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By Donald I. Kurth

The Bureau of Mines conducted experimental work on comminuting coal. The size distributions of coarse fragments and fine particles were obtained under different modes of energy application--drop, impact crushing, wedge impact, compression, and shear tests. Four levels of energy application were used in the impact crushing and wedge impact tests. Airborne dust and respirable air-borne dust distributions were obtained for the impact crushing and wedge impact tests. Analyses of nonairborne dust and coarse fragment-fine particle distributions were carried out on impact, wedge, compression, and shear tests. The experimental size data on nonairborne dust were fitted to normal, log-normal, power law, Weibull, log-Weibull, and exponential distribution functions. Both the nonairborne dust and the coarse fragment-fine particle size distributions are best described by Weibull distributions. For the impact crushing tests, mean product size was found to be inversely related to specific crushing energy. The particle counts in a given size range of airborne and nonairborne dust were found to increase with increased input energy and specific crushing energy. However, in another sense the particle distributions were independent of energy level; that is, the percent-ages in a given size range were approximately constant regardless of energy level. Respirable airborne dust was related to respirable-size nonairborne dust by a power law.

Jan 1, 1975

By R. G. Travis

1. Reserve estimates have been made for eight coal beds in Monongalia County, W. Va., but only the Pittsburgh, Sewickley, and Upper Freeport beds are important at this time. The Pittsburgh, Sewickley, Waynesburg, and Upper Freeport beds contain the largest recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 3,526 million tons as of January 1, 1954. Of this total, 3,294 mil-lion tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By M. M. Wong, J. E. Klosterman

Scrap beryllium chips ( nominally 96 to 97 percent Be ) were electrore fined in a prototype cell with 408 lb of electrolyte composed of 52.4 mole - percent LiCl , 36.3 mole - percent KC1 , and 11.3 mole - percent BeCl2 . The cell temperature was 500 ° C. In a typical 10-3 /4 - hour deposition cycle , 0.415 pound of metal was produced ; the metal contained impurities in parts per million as follows : C , 700 ; 0 , 610 ; Al , 34 ; Ca , 32 ; Cu , 20 ; Fe , 25 ; Mg , 9 ; and Mn , 23 . Operation of the prototype cell for 2 years demonstrated that adapting the electrorefining process to an enlarged scale of operation presented few difficulties in mechanical functions , maintenance of optimum operating conditions , and control of product purity . After the spent anode feed was leached in a 5 - percent nitric acid solution and the fine - sized particles were removed , it was recycled in some tests . The metal produced was somewhat higher in impurities than metal from the fresh scrap chips .

Jan 1, 1964

By M. E. Tyrrell

Mixtures of zirconium diboride and iron, cobalt, and nickel were resistance sintered to high-density compacts using modified electric welding equipment. To evaluate the use of iron, cobalt, or nickel as binders for zirconium diboride, the sintered compacts were examined in polished section and tested for crushing strength, hardness, microhardness, oxidation rate, and resistance to mechanical shock. Each of the zirconium diboride-metal mixtures produced brittle cermets, but the hardness was generally satisfactory. The iron- and cobalt-bonded cermets exhibited rather poor oxidation resistance. Cobalt provided the least brittle bond, and nickel, the hardest and most resistant to oxidation. Iron tended to form chalky compacts with low resistance to mechanical shock.

