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By W. A. Plachner, Schiller E. A., S. P. Santiago

"The Monkman Coal Property is located in the Northeast Coal Block of British Columbia. It is divided into the Duke Mountain Block on the north east and the Dip Slope on the west. Together, these areas cover 39,503 ha of coal licences.The property is underlain by Jurassic and Lower Cretaceous marine and continental sedimentary rocks. Economic coal measures are contained within the Gates Formation. Exploration of the property began in the early I970s, with drilling commencing in 1975. To date, 255 holes have been drilled and nine adits have been driven to recover unoxidized coal samples.The property has a geological resource potential of 2.8 billion tonnes of medium and high-volatile bituminous coal. Medium-volatile bituminous reserves, totalling 68.9 million ROM tonnes at an over-all strip ratio of 6.3:1, have been identified in three pit areas in the Duke Mountain Block.Construction start-up will commence when sales contracts are arranged. The clean coal will be exported via the Ridley Island Terminal at Prince Rupert.IntroductionThe Monkman Coal Property is located in the Northeast Coal Block of British Columbia in the southern port ion of the Peace River Coalfield. The coal field encompasses a strike length of 250 km of Lower Cretaceous coal-bearing strata in which 13 companies have identified several billion tonnes of resources and several hundred million tonnes of reserves. Currently, two companies with contracts are in the construction phase, and are scheduled to produce coal by early 1984. Quintette Coal Ltd. has a contract with Japanese steel mills to supply annually 5.0 million tonnes of metallurgical and 1.5 million tonnes of thermal coal. Teck Corporation (Bullmoose property) has a contract to supply 1.7 million tonnes of metallurgical coal annually."

Jan 1, 1983

By W W. Moorhouse

A survey of recent literature indicates that sulphides occur in the volcanic rocks of the Archean, or in sedimentary rocks intercalated with the volcanic rocks. The thick sedimentary sections are generally poor in sulphides. Thus, the widespread pyrite and pyrrhotite mineralization in the Archean may be largely of volcanic origin. Introduction I N this paper, commercial base-metal deposits will not be considered, as they are dealt with in other papers of the Symposium. Instead, attention will be focused on those sulphides, often associated with graphitic argillites or tuffs, which have appeared in such embarrassing abundance in electromagnetic surveys of Archean areas. The data on which the paper is based are drawn from recent reports of the Ontario Department of Mines, the Quebec Department of Natural Resources and the Geological Survey of Canada. The information available from these sources is unfortunately limited, because sulphides commonly occur in sheared rocks, such as black argillites and tuffs, which rarely form conspicuous outcrops, and may not be exposed at all. Thus, in the absence of geophysical information, even detailed mapping may fail to reveal the presence of sulphide-rich rocks.

Jan 1, 1965

By E. H. Kranck

Introduction Baffin Island is still too in-accessible to be of interest to the mining industry. However, twenty years ago few people dreamed of mining iron ?ore in Labrador. A journey by air to the most remote places in the Arctic is today no more remarkable than a trip to Europe, and the technical difficulties of mining minerals of high value are not insurmountable. Some ?observations concerning the geology and mineral possibilities of Baffin Island, the largest of the Arctic islands, may therefore interest the members of the Institute, in spite of problematic practical value of the subject. The following short account is mainly based on observations made during the Baird Expedition of the Arctic Institute of North America last summer 1950), and on information available from earlier expeditions. Early Work Baffin Island was one of the first parts of Canada to attract prospectors. Frobisher sent a shipload of rocks, which he believed contained precious metals, from Baffin Island to England. This attempt, however, was a failure and no further serious prospecting work has, so far as I know, been done. During the past few years geological mapping has been carried out by the Geological Survey of Canada (Fortier. Davison, 1949-1950) in the southern parts ?of the island, along the coast of Hudson strait. In 1942, Weeks mapped the coast from Pangnirtung to the head of Cumberland fiord, and Netteling river up to Netteling lake. In the northern parts of the island, only scattered observations have been made ?by Bell, Watkins, Baird, and others.

