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By H. Vermette, J. Demers, R. Leclerc, P. Bergeron, P. Hudon, A. Lessard

The Arvida Smelter marked its 80th anniversary in 2006. Arvida currently operates 6 potrooms equipped with prebaked side-feeding pots producing 160 000t of aluminum per year, requiring the supply of 300 000t of alumina per year. In the past, to ensure reliable alumina supplies to the pots, especially in winter, a safety stock of alumina was kept inside the plant. The improved reliability of shipping on the Saguenay River has cut the need for such a stock. However, the stoppage of 8 Soderbergtechnology potrooms, starting in the 1980s up to 2003, generated alumina from the cleaning of pot pits, totaling 18000t and leading to the building-up of a significant alumina stock again. Concerns over working conditions, effect on potroom operations, and dust emissions prevented Arvida from tackling effectively this impressive alumina stock. Yet the increasing cost of alumina has created a strong motivation to use the stored alumina. In 2004 Arvida launched a project to recycle the stored alumina. This 4-year project aimed at clearing the alumina stock without affecting the operation of the smelter. It involved changing work organization, improving equipment and controlling the effect of the recycled alumina on the smelting process and working conditions.

Jan 1, 2006

By G. Lafont

Aug 1, 2013

By H. J. B. Couto, J. G. S. Puelles, M. L. Torem, R. H. Rojas, A. G. Merma

Understanding the limits of fine particle flotation is fundamental to achieving a significant and selective separation. Conventional flotation processes are not suitable to treat these particles because of their low collision efficiency. This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. In this sense, this study assesses the effect of current density and pH on bubble size in a binary electroflotation cell. An increase in the bubble generation rate was reported with an increase in current density. In addition, at acid pH values, the size of oxygen bubbles increased and conversely decreased at basic pH values; this may be due to the electrostatic attraction between the oxygen bubbles and the anode resulting in a greater nucleation time. An opposite trend was observed with the hydrogen bubbles. These results are in agreement with their electrokinetic studies, which reported that at acid conditions the bubble surface may be positively charged for both the hydrogen and the oxygen bubbles. Finally the bubble size was slightly affected by the electrolyte concentration, resulting in smaller diameter bubbles at higher concentrations.

Jan 1, 2016

By Unkown

The Province-wide road ban on movement of heavy loads has had the effect of curtailing or stopping development in several areas. In the Leduc area, the discovery well has been restricted in flow to only a fraction of normal due to limited storage space, but drilling at Imperial Leduc Nos. 2, 3, and 4 has been continued for the past few weeks. The No. 2 well is within 100 feet of the producing horizon and should be completed within the next few days. According to reports, it has been logging slightly lower, structurally, than the discovery well, but, regardless of the outcome, it has been an important test to determine westerly cross-section of the Leduc structure. No official reports have been made available of any tests made during the drilling of the well, but it is understood that promising oil and gas shows have been indicated in higher formations. Actual drilling operations have not been commenced by any of the other companies holding leases in the immediate area but it is expected that, when road bans are removed and equipment is assured, several wells will be commenced. Announcement has been made that Imperial Oil, Limited, will drill a well near Battle lake, about thirty-five miles southwest of the Leduc field. Location of the well has been made following an extensive seismograph survey of the area, with total depth of the test well expected to be in the 8,000- to 8,500-foot range. Drilling will be done with the heavy-duty rig last used at the De Winton test. Imperial Oil have abandoned hope of oil production in the Provost area after drilling nine wells, but will retain their interest in the gas field that has been developed. Of the wells drilled, four indicated gas flows ranging from 1,060 to 13,200 M.c.f. per day.

