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By F. Moraw

The use of redox fuel cells in which oxygen is replaced by other oxidants such as ferric ions can have significant advantages [1-3]. For example, the cathodic reaction rate (e.g., exchange current density) can be increased by several orders of magnitude compared to the oxygen reduction reaction, and platinum group metal (PGM) catalysts are not required. As a result of the higher aqueous solubility of the oxidant in a redox fuel cell compared to that of oxygen the rate of mass transfer (e.g., limiting current density) is greater by several orders of magnitude. The redox fuel cell can achieve high efficiencies and has other fuel cell advantages. The main issue with the redox fuel cell cathode is the regeneration of the oxidant where low conversion efficiencies are achieved even with platinum group metal (PGM) catalysts. In the work discussed here the Fe3+/Fe2+ redox fuel cell cathode is characterized over a range of electrolyte concentrations and operating conditions, and electrode materials. Cyclic voltammetry and electrochemical impedance spectroscopy are mainly used for electrochemical characterization and mechanistic determination of the cathode redox couple. Further characterization with selected compositions and materials is done in a redox fuel cell (hydrogen - Fe3+/Fe2+). The mechanism and the advantages and disadvantages of the fuel cell redox cathode are discussed with respect to other approaches and other redox couples.

Jan 1, 2005

By M. C. Bétournay

? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough ? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough Disadvantages ? High cost and long time for equipment development ? Hard rock mining condition limitations ? Size of equipment ? Equipment set-up time, down time ? Performance does not meet financial return targets ? Ground control issues ? Drill and blast retains overall advantage

Feb 1, 2008

By Mohammad Mehdi Salarirad

Fouling of activated carbon by different organic species is a great concern in carbon in pulp and carbon in leach circuits. The rate of gold adsorption onto activated carbon from synthetic gold solutions which contained different amounts of potassium ethyl xanthate (PEX), potassium isobutyl xanthate (PIBX), and methyl isobutyl carbinol (MIBC) were evaluated through batch adsorption tests. The results of these experiments showed that the gold sorption rate rapidly decreases by increasing the concentration of collectors including PIBX and PEX up to 20 mg/L and at higher concentrations, the kinetic rate constant (i.e., k value) gradually leveled off to 53 h-1 for PIBX, which is 46% lower than the 99 h-1 for PEX. At low concentrations of up to 15 mg/L of MIBC, a gradual decrease of the rate constant was observed, while at higher concentrations, the decrease was found to be more pronounced. The gold loading capacity and the rate of gold adsorption onto activated carbon from a gold cyanidation pulp in the presence of flotation reagents were also evaluated. The results of these experiments showed that the flotation reagents have no significant effect on the gold loading capacity of activated carbon at prolong adsorption period, meanwhile the rate of gold adsorption continuously decreases by increasing the concentration of flotation reagents in the leaching solution.

Oct 1, 2011

By A. L. Williamson

Bio-mining, the use of micro-organisms to recover elements of interest, is potentially useful for the economic extraction and recovery of ore metals from a variety of ore deposits, including the lowergrade uranium deposits found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The metabolism of chemolithotropic bacterium Acidithiobacillus ferrooxidans depends on an ability to derive energy and reducing power from the oxidation of ferrous iron found in a varirty of iron sulphide minerals associated with base, precious metal and uraniferous ores. The characteristics of this bacterium, especially the ability to oxidize both iron and sulphur with an associated high tolerance of low acidity, allow the organism to contribute significantly to bio-mining processes. Under ideal conditions, A. ferrooxidans promotes the oxidation of ferrous iron in low sulphide ore materials, breaking the crystal structure of the ore minerals .releasing protons to the surrounding solutions, thus promoting the dissolution of uranium and rare earth elements, among others. This paper provides an overview of elemental dissolution and release of uranium, rare earth elements and investigates the acid generating potential of the final residues, from a series of environmentally controlled, biologically-mediated uranium ore extraction experiments. The findings will be used to guide in the design of larger scale bio-leaching experiments to further assess the potential for successful bio-mining operations along the Quirke Syncline.

