Search Documents

By E. P. Olberg, A. Yu. Chikin, S. V. Petrov, M. P. Belykh, N. L. Belkova

"Bacteria that grow in autochtonous communities of gold heap leaching (HL) wastes are adapted to high concentrations of contaminants and environmental conditions. An example of a mine in the Sakha (Yakutia) Republic showed that the bacterial factor had a significant influence on cyanide breakdown and copper and nickel removal in the conditions of HL ore pile zoning compared to chemical oxidation. The diversity of bacterial communities growing in natural and simulated conditions of a HL ore pile was determined for the purpose of the study. The identified bacterial communities included genus Achromobacter and Serratia, which were found to be adapted to a wide range of temperature and can be considered as potential microorganisms for detoxification of gold HL wastes. INTRODUCTION Technologies and systems of passive treatment are of a special interest in relation to solving environmental problems of gold HL wastes detoxification, when neutralization time is not considered as a limitation (Alvarez et al. 2005). Passive treatment methods are based on reagentless spontaneous breakdown of cyanide caused by natural factors, including activity of autochthonous bacterial communities. Implementation of a reagentless biodetoxification technology for mature HL operations provides reduction of environmental impact on industrial site locations and substantial economic benefits compared to conventional chemical processes of neutralization that prevail in the Russian Federation territory. Passive treatment of cyanide-containing wastes was investigated by M. Botz, T. Mudder, S.V. Petrov, L. Simovic, A. Smith, C.A. Young etc. However, the bacterial factor (autochtonous bacterial communities) role in this process is practically unexplored. Thus, the aims of the study included the investigation of a bacterial factor influence on passive treatment of gold HL wastes and the identification of functional groups of bacteria involved in passive treatment."

Jan 1, 2018

By Fengming Li, Baocheng Song, Yuemin Zhao, Hailin Dong, Liping Peng, Chusheng Liu, Chenlong Duan

The large-scale vibrating screens with high processing capacity and efficiency are now in great demand in the mineral processing industry of China. However, as the equipment is always suffering from the strong external harmonic exciting force, the inertial force and the impact from the minerals, the fracture of the beam and the crack of the lateral plate are easy to occur, which has a negative effect on the reliability of the equipment itself and the industrial production. Considering the essential high reliability of the equipment, a new large-scale vibrating screen with duplex statically indeterminate mesh beam structure (VSDSIMBS) was developed. The natural characteristics, namely, the natural frequency (or the modal frequencies) and the natural mode, and the dynamic characteristics of the VSDSIMBS were obtained by the modal analysis and the harmonic response analysis. In addition, the dimensions and the constructions of the statically indeterminate plate and the mesh beam were chosen as the design parameters, to which the sensitivity of the whole mass, the maximum deformation and the maximum stress of the duplex statically indeterminate mesh beam structure (DSIMBS) were summarized for the optimization of the DSIMBS. Now the large-scale VSDSIMBS is being well used in China.

Jan 1, 2014

By D. Saramak

The comminution technology based on High-Pressure Grinding Rolls presses (HPGR) application is currently one of the most efficient methods of hard ore comminution from the scope of the energy consumption and the development of industrial HPGR applications in ore preparation circuits is presently the world trend. However, even though the technology is already in use in many countries, which are the leaders in application of modern mining technology, there is still lack of base investigations over the HPGR performance. Throughput and energetic models of HPGR performance are quite well developed, but technological models predicting the comminution effects still needs an in-depth research. In the paper authors present the method of modeling of HPGR products? particle size distribution with using of suitable mathematical models. A basis of the HPGR performance assessment and HPGR-based crushing circuits design is a product?s particle size distribution. In order to precisely determine the particle size distribution of a HPGR product, parameters of product?s particle size distributions should be conditional on the main technical parameters of the roller press like operating pressure and the speed of rolls. The most accurate approximation of a distribution of size particle d appeared the Weibull?s truncated distribution and it is possible to obtain significant relationships between the approximation formula and the value of operating pressure, or feed characteristics. It makes possible a determination of mass recoveries of the product?s respective size fractions and the productivity planning. Instead of pressure (P), the other HPGR operating parameters can be applied, but the P value appears to produce the most relevant relationship. Keywords: HPGR, comminution, particle size distribution, ore processing

