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By H. W. St. Clair

Sampling of heterogeneous mixtures of fused metals or solidified melts is subject to errors not met in sampling finely ground ores or granular materials. These errors arise largely because of the segregation of constituent metals that usually takes place during solidification. It is seldom that a random sample of a lot of metal will represent the composition of the entire lot. The problem becomes especially difficult when it is necessary to make accurate analyses for a segregated impurity present in very small amounts. This paper discusses some of the pertinent experimental observations made in selecting a method for sampling melts of aluminum and zinc containing small amounts of iron and silicon as impurities. Although this experimental study dealt only with sampling this specific combination of metals, many aspects of the study apply generally to any mixture of mol ten metals containing minor constituents that segregate rapidly during freezing of the melt.

Jan 1, 1949

Objective: To enable mine operators and mine inspectors to make quick and accurate measurements of the explosible nature of coal and rock dust mixtures.

Jul 1, 2008

By Scott Turner

We are here today to witness the graduation of 63 young men as Engineers in the mineral industries . It is an important occasion and one in which the public takes a keen interest , since this school has long been famous for the educational facilities it affords young men, and for the high professional standing of its graduates . : : : It is fitting that once each year we should pause to review the path the student has traveled , and to reflect upon the perspective opening before him as an engineer . I was invited to come from Washington to take part in this ceremony and to say something to these young graduates . In searching for a theme ," it occurred to me. that perhaps my best contribution would be to duscuss certain beliefs as to college training , deal with the situation in which the young engineer finds himself on graduation , touch on the new ideas of the social and political responsibilities of the engineer , and point out what he may expect to find in practice , and , above all , what he must do to orient himself properly in the mining profession and maintain the best traditions of our brotherhood . Let us first review your college days and see what they have done for you . I am told there are still many temptations in college . I know there used to be . Rest assured the same holds true in the professional life ahead of you. The main difference is , perhaps , that your greatest temptations in college were those offered by your teachers , who tried to entice you into realms of harder work, closer application , increased concentration , clearer thinking and better understanding , by animating your curiosity and increasing your powers of reasoning and of observation . In other words , here you have carefully and systematically been decoyed toward finer and loftier things . Do not expect that similar helpful influences will greet you on every side in your professional life . Often quite the contrary is the case .

Oct 1, 1930

The Bureau of Mines, in an effort to improve resource conservation, mine planning and development, is currently investigating the loading behavior of pillars in multiple-seam developments. The simultaneous mining of two or more coalbeds may cause instability between room-and-pillar operations resulting in an interaction known as pillar load transfer. Although pillars may be adequately designed for single-seam mining, the development of a second seam may complicate loading conditions in both operations. If pillars are not adequately designed to contend with this load transfer, failure of the mine structure may result. To improve multiple-seam development and pillar design, the Bureau studied the loading characteristics of pillars in three separate multiple-seam operations. In all three cases, instrumented pillars recorded increasing pressure after development of the second seam. Increases in the average pillar pressure ranged from 7 to 110 pct over predicted overburden loads. An analysis of pillar loading before and after second-seam mining indicates that the ratio of overburden to innerburden thickness is a critical factor influencing load transfer. Based on this relationship, safety factors for case study pillars are calculated and alternative design considerations are discussed.

Jan 1, 1988

By Charles L. Harnes

A mineral pigment is a colored substance dug from the ground, which after treatment can be mixed with a drying oil to form a paint. Not all colored earths, however, can be made into satisfactory pigment. Much depends upon the attractiveness and uniformity of the color and the ease of purification. Mineral pigments are distinguished from chemical pigments by a difference in origin and treatment. Chemical pigments are not found ready-made in the earth but must be synthesized or otherwise obtained from other compounds or elements; for example, cadmium yellow, a chemical pigment, is precipitated from a solution of cadmium chloride, hydrochloric acid, and sodium sulfide.

