineer of the Bureau of Mines, reported that in Germany, Belgium, and France stiff hats made of papier mache or felt rosin are in use. Similar hats are generally employed in the Lake Superior District. In building the subways of New York and Philadelphia it was the practice of engineers and workers to let the hair grow very long and to wear a close fitting cap or felt hat. In Germany the hats are high like the military helmets, whereas in France and Belgium they fit more closely to the crown. In England the practice is mixed. As a rule the miners use soft padded caps, but in Yorkshire many of the miners use sole leather, tight-fitting caps of jockey pattern with the seam forting a little ridge down the middle of the cap. These hats are very useful allow thin beds of coal, as in crawling one is very likely to strike his head a sharp piece of rock or on a timber. Of course, such mishaps are more likely to occur to a man not familiar with the mine. It must be admitted such hats do not stick on well, though this is usually due to their not being especially fitted. The German hat is particularly unsuited to an American-shaped head.It is interesting to note that on the continent tight cotton caps are generally worn over the hair and under the hard hat. This is a measure for cleanliness which is excellent. In low beds of coal share much crawling on hands and knees is necessary the dirt and coal dust sift down, making the miner black and dirty. In metal mines stiff hats are of especial use in shaft work; also in raises or high stapes. A small fragment of rock falling some distance either down a shaft or raise would kill a man if it struck him squarely on the head. A stiff hat or helmet may protect him and save his life. At a station in a shaft where men are loading the cage or skip, some kind of adequate head protector should be compulsory. A head-protecting hat or cup which is also a good insulator should be worn where there is danger of striking one's head against a wire carving an electric current."

Jun 1, 1920

By Edward F. Divers

Tills U.S. Bureau of Mines report briefly evaluates the advantages and disadvantages of basic dust control techniques presently used by U.S. coal preparation and mineral processing plants. These include ventilation, baghouse-type collectors, wet scrubbers, electrostatic precipitators, source control, sprays, good housekeeping, and personal protection devices. Two specific problems in these types of operations are also considered: dust collector system duct clogging, and control room dust control. Information provided in this report results from dust control research projects conducted by the Bureau at various coal preparation and mineral processing plants over the past decade to reduce workers' dust exposure. These studies indicate that plant ventilation systems normally provide the most cost effective method for dust control. Baghouses and scrubbers were also effective in specific applications, and examples of each are given. In extreme dust conditions, personal protection devices, such as respirators or the dust helmet, can also be highly cost effective.

Jan 1, 1990

By R. A. Beall

Homogeneous zirconium-alloy ingots have been cast on a production basis by the consumable-electrode arc-melting process at the Northwest Electrodevelopment Experiment Station, Bureau of Mines, Albany, Oreg. This paper describes the various methods used to introduce alloying materials into the ingot and evaluates 1 each method by the degree of homogeneity of resulting ingots, as determined in tests on sections cut from the ingots. As many as 30 or more ingots, each 6 to 10 inches in diameter and weighing 300 to 500 pounds, were melted, using each method; and, as most of them subsequently were fabricated to strip 0.1 inch thick, the test results are considered to be representative of production practice. Ingot homogeneity has been considered more difficult to achieve in arc-melting practice than by methods where the molten metal is poured into molds and the addition can be stirred into the total mass of metal before casting. Owing to the unique requirements of consumable-electrode arc melting the addition can be made only to that part of the total mass of the ingot that is molten at one time. Observation of the flowlines in 500-pound ingots produced at Albany indicates that the molten pool has a maximum depth about equal to the ingot diameter. The weight of metal molten at one time is, therefore, not over 100 pounds. Characteristically, the arc-melting process is conducive to segregation, which can be overcome, at least partly, by adding the alloy constituents almost continuously during casting.