Jan 1, 1963

By F. G. Miller

[Petroleum technoloF;istz and 1 rot-re s s ive OT e:?ztors. con stantl;, are striving to increase the percentage of oil that y to recovered from reservoir rocks throe::;:: wells. The exhaustive studies that have been made of the function of natural r:; as in t h-_ T r odI action of oil, for cx<n.mTnle, have aidedd of.erators greatly in incroasin,&apos; the q-:Arrntity of oil recovered from reservoirs. i.rtural gas dissolv3d in ar--d otinerwwisa &apos;1s&apos;.,ocintjd under rre3suro with oil in roscrvoir roci.s, howover, i:; not the only source of energy available for moving oil through sa&apos;:&apos;l to wells. l becoming "reservoir-energy conscious&apos;t engineers hr-vo -d o^.rued t}:-Lt in many petroleum reservoirs the edgewater flanking t -,e oil accum.-,lation conetitutos a potential source of onergy capable, tL-ou;_h rro? gr control, oil&apos; increasing oil-recovery efficiencies materially. i o ]enter is ti-.-,, on-cronchinunt of water into the oil- and gas--fillod ?art of the reservoir considered as an evil to be combatted by devious mot&apos;:r:ci :i,.t r,ttL er a natural conseque::c4, incident to the withdrawal of oil nna gas from the wells, that nay be T.usod advantrt eou ;ly in lonr`t}toning tr e r&apos;lowin g lift of wells a.nd, i norcas in:; the economic recovery of oil and Little is known about the by which water off: oratos in driving nil throe:gh reservoir roc:-.:,, nd i:. a scorcity of rubli:;Lad informs-¬t .on nn rates of :)Ov.:m.,:- t of : r.tcr ..at v:1:11 res,-_lt in ^r i-nu oil recoveries. Bureau of :fines engine_:? ; - reciate. the r,aucity of scientific knowledge or. the &apos;test methods of a,r.lying the natural water arive to in¬crease oil-recovery efficiencies ant ,i.;?l __-itir?,~ ting irties that will, they hope, Contribute to t.1&apos;.e T ros?Jr.t. small _ %nd of information now av tilable on tt:e cubjoct. This r».crt a oyno-.::is or brief comrilnt.ion of r,ublished data and thought accuinulnt.~d so far, to la)or;~.tory ox-:erimnntrr¬tiorn and, further rosoarch on the z_rrinciplos unri;rlyir..g the natr.rr+1 eater drive no it nffocts oil recovery. :Lie writer:: Lore that t.i.c cx-nositiorn of a?rzilable inforr-at ion i rcs?r.toi in the rernrt r .-II .i ,.1rtt cor_jt_-i:ctive tho.-_.I_t and efforts loadir,-z to -:ard more con.r .ote extraction n;&apos; o tl from reservoirs.]

Jan 1, 1938

By O. M. Bishop

From October 1943 to March 1944, the Bureau of Mines conducted core drilling at the Victory fluorspar mine, Hardin County, Ill. to test the Fredonia limestone and the included sub-Rosiclare sandstone zone beneath the existing stopes. Twenty-one vertical holes were drilled to an average depth of 60 feet. Ore was penetrated in six holes. Since its discovery in 1927, the Victory mine has produced approximately 5 percent of the total fluorspar mined in the United states after that date. The ore discovered in the early mine development is now exhausted, except that contained in pillars drifting to the northeast has partly developed one substantial ore body, and company drilling has indicated another nearby. The increasing need for fluorite for war use in 1943 suggested the desirability of mining the pillars, provided it could be established that no ore beds existed below the stopes or in areas to which access would be obtained through the present workings. This work describes the work accomplished during the project and presents the data obtained.

Jan 1, 1948

By Oliver Bowles

"Asbestos" is not the name of a distinct mineral species but is rather a commercial term applied to fibrous varieties of several minerals. The origin and significance of names applied to asbestos by early writers are discussed in the section devoted to sources of supply and terms employed in ancient times. VARIETIES The most useful variety of asbestos is chrysotile, a fibrous serpentine the composition of which is expressed by the formula H4Mg3Si209. Chrysotile is characterized by a strength and flexibility that permit the use of the longer fibers for spinning. The bulk of the world production of both long and short fibers, is of this variety.