Jan 1, 1942

By C. L. Klingman

The Bureau of Mines tested eight commercially available, activated charcoals experimentally to compare the following characteristics: capacity for adsorption of nitrogen at 77° K and 170 atmospheres' pressure, surface area, carbon tetrachloride adsorption capacity, hardness, and density. The nitrogen adsorption test was devised to simulate plant conditions occurring in the final step of purification in Bureau helium faciliti.es. The remaining tests were patterned after empirical acceptance tests that are widely used throughout the adsorbent industry. Surface area and carbon tetrachloride adsorption correlated well with nitrogen adsorption. The samples with low density generally had better adsorption qualities than those of higher density. The carbon tetrachloride test appeared to be the most practical for selecting a charcoal to be purchased, but an attrition, or hardness test should also be run to be sure the charcoal will not crumble in use.

Jan 1, 1966

By K. C. Dean

A flotation method was developed by the Bureau of Mines for concentrating pollucite, a cesium-aluminum-silicate mineral that may contain from 20 to 40 percent cesium oxide. Separation of the pollucite from three typical ores was achieved by froth flotation of the associated micas, feldspars, and other gangue minerals, using sulfuric and hydrofluoric acids and a cationic-type collector. A low-tenor, 8 percent cesium ore from Maine was upgraded to 20 percent cesium with recovery of 87 percent of the cesium. Relatively high- grade ores from Canada and Southern Rhodesia were beneficiated at lower ratios of concentration to 28 and 29 percent cesium content respectively with recovery of over 92 percent of the cesium. In addition to concentrating the cesium content of ores, the method also effectively separates cesium from sodium, potassium, and lithium, and in certain ores from rubidium. This is accomplished by selective froth flotation of the alkali metal-bearing gangue minerals such as lepidolite, other micas, and feldspars. Since the alkali metals, especially potassium and rubidium, are difficult to separate chemically or thermally from cesium to prepare high- purity cesium products, separation by physical mans is important.

Jan 1, 1962

By Dennis A. Hansen

The solubility of anhydrous aluminum chloride in solutions of titanium tetrachloride and vanadium tetrachloride was determined as part of a re-search project-by the Bureau of Mines to make a homogeneous alloy sponge of titanium, vanadium, and aluminum. Solubility curves were established using an autoclave at 75°, 100°, 125°, and 150° C. The solubility of AJC13 in TiC14 is 0.2 wt pct at 75° C; it increases to 18.3 wt pct at 150° C. The data concur with data from earlier researchers of this bi-nary system for 75° to 125° C. For the VC14-AlC13 binary system the solubility of AlC13 is 0.1 wt pct at 75° C, increasing to 1.6 wt pct at 150° C. For the TiC14-AlClrVC14 ternary system the solubility of AlC13 decreases from the values found with a pure TiC14-AlC13 system to the lower values found with a pure VC14-AlC13 system at the respective temperatures.

Jan 1, 1986

By A. L. Engel

[This report describes preliminary tests of samples from six deposits of oxidized copper ores .in Nevada. The tests for the most part were confined to laboratory-scale acid leaching to extract the copper.'The exceptions consisted of flotation tests to demons' ate the possibilities of treating the ore by that method. The samples tested were representative of oxidized copper ores from six counties in all parts of Nevada. The results obtained by the preliminary tests described were indicative of the extractions of copper to be expected, In the five leaching experiments, the approximate consumption of acid was also indicated.]

Jan 1, 1953

By R. S. DeCesare

Operation of the Bureau of Mines raw refuse continuous separation pilot plant is described, including modifications made to plant equipment for improved performance. Products recovered from refuse, many of which have been evaluated by other laboratories and private firms, are discussed. Sampling procedures used in the pilot plant and detailed data obtained from processing refuse from 13 municipalities are presented in appendixes. Fuel evaluations made on combustible fractions of refuse from the various municipalities are also presented. Information and data obtained at the pilot plant have been used to assist many municipalities in solving their urban refuse problems.

Jan 1, 1980

By Hillary W. St. Clair

Reaction rate coefficients were determined from analyses of the effluent gas for the reduction of granular ferrous oxide to metallic iron by passing carbon monoxide through a packed bed of oxide at a controlled rate in the temperature range 1,000° to 1,300° C. Coefficients were determined by the comparison of observed analyses and calculated analyses using a mathematical model that takes into account the nonuniform composition of both the solid oxide and the gas. A method is also given for finding the value of the rate coefficient that best fits the observed data.

