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Ni and samaria-doped ceria (Ni-SDC) cermet are desirable materials for making a solid oxide fuel cell anode working at intermediate temperature (800°C or lower) due to its good ionic/electronic conductivity at the reduced operating temperature. An advantage of the use of a Ni-SDC anode is the enlargement of the effective reaction zone in the interfacial area between the anode and the electrolyte. As a result of the mixed ionic/electronic conductivity of the anode, the electrode reaction rate is enhanced. Investigations into the properties of the ceria-based anode reveal that the performance of the anode is closely related to its microstructures, which are dependent on the composition and fabrication conditions of the ceramics. In this paper, a method for quantitative characterization and correlation of Ni-SDC cermet microstructures to the performance of an anode is investigated. A series of Ni-SDC anode samples are prepared by screen-printing (SP) and spin-coating (SC) techniques, and different microstructures of the samples are obtained through controlling the SP or SC conditions and the sintering temperature. Individual phases (Ni, SDC and pore) in the tri-phase boundary (TPB) microstructures in the electrode are differentiated and segmented from each other in optical and SEM images based on the differences in refractivity and atomic contrasts among the phases. The geometric properties of the segmented phases are characterized using image analysis methods, so that a quantitative skeleton illustrating the TPB microstructures of the Ni-SDC electrode is obtained. Statistical analysis of the distribution of the three phases in the TPB microstructures is performed and the relationship of the microstructures with the optimum electrode is interpreted in terms of the microstructure analysis data.

Jan 1, 2005

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By Mike Power

Geophysical techniques have played a pivotal role in northern kimberlite exploration since the initial discovery at Point Lake in 1991. In the Slave Craton and surrounding regions, there are definite contrasts in physical properties between kimberlite intrusions and surrounding bedrock. Kimberlite commonly displays higher magnetic susceptibility, distinctive remnant magnetism, low electrical resistivity and lower density than surrounding rocks. In addition, the distinctive geometry of kimberlite pipes is reflected in geophysical responses which further facilitates target discrimination. There has been an evolution in geophysical exploration strategies over the past 12 years. Helicopter total magnetic field and electromagnetic (HEM) surveys have proven to the most cost-effective means of conducting first pass investigations in prospective areas. During the early 1990's, total magnetic field and frequency domain electromagnetic surveys were virtually the sole techniques employed during follow-up surveys. Inevitably, the initially high rates of kimberlite discovery declined in the areas surrounding the original finds. Marginal magnetic and EM anomalies were all that remained to be tested and this spurred interest in the improvement of existing interpretation algorithms and in the application of additional complementary techniques to reduce the exploration risk. Gravity has become a popular third survey following the deployment of the Falcon (TM) airborne gravity gradiometer system by BHP Billiton in 1999 and improvements in ground techniques. Ground penetrating radar (GPR) has proven to be particularly useful in delineating kimberlite pipes following drill discovery and in exploring for kimberlite dykes in settings where indicator mineral trains indicate such targets are likely. Seismic methods have been tested for both reconnaissance and delineation but remain underemployed. Given the high cost of drilling in the North and the proven success of geophysical techniques in reducing exploration risk, it is likely that an increasingly diverse range of geophysical techniques and innovative interpretation techniques will continue to be applied in kimberlite exploration.

