Search Documents

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

By R. A. Rabnett, G. Paget, Patrick Walsh

"Tumbler Ridge, Canada's newest resource community, has been developed differently than have been other resource communities.Since its conceptualization, emphasis has been placed on the establishment of a traditional municipal government at early a stage as possible.Planning f or the community goes back to 1977. By then, extensive study by provincial agencies had shown a new resource town would be required to exploit north east coal. The Ministry of Municipal Affairs, in conjunction with a consultant named R.A. Rabnett began the extensive Tumbler Ridge conceptual plan.The results of the conceptual plan are evident in the organizational and planning goals of Tumbler Ridge. In every aspect from the election of officials to some financial matters, the town functions as a normal municipality. With the resource companies of the North East Coal Development within its municipal boundaries. Tumbler Ridge has been able to debenture its capital projects against its municipal tax base.The town's ability to function as a normal municipality is enhanced by its control over Crown land it has purchased from the province. This gives it further control over the development of the community and helps in establishing agreements with the resource companies and the provincial government to ensure that housing and service needs are met. While resource company representatives sit on certain municipal committees, their roles are advisory in nature.The community continues to move toward full municipal status and will have a fully elected Council by 1986.BackgroundPlanning for the development of northeast British Columbia coal resources began in 1976 under the aegis of the provincial Cabinet Committee on Coal Development. A series of subcommittees were established including a Townsite/Community Development subcommittee. The Ministry of Municipal Affairs chaired this subcommittee and continued as the lead agency for the provincial settlement planning effort over the period 1976 to 1981."

Jan 1, 1983

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By P. L. Wright

"This is a brief history of the development of the mining project, with a description of the proven geology. The paper describes how the experiences gained progressively demanded change in the mine design. The equipment used is described, together with methods of working. Interesting facts have been proved regarding gas emissions and roof. supi;iort. The. working cycles evolved are completely flexible m operation and lend themselves to maximum utilization of the most productive units. The two underground mines are compared, showing the variance in conditions already experienced. Programs currently in operation to improve standards and production are: the training of miners, maintenance men and officials; experiments in floor consolidation and continuing roof support trials; and the effect of comparative stability of working crews on the performance of the operation."

Jan 1, 1973

By H. Al-Kazzaz

The effects of laser power and joint gap on the welding quality of 2-mm butt joints of ZE41A-T5 sand castings were investigated using a continuous wave 4 kW Nd:YAG laser system and 1.6-mm EZ33A-T5 filler wire at a welding speed of 6 m/min and surface defocusing. The smooth weld profiles with the minor welding defects were obtained at a laser power of 4 kW and joint gap of 0.3-0.4 mm. The hardness values in the fusion zone are similar to those of the base metal but there is a drop in the heat-affected zone after a natural aging of 18 months.

Jan 1, 2006

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By K. M. Ed

MR. J. C. NICHOLSON: The author has discussed his subject in a very thorough manner. One difficulty is the tendency to regard a 'permitted' explosive as a 'safe' explosive. There is no such article as a safe explosive; any explosive is only as safe as the man who handles it. In making up the primer, the method illustrated in the paper is alright for the ordinary explosive but not so for the sheathed explosive, for the sheathing would be punctured. MR. T. L. McCALL: I fee! quite certain that there would be little, if any, trouble from flame shots or misfires if the author's suggestions were carried out. There is a tendency on the part of the shot-firer to over-shoot, so as to bring clown more coal for the miner, and frequently a shot has not sufficient burden imposed upon it. Shooting one hole may not only lessen the burden on an adjacent hole, but may practically release it altogether, in which case the second hole should be fired with a very small charge, or perhaps it might not be necessary to shoot it at all. While the paper refers to shooting in the coal only, it should be under-stood that the instructions given are equally applicable to brushing shots. I do not wish to bring up any contentious point, but would the author say a word on cushioning with air gaps and on multiple shooting? Single shooting in rock might open up a feeder of gas which could be ignited by the ?second shot.

Jan 1, 1940

By J. B. Mitchell

Using digital image correlation the evolution of strain and strain at the onset of localisation resulting in a hot tear has been determined for alloys AA6111 and Al¬0.5wt% Cu during solidification. High resolution images of hot tear formation and growth were captured during a constrained bar test that incorporated a glass window above a central hot spot region. The images were analysed using digital image correlation software to measure the evolution of displacement and strain based on tracking the motion of discrete features on the as-cast surface of the sample. Temperature data was also acquired with a thermocouple cast into the sample in close proximity to the hot tear. The interval starting from the point immediately after solidification shrinkage ends (the metal pulls away from the glass) and finishing when the first sign of a crack or hot tear is visible to the eye was used to determine strain data. The minimum strain at which strain localisation occurs was found to be 0.0069 in AA6111 and 0.0021 for A1-0.5%Cu.