Jan 1, 1951

By R. F. Sharpe

THE Bullion mine, in the famous Cariboo district of British Columbia, is situated on the left bank of the South fork of the Quesnel river, approximately three miles below the outlet of Quesnel lake. A good road leads 63 miles northeast to the property from Williams lake, the railhead on the Pacific Great Eastern railway. The mine may also be reached over good roads from Vancouver via the Fraser canyon, Ashcroft, Clinton, and the 150-mile house, a total distance of 407 miles. In the early days of placer mining on the South fork of the Quesnel, several rich bars were found. The 'pay' on one of these at the mouth of Dancing Bill gulch was followed up the gulch by a Chinese company, who proved to be the discoverers of the present Bullion mine. This Chinese company commenced working in 1884, in what was then referred to as the China pit. Although working under very primitive conditions, it is reported that, during the ten years they operated the property, they recovered in excess of $900,000 in gold. This somewhat large recovery was due to a local concentration, the result of Dancing Bill creek having meandered down that portion of the channel and washed off the overburden. In 1894, a syndicate composed largely of the Canadian Pacific Railway directorate of that time, with J. B. Hobson as their field manager, acquired the property, as the apparent magnitude of the operation was too great for the resources of the Chinese company. Mr. Hobson, during the first ten years of his regime, developed the mine into a large-scale hydraulic operation, and during that period, from 1894 to 1905, recovered approximately $1,234,000 in gold. In 1906, the property was sold to the Guggenheim Exploration Company, who retained Mr. Hobson as Manager and embarked on an extensive programme to bring in additional water. This project was never completed, however, work being suddenly abandoned in 1907 and the mine closed down. Shortly afterwards, the property was purchased by a small operator on what is believed to have been largely borrowed capital. This venture resulted in no production, but in much litigation, which eventually reached the Privy Council in 1920.

Jan 1, 1939

By M. D. Griffith

"Ventilation models are a vital tool to ensure ventilation designs can provide airflow to all work areas in a mine. Airway resistance and variations in natural ventilation pressures will affect simulated airflow and heat distribution through a mine. Validating ventilation model resistances and pressures to the exact underground conditions can be difficult and the variances can contribute to significantly different simulation results depending on the structure of the ventilation design. The study will use sensitivity analysis to explore examples of variability of simulated airflow due to small resistance, heat and natural ventilation changes and thereby help the user identify both trustworthy and potentially unreliable parts of a mine ventilation model. INTRODUCTION Mine ventilation network modeling is a vital tool for ventilation professionals and has become increasingly relied upon during the design and operation phase of mine ventilation systems. However, they provide only an approximation of reality, and caution must always be exercised when drawing conclusions or making decisions based on simulated data. Ventilation modelling should be performed by persons with a sound fundamental knowledge of ventilation and ideally should be validated with field data, but in large mines, or mines which are yet to be mined, accurate input of the simulation variables can be difficult, and errors and inaccuracies may be difficult or impossible to avoid. This study discusses and investigates the sensitivity of the mine ventilation simulation results to input errors. In addition, there are limitations to what steady-state airflow and heat simulations can model, regardless of the accuracy of the model inputs. In some situations, steady-state solvers cannot capture the dynamic changing behavior of a ventilation system. This study will also describe and apply techniques to analyze the natural variability of mine conditions on ventilation models. The consequences of poor accuracy in some parts of a mine model may impact on the health and safety criteria of ventilation designs. For example, if an airway is required to flow in a particular direction and quantity, then despite a ventilation model showing correctly designed conditions, small errors in input values may result in incorrect prediction of the direction or quantity of airflow. This may create unexpected buildup of heat or gases during operational activities, causing safety issues or operational delays. The ability to know which parts of a mine ventilation model have increased potential for poor simulation results will allow engineers to consider the ventilation design and make changes if required to better guarantee the required design flows."