Jan 1, 1956

By John Gross

"Introduction.Southern Illinois and Kentucky are credited with approximately 90% of the fluorspar production of the United States. A small amount of high-grade acid, spar is obtained from the ore by band sorting; the greater part, however, is recovered by jigs and tables as gravel spar containing approximately 85% calcium fluoride. In the jigging and tabling operations, galena is recovered, and enough silica and calcite are removed to raise the calcium fluoride content of the gravel spar to 85%. However, the removal of silica and calcite results in a large loss of spar. With increasing depth in the mines, zinc sulphide, sphalerite, is encountered in increasing quantity and the removal of this has become a serious problem. While the sphalerite can be fairly well removed from the spar by present milling methods, a marketable zinc concentrate can not be made. The experiments described below were made on fluorspar ore from Southern Illinois, by the mining experiment station of the U. S. Bureau of Mines, at Rolla, Mo., in cooperation with the Missouri School of Mines and Metallurgy.The ore tested contained. 7.3% lead, 27.9% zinc, 35.7% calcium fluoride, 9.5% silica and 4.7%. calcite.Tests and Results. In some preliminary tests it was noticed that a portion of the finely crushed ore adhered strongly to the sample pans, and upon investigation it was found that the adhering material was practically clean spar. By utilizing this property of adhesion 46.8% of the spar was recovered as a product containing 98.3% calcium fluoride. This suggested the possibility of using electrostatic separation."

Jul 1, 1921

By Wm. W. Odell

A study of certain gas making and fuel problems peculiar to the gas industry of California has been made by the Bureau of Mines. The work was done at the request of, and in cooperation with The California Gas Research Council 2, for the purpose of obtaining basic information on the gas-making fuels available to California, and their applicability to the present and future needs of the gas industry in that State. The data obtained have been applied in outlining a construction program, and indicate the possibilities in efficiently utilizing fuels in making gas by other than the oil-gas process. This paper presents an outline of the study and a summary of the principal results obtained, with some of the more important conclusions and recommendations based on this data. Gas is produced in California by processes which are both unique and different from those common to other parts of the United States. The bulk of the manufactured gas is made in and distributed from two main districts which are centers of population - namely, the Los Angeles district and the San Francisco Bay district. The gas manufactured in the Bay district is, almost exclusively oil-gas, whereas that produced in the southern part of the State, where natural gas is available, is mostly mixed natural gas and reformed-gas, but oil-gas is the chief product when the supply of natural gas is inadequate. Practically all of the gas companies are equipped with oil-gas generating apparatus, and anticipate using it in the future. As the continued use of the oil-gas process to the exclusion of all other processes, depends upon a continued supply of oil at a low cost, and the prospect of obtaining such low-priced oil in the future is somewhat uncertain, the questions have arisen: What will the future gas-making process or processes be? When will it be necessary to make plans for the installation of different gas generating equipment, and what will that equipment comprise?

Jan 1, 1926

By H. B. Brunot, L. C. IlsLey

The design , construction, inspection , and test for permissibility of a storage- battery locomotive outfit in accordance with the requirements of Schedule 15* represents a large amount of work, first on the part of the locomotive manufacturer and secondly on the part of the Bureau of Mines . Detailed information of the first investigation under the schedule is presented here . This investigation covers the inspection and test of a storage- battery locomotive manufactured by the Geo . D. Whitcomb Co. , Rochelle , Ill . , to which Approval No. 1500 was assigned ,

Feb 1, 1923

By Irving Hartmann

Following the severe starch-dust explosion in the casting department of a large candy factory nearly 2 years ago, great interest has been shown in the explosive properties and the safe manufacture and handling of powdered starches. Under the auspices of the National Fire Protection Association, a committee has been formed to prepare a code aimed at preventing dust explosions in the confectionery industry. One objective of this code will be to reduce the explosion hazards of starches that are widely used for molding, dusting, and other candy-manufacturing processes. The explosibilities of starches and starch mixtures have been studied in the laboratories of the Bureau of Mines and elsewhere. The results of the initial experiments made by the Bureau on 10 samples of cornstarch and mixtures of cornstarch with other materials have been published. In response to numerous requests for additional information, further laboratory studies have been conducted. Data have been obtained on the effects of dust concentration, particle size, moisture content, admixture of .calcium carbonate, and on the effect of oil treatment on the explosibility of cornstarch. The results of this investigation are summarized in this report.