Sep 1, 2012

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By A. Usov

The studies carried out by the Russian researchers and those carried out jointly within some contracts with scientific organizations and companies of other countries, show that the electric pulse disintegration of materials (ED), proposed and investigated in detail in Russia (Kalyatsky, et al, 1980; Usov et al, 1987; Semkin et al, 1995; Usov and Tsukerman, 2000; Kurets et al, 2002) has been widely recognized and developed abroad (Andres, 1995; Inoue et al, 2000; Biela et al, 2008). The Russian and international journals and the proceedings of the conferences dealing with the electric pulse disintegration pay great attention to the principal principals of selective disintegration of materials. There is no, however, any information concerning both the technical means developed to implement the technique and the assessment of their performance, which would be necessary in objective assessment of the industrial use of the technology. The results of long-term studies of the technique and technologies of electric pulse disaggregation by research institutes such as Research Institute of High Voltages (Tomsk), Kola Science Centre of RAS (Apatity), Institute "Mekhanobr"(S.Pertersburg) described. Exploratory stands and technological installations are developed to carry out pilot tests and operations under production conditions. Basic circuits and classification of technical means electric pulse disintegration of the materials are proposed, the analysis of transportation schemes and classification of the material in the disintegration apparatus are given, construction of chambers for continuous stadial disintegration of ores and materials are presented. The features and technological efficiency of electric pulse disintegration of various types of ores, and the spheres of effective use of the method have been determined. Keywords: electropulse disintegration, disintegration machines, chambers of comminution, stadial comminution.

Sep 1, 2012

By M. P. Krasteva

The froth flotation process for separation of mineral ores depends on the establishment of care-fully controlled froth. The formation of very stable froth in the flotation circuit is a problem that may occur in many plants, resulting in down-time, low quality and grade of final product and considerable expenses. Froths build up on the top surfaces of thickeners, tanks and flotation cells until they overflow, or until the efficiency of the circuit is impaired. A similar problem exists in Assarel concentrator, Assarel-Medet PLC, Bulgaria. Copper and copper-pyrite ores are dressed in Assarel concentrator. They are characterized with variable and complex mineral and physical composition. During the flotation cycle, resilient and difficult to break-down froth is formed, which subsequently impedes the process of thickening and clear overflow obtaining. Due to this problem continuous sampling in the cycle of thickening was conducted. The mineralogical, chemical composition, particle size distribution and solid phase content of the products were determined. It was established that the solid phase of the froth build up on the top surface of the thickener differs considerably from this one of the thickener underflow. The data clearly indicates that a separation process takes place on the top surface of the thickener ? fine particles of chalcopyrite are concentrated in the froth. The role of chemical reagent addition in the break-down of the flotation froth is investigated in terms of surface chemical phenomena involved in the stabilized froths. Measurements of the coper minerals wettability and surface tension at the air/liquid interface were performed. The surface active agent AERODRI® dewatering aids were laboratory tested. Bench-scale froth collapse tests were conducted. Reagent addition into pulp-froth system promotes and leads to a bubble coalescence, an improvement of the wetting of the mineral particles and a decrease of the surface tension at the air/liquid interface. The results of the laboratory experiments showed that the presence of the surface active agent leads to considerably decrease of the froth stability and the destruction of the deleterious froths build up on the top surface of the thickeners in Assarel concentrator.