Jan 1, 2007

By John (Jack) D. Young, Frank M. Wheeler

Metallurgical plants are typically large, complex facilities. Their design is a multidisciplinary activity with a wide range of inputs, based on: the business case; metallurgical and process requirements; and the main processing equipment selection. Many constraints limit what can be achieved. Appropriate phasing of the design and development, and clear go/no-go decision criteria, are critical to successful implementation of a plant design project. Risk management concepts are used as a framework for successful project development, working from the business case, through project development, to implementation and startup, paying constant attention to technology, safe design, and sustainability. 1.1 INTRODUCTION The subject of “Metallurgical Plant Design” is the design of metallurgical plant facilities in the broadest sense. Plant design represents the culmination of many multidisciplinary activities: knowledge of process metallurgy is applied to design facilities to manufacture useful, economical, metal-based products. In the field of metallurgy, plant design is often overlooked, and its unique requirements are commonly not well understood, let alone appreciated. This book is a contribution to remedying this situation. The focus is the specifics of the metals industries, because an extensive literature already exists on the general topic of plant design.

Jan 1, 2015

By R. Neumann, O. Gomes, S. Gaydardzhiev

"Phosphorus in iron ores is considered as a deleterious component to iron making reflecting in cold shortness of the produced steel. The present study investigates the phosphorus migration pattern resulting from thermal treatment of an oolitic-type iron concentrate with and without additives. To this end focused mineralogical and microscopic observations were performed. The results have shown that roasting with alkaline additive drives phosphorus outside the hematite hosting mineral, however it remains evenly distributed inside the volume of the oolites. It penetrates inside the newly formed cementing phases of Al- Na-Si-Fe-type and also fills the interstices between the crystals. Other than phosphorus, aluminum, calcium and iron tend also to migrate towards the amorphous-type cementing phase. Finally, the possibilities for P removal by means of magnetic separation and acid leaching of the roasted concentrate were evaluated. The obtained final product presents a standard iron concentrate suitable for steelmaking with its phosphorous being dropped from 0.71% to 0.05% and iron grade of a nearly 66% being reached. INTRODUCTIONSignificant proven reserves of iron ores are still not exploitable due to lack of an economically viable and efficient technology for removal of phosphorus. Among them are the oolitic iron ores with high phosphorus which are estimated to nearly 377 billion tons (Hernandez et al., 2012). Phosphorus is a deleterious component giving a cold shortness to steel and often is penalized if exceeding 0.07%. Most of the high-P iron ores are considered refractory since phosphorus is finely disseminated and is evenly met as phosphate groups inclusions inside the limonite structure. Studies on inclusion of phosphorus in artificially synthesized goethite have shown that it is adsorbed as [HPO4]2- groups bridging the adjacent iron ions (Parfit et al., 1975). The high-phos iron ore originating from Lisakovsk deposit, Kazakhstan presents a similar mineralogical issue because the quantity of P, met as solid solution, is substantially higher than the one in P-containing minerals. A potential reason for that is the ore body formation process from the slow deposition of iron-rich precipitates together with clastic erosional sediments in rivers. There is significant quartz and clays inside and around the oolites. The deposit contains about 1.7 billion tons of measured and indicated reserves at 35–41% iron and 1.1 billion tons of inferred ore have been delineated possessing nearly the same chemical composition (Golubovskaya, 2003; Kokal et al., 2003)."

Jan 1, 2016

By Y. Zedan

Cutting fluids play important roles during machining, including the reduction of friction and temperature. Using a cutting fluid, however, degrades the quality of the environment and increases machining costs. The aim of the present research work is to study the effect of cutting fluids and their interactions with cutting parameters on the quality of holes during the drilling of 6061-T6 aluminum alloys. The lubrication types and modes investigated are dry machining, flood lubricant machining and minimum quantity lubrication machining (MQL), while the part quality criteria include the surface finish, the dimensional accuracy, and burr forms and sizes. A scanning electron microscope (SEM) was used to investigate the formation of built-up edges (BUE) in the drill flutes as well as the surface texture of drilled holes. It was found that dry machining and MQL machining can produce parts having quality levels comparable to those obtained in wet machining, when using the optimal cutting conditions.