Jan 1, 1950

By A. J. Keast

This circular is one of a series dealing with the exploration, equipping, and development of mining properties, prepared and published by the United States Bureau of Mines in cooperation with various mining and exploration companies in the United States and Canada. This series of papers will supplement an earlier one which covered the methods and costs of mining and milling at a large number of producing mines. The present paper describes the exploration, equipping, and developing of a group of 18 claims remote from rail transportation, and the transport of equipment and heavy supplies for a distance of 120 miles by tractor over ice and winter roads, and of men and lighter supplies by airplane.

Jan 1, 1933

By James J. Olson

The Bureau of Mines used micro fracture density analysis of quartz grains in thin sections and diametric pulse velocity measurements along preblast and postblast cores to determine the nature and extent of rock damage produced by small (0.25-,0.50-,1.0-, and 2.0-kg) charges of high intensity explosive (C-4) in granite. Pulse velocities from the postblast cores were significantly lower than velocities from the preblast cores and, with the core logs, provided clear identification of the upper and sometimes the lower limits of most severe damage. These zones ranged from about 1.68 ft for the 0.25-kg blast to 4.16 ft for the 2.0-kg blast. Microfracture densities from postblast cores were significantly higher and more variable than densities measured from preblast cores. The microfracture density measurements showed that microscopic damage was present far past the zones of most severe damage as delineated by the pulse velocity logs and core logs. An exponential relation-ship was observed between the micro fracture density levels and the charge weight.

Jan 1, 1973

By L. G. Marshall

The geology, mining, beneficiating, types of products, and costs in terms of percent of total costs and of labor, power, and supplies of two crushed- limestone operations in Madison County, Iowa, are described in this paper. The operations are basically similar, differing in refinements in mining, product types, and markets. The operations are comparable as to personnel and as to weighted costs in terms of percent of total costs and in terms of man-hours, power, and supplies. The waste-to-stone stripping ratio is 1 to 0.8 at both operations, the powder factor is 0.29 pound of explosives per ton of stone, and daily production is 95 tons per man-shift. Both companies use crawler-mounted diesel shovels for loading, truck transportation, wagon drills, and dry screening.

Jan 1, 1963

By Elton L. Litchfield

The techniques for direct initiation of detonation, developed by the Bureau of Mines, have been applied to gaseous mixtures of oxygen with methane, 'thane, propane, butane, or hexane. An exploding wire was used as the initiation source to determine minimum stored electrical energies required to effect detonation of mixtures between one-half and two times the stoichiometric fuel ratios. Detonations were obtained in the most easily initiated mixtures of ethane, propane, butane, and hexane for initiation energies between 24 and 33 joules at 1 atm and 28-43 joules at 0.5 atm initial pressure. Methane mixtures, at 1 atm, were not observed to detonate when initiated with up to 484 joules.

Jan 1, 1966

By M. V. Potter

"In nearly all fields of investigation, research laboratories and routine testing laboratories encounter problems in which the primary determinations involved in the study require the measurement of mechanical vibrations or motions. These vibrations,may be of an oscillatory nature covering frequencies from a few cycles per second up to hundreds of Kilocycles per second, or they may be more or less uniform study nations occurring at rather slow rates. In electrical, or mechanical methods. In the optical case the to cause the deflection of a light beam such that the motion of the mechanican system of the beam can be determined, then by direct the by direct observation on a suitable scale or by recording it’s the electrical methods the motions can be made to changes in resistance, capacity or inductance proportion to the mechanical displacement or electromagnetic means can used to generate directly a voltage that will be porpertuial to the instantaneous vicinity of the vibrations. Other devices are used in a special instance, also but in any cause the electrical methods produce a current that is an electrical counterpart of the mechanical motion, and the motion can then be studied by direct measurements of the current or by recording the current on suitable recording meters or oscillography. Mechanical methods are used in some instance but are generally not as convenient nor as flexible as the optical and electrical methods."