Aug 1, 2010

By K. Oishi

We have developed a 76Cu-3Si-21Zn alloy "ECOBRASS®" containing no lead. When 3% Si is added to a 78Cu-22Zn alloy, kappa and gamma phases participate uniformly in the alpha matrix. When being machined, stress concentrates on these hard phases, namely kappa and gamma, and thereby lowering the required cutting force and yielding segmentalized chips without lubricant. Kappa and gamma phases transform into beta phase under high temperature, which makes it easier to extrude and/or forge the alloy. When 0.08% P and 50 ppm Zr are co-added, the grains of ECOBRASS® castings are refined significantly to become as small as several dozens of micrometers. The grain refinement by the co-addition of P and Zr improves castability, tensile strength and elongation of ECOBRASS® castings. Meanwhile, the lead leachate from an ECOBRASS® water meter, field-tested in pH 6.8 drinking water for one year, was less than 5 ppb without correction. No indication of dezincification corrosion was observed, either. ECOBRASS® is equally suitable for rods, forgings and castings, and makes it possible to produce a complete set of plumbing parts (valves, faucets, etc.) by its own. This way, not only improving recyclability, ECOBRASS® also realizes size and weight reduction due to its good corrosion resistance and high strength.

Jan 1, 2007

By M. Xian, M. Jahazi, Y. L. Lin

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded at different defocusing distances on two surface conditions (as-cast or machined) using a continuous wave 4 kW Nd:YAG laser system at a power of 2.5 kW and a welding speed of 6.0 m/min. Two welding modes (conduction or keyhole) have been observed. The adjustment of defocusing distance can greatly influence the establishment of conduction or keyhole modes. On the machined surface conditions conduction welding is obtained at a power density of 4.0 x 105 W/cm2. In contrast, keyhole welding is reached at a threshold irradiance of 1.5 x 106 W/cm2. Neither conduction nor stable keyhole modes have been established at a range of power density from 7.7 x 105 to 1.2 x 106 W/cm2 on the machined surface conditions. On the as-cast surface conditions keyhole is obtained at a power density as low as 4.0 x 105 W/cm2 but good surface quality is obtained at a defocusing of +2 mm. The as-cast surfaces require lower power irradiance for the formation of keyholes indicating that they have higher energy absorptivity for Nd:YAG laser beams probably due to coarse surface morphology.

Jan 1, 2004

By Z. -G. Ren, J. -S. Qian, Y. -G. Yang

The waste slags from chemical and metallurgical plants contain approximately wt 1% water soluble Cr6+. This hexavalent chromium is very harmful to human health, and the treatment of the slags has concerned metallurgists for many years. A sintering method was developed to treat the waste slag. In this process, sinter was made from a mixture of the waste slag containing hexavalent chromium, iron concentrate and coke breezes. During sintering, hexavalent chromium was reduced to trivalent chromium. The latter is known as a non-harmful material and can be used as chromium resource for the production of ferrochromium or chromium-containing cast iron. After sintering the hexavalent chromium in the sinter could be reduced to less than 0.0008%. It was found that the waste slag with fine particles was favourable to the Cr6+ removal. An increase of carbon content in the sintering mixture could increase the rate of Cr6+ removal and the strength of the sinter produced. The rate of Cr6+ removal increased with increasing basicity of the sintering materials with basicity less than B=1.8, above which it decreased with increasing basicity. Blast furnace was found to operate smoothly when using the sinter made from the waste slag containing chromium. However the productivity of sintering machine was slightly low compared to the sintering operation using ordinary raw materials.

Jan 1, 2004

By A. Lemay, G. Morin, C. Desmeules

"Incorporated in 1976, Sidbec Normines was mandated to exploit a deposit of specular hematite at Fire Lake. A combined effort of three companies, Sidbec, which holds 50. 1 % of the actions, British Steel Corporation another 41.67 % and finally Quebec Cartier Mining, a subsiduary of U.S. Steel Corporation, with still another 8.23 %.The deposit is located 60 miles north of the town of Gagnon. The extracted ore is crushed, in a giratory crusher, to-8 11 chunks, and from there, it is transported, by rail, to a concentrator at Lac Jeannine.A concentrate containing 65.5 % Fe and 5.5 % Sio2 is produced, using conventional methods like autogeneous mil ls and spirals. The concentrate is then transported by rail to the Port Cartier installations.The installations in Port Cartier include a secondary concentrator, a pellet plant, and stockpiling facilities for pellets and concentrate. The pellet plant has two product lines in paralel, producing a total designed tonnage of 6 millions tons of iron ore pellets, of which 3mi11ions tons are used in direct reduction furnaces.The secondary concentrator is designed to remove a portion of the silica contained in the ore, usually less than 2 % Si02 should remain from the original 5.5 % Si02 in order to produce iron ore pellets which are well suited for use in direct reduction and electric furnaces."