May 1, 2003

By H. Saari, D. Y. Seo, J. Beddoes, T. R. Bieler

Prior work on effects of lamellar orientation on creep rates and other mechanical properties have shown that having lamellae parallel to the tensile axis provides optimal creep resistance and good strength. Consequently, a directional solidification system was used to examine the effect of solidification rate on the development of crystals with lamellae parallel to the growth direction. The nominal chemical composition of TiAl ingots was Ti-46A1-2Mo-2Nb (at%) and the ingots were 20 mm in diameter and 180 mm long. The master alloy bars were placed in a high purity yttria mold on a copper chill plate and raised into the hot zone of a Bridgman furnace. The alloys were melted and then directionally solidified at withdrawal rates of 4, 8, and 12 mm/min. As-cast specimens were sectioned at positions of 4, 22, 66, 111, and 155 mm from the bottom of the ingot to evaluate microstructure and crystallographic texture as a function of distance from the bottom of the ingot. The directionally solidified microstructure consists of continuous columnar grains with fully lamellar structure, a network morphology of primary 13, yttria particles, and interlocked columnar boundaries. For all three ingots, the texture at 4 mm shows many peaks, with isolated strong peaks, and a slight tendency toward <111> plane normals within about 20° of the cylindrical axis. At 155 mm, all specimens showed substantially stronger clustering of <111> orientations near the cylinder axis, with the strongest clustering of poles occurring for the 8 and 12 mm/min specimens. Analysis of diffraction peaks indicates that strongly compressive residual stresses in the radial direction are present in the casting. The combined microscopy and texture analysis provides more complete understanding of the processes of directional solidification of TiAl alloys.

Jan 1, 2004

By Bryon Bisiaux, Walter Valery, Sonny Mwansa, George Amonoo, Adrian Dance

"Newmont Ghana Gold Limited’s Ahafo operation have been working with Metso Process Technology & Innovation (PTI) since early 2009 to increase mill throughput from a combination of controlled blasting practices and optimised primary crusher and grinding circuit conditions. For such Mineto-Mill projects, PTI’s methodology is termed Process Integration & Optimisation (PIO).Ahafo operate a SAG mill, ball mill and pebble crusher (SABC) circuit that processes a range of primary ore of varying hardness from different pits which is blended with soft oxide material. The PTI study focussed on ball mill limited material from the Apensu open pit.Following a benchmarking study of all blasting, crushing and grinding practices in January 2009, PTI recommended changes in both blasting and crushing conditions in order to generate a finer feed size to the SAG mill. Additional operating changes in the grinding circuit were recommended.A series of trials were conducted in November 2009 where three blasts were fired using a different blast design (hole diameter and explosive type) in the same area of the Apensu pit as the benchmarked material in January 2009. Top and bottom benches (or flitches) from each blast were sent exclusively to the grinding circuit and the material was tracked using PTI’s SmartTag™ system.The results from the six trials showed a significant increase in primary ore throughput at a reduced blend of oxide material. Ahafo have since standardised on these modified blasting conditions for all Apensu ore zones and have been able to sustain higher throughput compared to historical performance on similar material.This paper summarises the phases of the PIO project, the changes made in operating practices and the outcomes of the blasting trials that validated the predicted increase in mill throughput."

Jan 1, 2012

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By G. H. K. Pearse

Sulphur is derived from both 'voluntary' and 'involuntary' production. The former category includes sulphur obtained from elemental sulphur deposits and from pyrite and gypsumanhydrite deposits. Sulphur in the latter category is produced by pollution abatement at fossil Juel plants and from treatment of metallic sulphides. Canada is the world's largest sulphur exporter and third largest producer. Main resources of Canadian sulphur are sulphurous fossil fuels, metallic sulphides and native sulphur. Only the first two sources have produced sulphur in Canada 10 date; the first source accounts for over 85% of total Canadian production. Future sulphur sources will be derived increasingly through pollution abatement and decreasingly through voluntary production.

Jan 1, 1984

By D. MacGREGOR, VERA TUREK

The St. Canul and Ste. Scholastique orthoquartzite sanrjstone deposits are located within the Potsdam Formation near Montreal. The sandstone lies on Precambrian basement and is Cam/3rian to Ordovician in age. The Potsdam Formation shows two distinct stages of development. One created a deepwater facies represented by impure, limey or shaley sandstone; the other produced a shallow facies composed of grey, highpurity sandstone. The shallow-water orthoquartzitic sandstone at St. Canul is being mined and beneficiated by lndusmin Limited. The operation manufactures a wide range of silica products and supplies industrial areas of Quebec and Ontario with material for the glass, foundry, silicon carbide and ceramic industries.

