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By Muhammad Zaka Emad

ABSTRACT: Sublevel stoping mining methods with delayed backfill employs cemented rockfill (CRF) as a backfill material. It is used in underground mines to achieve ground control and reduce wall slough. In addition CRF serves to reduce development waste and provides a working surface for mining the upper levels. Efforts to optimize CRF practices have been published. This paper presents a detailed review of CRF practices in open stoping mining systems with reference to case studies. A new methodology is suggested in a simple stepwise approach, which can be adopted for site specific conditions. The need of laboratory testing and quality control program is discussed based on the published literature.

May 1, 2013

By J. D. T. Steyl

"This paper presents a phenomenological model of the rate of iron(III) precipitation in batch and continuous autoclaves at medium temperature operating conditions. The rate expressions are based on information obtained from the literature and experimentation at low and high pulp densities. Special allowance is made for the formation of surface nuclei, which appears to be promoted at a higher iron(III) precipitate surface area, especially in suspensions of lower terminal acidity. This leads to the formation of secondary particulates and provides the required link to simulate high pulp density leaching-precipitation systems, using low pulp density batch precipitation data. In particular, the model allows direct application of the simulation to the autoclave oxidation of iron-containing copper sulfide concentrates and provides a good estimation of the relative precipitation rate of hematite, the preferred product, compared to hydronium jarosite. Some interesting mechanistic understandings of iron(III) precipitation in autoclaves are further elucidated.INTRODUCTIONThe objective of this work is to describe the rate of iron(III) precipitation and the relative amounts of hematite compared to hydronium jarosite precipitation during batch and continuous chalcopyrite oxidation under medium temperature (MT) (~130 to 160ºC) autoclave conditions. Published information has not yet revealed sufficient mechanistic insights about this sparingly soluble salt system under these conditions. The rate expressions in this paper are based in part on current literature information, supplemented by qualitative experimental observation at low pulp density conditions, in particular the high-resolution backscatter electron (BSE) images and particle size distributions (PSDs) of the precipitates. A summary of this work and insights from the literature are presented first, after which the behaviour of iron(III) in high pulp density leaching systems is used to derive a phenomenological expression of the effect of existing iron(III) precipitate surface area on the precipitation rate. The overall regression encapsulates all the experimental results, i.e., those obtained in both batch and continuous autoclave configurations (Steyl, 2012a)."

Jan 1, 2012

By R. Drozd

"The Bullmoose Mine is currently under construction in the North East Coal area of British Columbia, and approximately $300 million will be spent to bring this 2.3 million-tonnes-per-year metallurgical and thermal coal mine into production by December 1, 1983.The project is an unincorporated joint venture undertaking, with Teck-Bullmoose Coal Inc., a wholly-owned subsidiary of Teck Corporation, holding 51%, Lornex Mining Corporation holding 39%, and Nissho-Iwai (Canada) Ltd. holding 10%. Bullmoose Operating Corporation will be the manager and operator of the project.This paper will broadly cover the history and exploration work on the property, the geology, open-pit mining plans and equipment, the preparation plant flowsheet from breaker station to clean coal silo, the 35 km highway truck haul, the railroad loadout system, manpower requirements, construction progress, approvals and permits, and general financial arrangements.IntroductionThe Bullmoose Mine Project"" is located about 87 road kilometres south of Chetwynd, B.C. and consists of an open-pit coal mine, a plant facility in the Bullmoose Creek valley below the mine, and a separate rail loadout facility on the British Columbia Railway Branchline near the new town of Tumbler Ridge some 35 road km to the east.The plant will be capable of producing a total of 2.3 million tonnes per year (mty) of washed metallurgical and thermal coal. Long-term metallurgical coal contracts for high quality, medium volatile, bituminous coal have been signed with nine Japanese buyers for 1.7 mty, and the balance of 0.6 mty will be thermal coal production.Plant construction began in the spring of 1982, and in May 1983, preproduction waste and overburden removal in the mine will commence. The plant should be fully operational by December 1983, and first vessel loading at the Ridley Island port is scheduled for January 1984."