Jan 1, 1981

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By C. -K. Fang, T. H. Chuang

"Temperature effects on the erosion of the 6063 aluminum alloy were investigated. Erosion experiments were performed by sandblasting silicon carbide particles of 80 grit size. The target volume loss, and worn depths of the eroded material were investigated at different temperatures. It was found that the temperature had only a minor impact on the peak attack angle. The effect of temperature on erosion damage depended on the relative humidity (RH) of the environment. IntroductionThe synergy of wind and sand or dust may result in the erosion of materials. However, the severity of erosion damage in different areas and in different seasons might be varied, depending on environmental variables such as temperature and humidity. As a result, determining the effect of environmental variables on erosion damage is important in selecting or ranking materials for their suitable applications in diverse areas.The relationship between erosion wastage and temperature is governed by many factors including temperature dependent properties of the material (strength, ductility, toughness, and dynamic hardness, etc.), mechanical erosion characteristics, the rate of oxidation, and the mechanical properties of oxides. Although the effect of temperature on erosion has been studied for engineering materials (Smeltzer et al., 1970; Gat and Tabakoff, 1978; 1980; Levy et al., 1986; Levy and Man, 1986; Chinnadurai and Bahadur, 1995; Howard and Ball, 1997; Colclough and Yeomans, 1997; Suckling and Allen, 1997), published literature dealing with aluminum alloy is rather limited."

Jan 1, 2000

By J. I. Jr. Moore

Many articles have been written about the various operations of Britannia mines and mill, as well as treatises on the geology and ore deposits. A partial list of these papers is given below. Most of these papers have covered well the history of Britannia, and have included a thorough discussion of the geology and ore deposits; therefore, in this paper, no account of these subjects. is necessary. However, a short description of the ore deposits will be given as an aid to a clear understanding of the descriptions of the various mining methods. The Ore Deposits The ore deposits at Britannia occur along a shear zone and are five in number, named for the claims in which they lie, as follows: Jane, Bluff, Fairview, Empress, and Victoria. Each of these deposits is called a mine, as they are separated by 500 to 1,000 feet of barren ground. The Jane mine, although the first producer of the Britannia group, has not been in operation for a number of years. The deposit is a silicified replacement in sediments; with very little evidence of shearing. The Bluff deposit is a highly silicified replacement in porphyry, massive and irregular, very hard in the upper 600 feet with practically no shearing, and softer within chlorite schist in its lower 1,000 feet . The Fairview deposit consists of a series of twelve distinct veins or lodes, rather lenticular in shape, and occasionally merging.

Jan 1, 1928

By M. Piard

The scarcity of literature referring to mines in the Rockies has compelled the writer to co-ordinate information and advice taken at the very source. Help was gladly given by active inspectors and mine bosses. Although the field is unimportant at the present time, due to its distance from markets for raw coal, it is quite worthy of the attention it is receiving from two continents; for, with the commercial synthesis of liquid fuels, it would become the largest fuel laboratory in the world, provided, of course, that freight cost drops to a low comparative level. As explained below, there are no obstacles to economical and safe operation under anything like the typical outcrop shown in Figure 1. Although coal dust is probably more dangerous in the Rockies than anywhere else, the damp outcrops afford means of control. The abundant gas may be bled to the open air, and the rigid roof will settle gradually under a wide span of opened outcropping. The Panel Retreating Wall The Measures: Coal measures having an attitude similar to that shown in cross-section in Figure x are characteristic of the active coalfield on the Alberta side of the Rockies, and they are also found on large tracts of undeveloped land west of the divide. The small anticlines, not shown in the cross-section, do not affect the progress of a pillar line, provided their crests are connected to the atmosphere by drainage bore-holes.