Jan 1, 1947

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By BARRY BANNATYNE

About 90 per cent of Manitoba's industrial minerals production is for structural materials. Most of these come from the Paleozoic rocks west of the Precarnbrian Shield, or from glacial deposits that are extensive throughout Manitoba. The major raw materials are sand and gravel, and carbonate rocks for crushed stone (and also dolomite for high-magnesia lime, high-calcium limestone for lime and Portland cement, and dolomitic limestone for Tyndall stone). Glacial lake clays are used both in cement and in lightweight aggregate. The Jurassic and Cretaceous strata exposed along or near the Manitoba Escarpment include siliceous, carbonaceous, kaolinitic and illitic shales, all of which are quarried by Red River Brick and Tile in the Pembina Mountain and Ste. Rose areas for use in a brick plant at Lockport. Non-swelling bentonite near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation is of value as an absorbent clay, and is the only commercial source in production in Canada. It has been quarried by Pembina Mountain Clays Limited since 1940. Gypsum occurs in the Jurassic Amaranth Formation and supplies much of the market for wallboard and Portland cement additive in the Prairie Provinces. Quarries are operated at Gypsumville by Domtar Construction Materials Limited, and north of Amaranth by Westroc Industries Limited. Silica sand from the Ordovician Winnipeg Formation is of glass-grade quality, and about 100,000 tonnes are produced annually by Steel Brothers Canada Limited on Black Island . It is used as a glass sand, as foundry sand, for sand blasting, and as a filter-bed sand .

Jan 1, 1984

By J. A. Finch, A. M. Elmahdy

Blending frothers is becoming common in flotation practice apparently enhancing performance. However, there have been no studies to understand the blend mechanism. In this paper, the effect of two frother blends ofF150 (polyglycol) with MIBC or pentanol (both alcohols) on bubble size, gas holdup and froth height is reported. The blends focused on a small addition of the polyglycol to the alcohols as base frother. The tests showed that the bubble size at blend concentration below the critical coalescence concentration (CCC) of the base frother was decreased but was significantly larger above the base CCC. Froth build-up showed a strong synergistic effect.

Jan 1, 2009

By H. Alzraiee

Traditional planning methods such as CPM and PERT have been useful tools to manage construction projects. However, the underlying model of these traditional methods often seems to fail to represent real projects as they tend to assume no interrelationship between project components. In reality, project components have complex dynamic feedback process that requires modeling of inherent uncertainty in the execution of these projects. Nevertheless, this dynamic nature and uncertainty have not been explicitly addressed by traditional planning methods. Project failure can be attributed to poor representation of the inner and outer aspects of operations that are responsible for project dynamics. Uncontrollable external forces are often cited but the real cause may be internal such as the feedback process among components of the project. An alternative perspective is offered in this paper through system dynamics (SD) that accounts for the feedback process and discrete event simulation (DES) for modeling the uncertainty. The proposed method utilizes SD method for modeling project dynamics and DES method coupled with CPM network for operational details and uncertainty, respectively. A case study that involves preparing engineering drawings in a design office is used to demonstrate the use of the developed method and to highlight its capabilities. Modeling the dynamic dimension is expected to enhance planning and scheduling of construction operations and to provide a better understanding of the impact of various internal and external factors on project schedule and productivity performance.

Aug 1, 2013

The hydrometallurgical treatment of copper ores and concentrates continues to be an active field of innovation. The direct extraction of copper from ores containing chalcopyrite is an important development to provide an alternative to flotation-smelting and refining. Jetti Resources (with the University of British Columbia) and the JX Nippon Group have developed process options for chalcopyrite heap leaching. Biological heap leaching developments for chalcopyrite are also continuing in parallel. These direct leaching technologies are also very attractive for arsenical ores. The atmospheric leaching of copper concentrates is an attractive option along with autoclave processing. The Galvanox™ Process is the focus of commercialization by InCoR Galvanox Holdings under exclusive license by the University of British Columbia. The Galvanox™ Process can be used to treat chalcopyrite or enargite containing concentrates to high copper extraction with simultaneous precipitation of arsenic as atmospheric scorodite. FLSmidth has continued development of the Rapid Oxidative Leach (ROL) and associated technologies for chalcopyrite leaching. The Glencore Albion Copper Process using ultra fine grinding of copper concentrates and atmospheric leaching has found application in central Africa. The pressure leaching of copper concentrates continues to be attractive for rapid, complete oxidation of sulfide minerals with high copper extraction and arsenic stabilization of iron-arsenate minerals and precipitates. The Ecometales PLCC project is designed to use high temperature total pressure oxidation for treatment of an arsenical copper concentrate with use of existing copper SX-EW facilities for copper cathode production. The excess acid from the autoclave process will be used to make up the acid demand for associated copper ore heap and dump leaching operations. INTRODUCTION The recovery of copper from ores is dominated by the flotation of copper concentrates followed by smelting—converting and electrorefining. This process has been enabled by the development of froth flotation and progressively made more efficient by advances in smelting and converting technologies.