Jan 1, 2014

By Willis Forsling, Prabhakar Swarna, Hanumantha Rao Kota

The solubility of wollastonite and its Hallimond flotation behavior as a function of dodecylamine concentration and pH are examined. The flotation response is characterized by adsorption and surface energy in the presence of amine. The methods of UV-Visible and FT-IR spectroscopy for adsorption and sessile-drop contact angle for surface energy estimation are employed. The results of wollastonite dissolution clearly showed its non uniform dissolution. The surfaces are depleted with calcium ions and became rich in silicon within 10 min of flotation time. Maximum flotation of wollastonite corresponds to a half monolayer coverage of amine, which is substantiated by the surface energy parameters. A good correlation between flotation, adsorption and surface energy as a function of amine concentration and pH was observed. The sudden increase in wollastonite flotation and amine adsorption at and above 5x10-5 M initial amine concentration is thought to be due to two-dimensional precipitation of amine on surface in accordance with the recent 2D-3D precipitation model of amine adsorption on silicate minerals.

Jan 1, 2003

By C. Dorfling

Experimental work was performed using a bench scale autoclave to evaluate the effects that leaching temperature, pressure, initial acid concentration, and the solid to liquid ratio have on the behaviour of base metals and platinum group metals in a high-pressure sulphuric acid oxygen leaching system. The concentrations of metals in the leach solution were measured over time at different leaching conditions. At the conditions investigated, the initial acid concentration had the largest influence on the copper leaching kinetics, while the leaching rates of the other precious metals (OPMs: rhodium, ruthenium, and iridium) were highly dependent on the leaching temperature. A set of chemical reactions that can be used to describe the leaching chemistry was proposed, and the associated reaction kinetics were quantified. As a first estimation, the rate expressions were considered first order, and the rate constants were determined using the method of least squares, considering the experimental and predicted concentrations obtained for the different leaching conditions. Of the OPM compounds, the sulphides showed the fastest dissolution rate, followed by OPM alloys, and finally the OPM oxides. During the initial leaching stages, base metals and OPMs competed for the available dissolved oxygen, with oxygen being preferentially used for copper leaching. Precipitation of OPMs during the initial leaching stages can be ascribed to copper and nickel dissolution according to exchange reactions between dissolved OPMs and copper present as digenite or nickel present as polydymite. Control of the autoclave residence time is of particular importance to enhance the selectivity of this leaching step, given the dependence of the PGM leaching rates on the extent of copper dissolution.

Sep 1, 2012

By J. K. Afidenyo

Microbial pretreatment of a double refractory gold ore was investigated using a white rot fungus, Coriolus versicolor (ATTC 20869) to improve gold extraction. A series of preliminary tests were conducted to determine the amenability of the ore to fungus degradation. Pulp density, temperature, pH and retention times were the process variables considered. Both a single. Stage and two-step processes were studied to establish process conditions. During the single stage process, the ore was contacted with the fungus culture (biotic) for 3weeks at 30°C and pH 10.0. For the two-step process, the first step involves ore contact with the culture medium (abiotic) at 45°C and pH 10.0 followed by fungal contact (biotic) at 30°C. Results indicated that carbonaceous matter is not degraded but passivated by the fungus; as preg-robbing activities dropped significantly from 18.1% to below 1.0%. The single stage process resulted in higher gold recovery than the two-step process Gold ex-traction by cyanidation of the pretreated ore was 78.9% for the single stage compared with 15.0% for the untreated ore. In the two-step process, only 73.3% gold extraction was achieved. Application of the two step process conditions to a high grade flotation concentrate, resulted in 93.3% gold ex-traction as against untreated concentrate of 30.5%. The results show that the microbial pretreatment process degraded sulfide sulfur, passivated carbonaceous matter and enhanced gold extraction from double refractory gold ore and concentrate.

Jan 1, 2014

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By I. S. M. K. Ilankoon

In heap leaching the transport of the acid from the drippers to the surface of the ore particles is a major factor in the overall performance of a heap. This flow behavior is complex as the flow is unsaturated and occurs along a tortuous set of inter-particle channels and connections. Previous modeling of this system has used equations from oil and ground water flow to model these systems, but the applicability of these models with the larger particles found in typical heaps is suspect as these systems are not necessarily capillary dominated. In particular, as the characteristic particle size goes from below to above a few centimeters, the flow changes from capillary to gravity dominated. This means that typical heap leaching heaps cover this interesting, but complex, transitional fluid flow regime. In this paper a set of experimental studies of this flow, including PEPT (positron emission particle tracking) based tracer experiments, highly accurate liquid holdup measurements and axial dispersion experiments using salt tracers will be presented. In this study, flow through mono-dispersed particle beds was carried out. In particular, the hysteresis in the liquid holdup as the liquid flow rate into the particle bed is varied is investigated, since this hysteresis means that the relationship between flow rate and holdup is history dependent, an effect not included in models currently used to describe fluid flow in heaps. A theoretical model that describes this hysteresis will also be presented. Keywords: heap leaching, hydrometallurgy, modeling