Jan 1, 1968

By H. S. Caldwell

The objective of this investigation by the Bureau of Mines was to develop and test for laboratory use a retort embodying many features required for practical commercial-scale applications of vacuum distillation of metals. A gas-fired vacuum retort was developed comprising a hollow, cylindrical graphite liner encased in a thin shell of stainless steel. The liner prevents the shell from collapsing under vacuum and protects it from corrosion by metal vapors and the molten metal charge. The vacuum-tight shell protects the liner from oxidation and flame erosion. The retort was used to distill zinc from dross and die-casting scrap. More than 99 percent of the zinc was recovered as a condensate containing 99.8 to 99.9 percent zinc. (Atmospheric distillation recovers 95 to 98 percent at a purity of 99.5 percent zinc.) Distillation rates of 50 pounds of zinc per hour were attained at a temperature of 65° C. with pressures ranging between 50 and 100 microns. Distillation at this low temperature is not practicable at atmospheric pressure. Also, the retort is suitable for distilling other volatile metals such as cadmium and magnesium.

Jan 1, 1961

By R. J. Heemstra

A method was developed for calibrating photographic emulsions and retrieving working curves for emission spectrography. The values obtained from a digital readout or a recorder chart of a comparator-microphotometer are converted to light intensity values using an emulsion characteristic curve derived from a quartic polynomial preliminary curve. The characteristic curve, consisting of Seidel transform versus the logarithm of intensity, is split into two cubic polynomials at the zero value of the transform, resulting in eight emulsion calibration coefficients. These methods allow use of the calibration curves even at very small and very high intensities, thus extending the range of analysis. Use of a small computer allows rapid calculations. A computer program was written to formulate, code, and file each working curve along with its statistical error. Proper coding of the input data permits the direct printout of the concentration of the elements under investigation.

Jan 1, 1970

By J. G. Donaldson

Binary alloys of molybdenum and tungsten were prepared by the Bureau of Mines in laboratory-scale experiments by hydrogen reduction of their vaporized hexafluorides. Near-optimum deposition parameters were determined, and the nature of the deposited alloys was investigated. Dense, homogeneous alloys were codeposited between 650° and 750° C with a reduction efficiency of more than 75 percent. The alloy composition was uniform when the hydrogen ratio in the gas feed mixture did not exceed 3 times the stoichiometric requirement. Regulating the proportions of the metal hexafluorides in the gas feed provided a large degree of control over the composition of the deposit. Hardness of the deposits varied directly with the proportion of excess hydro,,,, in the gas feed and with the weight-percent of tungsten in the alloy. Hardness was not affected by deposition temperature over the range 650° to 750° C for specimens of similar composition. Extreme brittleness and unsuitable physical shapes of the alloys prevented tensile strength measurements.

Jan 1, 1966

By O. C. Blade, Elizabeth Hughes

Conservation in the utilization of any product is always subject to improvement if the composition and properties of the product are known. Petroleum is no exception, and knowledge of the characteristics of crude oils, even when given on the broad basis of routine type analyses has proved useful to chemists, engineers, and geologists in improving pro- duction and utilization of petroleum. For a quarter of a century the Bureau of Mines has sought to provide such information regarding crude oils and has analyzed many samples of petroleum by its standardized rou- tine method. Most of these analyses have been published, sometimes in special compilations, other times in connection with reports of research on petroleum. This report is a finding index for all analyses published up to January 1, 1948. The routine method used for all these analyses is basically the same as that described by Dean, et al.. Briefly, the procedure consists of testing by standard methods, small samples of a crude oil for gravity, sulfur, color, and viscosity, and of distilling a sample of the crude oil by a standardized procedure and determining certain properties in the sep- arated fractions and residuum. Careful records are made during the proce- dure, and the distillation data obtained are used to calculate the approx- imate amounts of products present in the sample such as percents of gas- oline, kerosine, gas oil, and lubricants. The data obtained are recorded on a standard analytical report form. An analysis of a sample of typical midcontinent crude oil is shown in table 1. Compilation of these analyses, sometimes in tabular form and usually for specific geographic areas, are published from time to time. Analyses are often shown in connection with other studies, such as engineering field reports. This bibliography is a compilation of references to 115 publications, which contain analyses of crude oils by the Bureau of Mines. References may be found to analyses of crude oils from the United States, Canada,