Jan 1, 1984

By Alexander Smith

Surf Point and Edye Pass mines are on the northwestern part of Porcher island; 25 miles southwest of Prince Rupert. During the 1930's they produced about $750; 000 in gold from ore averaging better than one-half ounce a ton. The deposits are quartz veins; containing auriferous pyrite; concentrates average about 8 oz. gold a ton. The veins occur in a quartz diorite; stock. Their distribution shows an apparent control by primary flow structures; for the principal deposits lie on the axis of an arch of flow layers. The technique used in mapping the structures in the intrusive is that known as the Cloos method and described by Balk.

Jan 1, 1954

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010

By L. V. Bell

"The gold deposits of the Caribou mine are representative of those of the Province of Nova Scotia as a whole. The ore shoots within the deposits, in common with those elsewhere within the Province, are associated usually with interruptions or irregularities in the broader and uniform fold structures. The structural factors localizing ore deposition as applied more specifically to the Caribou mine are demonstrated chiefly by the close relationship of the two principal ore shoots, known as the main orebody and the 'high-grade' vein, with a pitching drag fold developed in the southeast limb of the major northeast-southwest trending anticlinal fold or elongated dome that constitutes the primary structural feature of the Caribou gold district. It is of interest to note that the evidence indicates that this drag fold, in common with other folds subsidiary to the primary fold, formed as a result of movement similar in nature to that which caused the primary fold itself. Presumably, therefore, these folds are coincident in time.The property described here as the Caribou mine is an amalgamation of two adjacent properties formerly known as the Ross and the Nova Scotia Gold, but which since 1934 have been controlled and operated as a unit by The Consolidated Mining and Smelting Company of Canada, Limited. The Caribou mine is situated in the Caribou gold district about 45 miles to the northeast of the city of Halifax and about 6 miles to the north of the Moose River gold district.The history of mining at Caribou dates back to 1867. The first recorded gold production is for 1869. From 1869 to 1933 the gold produced from the mines of the Caribou district aggregated 47,249 oz. from 93,234 tons of ore treated. The grade of the ore on the basis of the gold actually recovered from the district would thus average 72 oz. gold a ton, which, as will be noted from the following, is precisely the grade of the ore treated from the Caribou mine during operations by The Consolidated Mining and Smelting Company. These operations commenced in September, 1934, and milling on a commercial basis was under way during 1938. Since that time production, apart from a short period in 1945 during which efforts were concentrated on development work, was continuous to early in 1947, when the mine closed down owing to exhaustion of the known orebodies. Gold produced from the Caribou mine by The Consolidated Mining and Smelting Company from September, 1934, to the close of 1946 aggregated 43,205 oz. from 90,754 tons of ore milled; the grade of ore treated averaged 0.50 oz. gold a ton. The indicated average grade of O.S oz. gold a ton for the ore of the Caribou district throughout its mining history ranks somewhat higher than the 0.37 oz. a ton average for the ore milled to date from the several gold districts throughout the Province as a whole according to the production statistics of the Provincial Department of Mines."

Jan 1, 1954

By Z. S. Abisheva

The Zhezkazgan copper sulfide ore deposit in Kazakhstan contains both rhenium and the rare osmium isotope "osmium-187" (187Os) in the high isotopic purity of 99.4 ± 0.2%. This isotope is believed to have originated as a result of the disintegration of one of the rhenium isotopes, according to the reaction: 187Re75 ?> 1870576 + B- + v~ (where B is a 13-particle, v~ is a 3-disintegration antineutrino). The distribution of osmium and rhenium in metallurgical byproducts produced during the recovery of copper from these ores has been studied and process flowsheets for the processing of rhenium and osmium-containing byproducts have been developed.

Jan 1, 2007

By Peter McBride

Human excellence in all areas of endeavour is acknowledged and recognized. Establishing role models and spreading the word on best practices helps broader audiences. For on-the-job safety, recognition awards are a component of successful programs. In Canada?s mining industry since 1941, the John T. Ryan Safety Trophies initiative has contributed to the sector?s improving record in this area. The much sought after and rich in history John T. Ryan trophies are recognized symbols of safety excellence in Canada. The effectiveness of the Ryan safety recognition program in Canada has led to its export to other mining countries seeking to improve their overall safety performance.