Feb 1, 1943

By Charles K. Rose

This paper presents some research studies of the rotary drilling of oil shale at the Bureau of Mines Oil-Shale Mine, Rifle, Colo. The experimental procedures and the rotary drill test equipment are described. Theories of rock drillability, rotary bit cutting action, and bit design are presented and discussed. The actions of various bit designs are analyzed and compared with the observed results of actual drilling tests. A cost estimate is made for drilling Colorado oil shale.

Jan 1, 1955

By P. C. Good

Work was done to determine conditions necessary for efficient electrodeposition of aluminum from fused chloride electrolytes. Aluminum was deposited from a molten chloride salt electrolyte over a temperature range of 150° to 750° C. At lower temperatures in a heat-resistant glass cell, aluminum was deposited on stainless steel and on aluminum cathodes. The deposit was recovered in the form of light, feathery dendrites that could not be consolidated. At 750° C, molten aluminum was deposited at cathode current efficiencies as high as 90 to 100 percent on titanium diboride cathodes and in molten aluminum cathodes. Nitride-bonded silicon carbide was the best cell material, although porcelain was also used. The electrolyte consisted of a mixture of sodium and potassium chlorides in 1 to 1 mole ratio, containing aluminum chloride in concentrations ranging from 2 to 30 weight-percent in cells holding up to 1,000 grams of electrolyte. Generally favorable results were attained in studies made at temperatures greater than the melting point of aluminum.

Jan 1, 1966

By W. J. Johnson

This report presents the Phase I progress in the development of a Radar Coal Thickness Sensor (RCTS) being conducted by Boeing Aerospace and Electronics for the Bureau of Mines. A method is developed for measuring both the dielectric constant and depth of the coal shale interface using a modified UHF network analyzer and antennas in proximity to the surface of the coal. Both bistatic and monostatic systems, are compared. The algorithm technique uses synthetic range gating for clutter rejection and full polarimetric scattering matrix techniques to extract the dielectric constant and depth to sub-wavelength accuracies. Tests were run both in the lab and in a coal mine to build an error budget and demonstrate a validation of the model. The development of a prototype radar suitable for coal mine robotics is specified.

Jan 1, 1990

By Edward L. Burwell

The Bureau of Mines investigated the use of dilute polymer in brine solutions to increase the efficiency of air in gas flooding model oil reservoirs. Slugs (0.23 pore volume) of 500 ppm polyacrylamide were injected into a model, consisting of a high- and a low-permeability core, that had been previously gas flooded to residual oil. Gas flooding was then resumed. Of the total gas volume injected, the percentage entering the high-permeability zone was greatly reduced after polymer injection but remained unchanged when slugs of water without polymer were used.

Jan 1, 1970

Research workers from the Bureau of Mines and industry met with other government and industry representatives at the Mont Chateau Lodge, Morgantown, W. Va., on May 30-31, 1973, to discuss the current status of methane control in eastern U.S. coal mines. The opening remarks, the eight technical presentations, and the discussions of the members of a government-industry panel are published here for the benefit of those concerned with the control of methane in coal mines. In addition, an introduction has been added to present the background of work in this field.

Jan 1, 1973

By Charles Prasky

This report describes bench-scale studies and pilot-plant development of the Bureau of Mines process for roasting iron ores with a ferrous scrap reductant, such as discarded automobile hulks, to yield artificial magnetite. Quality magnetic concentrates containing about 66 percent iron and 6 percent silica with iron recoveries of over 90 percent were obtained after roasting fine-grained oxidized or nonmagnetic taconite with unburned, sheared automobile hulks in a rotary kiln. The relatively complete oxidation of the lighter gage metal in the automobile during roasting resulted in a metallic byproduct consisting of the unconsumed heavier gage metal scrap. This residual or tailored scrap is potentially useful as heavy melting stock and has more value than the original automobile hulk.

Jan 1, 1970

By Oliver Bowles

The term "stone" in its broader sense includes not only the well-known limestone, marble, granite, sandstone, and slate but also precious and semi precious stones and many minerals and rocks not included in the principal groups. Stones have long been used for structural and ornamental purposes. To be so used, they must be cut to various shapes and sizes, and some must be polished to bring out their inherent attractiveness.

Jan 1, 1958