Jan 1, 2019

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke's law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section's susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By W. D. Robbson

DR. G. W. RAMSEY (l): A study of our non-treatment silicosis autopsy material for the years 1940-43 inclusive, in addition to the common findings of fibrosis, nodules, and emphysema, shows marked thickening of the alveolar walls. This change is due to one or more of the following factors: congestion, edema, accumulation of both small and large monocuclear cells within the interstitial tissues and large monocuclear cells attached to the lining membrane of the alveolar sacs. This alteration in the alveolar walls, we believe, is one of the most important factors in producing impaired pulmonary function. Comparison of our first autopsy material of a case receiving twenty aluminium treatments beginning June, 1943, shows a striking change in the alveolar walls. In all areas free of silocotic nodules and fibrous tissue, the alveolar walls approach normal thickness and are free of cellular deposits. No change was noted in the old processes and none was expected. We believe that these changes in the alveolar walls were brought about by the aluminium therapy and that they constitute a major factor in the improved pulmonary ventilation noted in treatment cases.

Jan 1, 1945

By Farzad Mohammadi, David Kratochvil, Patrick Littlejohn

"With more rigorous regulations being enacted in the mining industry, a need exists for cost effective and environmentally compliant technologies to remove selenium from mine impacted waters to ultra-low concentrations. Existing selenium treatment methods have high life cycle costs, introduce risks of acute fish toxicity, and produce biological waste residues that represent future liabilities. Furthermore, achieving selenium discharge limits of less than 4 ppb is a challenge for existing technologies. Selen-IX™ is a technology developed by BioteQ that selectively removes selenium from mine impacted waters to less than 1 ppb. The technology is purely physico-chemical and takes advantage of the basic principles of ion exchange and electrochemistry. Unlike conventional electrocoagulation that removes suspended solids and breaks emulsions or oxidizes heavy metals, the electrochemical process employed by Selen-IX™ relies on creating conditions where iron acts as a highly effective reducing reagent transforming selenium from a dissolved species into elemental selenium bound in a solid phase. The iron-selenium by-product of Selen-IX™ is an inorganic, non-hazardous and chemically stable solid. Due to their high iron content, the solids produced by Selen-IX™ are of interest to the steel making industry as a low cost feedstock. This offtake potential can not only reduce the life cycle cost of selenium removal by reducing disposal costs but more importantly, eliminate the risk of future environmental liabilities. In this paper, the basics of Selen-IX™ technology are presented along with results of successful piloting on streams from coal and copper-gold deposits.INTRODUCTIONVarious contaminants are released into mining wastewater during the extraction and processing of metals. One such contaminant is selenium. A naturally occurring element found in rocks and minerals, mining activities accelerate its release into the environment. Selenium in trace quantities is essential to all life forms but at higher concentrations it can be harmful, especially to aquatic life where selenium bioaccumulation can lead to reproductive deficiencies."