Jan 1, 1983

By A. Coulombe

"RésuméL’analyse des séquences d’exploitation, actuellement en usage pour les gisements très inclinés, a démontré qu’elles ne sont pas toujours optimales du point de vue du contrôle des terrains et de la concentration des travaux d’abattage (nombre de chantiers simultanément en opération). Effectivement plusieurs séquences sont très propices à la création des nombreuses zones de hautes contraintes, qui sont à l’origine des effets de pilier. L’étude de cas de la mine Lac Shortt a démontré que certaines séquences d’exploitation, actuellement en usage, ne sont surtout pas adéquates dans le cas d’un état élevé des contraintes naturelles. En effet la mine a eu de sérieuses problèmes avec le contrôle des terrains (coups de terrains et les effondrements des épontes). Ces effondrements étaient responsables de la dilution excessive et des pertes importantes des réserves minières. Les deux nouvelles séquences proposées, visent la meilleure redistribution des contraintes d’exploitation en vue d’éliminer la création des effets de pilier. En plus elles permettent une concentration plus élevée des travaux d’abattage.À notre avis les séquences proposées pourraient améliorer substantiellement la stabilité des chantiers d’abattage et par la suite les performances technique et économique des opérations souterraines. ABSTRACTThe planning of underground mining sequences represents an important aspect of the mining operation. The analysis of mining sequences actually in use for very steep orebodies has demonstrated that they are not always optimal, considering ground control and the number of stopes simultaneously in extraction. These sequences are conducive to the creation in the rockmass of several stressed zones caused by pillar effects. The case study of Lac Shortt mine showed that the sequences of exploitation currently in use are not adequate especially in the case of a high state of the natural constraints. Indeed, the mine had serious problems with ground control (rock bursts and collapse of walls). These collapses were responsible for excessive dilution and significant losses of mining reserves. The two new sequences suggested aim for the best redistribution of exploitation constraints in order to eliminate creation of pillar effects. Moreover, they allow a higher number of stopes to be extracted simultaneously. In the opinion of the authors, the sequences suggested could substantially improve the stability of working areas and, thereafter, technical and economical performances of the underground operations."

Jan 1, 1998

By M. Al Mukhtar, D. Hoxha, X. Brunetaud, D. P. Do, C. Auvray, L. Michel

"Mechanical behavior of rock joints is often the key factor governing the response of complex structures constructed in fractured rock masses such as underground openings or of objects assembling various stones blocks such as historical building walls or damaged marble statues. This paper aims at developing a theoretical model to describe the behavior of fresh joints based on the description of their morphology. The main idea of the model is to establish a link between the effective contact surface of joints and the frictional coefficient. Beginning from a chosen level of joint surface description where a joint is considered as “smooth”, the model describes the added friction with respect to the increase of the contact surface of the joints and the distribution of stress in these contacts. The model developed initially for asperities with regular geometry is firstly compared with existing models and then applied on fresh artificial joints. For that, healthy artificial joints have been characterised using in one hand classical CNL shearing tests and in another hand the morphology of joints. The joints surfaces are digitized before testing using a high resolution laser scanner (Konica Minelota Vivid 910) allowing to obtain a precision up to 10µm. From these scanned surfaces the morphology of joints is characterised on the profiles running in the direction of shearing and a mean value of friction is calculated using the developed model. This calculated value is then compared with that obtained from CNL shearing test and a good approximation is notedINTRODUCTIONThe role of the mechanical behavior of rock joints on the overall response of fractured rock masses is well established in many fields of engineering activity going from the stability of underground constructions (Souley M, Hoxha D, Homand F 1999), rock slope stability (Einstein H.H. Veneziano D., Baecher GB., O’Reilly K.J, 1983, Jaeger 1971), various rehabilitation of masonry construction, damaged stone artworks restoration (Michel L., Do D.P, Coignard B, Hoxha, 2014) and so on. In the same time the characterisation of the behavior of joints and their modeling is nowadays a dynamic field of research or/and investigations and many alternative approaches have been proposed (Barton, N.R. and Choubey, V. 1977, Tatone, S.A. Bryan, Grasselli Giovanni 2010, William C E. 2007). While empirical relations of shear strength with various parameters of the joint morphology are the most used in practice because of their simplicity (Barton. and Choubey, 1977, Barton 1973, Bandis S., Lumsden A. C. and Barton N. R. 1983) many other models of joint strength are developed based on mechanistic considerations (Haberfield CM, Johnston IW. 1994), multiscale approaches (Yang Z.Y., Di C.C., Yen K.C. 2001, Fardin N., O. Stephansson, Lanru Jing 2001) or micromechanical ones (A. Serrano, C. Olalla, R.A. Galindo 2014) to mention just a few of research trends on rock joints modeling."