Jan 1, 1935

By H. C. Miller

For nearly a score of years the American petroleum industry has faced the problem of maintaining its economic structure while oil -producing potentialities greatly exceeded the increasing market demand for oil and its products . However , the combination of maximum civilian demand with rising defense requirements caused an all - time peak in crudeoil production in the latter half of 1941 , with a daily production (as estimated by the Bureau of Mines ) of 4,139,000 barrels in December - an increase of 16 percent over the daily production of 3,573,000 barrels in December 1940. In the event of a long war , a continuing , steady, and adequate supply of petroleum and its products for military and required civilian needs is essential, and the efficiency of recovery of oil from natural underground reservoirs will have to be maximum. Whereas it may not be possible to increase production in some fields , the output from others may have to be drawn at a much faster rate than formerly . More than 10 years ' experience in operating oil fields under proration control has demonstrated to petroleum engineers that some of the efficiency of recovery of oil from reservoir sands and rocks is sacrificed if the oil and gas are withdrawn at too . rapid a rate . As petroleum is an irreplaceable natural resource for which suitable substitutes probably will not be available in desired quantities for many years , any producing method that jeopardizes the quantity of oil that may be recovered from underground reservoirs must be considered at this time of declared war against aggressor nations as conflicting with the best interests of national defense . At best, the efficient recovery of oil is a complex problem . It involves not only a knowledge and application of the fundamentals of fluid flow through porous mediums, but the sources of energy responsible for the movement of oil and gas through reservoir sands and porous rocks to wells must be known to determine the best practices for extracting these hydrocarbons . Reservoir energy is of two kinds - (1 ) water under hydrostatic head underlying the oil in the extraneous parts of the reservoir system and ( 2 ) natural gas under pressure as "free " gas in the reservoir or in solution in the oil . Inasmuch as the efficiency of oil recovery depends largely on the manner in which reservoir energy is used to move oil through reservoir sands and porous rocks to wells , optimum practices for withdrawing the oil cannot be determined until it has been established that the oil in the reservoirs is being forced to wells by an internal gas expansion, by a natural water drive , or by a combination of gas expansion and water drive . There is a fundamental difference in the performance characteristics of gas - expansion and water - drive reservoirs . In a strictly gas - expansion reservoir the energy available to move oil and gas through the porous formations to wells results solely from gas pressure , which is maximum when the reservoir is tapped by the first well . Pressures decline as oil and gas are withdrawn ; consequently, the energy available for moving oil and gas through the oil - bearing formations to wells decreases with production . Curtailing the oil - production rate or shutting in gas - expansion reservoirs entirely will not act to replenish energy previously used in the production of oil and gas ; in their operation , therefore , it is especially important not to waste reservoir energy - the production of oil with high gas : oil ratios will be reflected in lower ultimate recoveries of oil .

Apr 1, 1942

By James W. Townsend

The Vicksburg mining property lies in the southeastern foothills of the Star mining district, Beaver County, Utah (fig. 1). Within a few miles of the Vicksburg mine, lying in a semicircle from south to northwest, are such past producers of lead-silver ores as the Moscow, Hoosier Boy, Red Warrior, Wild. Bill, Harrington-Hickory, and many others. Farther to the north, in the San Francisco district, are the famous Horn Silver and Cactus mines. The formation at the Vicksburg property consists of interbedded limestone, shale, and dolomitic limestone. These beds have been metamorphosed by the intrusion of irregular masses of porphyritic igneous rocks grading from quartz-monzonite to granodiorite. Ore deposition is in north-trending fissures of sheeted zones, contact metamorphic in type. These depositions were subsequently altered to gossan. A preliminary investigation of the Vicksburg property involving surveying, mapping, and sampling was made by W. A. Young and F. H. Gunnell, engineers of the Bureau of Mines, in the fall of 1946. As a result of the investigation, a project was set up to investigate the possibility of ore occurrence at greater depth on the fissures under the mineralized zone by diamond drilling.

Jan 1, 1950

By B. B. Letson

The heats of formation of lithium chloride and lithium oxalate were determined with the aid of a Bureau-developed, glass Dewar-type solution calorimeter which uses thermistors as its temperature sensing element. Values obtained at 298.15° K were -98.38 ± 0.54 kcal/mole for lithium chloride and -329.02 ± 0.79 kcal/mole for lithium oxalate, using graphite as the standard state for carbon.

Jan 1, 1965

By R. W. Van Dolah, N. E. Hanna, F. C. Gibson

Measures that were taken to eliminate noise resulting from explosives work at the Bureau of Mines facility at Bruceton , Pa . , are described . A method for monitoring sound transmission characteristics of the atmosphere and control of the explosives testing is presented as a noise control measure that offered partial relief during the period in which the modifications were made . Design details of the replacement gallery , used for permissibility testing of explosives , and the modifications of four types of bombproofs are given . Operation of the closed facilities are completely satisfactory , and the noise problem has been entirely eliminated .