Sep 1, 2012

By C. Han

The analytical results of Dagushan grinding workshop primary grinding operation product show that the size fraction of -0.079mm is 32.88%, the size fraction of -0.01mm is 9.97%, the rate of -0.01mm size fraction and -0.079mm size fraction is 30.32%. It means that there is too much -0.01mm size fraction in primary grinding operation product and fall out that there will not be a better result in following operations. Several tests have been carried out to control the size distributing of the primary grinding operation product according to confirm the appropriate conditions of grinding operation. Integrate with theoretic count, grinding property tests show that the appropriate rev ratio of ball mill should be between 85% and 90% so as to get better size distributing. Based on the results of grinding property tests, the shocking property tests simulated the momentum of different diameter steel balls in the ball mill have been carried out. It showed that if want to get better size distributing the appropriate diameter of steel ball should be 110mm. The tests result shows that regulate diameter of steel ball and rev ratio of ball mill could control the size distributing. Contrast to the technical parameters of ball mill in grinding operation now, there are some significant advices are given for practice and industrial tests.

Jan 1, 2014

By Kremena Dedelyanova, Tsvetan Damyanov, Nikolay Hristov, Evgeni Kostadinov, Lubomir Kuzev

"Spherical grinding media (balls) are the most widely used media for comminution of ores by grinding. One way to optimize the grinding process in a tumbling mill is associated with the development and testing of a new media shape. By modelling simulation study of the behaviour of two types of grinding media (balls and tetraballpebs) in the grinding process was conducted to determine the possible advantages of the new media shape. Tetraballpebs are in the shape of tetrahedrons with spherical convex walls. D305 mm and L305 mm Bond ball mill sizes were used in the experiment. They are modelled milling tetraballpebs bodies corresponding by weight to five ball sizes, namely ¾, 7/8, 1, 1¼ and 1½ inches which form the grinding media used in a Bond ball mill. They are cast steel grinding bodies. Studies carried out with both types of grinding media include equal number of milling bodies of the same weight and volume. Having thus ensured a uniform mass of the grinding media and the same number of milling bodies, all other conditions and process parameters being identical, conclusions can be drawn about the influence of the grinding media shape on the grinding process. Compared to steel balls, the tetraballpebs used in laboratory tests carried out in closed cycle by Bond ball mill and the study of the rate of grinding gave five to six per cent higher yield of a control size of minus 0.1 mm. Measurements of the Bond ball mill power consumption demonstrated that tetraballpebs grinding media achieved energy saving of 4.7 per cent for the production of one gram of the control size of minus 0.1 mm."

Jan 1, 2014

By R. S. Wang

The flotation of pyrite which be pretreated by electrochemical ways under external controlled voltages in different pH is explored. The floatability of pyrite is increased indistinctively after being pretreated in acidic and xanthate environment; Whereas, it is increased obviously between 400~800 millivolt in alkaline and xanthate condition. The reason for higher recovery of pyrite is that oxida-tion reaction, which results in S0 and S02, takes place on its surface, and that ethyl xanthate is oxi-dized into dixanthogen. In the meantime, the kinetics and mechanism is also studied.