Jan 1, 2015

By Zhenyu Han, Dion Weatherley, Ruslan Puscasu

"This study aims to demonstrate the capacity of the Discrete Element Method (DEM) to model and simulate fracture in brittle rock, capture the crack propagation process and determine crack propagation rates for various levels of external loading. In the numerical experiments reported here, a macroscopically homogeneous body of brittle rock, containing a single pre-existing crack, was subjected to tensile stress loading. Simulations concerned with model I crack growth process in 3D were carried out. The process of fracture has been observed under various steady state and dynamic conditions. The numerical results obtained reproduce qualitatively and quantitatively a variety of observed fracture phenomena. Specifically, this study examined the onset of cracks, single dominant cracks that grow across the specimen, crack bifurcations and branching. The density of fractures that can be nucleated and grow to a significant size with and without arresting each other, crack growth speed and stress distribution, all have been consistently and systematically analyzed. Suggestions on potential future developments are made and discussed.INTRODUCTIONFracture and failure mechanics are very important in mining, manufacturing, materials processing, mineral processing, civil and mechanical engineering, and many other disciplines of science and engineering. Yet, due to the complexity of fracture phenomena, no theoretical models of broad applicability are currently available (Bieniawski 1967). The simulation of crack propagation is therefore considered an open question in numerical rock mechanics. Although, a significant body of experimental research on fracture of materials was carried out since the early days of fracture mechanics (circa 1940s) (Poncelet 1946, Mott 1948), often in parallel with the development of fracture mechanics theories as well as with the development of experimental and observational techniques themselves, the experimental results were often done on particular classes of material such as glasses and other very brittle materials. Indeed, a number of specific experimental observations on the behavior of growing cracks in brittle materials were made in the 1940s for which generally accepted explanations based on physical principles are still lacking. Likewise, quantitative numerical modeling, based on both continuum and discrete methods, as a basis for understanding dynamic crack growth is still in a preliminary stage."

Jan 1, 2015

By Roger Lafrance

"This paper discusses various aspects affected by the use of large-diameter boreholes in underground mines. Topics covered consist of noxious fumes, vibrations, post-blast effects, various types of explosives, the cordine system in production blasts, the slider primer system and wall-control methods. In general, the paper is an overview of this important fact of underground mining.IntroductionWith economical factors leading the way, many reasons motivated drilling equipment companies to develop equipment that can drill holes up to eight inches in diameter and even larger for underground applications. One of these other reasons is the fact that many orebodies were considered marginal, given the high costs of conventional mining methods utilizing small diameter boreholes. With these criteria in mind, accelerated programs were put in motion to develop equipment that would reduce both-development and production costs in underground mines. Change s in any basic program often affect other areas down the line. This is particularly true with the ad vent of large-diameter boreholes underground.C-I-L Inc. is certainly no stranger to this phenomena. Whether production headings increase in size and tonnage or whether production increases due to lower costs, one fact remains unchanged and that is the fact that all development and production holes are loaded and blasted whether they be of small or large diameter. Due to this fact, C-I-L Inc., as a leading explosives manufacturer, initiated a program to examine blasting methods in use in surface work with the intent of revising these method s for underground applications. Research facilities were also oriented toward developing appropriate products. This was a task that was accepted with anticipation, with the result that many new blasting systems and methods were brought forward, thanks to the collective efforts of both the consumers and manufacturers."