Jan 1, 1928

By M. H. Ali

Codelco, a multi-process primary copper producer, is undertaking a full life cycle inventory (LCI) of all its commercial products based on copper and molybdenum. During this work, many questions have surfaced regarding the contribution of process unit design to specific aspects of a product's LCI and, more importantly, how such designs could be improved using a life cycle perspective. Management strategy efforts were undertaken to improve the LCI footprint, however it was found that the corrective actions were almost impossible to apply at the operation level in plant, given the ongoing timing pressures of extractive mining, and costs saving priorities. Additionally, it was found that most of the important comparative differences between operations had structural reasons. In this circumstance, the LCI practitioner group from 1M2, and the environmental managers from Codelco, decided to shift its efforts to place the critical LC1 aspects to the design process of future developments. Hatch Associates has developed unique tools in their Sustainable Plant Design (SPD) package that compliment and enhance LCA methods; these effectively drive sustainability into the heart of the design process. By using LCA and SPD in a project design phase, you cannot only address potential hotspots, but also decide on materials, location and size of certain facilities to optimize for energy efficiency. Moreover, you can avoid the shifting of environmental burdens upstream or downstream within the plant and finally it is extremely useful in identifying opportunities for greenhouse gas reduction.

Jan 1, 2007

By J. C. Glandus, N. Tessier-Doyen, M. Huger

The Young's modulus of bi-phased model materials (vitreous matrix containing spherical alumina inclusions) have been determined by two complementary approaches: experimental and analytical. If the matrix and inclusions exhibit close coefficients of thermal expansion, the experimental results lie in the vicinity of the lower bound of the Hashin & Shtrikman's model. If there is a dilatometric disagreement between the components, untypical behaviors, similar to those obtained for a family of industrial refractory materials, were observed when the temperature varies.

Jan 1, 2004

By Robert B. Parsons

"Finance Minister Paul Martin's first budget disappointed almost everyone. The business sector was disappointed at the some what feeble attempt to grapple with the country's deficit. The mining industry was disappointed by tax proposals regarding mine reclamation that fall short of the industry's needs. Has anybody been happy with a federal budget? Federal Budget DisappointsThe federal government's budget papers that were tabled on February 22, 1994, contained a rather bizarre mixture of unrelated tax proposals. The budget signals an unexpected attack on the tax treatment of debt settlements, on certain types of corporate reorgani2ations, and on income earned by foreign affiliates. This is an old style budget, which proposes a pot pourri of technical changes and policy initiatives. Mine ReclamationEffective February 23, 1994, a taxpayer's contributions to a prescribed mine reclamation trust fund will be deductible as a current expense. The budget papers do not provide a definition of what will constitute a ""prescribed"" trust: this definition will surface in due course. However, the budget papers indicate that:• income earned in such trusts will be subject to tax each year;• all withdrawals from the trust (including income already taxed) will be included in computing the income for tax purposes of the recipient;• reclamation costs will continue to be fully deductible at the time incurred; and • contributions, trust earnings, and withdrawals will not be taken into account for the purposes of determining a taxpayer's resource allowance."

Jan 1, 1994

By Jian Li, V. Y. Gertsman, David C. Katz, M. Elboujdaini

Analysis of stress corrosion cracking (SCC) usually involves high-end analytical tools including scanning electron microscope (SEM) and analytical transmission electron microscope (TEM). In recent years, focused ion beam microscope (FIB) has found many applications in materials science fields. In this study, high-resolution FIB images have shown details of crack morphology and a plan-view TEM specimen containing the selected crack-tip was successfully prepared. The preparation of cross-sectioned samples containing crack tips was of paramount importance for subsequent TEM analyses.

Jan 1, 2004

By Chris D. Veldhoen

If you ask most diamond drillers if they have ever encountered methane gas, the answer would probably be yes. This paper explores a serious methane gas explosion that the author experienced while diamond drilling at a northerly Ontario mine. It is hoped that by documenting this event, people may be alerted to the hidden danger posed by confined methane in underground workings. Methane gas tends to be a problem the deeper you get in any Canadian gold mine. Common procedure when encountering methane is to take readings at the collar of the hole and at different lengths from the source. Monitoring continues until the readings drop below 0.25 ppm. Methane is a tasteless odorless gas that is usually locked up in the seams of the rock or is a product of decaying organic material. Occasionally, the gas is released abruptly over a short period of time. Sometimes the gas can continue to vent for months or even years. In small concentrations, methane is relatively safe. In concentrations under 0.25 ppm methane gas is considered safe to work around. Concentrations over 0.25 ppm can become dangerous. During the summer of 2001, Chris Veldhoen was drilling at a gold mine in Ontario. There were three electric hydraulic diamond drills on the 39 meter level, approximately 5200 feet deep. Two Longyear LM 55 drills were about 40 feet apart and another LM 75 was about 2000 feet away. The two LM 55?s were set up to drill holes no deeper than 350 meters. All three drills had been set up on the same spot for more than a month. None of the three drills had ever encountered methane gas in the entire time they had been drilling on the level. On the day shift of July 13 2001, the driller on Chris? cross shift hit a small pocket of gas. He tested the hole and got a reading above 0.25 ppm. He proceeded to rope off the area with a ?DO NOT ENTER - METHANE GAS? sign and a rope denying access beyond the sign. On Saturday, July 14, Chris was instructed to install a Margo plug in the hole that was emitting methane gas. Methane is usually odorless, but occasionally when encountered underground, is accompanied by a rotten egg smell. As he walked to the drill, he could not smell methane gas. He proceeded to test the hole and got a reading of 0.22 ppm methane. This number was in the acceptable range for drilling, but he plugged the hole anyway.