Jan 1, 2014

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By Qidong Zhang, Yongsheng Song, Wenjuan Li, Guiying Zhou, Kun Song

"Molybdenum is a very important rare mineral resources, which exists largely in oxidized ores and sulphide ores in nature. About 99% of metallic molybdenum comes from molybdenite. The talcose molybdenum resources are abundant but the resources utilization is low, because the talc is naturally hydrophobic and the floatability of talc is similar with molybdenite, which lead to difficult separation by flotation. Talc is easy entry into concentrate in flotation which can cause the content of MgO overhigh, therefore the molybdenum concentrate grade can not meet the industrial requirements. Thus the utilization level of talcose molybdenum resources has been restricted greatly.The adsorption of water on talc and molybdenite surfaces and natural floatability of minerals were studied by density functional theory method. The results showed that molybdenite and talc were layered minerals which exhibited similar surface wettability and H2O molecule prefers to stay with water rather than the minerals surfaces. N2 is adsorbed on talc and molybdenite surfaces more easily than H2O. The interaction and flotation behavior were studied by SEM and flotation experiments. The reason why talc interferes with the flotation molybdenite has been revealed. The agglomeration between molybenite and talc was caused easily in neutral or acidity solution, and it was dispersing between molybenite and talc particles in alkaline solution. The flotation results showed that good floatability of talc was the key factor causing a low grade of concentrate in alkaline solution. Thus, it is the key factor to enlarge floatability difference between molybdenite and talc.INTRODUCTIONMolybdenum is a kind of important rare metal and strategic reserve resources (Zhitao Y et al, 2016a). Due to excellent characteristic, such as high melting point, good thermal property and et al, it’s widely used in metallurgy, machinery, chemical, aerospace, and many other areas. It has become an indispensable metal in modern industry. Molybdenum generally exist in the form of molybdenite which is a kind of mineral with excellent natural floatability. Talc is a kind of typical hydrous and layered magnesium silicate minerals (Beattie D et al,2006a), which is one of the most common gangue mineral of the platinum group metal ores and metal sulfide ores (Tao L et al,2011). Due to its good native floatability, talc is easy entry into the concentrate product with foam in the process of sulfide ore flotation (Kelebek S and Smith S, 2006b), which resulted in decreasing concentrate indexes. Not on that, the high-content MgO of concentrate will also produce a series of adverse impact to the subsequent smelting (Lotter N O et al, 2008). Therefore, it is difficult to separate talc from sulfide ore concentrate effectively."

Jan 1, 2018

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:- flotation tailings of crystalline graphite minerals- outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers.The most important variables affecting the leaching process, such as grain size, mineralogical species, reagent consumption, and so on, were previously studied. (Weiss, L.1985)On the basis of the present study results, the possible definition of an economically viable mineralization will be analyzed to define an auriferous district."

Jan 1, 2003

By L. Bbosa

Positron Emission Particle Tracking (PEPT) and the Discrete Element Method (DEM) are used to investigate Power Draw in a laboratory scale tumbling mill. The mill is run dry in batch mode at different speeds using mono-size charge of glass beads, and is mounted along with a torque transducer to measure power. Particle tracking information from PEPT is used to reconstruct the motion of glass beads and infer the overall charge behavior, while DEM is employed to simulate particle motion and interaction, with collision mechanics calculated using the Hertz-Mindlin contact model. For PEPT and DEM data, the product of torque and average angular velocities in discrete cells are accumulated to obtain mill power. This method is found to be within statistical agreement with measured power for all tests. Spatial distributions plotted from this approach highlight the regions of the mill that draw the greatest power. A second technique to obtain Power Draw from DEM data which sums particle forces against the mill geometry is similarly found to accurately predict mill power with lower statistical error. Keywords: Power Draw, PEPT, DEM