Jan 1, 1984

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By M. N. Vu, G. Armand, A. Noiret, D. Seyedi

Extensive experimental observations have been performed around drifts and shafts at the Meuse Haute-Marne (North-Eastern France) Underground Research Laboratory (URL) to assess the extent and pattern of the induced fracture networks in Callovo-Oxfordian claystone. Two types of fractures can be distinguished, namely; shear (mode II) and extension unloading (mode I) fractures. The main goal of the present paper is to provide insights on the extent of damaged zone around the drifts by numerical simulations. A two-step approach is considered. First, 2D elastic calculations are performed for simulating the excavation of a drift following the direction of the major in situ horizontal stress. The evolution of the stress and strain tensors around drifts are calculated by applying an elliptic convergence function on the drift wall. Two failure criteria are then verified for the induced damage. An equivalent strain and an elastic energy based damage criteria are considered. The obtained results show that the employed simplified approach provides rather good results for the extent of the damaged zone for drifts parallel to major horizontal stress. However, post-processing elastic results leads to overestimating the vertical extent of the damage zone and underestimating its lateral extent, where the in situ stress state is quasi-isotropic in a section of drift. Nevertheless, the obtained results show that an energy based damage criterion could be considered as a potential way for reproducing the extent of the damaged zones if a convergence function can be defined for the drift.

Jan 1, 2015

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By Shugang Li

Coal and coal-bed methane are valuable energy resources. If they can be extracted simultaneously and safely, the triple purposes of mine safety production, new energy resource supply and environmental protection can be fulfilled. After mining, the mining induced fissure distribution feature and methane delivery behavior in overlying strata were closely related to the relieved methane degasification. Using physical simulation and numerical simulation, it was explained that the distribution feature of mining induced fissure was the Elliptic Paraboloid Zone (EPZ) in three-dimensional space. Based on the key stratum theory, the types, parameters, characteristics and dynamic evolution behavior of the mining induced fissure EPZ were analyzed. Applying environmental fluid mechanics and the mass transfer theory, the relieved methane floating-diffusion equation of the EPZ was established, and the corresponding transport process was analyzed. Using the field practice of relieved methane degasification in Tianchi Coal Mine, it explained that the mining induced fissure EPZ was the storage and delivery area of relieved methane. The degasification effect will thus be useful if the drainage system is laid in the EPZ. Such studies can provide the theoretical basis and technical support for the safe simultaneous extraction of coal and methane.

Aug 1, 2013

By Kim H. Shikaze, John R. Hawley

"Even though acid mine drainage is an old problem, particularly in coal mining areas, its appearance in the form of a major environmental hazard in the hardrock mining districts of Ontario was unexpected. The yellow and amber coloured wastes that characterize an acid mine drainage situation were first noted by the Ontario Water Resources Commission in the uranium mining Elliot Lake district. Problems of a similar nature were also noted in the copper-lead-zinc camp at Manitouwadge, the nickel camp at Sudbury and at numerous isolated base metal properties, both in and out of the Province of Ontario.Without exception, when acid mine drainage type effluents were evident, the specific companies involved worked sulphide or sulphide-associated ores. Without exception, the ore bodies contained quantities of iron sulphide (in various mineralogical forms) and, without exception, the milling circuits serving these operations were such that the iron sulphides were rejected to the tailings areas as waste.Once in a tailings area and after a varying period of time, iron sulphides react to form water soluble salts which, when discharged in the effluents from the tailings area, can affect stream chemistry and stream ecology.It is not unusual that the minerals pyrite, marcasite and pyrrhotite (all iron sulphides) react to form a stable oxide under atmospheric conditions. The law of stability of rocks and minerals, for instance, states that rocks and minerals are stable only in the environment of their formation and, as the environment surrounding them changes, the rocks and minerals tend to change to other species which are relatively more nearly stable under the conditions of the new environment (a). Under atmospheric conditions, iron oxide exhibits a greater stability than iron sulphide."