Jun 1, 1948

By W. H. Ode, W. A. Selvig

Briefly, this swelling test consists in heating 1 gram of pulverized coal in a silica crucible over a gas flame under prescribed conditions to form a coke button which is compared in size and shape with a series of standard profiles numbered 1 to 9. These profiles are intended to cover the size and shape of buttons obtained from coals covering a wide range in plastic properties. The number of the standard profile with which the maximum cross-sectional area of the button most nearly corresponds is recorded as the swelling index. Although the swelling test showed poor relationships with the various tests that were used for measuring expansion or contraction of coal during carbonization, it gave indications of having value in measuring free-swelling and coking properties of coals when burned on fuel tests. An opportunity to investigate this occurred when an engineering company reported pronounced differences in burning characteristics on grates of various shipments of Pocahontas coal. Some of these coals gave trouble by swelling excessively and clogging the grate. Samples were obtained, and it was found that the troublesome coals gave radically higher free-swelling numbers than did the coals that performed satisfactorily. Also, it was found that the free-swelling index test gave better differentiation between coals than could be obtained from the coke buttons from the standard volatile-matter test or iron agglutination-value results. The results of the free-swelling test were confirmed by the Subcommittee on Plasticity and Swelling, Coal, a special group of the Subcommittee, under the chairmanship of R.A. Shuman, worked along with the test method. Estberg, Limacher, and Shuman of the Battelle Memorial Institute investigated the various factors affecting the test and found that the swelling index was a good indication of the suitability of coal for performance on residential-type stokers from the swelling characteristics of the coal. Data were presented that also showed that the index was helpful in the selection of coal for industrial underfeed stokers.

Feb 1, 1948

By J. A. Eisele

The Federal Bureau of Mines is engaged in a continuing program on the recovery of alumina from domestic source materials. Of the six processes being studied, current efforts focus on HCl leach of clays. A key step in the HCI process is the removal of iron from the aluminum chloride leach liquor. This was accomplished .by solvent extracting the iron with a tertiary amine in kerosine to which decanol was added as a phase modifier. In a mixer-settler operation, iron in the raffinate was reduced to <10 ppm in two extraction stages from a feed containing 1.4 gil Fe. Iron was stripped from the organic phase in three stages with dilute HCl.

Jan 1, 1976

By Gerrit V. R. Goodman

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 4D ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face? 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm. This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 4D ft.

Jan 1, 2010

By P. M. Sullivan

The principles and application of amalgam electrolysis to the recovery of zinc and tin from secondary products were studied; this Bureau of Mines project was one phase of investigating the development of more efficient methods for processing iron-bearing zinc and tin to produce both base metals of high purity. Zinc of 99-99-percent purity was recovered from galvanizer&apos;s dross with recovery efficiency of 98 percent. Tin of 99.9-to 99.99-percent purity was recovered from hardhead with recovery efficiency of 81 percent. Both materials were treated by the same method in separate systems. Mercury was used to leach zinc from dross and tin from hardhead to form amalgams of each metal, both of which were subsequently refined electrolytically to produce high-purity metal. Impurities that were contained in both secondary products behaved as theoretically predicted; impurities that were insoluble in mercury remained as sludge in the leaching column. Except for lead, the readily amalgamated impurities were prevented from fouling the electrolyte by the blocking action of the amalgam electrode. Lead impurity in the tin-refining system dissolved and immediately precipitated as the sulfate. The primary advantage of the amalgam refining method lies in direct recovery of the extremely pure base metal from highly contaminated secondary material.

Jan 1, 1961

By Robert J. Hundhausen

This information circular is one of a series of Bureau of Mines reports dealing with mining and milling methods and costs . It describes the operations at the Little Pittsburg mine in the Pine Creek area of the Coeur d'Alene mining region near Kellogg , Idaho . The mine and mill have been operated successfully from 1942 to the present .

Feb 1, 1948