Jan 1, 1964

By A. D. Hahn

This report describes reconnaissance by the Federal Bureau of Mines of titanium-bearing sandstone in Kemper County, Miss. The purpose was to determine the ilmenite, rutile, and associated heavy-mineral content of black-sand-bearing Eocene deltaic formations" The investigation was part of a survey of titanium resources of the United States. Ilmenite (FeTi03), an iron-titanium oxide, is the major titanium-bearing mineral consumed in the titanium pigment industry. Rutile (Ti02), titanium oxide, is used mainly in producing welding-rod coatings and titanium metal. The fieldwork was conducted during the first half of November 1959. Seven holes, totaling 304 feet of bore, from which 64 samples of cuttings were taken, were drilled in the north-central part of the county; and two holes, totaling 172 feet of bore, from which 34 samples of cuttings were taken, were drilled in the southeastern part.

Jan 1, 1961

By K. S. Gritton

The Bureau of Mines investigated the feasibility of numerlcally modeling the sorption of cobalt, a vulnerable strategic and critical metal, from spent copper leach solutions in a multiple-compartment ion-exchange (MCIX) column. Equilibrium resin loadings, cobalt-sorption kinetics, and resin-fluidization characteristics were determined in simple laboratory tests, and a numerical model was developed to predict cobalt extraction and the MCIX-column resin inventory based upon the test results. The model was implemented on a microcomputer to approximate the solution to the set of differential equations that govern model performance. Results compared very well with data from 12 pilot-scale MCIX-column experiments. The average difference between predicted and actual cobalt extractions was 3.2 pct; the maximum difference was 9.3 pet. The actual and predicted resin inventories differed by an average of 5.8 pet, and the maximum difference was 12.0 pct.

Jan 1, 1987

By F. F. Aplan

Separation of the slightly soluble minerals (Ksp? 10-10), one from the other is one of the more difficult tasks confronting flotation engineers. This study has focused on means of separating such prominent members of this class as scheelite, fluorite and calcite from one another. Some experimental work has also been done on the minerals magnesite, dolomite and apatite. Carboxylic acid-type collectors are commonly used industrially to float all of these minerals. Thus, the problem at hand is to ascertain means of achieving selectivity between minerals known to respond rather similarly in flotation. Four techniques have been proposed for the separation of minerals of this class from each other: 1. Control of potential determining ions 2. Use of stereo-specific collectors 3. Use of flotation rate differences 4. Use of selective activating and depressing compounds. This study was directed toward a cursory evaluation of each of these techniques, and each was found to be a possible method of achieving selectivity. Stereo-specific collectors -- those whose parking area may closely match the available adsorption site on one mineral but not on another -- are a possible means of achieving selectivity between scheelite, fluorite and calcite. Stereo-hindered carboxylic acid salts and sulfonates all show selectivity between the three minerals tested. Separations also appear to be possible by the controlled use of the lattice ions (e.g., Ca and [W0=4] for scheelite, CaW04), H+, [OH-, C0-3 and HCO=3]; all of them ostensibly potential determining in the systems studied. Flotation rate differences of the minerals as a function of pH under conditions of starvation collector usage also showed promise. Scheelite and fluorite float most rapidly with sodium oleate in slightly acidic (pH 4-7) solutions whereas calcite floats most rapidly near pH 10. Use of Mn++, Pb++, or other heavy metal hydroxy complexes as activators was seen to effect each of the slightly soluble minerals differently. This is in sharp contrast to the oxygen containing, relatively insoluble minerals, where all minerals respond in a similar manner to such activation procedures. Results indicate that all four methods outlined above may potentially be used to achieve flotation separation of the slightly soluble minerals. More extensive research should be undertaken to detail the spcific applicability of each of the procedures and to make a more complete evaluation of the effect of collector type and concentration, mineral type, pH and size effects.

Jan 1, 1983

By P. A. Lawless

The objective of the research performed A for the Bureau of Mines on this contract was to develop a portable instrument for the detection of carbon monoxide (CO) in a mine environment. The desired characteristics were sensitivity and specificity for CO with a stable calibration. The sensor of the instrument was to be of metal oxide composition, requiring low power for compatibility with the types of batteries presently used in personal equipment in mines. The solid state design was also desired for ruggedness and small size. A key design feature of the instrument was to be provided by adherence to the intrinsic safety design requirements for electrical equipments operated in potentially exposive mine atmosphere. The Research Triangle Institute has prior experience in developing a solid state oxygen sensor using a thin film of zinc-oxide (Ref. 1) and experience in fabricating thin film devices. Solid state sensors utilized by other workers (Refs. 2, 3, 4, 5, 6) have included metal and semiconductor films and crystals of materials like carbon and aluminum oxide for the measurement of water vapor in the air and have relied upon measuring resistance and capacitance changes in the sensor in response to adsorbed vapors or gases. Since the effect of carbon monoxide in changing the resistance of various materials such as molybdenum, platinum, and zinc oxide had been reported (Refs. 7, 8, 9, 10), the requirements appeared to be realisable, although it was recognized even at the inception of the work that specificity to carbon monoxide might require the incorporation of more than one sensor.