Jan 1, 1971

By T. R. Eger

Miners can be exposed to whole-body vibration (WBV), when sitting or standing to operate mobile equipment. In order to prevent vibration-induced injury it is important to understand how miners can be exposed to vibration, the health risks associated with vibration exposure, methods to evaluate vibration exposure, and strategies to reduce vibration exposure. WBV exposure typically occurs when operating mobile equipment, such as a load-haul-dump vehicle, haulage truck, or dozer. The probability of health effects such as low back pain, neck pain, headaches, and gastrointestinal track problems occurring from daily vibration exposure can be determined based on criterion values published in ISO 2631-1 and EU Directive 2002/44/EC. A special case of WBV termed foot-transmitted vibration (FTV) occurs when a miner is exposed to vibration that travels through the feet. FTV typically occurs when standing on vibrating surfaces associated with the operation of locomotives, jumbo drills, bolters, or raise platforms; however, there is no set standard to evaluate health effects associated with FTV. Recent medical evidence confirms workers exposed to FTV can develop cold induced blanching of the toes, in addition to numbness and tingling in the feet and toes. In order to reduce the risk of adverse health effects from exposure to vibration, the hierarchy of controls (elimination; substitution; engineering; administration; and personal protective equipment) should be followed. Best practices should be used to minimize vibration exposure through equipment purchases (i.e. vehicles with lower vibration emissions and seats that attenuate vibration), reduced driving speeds, and improved road maintenance for example. The elimination of other risk factors, which increase injury risk when combined with WBV exposure, such as awkward working postures, should also be eliminated. Very little is known about FTV exposure therefore further research is required in order to develop exposure standards and identify prevention strategies.

Aug 1, 2013

By W. T. Robson

Introduction Ground failure, violent or otherwise, is a problem to be contended with wherever underground operations are carried out. The character and extent of the failure, whether superficial or of more serious proportions, is determined by a number of factors, among which might be mentioned: the depth and dimensions of the underground workings; the types and distribution of wall rocks; structural features of the ore and enclosing rocks; the degree of metamorphism; the dip of the orebody; concentration of mining operations; the rate of mining; the history of the excavations made on the orebody in question. This last factor implies the consideration of such points as the arrangement and distribution of stoping both past and present, the current sequence of scoping, the type and effectiveness of the support used in old and current workings, and the amount and distribution of unmined parts of the lode. With such a variety of conditions, it is only natural that the situation at one place in a mine will not be the same as that obtaining in another part of the same mine and, more than likely, will be quite different in another property.

Jan 1, 1946

By J. ?H. Chen

Remote sensing technologies have been applied to numerous fields and already benefited those in improving efficiency and recognition accuracy. Change of streamflow can be devastating to residents living along riversides. Still it is difficult to detect such deathly change in large area scale by traditional field surveys. The research aims at provision of detecting streamflow change using a mathematic method based on remote sensing technologies. The scope is on remote sensing stream images taken during the invasion by Typhoon Morakot, bringing one of the major catastrophes to Taiwan. An algorithm was adopted to deal with streamflow recognition on RGB images. The algorithm is capable of yielding change measured by meters and illustrates how main streams shift. An practical example for the Baolai area surrounded by Laonong stream shows that the streamflow moved 88 meters (36 pixels) toward the downtown area during the invasion by Typhoon Morakot. In addition, the results highlight all dangerous zones (scouring zones) for residents to prevent further potential damage.