Jan 1, 2019

By Chris Yellowega

The construction and startup of a new mine is a daunting task. To successfully locate, design, build and startup an immense human endeavour like a new mine, takes perseverance, planning, dedication and significant capital. The application of capital requires a thorough evaluation of risk and where that risk is most properly limited to create the risk/return profile. One area of significant capital and thus, significant risk is the selection and maintenance of the very machinery needed to deliver the creation of investor wealth. Albian Sands Energy is the operator of the new Muskeg River Mine located north of Fort McMurray in Alberta?s oilsands. The Muskeg River Mine is owned by a joint venture of three companies: Shell Canada, Chevron Canada Ltd.and Western Oil Sands. The mine is designed to run 400,000 tons per day, 365 days per year. The mine conditions vary from material as hard and of similar consistency to pavement to underfoot conditions as soft as saturated sands. Water cannot be drained below surface conditions, shovel teeth can disappear in less than 24 hours and the primary business is often constructing large civil structures that have little to do with the delivery of ore. The mine starts with the deposit (if it doesn?t exist, nothing else matters), moves into the design, the feasibility study and the approval. The evaluation of risk and the strategies surrounding the control of that risk truly lie after these stages are complete. The strategy and execution stage is where risk is eliminated or accommodated. The point at which the investors money is being spent is the point at which the decisions made cannot be reversed. It is of absolute importance that the execution of the decisions are consistent with the strategy agreed to, lest the investors need to be asked for more money. The key sources of risk identified for the Muskeg River Mine were recruitment of trained and experienced personnel and the delivery of ore to maximize early (<2yr) cash flow. The Muskeg River Mine personnel determined that to minimize risk, personnel would be recruited to operate the mine equipment yet, the requirements for maintaining the equipment would best be held by the manufacturer. The strategy was to obtain the correct equipment for the operation of the mine and leverage the supplier?s expertise to ensure the mine wasn?t training a maintenance organization at the same time as a mining organization. In essence the key strategy for the mine start up and early operation was to leverage the equipment suppliers to maintain and repair the equipment. Albian Sands would maximize the utilization of Maintain And Repair Contract?s.

May 1, 2003

By Robert A. Bosschart, Harold O. Seigel

"Most electromagnetic methods presently used in mining exploration are of the moving source type; i.e., the primary field source is moved simultaneously and in a fixed configuration with the receiver. Of the fixed-source methods, which employ a stationary primary field and a moving receiver, the Turam method is the most effective and has marked advantages over alternative electromagnetic methods. The results are little affected by topographic relief, and a high degree of resolution can be obtained because of the constant relation between source field and investigation area. Another inherent advantage of the Turam configuration is that it provides more favourable dimensional relations. Thus, the primary field attenuates at a much lower rate than in moving-source configurations and, secondly, the method is size sensitive; i.e., conductor size affects the strength of the response, which is not the case with moving-source methods. These factors result in a considerably better potential depth penetration."

Jan 1, 1966

By Wm. F. Wuest

INTRODUCTION THE Western Canada sedimentary basin has one feature in common with the Precambrian Shield area: it also was a great chemical laboratory. The mining industry of Canada exploits the end products of chemical experiments that occurred on the Shield during periods of repeated disturbances in Precambrian times. The petroleum industry on the other band exploits what also appears to be the final results of chemical experiments that took place throughout all of post-Precambrian up to Tertiary times. Since the subject of this paper is a factual study of Alberta well waters, no attempt is made to answer significant questions pertaining to the probable role waters play in the generation of oil, or to the significance of the effects of structure and depth on waters. Data from several hundred well-water analyses were compiled by the writer in a series of charts and diagrams, of which those included in this paper are representative. Early studies indicated the possibility that outstanding anomalies in general concentration of waters and in greatly increased concentration of elements such as calcium, magnesium, bromine, and iodine for example, might be expected from wells that produced oil or were in the immediate vicinity of producers. The water analyses from wells which? were drilled at a later date did not confirm this possibility, and it is suggested that, aside from their initial value to the petroleum engineer or to. those interested in the commercial possibilities of brines, no definite significance as an aid in oil discovery can be attributed to water analyses.

Jan 1, 1951

By Kenneth L. Graham

Horizontal directional drilling from existing underground workings will greatly reduce, if not replace, surface exploration drilling. Diminishing ore reserves along with increasing difficulty in acquiring access and permitting of drilling surface holes requires a change in procedure. The length and direction of the required long holes is site specific, but once determined could be quickly mobilized. Data would be available for a much more timely evaluation without any surface disturbance and required reclamation issues. Preplanned directional drilling from underground will also provide an evaluation of already inconsistent uranium deposits located under surface terrain that is inaccessible to surface drilling.