May 1, 2008

By Juan Pablo Vielma

In this work we study how to incorporate risk control to the generation of ultimate pits when orebodies are modeled through a finite number of conditional simulations. To control risk we consider a chance constraint on the value of the ultimate pit. We incorporate this measure into the generation of ultimate pits by solving a stochastic programming version of the ultimate pit problem. We compare this stochastic programming problem to previous approaches such as generating the ultimate pit for each simulation and the hybrid pit approach introduced by Whittle and Bozorgebrahimi. We also study the effect of using different number of simulations in the generation and evaluation of ultimate pits.

Oct 1, 2009

By P. J. Deveaux, M. J. Kreczmer

The Tartan Lake deposit 12 km northeast of Flin Flon, Manitoba, was discovered in March of 1984 during the investigation of a VLF anomaly. The discovery hole intersected 16.83 metres averaging 21 gm Au/tonne. Since then, 99 holes, over 21,000 metres, have been drilled outlining 419,491 tonnes grading 11.79 gm Au/tonne in a di stinct group of mineralized lenses referred to as the Main Zone. Three other mineralized zones are known on the property but no reserves have been allowed for these, the South , East and Base Line zones. The Main Zone consists of seven parallel, east-west striking, quartz lenses. The lenses dip steeply to the north and plunge steeply west to northwest. Lens number l strikes for 160m and extends vertically to the 90m level. Within th is lens there is a 60m interval of low grade materi al. Lens number 2 is located about 5-l0m within the foo twall of Lens number I. Near surface this lens stri kes for 40m, at 200m level the strike length increases to 200 m. To date the deepest mineralization on Lens 2 has been intersected at a vert ical depth of 527m. Five smaller lenses are located in the foo twall of Lens 2 , containing gold va lues similar to the two main lenses but erratically distributed. The South Zone, located 100m south of the Main Zone, strikes east-west fo r l00m above the 100m level. The East Zone, found 230m east of the Main Zone, strikes fo r 80m and may possibly be an ex tension of the South Zone. The Base Line Zone is located 275m south of the Main Zone. Sporadic, but very significant gold intersections have been obta ined1n all three zones. Gold-bearing quartz-ca rbonate tourmaline veins are generally confined to a silicous crystal tu ff hori zon. The crystal tuff exhi bits fi ve distinct types of alteration: silicification, sericitization, ca rbonati zation, chlorit ization and pyritization. Silicification has resulted in a perasive addition of silica and the generation of multiple quartz veins. Sericiti zation is restricted to the crystal tuff. All rock units are pervasively carbonatized . Ankerite is abundant in the quartz veins and within the shear zones, particul arly those located along the chilled margin of a nearby gabbro-diorite intrusion. Chloritization is widely spread th roughout the rock units, while pyritization fo rms a broad alteration halo associated with the orebody. Sulphide accesso ry minerals associated with the gold , whi ch fo r the most part appears to be free, are chalcopyrite and pyrite. Generally, the higher grade gold values are related to an increased content of sulphides in the qua rtz veins. The average sulphide content in the deposit is less than 5 %.

Jan 1, 1986

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By George Hope, Dave Green, Jacques McMullen

The Est Malartic mill has been treating massive sulphide, copper/gold ore from the Bousquet 2 mine since 1989. The need to minimize copper content in flotation tails which are leached for gold recovery and to produce a saleable copper concentrate led to the evaluation of Conventional, Column and HG flotation methods. The HG method was preferred and two full-scale cells were installed and operated over a two-year span. In 1992, it was decided to expand the mill capacity from 1500 tpd to 2500 tpd. A total of nine additional HG Tank Cells were installed to provide additional roughing and cleaning capacity. The expanded plant has been operating since June 1993.

Jan 1, 1994

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004