Aug 1, 2013

"A growing public awareness of work-related diseases such as pneumoconiosis and the impact of this awareness on legislative bodies and on the skilled labour market are reasons why the Canadian mining industry must consider dust control of top-drawer importance. Measurements and standards related to the hazard are necessary to control a dust situation and to avoid excessive risk. The author discusses some of the methods of measurement, standards proposed and terminology used in this developing technology. The purpose primarily is to give a better understanding of the basic advances achieved by those who have applied current knowledge with a measure of success."

Jan 1, 1972

By T. W. Sullivan

"This paper explores the history of AC static variable frequency control drive systems on open cast mining machinery, in particular electric mining shovels and electric walking draglines, over the past ten years. It critiques the peformance of these drive systems from a productivity and operating cost standpoint and evaluates the over-all success of the original design concepts as they were envisaged in the 1970s. The paper details the state-of-the-art as it exists today as well as design improvements contemplated for the immediate future.IntroductionConsidering the fact that the very first successful application of an alternating current electrical distribution system occurred at the Gold King gold mine near Ames, Colorado, U.S.A., in the year 1891, it seems somewhat ironic that almost 100 years later, AC excavator drive systems are just now becoming commonplace in the mining industry.If one were to read the biography of Lucien L. Nunn, the first person to successfully install a commercially viable alternating current power distribution system, one would quickly visualize a parallelism between his fight to achieve acceptance of his new lower cost technology and that of those commissioned with the belief that AC static variable frequency control drive systems are not only a better performing, lower cost drive system for mining excavators today, but moreover, the drive systems of the future in our industry.This paper will deal with the evolution and incorporation of AC static drive systems on open cast mining excavators. It will trace the history of the development of these drive systems in the mining industry, the current state-of-the-art concerning these systems, and what the future holds for these excavators in our industry."

Jan 1, 1990

By R. Erpelding

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

M INE production requires the coordination of the talents of men and the use of equipment. Mine operators maintain a continual surveillance of equipment, looking for improvements and modifications that will benefit them. Few give similar attention to the advances made in the education of mining engineers since they themselves graduated. That is not surprising. Education lacks the advertising budget available to manufacturers. A modification to improve a mechanical contrivance is advertised, and an advertiser's press releases get attention by publishers. The whole program for mining engineering education could be revolutionized and no one, except a few professors, would know about it. The Canadian Institute of Mining and Metallurgy's newly established General Commit-tee on Education can improve that situation. Nine groups of engineers in Canadian universities are trying to give undergraduates an education that will make them useful to the mineral industry as mining engineers. The tabulation offered here (Table I) is an analysis of the distribution of the undergraduate-teacher contact time.

Jan 1, 1963

By H. Itou

A mechanism of scorodite formation at ambient pressure was investigated using transmission electron microscopy (TEM). Several types of iron arsenate were obtained from Fe/As solutions (Fe/As = 1.0 and 1.5) at pH values of 1.0, 1.25 and 1.5 at 95°C. Amorphous FeAsO4.xH2O was precipitated from solutions having a higher mole ratio of Fe/As at pH l.5, even after 9 hours. A few micron sized particles were observed by SEM, but these proved to be agglomerates of 10-50 nm amorphous FeAsarxH2O particles when observed by TEM. This means that supersaturation of the solution causes the acceleration of nucleation of iron arsenate hydrate. Crystalline scorodite was obtained from a solution in which the Fe/As mole ratio was unity, at pH l.0 and pH 1.5, after 3 hours. Almond-type crystalline scorodite particles were observed by TEM and most of them showed high crystallinity. The addition of scorodite seed material enhanced the crystallization. Amorphous FeAsO4.xH2O, however, was observed at the surface of the seeds during the early stages of precipitation. It is postulated that crystalline scorodite is not directly precipitated even on crystalline scorodite seeds, but requires a certain time to crystallize on the seed material.

Jan 1, 2006