Aug 1, 2010

By E. J. Marcotte

"IntroductionDevelopments in the preparation, hydraulic transportation and placement of classified mill tailing as an effective backfill and support for mining excavations, have made feasible several advancements in mining methods that are safer and more economical. Hydraulic backfill systems have played an integral part in the development of more efficient cut-and-fill and blasthole stoping.The hydraulic transportation of tailing fill has made possible the elimination of expensive and laborious transportation, placement and spreading of gravel type fills. Also, in cut-andfill stopes, the use of hydraulically placed consolidated fill has largely eliminated the need to use extensive timbering for floors and supports, previously necessary when only gravel type, waste rock or unconsolidated tailing fill was used .Another important advantage of using mill tailing as backfill is that it decreases the need to contain a large portion of the mill solids waste in a surface disposal area and thus reduces environmental and ecological problems.Tailing Fill PropertiesConsolidated tailing fill consists of deslimed mill tailing and Portland cement. These two materials are mixed together in various proportions to form a high density slurry which is transferred underground by gravity through boreholes and pipelines. After placement underground, the water is drained off and the mixture is allowed to set. The strength of the consolidated fill is dependent on the cement content, particle size distribution and curing time. A typical tailing/ cement ratio used for bulk filling in stopes requiring vertical wall support is 30:1. Ratios ranging from 8:1 to 5: 1 are used for stope floors. High pulp densities minimize segregation and loss of cement during placement as well as reduce the amount of drainage water to be handled."

Jan 1, 1989

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011

By R. W. Pauls

"Many tens of thousands of hectares of forested land will be disturbed and reclaimed in the surface mineable Athabasca oil sands area during the next few decades. The surface area disturbed by Syncrude’s Mildred Lake development alone exceeds 10 000 ha to date. It is not clear that reforestation of disturbed areas will best accommodate the aspirations of all stakeholders, particularly traditional users of the land. A five-year research program by Syncrude Canada Limited and the Fort McKay First Nations has examined the feasibility of raising bison on land reclaimed after disturbance by oil sands development. Forage productivity and carrying capacity for bison was comparable to that of grasslands elsewhere in Alberta. Concerns regarding compaction of newly rebuilt soil by bison traffic proved unfounded. Bison demonstrated weight gains typical for ranched bison and calving rates averaged 90%, a value typical for ranched bison. The animal husbandry problems encountered were typical of those occurring on bison ranches elsewhere in Alberta. An economic analysis indicates that a 1000 ha bison ranch on reclaimed land has a net present value that compares very favourably with a similar area supporting commercial forest. Subject to approval by Alberta Environmental Protection, the current research project will be expanded as a pilot commercial ranching venture in order to explore its commercial viability as a business venture by the Fort McKay First Nations. At the same time, measures will be implemented to resolve various regulatory issues associated with commercial bison production in the oil sands area.BackgroundSyncrude Canada Ltd. (Syncrude) is proposing, in its land reclamation strategy, a feature that is, depending on one’s background and perspective, regarded as an innovative approach to land reclamation, a threat to the regional forest industry, a creative response to aboriginal stakeholder concerns, a reneging on reclamation commitments, an opportunity to provide an ongoing economic base for postoil sands regional economy, or an environmentally unsound use of the land. These diverse and sometimes strong reactions have been generated by the proposal to introduce bison, either free-ranging or commercial ranched, to the reclaimed landscape."