Jan 1, 1976

By D. Harrington

The record of fatalities from mine explosions in the United States during the past 44 years has been the best in the history of the mining industry, despite the fact that the number of fatalities from this cause during the past fiscal year now is nearly double that of the previous year. During there 4 fiscal years, mine explosions have resulted in an average of 45.5 deaths per year, compared with an average of 153 deaths per year for the preceding 5 years; an average of 542 deaths per year for the 3 years 1907-1909, inclusive, and a yearly average of 265 deaths per year for the 20 years prior to 1929. Other types of mine accidents also have been reduced during this period, but not to the same degree or by as large a percentage as mine explosions. The fact that in this fiscal year ended June 30, 1937, electricity was responsible for 60 percent of the explosions and 85.5 percent of the fatalities resulting therefrom (see tables 3 and 4) is evidence that either mine operators are lax in providing proper electrical equipment or there is laxity in the upkeep and use of electricity in our mines and more particularly in our coal mines. Several large coal-producing States that in the Fast have had numerous disastrous explosions have been free from such disasters for continuous periods of as long as 8 years. The bituminous mines of Pennsylvania, one of the largest coal-producing States, give a good example of what can be done to prevent explosions. &apos;his State, with its large number of operating mines, many with very definite hazards from gas or dust or both, has had only two major explosions (resulting in 16 fatalities) during the past 7 years; this is a decidedly good record compared with any similar period in the past and when it is considered that during this period about 750,000,000 tons of coal have been produced. Other good records are: Tennessee, without a single fatality from explosions during the past 9 years; Alabama, with 6 fatalities during the past 7 years; Illinois, with no explosions during the past 4 years; and

Jan 1, 1938

By Edwin B. Cook

This report presents the results of calculations of the equilibrium composition of the products of combustion with air of six different mixtures of octane CgH18, plus PbEt4 and halogen-bearing scavengers at three air-fuel ratios, at pressures of 5 and 30 atm., and at temperatures of 350°, 1,000°, 1,800°, and 2,000° K. The air-fuel weight ratio has the values 12, 15:12, and 18. The concentration of PbEt4, M, in milliliters per gallon of iso-octane, has the value 1 or 3. The word "case" is used to designate the halogen concentration. Three cases have been considered [ ]

Jan 1, 1953

By E. L. Garton

The Bureau of Mines for a number of years has been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2913. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By N. E. Hanna

The current Bureau of Mines active list of permissible explosives includes 124 brands. Thirteen are gelatinous and the rest are the more commonly used granular ammonium nitrate type. The list of permissible blasting devices comprises five Cardox models.

Jan 1, 1965

By John Ward Smith

The potential economic value of oil shale depends on the products from thermal degradation of the rock, because no other practical method for producing valuable material from oil shale has been found. Detailed study of thermal degradation behavior can aid in characterizing oil shales and their deposits and in evaluating oil-shale processing methods, Numerous publications describe various pyrolysis properties of oil shales (see surveys 3, 9, 11 and articles 1, 2, 4-8, 10, 12),4 but they do not describe a generally applicable analytical procedure for detailed evaluation of thermal degradation products. The analytical method presented here for such evaluations is designed to provide for: 1. Control of retorting conditions--temperature, heating, rate, reaction atmosphere--plus some control over retort pressure and carrier-gas flow, 2. Precise direct gravimetric measurement of the thermal degradation products--oil, water, gas, and spent charge (residue after thermal treatment of the charge). 3. Samples of all products. 4. Determination of the identities and amounts of gaseous compounds produced. 5. Elemental analysis and gross heating value of all products. 6. Determination of the distribution in the retorting products of the elements present in the original samples.

Jan 1, 1962