Sep 1, 2012

By Y. Foucaud, I. Filippova, L. Filippov

Flotation is the most common beneficiation route for tungsten ores, but the predominance of minerals with similar surface properties poses a real challenge. This study investigates the use of Falcon centrifugal separators for gangue minerals removal and desliming prior to flotation. A typical tungsten-bearing skarn ore (Tabuaço, Portugal) is used, containing scheelite (CaWO4) associated with dense calcium-bearing silicates (vesuvianite), fluorite, apatite and light silicates (feldspars) as gangue minerals. Two types of Falcon bowls (Falcon UF and Falcon SB) were used, prior to flotation tests with fatty acids as collectors and a combination of sodium carbonate and sodium silicate as gangue minerals depressants. This flowsheet was compared with a reverse configuration, using flotation prior to Falcon concentrator, and with a classical flowsheet, using hydrocyclone and flotation. Gravity pre-concentration and desliming with the Falcon concentrator were optimized through the design of experiments (DoE) methodology. The influences of pulp density, rotational speed, feed flowrate and fluidisation pressure (for the Falcon SB) were studied for both bowls. Results showed that the Falcon can be used as a desliming and pre-concentrating apparatus. Separation performances depend mainly on rotary speed and pulp density for the Falcon UF, whereas rotary speed and fluidisation pressure are the main parameters for the Falcon SB. With only one stage of Falcon SB, an enrichment ratio of 7.9 is obtained with a 65% WO3 recovery while 89% of apatite and fluorite are rejected, which constitutes a very good selectivity. In comparison, Falcon UF shows lower enrichment ratios, around 2.7. In terms of desliming, Falcon UF is as efficient as the hydrocyclone, while the Falcon SB is significantly more efficient. Hence, the use of Falcon SB prior to flotation improves the overall performance of the tungsten flotation route by desliming the flotation feed while pre-concentrating the scheelite. It impacts very advantageously the flotation, as most of the calcium-bearing minerals are eliminated. A Falcon SB stage prior to flotation yields a final concentrate grade of 29.7% WO3 with a recovery of only 36.8 % that should be optimized as the reagents dosages were not adapted to the pre-concentrated feed.

Jan 1, 2018

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki

"Hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in various applications. It has also been reported to reduce the recovery of sulfide minerals. Moreover, the previous work applied H2O2 aqueous solution in selective flotation of chalcopyrite and molybdenite. However, the oxidation method suffered in pilot scale test due to too long conditioning time. Furthermore, the excessive reagent consumption increased the reagent cost, causing the method not economically feasible. Consequently, further improvement is required to reduce the conditioning time and the reagent consumption. The oxidation performance of H2O2 can be improved by using ferrous iron as catalyst, producing a Fenton’s reagent which is more powerful oxidizer than the H2O2 itself. Therefore, the effect of Fenton’s reagent on the floatability of chalcopyrite and molybdenite was investigated in this study. The flotation test results show that selective flotation of chalcopyrite and molybdenite might be possible at low concentration of H2O2 aqueous solution by adding ferrous iron. Moreover, the conditioning time could be shortened by this improvement. To understand the phenomenon, surface characterization using atomic force microscopy (AFM) along with x-ray photoelectron spectroscopy (XPS) analysis were carried out. The AFM images show that the surface of chalcopyrite was readily covered with mountainous features which alters its hydrophobicity after the oxidation treatment. Meanwhile, the molybdenite surface remained clean and relatively hydrophobic. The XPS results indicate that the mountainous features are various oxidation products (i.e., FeOOH, Fe2(SO4)3, CuO, Cu(OH)2). Possible mechanisms of this phenomenon were proposed in this work.INTRODUCTIONConventionally, copper and molybdenum ores are separated in selective flotation circuits by using copper depressants (i.e., sodium hydrosulfide (NaHS), sodium sulfide (Na2S), and Nokes reagent (P2S5+NaOH)). However, these depressants are usually toxic or hazardous. Therefore, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, ozone, and plasma pre-treatment (Arbiter and Young 1951; Barzyk et al. 1981; Curtis 1941; Hirajima et al. 2014, 2017). Recent study by Chimonyo et al. (2016) reported the effect of H2O2 on reducing the recoveries of sulfide minerals. Moreover, Hirajima et al. (2017) demonstrated that H2O2 depressed the floatability of chalcopyrite and could deliver a selective separation on copper and molybdenum (Cu-Mo) bulk concentrate in flotation process. However, they reported that this method required a higher concentration of H2O2 and a longer treatment time (4.5 h) to get a comparable result to that of using NaHS as copper depressant. Therefore, further improvements are necessary to reduce the conditioning time and reagent consumption."

Jan 1, 2018