Jan 1, 1999

By R. Tipman

"In 25 years, processing of tar sand progressed from two small pilot plants to two major commercial operations owned by Syncrude and Suncor. These plants mine tar sand and extract the bitumen which is then converted into a synthetic crude oil. Considerable research on extraction of bitumen from tar sand has been undertaken by these two companies as well as other major oil producing companies, private individuals, universities and the federal and provincial governments. These studies have produced a number of alternate processing schemes which have yet to be commercialized. The producing companies are focusing their efforts on achieving increased processing efficiency, which includes improved bitumen recovery, reduced unit cost, energy conservation, and equipment reliability. In this review, the Syncrude process and examples of new process developments will be briefly described. IntroductionTwenty-five years ago, tar sand processing was limited to two pilot plants owned by Cities Service Athabasca Ltd., and Great Canadian Oil Sands. Earnest Manning was Premier of Alberta and was inviting proposals for the construction of a commercial tar sands plant. The invitations called for a much larger operation than those which had been undertaken in the past. All of the previous attempts at commercial operations up to 1960's had failed, largely because of a poor technical understanding of the process requirements, lack of suitable equipment, and lack of adequate capital. The previous record was not good. The pending new large scale plant was based on improved but not proven technology and equipment, which were developed from the pilot plant studies. In addition, the surplus of conventional oil in Alberta and low world oil prices were factors reducing the need for such a plant."

Jan 1, 1987

By Sadough vanini Ali

Charpy impact energy of functionally graded steels produced by electroslag remelting in crack divider configuration has been modeled in various strain rates. It has been well known that majority of materials indicate different behaviors under different strain rates and temperatures. Therefore, modifying the elastic-plastic model considering the effects of strain rates and temperature gives us an acceptable prediction of these composites behaviors in impact test. In this investigation, graded steel was divided in to several layers in which the layers have the same strains under the impact. Constitutive equation describing the flow stress variations as a function of strain rates and temperatures, have been used to express the stressstrain behavior of layers. The parameter values of constitutive equation determined for all the layers via using the boundary conditions based on composite graded behaviors which were the characterized ferrite, austenite, bainite and martensitte phases. Consequently by applying the rule of phase mixtures and ascribing the impact energy of each layer to the area of stress-strain curve of the same layer, the whole impact energy of composite is the sum of layers impact energy with considering the layers volume fraction.

Oct 1, 2011

By H. J. Conolly

The area around Osisko lake, the Horne mine, and the town of Rouyn, in northwestern Quebec, presents a most interesting structural problem. The present discussion is confined to an area around Osisko lake, about six miles long and three miles wide, shown in Figure 1. The writers are particularly indebted to Mr. Thayer Lindsley, of Ventures Limited, who sponsored the investigation and gave permission to publish this paper. Mr. H. L. Roscoe and Mr. Oliver Hall, of Noranda Mines, Limited, gave every possible assistance; and the Noranda geologists, Mr. H. M. Butterfield, Dr. Peter Priee, and Dr. G. G. Suffel, contributed many data and ideas. It is a pleasure to acknowledge also the fuidance of Dr. W. F. James and Dr. B. S. Buffam and the full use made o their maps and criticism. Dr. M. E. Wilson and Dr. A. Lang, of the Geological Survey of Canada, kindly furnished data on the geology in neighbouring fields. Mr. E. Bailey assisted ably in the field, and Mr. H. F. King kindly reviewed the text. Memoir 166 of the Geological Survey of Canada, The Geology and Ore Deposits of the Roztyn-Harricanaw Region, Quebec, by Cooke, James, and Mawdsley, proved an invaluable source of information. STRATIGRAPHY The following stratigraphie sequence is based in part upon the interpretation of the structure as outlined in this paper:

Jan 1, 1936

By J. Drozdiak

In this paper we present the results of preliminary investigations into the applicability of new laboratory scale tests for the prediction of operating gap and specific throughput in high pressure grinding rolls (HPGR). The work is a part of the CAMIRO HPGR research program being conducted at the University of British Columbia, which aims to develop a suite of small-scale tests and procedures for the selection and sizing of HPGRs. A focus of the presented study is to test sample types in terms of their terra-mechanics based characteristics and relate them to specific throughput and gap results from pilot HPGR testing on the same samples.