Jan 1, 2016

By Sergio Romo, Gerardo Fuentes, Adriana Garcés

Refractory ores with gold entrapped in a sulfide matrix, must be processed in a first stage with chemical or physical treatment in order to liberate the gold for a subsequent step with cyanide. The goal of this research was to compare the refractory behavior of a gold concentrate treated using two pretreatment methods: pressure oxidation and fine grinding. Gold concentrate from Viacha Mining in Bolivia, assaying 50.11 gpt, with a P80 of 131 ?m was used. The concentrate contains arsenopyrite and pyrite as main sulphides in the matrix. A preliminary test with cyanide resulted only 13.5% of gold extraction with 4 hours of stirred leaching. Using an autoclave oxidation with sulphuric acid and 12 bar oxygen pressure at 220°C pretreatment, the cyanide gold extraction increased to 69.0% in 4 hours. When material was ground in a pulverizer, producing a P80 of 20 ?m and the product directly cyanided, stirred leaching gave a gold extraction of 65% in 4 hours. For both techniques, the effect of temperature, sulfur produced in autoclave oxidation, optimization of the cyanide and the nature of residues were also studied.

Jan 1, 2014

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By A. Dolatmoradi

Nanocrystalline structure formations produced by severe plastic deformation in Fe-0.15C with initial ferritic-pearlitic and IF steel with ferritic microstructures have been studied through microstructural observation and microhardness measurements. It was found that the nanocrystalline region first forms near the surface of samples due to localized severe deformation. It was also observed that the nanocrystallization rate of Fe-0.15C and IF steels and the deformed layer thickness in these two materials are different with similar milling conditions. The crystallite size and structural evolution of the samples during milling was studied by employing XRD and SEM.

Jan 1, 2010

By K. T. Aye

An investigation into the leaching of chalcocite and covellite in cyanide solutions at concentrations typically encountered daring gold cyanidation has been conducted. The results indicate that, for both minerals, the extent of leaching is greater under anoxic conditions, but is still incomplete even in the presence of free cyanide ions, with undissolved copper solids remaining in equilibrium with solution species. The speciation of the sulfur and cyanide reaction products in solution are interpreted in terms of the fast formation of a copper(I)- cyanide complexes in solution and a sulfur-rich copper(I) polysulfide solid phase, which then reacts more slowly to produce thiocyanate ions.

Jan 1, 2011

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By B. Adams, T. Angelov, G. Sasov, D. Steinhilber, A. L. Tsekov, S. Neufeind

A complementary ion exchange/solvent extraction process for the recovery of copper from low- grade ores is described. It has successfully been implemented on a full-scale plant level at the Buchim Copper Mine in Macedonia, yielding a maximum copper cathode production of 2400 tons per year. Compared with conventional SX/EW operations, this technology makes the exploitation of low-grade copper ores economically attractive, due to reduced operational and capital expenditures. Furthermore, the additional Lewatit® ion-exchange installations diminish the volumes of harmful organic substances in the following SX step and minimise the risks associated with the handling and usage of these chemicals, such as environmental pollution or fires. Finally, the significantly diminished quantities of liquids for the SX operation have a tremendous effect on the footprint of the plant (ca. 50% less) thereby leading to a reduction of capital expenditures. This paper reviews the main stages of the combined IX/SX process, the applications for metal recovery and introduces projects where the process is applied. Key findings of the process are also presented. A comprehensive technical comparison between processes has been carried out. This paper also evaluates the advantages of using combined IX/SX technology as a purification and separation step in copper production process, with the aim of further increasing the overall copper recovery and to ensure that a suitable copper concentration in the advanced electrolyte is achieved. The implementation of a Ion Exchange (IX) process in the classic Solvent Extraction-Electrowinning process(SX/EW) is found to be beneficial for processing of pregnant leach solutions both from spent and new copper heaps and dumps, acid mine drainage and other industrial streams without any preconditioning as well as in terms of achieving improved recoveries and copper cathode quality. INTRODUCTION The concentration and separation of copper from primary leachates is one of the key operations in the hydrometallurgical processing of oxide ores (Langner, 2011). Conventionally, this basic operation is conducted by submitting the pregnant leach solution (PLS), with a 1–5 g/L Cu content, from the initial sulfuric acid leach to a solvent-extraction (SX) process in which copper reports to the organic phase. After phase separation, the metal is stripped from the extractant/diluent mixture employing sulfuric acid to furnish a concentrated metal solution, usually containing 40–50 g Cu/L. The final products of the overall process are copper cathodes, which are obtained from a terminal electrowinning step.

Jan 1, 2019

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018