May 1, 2004

By J. D. Bateman, A. S. Dadson

"The Giant claims are on the west side of Yellowknife bay about 1 ½ miles north of the settlement of Yellowknife. They were staked in 1935 by prospectors in the employ of Burwash Yellowknife Gold Mines, Limited, and were transferred to Giant Yellowknife Gold Mines, Limited, in 1937, on the incorporation of that Company. During the period 1936 to 1940 a number of surface discoveries were investigated by trenching, test pitting, and diamond drilling. A shallow inclined shaft was sunk on the Brock zone, a system of narrow and irregular quartz veins, and some 75 tons of high-grade ore was mined and shipped to the Trail smelter. In 1943 management control was acquired by Frobisher Exploration Company, Limited. An intensive campaign of diamond drilling was commenced in January 1944 and carried on continuously for 2 years. This drilling indicated the presence of substantial gold orebodies lying within well-developed shear zones. Two shafts, 1 ¼ miles apart, were sunk during 1946 and underground development started on two of the orebodies.The claims are underlain largely by rocks of the Yellowknife greenstone belt, which extends from the shore of Great Slave lake along the west side of Yell ow knife bay and northward . The most conspicuous structural features are the steeply dipping late faults. The chief of these is the West Bay, which bisects the greenstone belt at an acute angle and crosses the southern part of the Giant group. At the 'big bend' near the west boundary of the claims there is a remarkably sudden change in the strike of the fault, from about 12° N.W. to about 3° N.E. The apparent horizontal displacement along this fault is of the order of 3 miles, with the east side moved relatively north. There are also a large number of lesser faults with apparent horizontal displacements of a few feet up to l,70J feet for the Townsite fault. Most of these faults trend north to northwest. Surface examination indicates that, at least for most of them, the movement corresponds to that along the West Bay fault, that is, the east side moved relatively north. According to the available evidence, all or most•of the movem:nt along the West Bay fault and along the lesser faults was post-ore. Late diabase dyk:s that cut through ore-bearing shear zones, with chilled margins in contact with the mineralized material, are apparently displaced to the same extent as earlier geological markers. ( see Frontispiece. )"

Jan 1, 1954

By Mohammadreza Jalali

Alberta contains over 400 billion barrels of viscous crude oil in fractured carbonates but there is no viable extraction technology as yet. Petroleum geomechanics has become a vital part of the assessment of such hydrocarbon reserves, especially for naturally fractured cases, which are particularly challenging in terms of accurate recovery prediction because of joint fabric complexity and lithological heterogeneity. As a result of interconnected fractures, transport properties of fractures (mostly permeability issues rather than thermal effects) are affected by production and injection activities that change the pore pressures, temperatures, saturations, and effective stresses. Enhanced oil recovery methods involving massive amounts of fluid injection (hot or cold) at high pressure (pinj) may be used to mobilize and produce the oil; therefore, deeper understanding of the fractured systems is desirable. Pressure and temperature variations in a fractured reservoir change the in situ stresses in the reservoir and surrounding rocks; this affects fracture apertures, radically changing the bulk flow properties because flux rate is highly sensitive to aperture. Hence, coupled pressure, temperature and effective stress changes must be considered for fractured reservoirs under a thermo-hydro-mechanical (THM) coupling approach.A hybrid FDM/DDM coupled method is presented to couple pore pressure and stress around a fracture in an impermeable matrix block. Deformation and stresses are calculated in each time step and then fracture permeability, which is the most sensitive petrophysical parameter in fractured reservoirs, is updated based on the fracture aperture variation. This model is then verified with UDEC (Universal Distinct Element Code) which uses a discrete approach to cope with fractured rock mass behavior.

Jun 1, 2012

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007