Jan 1, 2012

By J. Starkey

A comminution circuit in recent history, is one of the most difficult parts of a mineral processing plant to design with confidence. It is usually the most costly part of a plant to build, and it can consume up to half or more of the energy used on a mine site. To suggest that comminution energy usage is sustainable in the long term is not possible at this time. What we have to choose from today, based on more than 50 years of experience, does include the best available technology, and the best way to design it. There is controversy in the industry as to how to properly approach the subject of comminution design, with many of the optional solutions requiring a level of training and expertise beyond the ability of a non-specialist engineer. Semi-autogenous grinding technology in particular, has not been properly appreciated because of many recent mistakes in its application and design, which have blurred the positive perception about what SAG technology is, how it can be used, and how it needs to be designed and built. In order to change this, mine owners and senior managers need to take responsibility for, and learn to understand the fundamental challenges that a comminution circuit poses to the project, to the design process, to the operators who use the equipment, and to the resulting metallurgy. This address is intended to summarize these challenges and offer fundamental engineering solutions, which are clear, specific and in a format which is directly applicable to the mining and mineral engineering community.

Jan 1, 2018

By S. A. Sadough vanini

In this paper, Stress-Strain-Temperature relations for Shape Memory Alloys are studied. Temperature effects on Shape Memory Alloys are different from those related to ordinary materials. In ordinary materials, elastic characteristics can be assumed to be constant in low temperature ranges, and only the deflection arising from temperature changes could be added to the elastic defection. As long as two phases of austenite and martensite could be present in Shape Memory Alloys simultaneously, elastic modulus follows temperature and temperature gradient. In continue a smart actuator is investigated considering a homogeneous cantilever beam. Beam bending is established by using shape memory wires. An initial strain is imposed to shape memory wires in a low temperature, and then, they are installed in the outer surface of the beam. Therefore, since the temperature is imposed in these wires and they cannot have free recovery strain, the compressive recovery stress will be produced in the outer surface. This will result in a deflection in axial direction of the beam. At first, beam deflection is calculated on the basis of theoretical relations and solving the relevant differential equations. Afterwards, experimental tests are performed on an elastomeric beam equipped with shape memory wires. When a voltage is applied, a temperature rise will occur in the wires; then, this temperature rise causes a deflection in the beam. Finally, the theoretical and experimental results? comparison indicates a good conformity. One capability of this actuator is its high flexibility, and by controlling the inlet current, the end-beam deflection can be controlled.

Oct 1, 2011

By H. G. Harper, R. C. Hart

"The Mississagi quartzite is the basal formation of the Quirke Lake trough. As it is traced around the rim, a gradual change in dip is observed, as follows:Northwest corner 50 degrees south.Algom Quirke mine 34 degrees south.Quirke Lake 25 degrees south.Whiskey Lake 22 degrees west.Pecors Lake 25 degrees north.Algom Nordic mine 18 degrees north.Elliot Lake 11 degrees north.Pistol Lake 5-7 degrees west.Thus the apparent synclinal axis is a curving east-west line lying closer to the north limb than to the south. The axis appears to plunge west at about 5 degrees.The Huronian sediments lie on a basement of granites, gabbros, and volcanics. Diamond drill evidence indicates that this basement has a surface of peneplanation, and that the areas of soft basic rock have a smoother topography than the granite. For the most part the orebodies at the Quirke and Nordic mines overlie a basement of soft basic rock.The Mississagi formation is the host rock of the deposits, and its primary structures are suggestive of the conditions under which the conglomerate beds were deposited. Cross-bedding is common, although normal bedding varies from thick to thin to essentially lacking. Grain gradation is not common. Where coarse and fine grains occur together, the coarse tend to be more rounded than the fine. These features are characteristic of shallow-water deposits, laid down above the lower limit of wave action. Therefore, the quartz-pebble conglomerates probably represent ancient water courses, bays, beaches, and bars.The causes governing the creation of the trough can only be conjectured, but there is evidence that both subsidence and compressive stresses played active roles. Drag-folds in argillite beds near Whiskey Lake indicate compressive stress. On the other hand, gentle crumpling in thin-bedded limestones on Quirke Lake is probably due to pre-induration slumping and folding. If strong compression had been widespread within the trough, one would expect drag-folding and shearing of the incompetent beds to be more general. Two large-scale, fold-like structures were mapped by Collins, but their axes do not parallel the trough axis, and they are therefore not related to the major structure."

Jan 1, 1949

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi&apos;g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951