Jan 1, 2011

By J. W. Matousek

Since the late 1800s, copper-nickel ores have been mined and smelted in the Sudbury area. The Canadian Copper Company, the Copper Cliff ancestor of Inco Limited, commenced operations with a blast furnace smelter in 1888. Coal-fired reverberatory furnaces were added in 1911 and multihearth roasters in 1914. The blast and reverberatory furnaces smelted, respectively, coppernickel ores and ore fines until 1930, when a milling process and plant began operating to concentrate and separate the minerals of these two metals. Two reasons for this delay were: (1) the availability of high grade ores suitable for direct smelting; and (2) the difficulties in making the copper-nickel separation. The Mond Nickel Company, however, practiced flotation at its Coniston Smelter site from 1914 to 1930. A bulk concentrate containing six per cent copper and five per cent nickel was recovered from ore of 1.6 per cent each of copper and nickel. Gravity (table) and magnetic concentrates were also produced. Inco Limited (then The International Nickel Company) began laboratory-scale flotation tests on its ores in 1918. This work led, ultimately (in 1930), to the construction of the 7500 tonne-per-day Copper Cliff Mill, designed to recover separate copper and nickel concentrates. Its capacity was expanded to 11000 tpd in 1936, to 18 000 in 1940, and to 27 000 in 1942. Since 1971 it has operated to process only the bulk flotation products from other mills to yield individual nickel and copper concentrates.

Jan 1, 1999

By L. E. Djingheuzian

"ForewordTHE FOLLOWING excerpt is taken from Fine Grinding Investigations at Lake Shore Mines (C.I.M., Trans., Vol. XLIII, 1940, p. 307):""MacCalman, who has carried out exhaustive testing on the accuracy of screen analysis, makes the following statement in his report, The Accuracy of Sieving Tests, Industrial Chemistry (London, England), Vol. XIV, p. 231:"" 'It will be shown that, as no specific relationship between the sieving value and the various dimensional features of the sieve is evident, though there is an apparent tendency for the sieving value to follow the average aperture size, it is apparently impossible to define the sieving value of a screen from dimensions alone, and the calibration of sieves for important tests on a specific material, whereby the sieving values of these sieves are related to that of an arbitrarily chosen master sieve by correction values, will be recommended."" 'It will be emphasized that these correction values are probably not applicable to other materials, or the same material of different size composition. Sieve users, for important tests or in cases of dispute, will be recommended to calibrate their sieves against a mutually acceptable standard with specified conditions of test, and to recalibrate at intervals' ""."

Jan 1, 1953

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004

By Thomas Hauquin, Olivier Deck, Yann Gunzburger

"In this study, 2D numerical modeling of a room-and-pillar mine is conducted along with the calculation of all terms of the mechanical energy balance. Simulations of different geometrical and geomechanical configurations are performed in order to investigate the conditions that favor a high seismic energy release (instability) during the excavation (removal) of one single pillar. At first, classical stressstrain simulations enable us to estimate the elastic and quasi-static response of the mine. Then, owing to the implementation of new functions in the modeling code, the seismic energy released when the pillar is removed is calculated. The obtained values are found to be in agreement with those calculated analytically using a modified energy balance based on the works by Cook (1967) and Salamon (1984).It is shown that the mine’s proneness to release large amounts of seismic energy, after sudden removal of one single pillar, mainly depends on three parameters: the initial extraction ratio of the mine, the depth of the exploited seam and the Young’s modulus of the surrounding rock mass compared to that of the ore. Moreover, it is pointed out that the magnitude of the seismic energy can be greater than that of the stored elastic energy, meaning that the dynamic (seismic) transient stresses should not be neglected when compared to the quasi-static stresses, particularly when trying to prevent the risk of rockburst and collapse in underground mines."

Jan 1, 2015

By A. Eslami, H. Tabatabaei, M. Kolandoozan, Z. Manafi, A. R. Shahverdi, M. Noaparast, M. Oliazadeh

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulphide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A. ferrooxidans was used to change the surface chemistry of pyrite and copper sulphide ores and consequently, their flotation behaviour. In the presence of A. ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulphide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria can be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50% lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By O. Bouaziz, O. Magnea, P. Cugy, E. F. Rauch

The experimental difficulty to perform Equal Channel Angular Extrusion (ECAE) of a bulk sample of hard material such as steel was overcome. The original method proposed in this paper consists in replacing the bulk sample by a stack of alternated hard metal (steel) and soft metal (aluminium) sheets. By applying this procedure to an Interstitial Free steel (IF steel), 2.7µm grain sized material was obtained after recrystallisation. Its mechanical properties (hardness, formability in shear, hardenability and faigue limit) were investigated and compared with the properties of the same IF steel with conventional grain sizes (12m and 25µm).

Jan 1, 2004

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016