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By A. Idegami, M. Imamura, S. Heguri, Y. Ozaki

"Nickel powder can be produced by the reduction of a nickel ammine complex solution by hydrogen at high temperature and pressure. To minimize the deposition of fine nickel on the surface of the reactor and other equipment, seed crystals are added to the initial solution to promote nucleation of the nickel powder. Such seed crystals catalyze the precipitation of the nickel particles on the surface of the seed and enhance grain growth. In this study, nickel nuclei were precipitated by the addition of a polymer to the nickel ammine complex solution, resulting in the production of nickel powder. Thus, we herein propose a model that explains the effect of the polymer in the precipitation of nickel nuclei.INTRODUCTIONNickel powder is commonly produced via a hydrometallurgical process from the hydrogen reduction of a solution containing a nickel ammine complex at high temperatures and pressures, and this process was commercialized in the 1950s by Sherritt Gordon (Sherritt International, Canada, Benson & Colvin,1973; The Staff, Research and Development Division, Sherritt Gordon Mines, Ltd., 1958).In the above transformation, upon the injection of hydrogen gas into the solution, nickel is reduced as outlined in Equation(1), ultimately resulting in the production of nickel powder.Ni(NH3)nSO4+ H2?Ni+ (NH4)2SO4+ (n-2)NH3(n:2–6)(1)In this process, seed crystals are added to the reactor to suppress the precipitation of fine nickel (scaling) and to enhance nickel reduction (Benson & Colvin, 1973; Mackiw, Lin & Kunda, 1957). More specifically, iron sulfate and a small amount of dispersant polymer are added, which leads to the formation of nuclei. Upon subsequent hydrogen reduction, the reduced nickel can then be deposited on the nuclei, allowing nickel particle growth to take place. However, this results in iron contamination in the final nickel product, and so the use of pure nickel as a seed crystal is desirable to produce high quality nickel powders."

Jan 1, 2017

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By Ray Mason

Marathon PGM Corporation?s PGM-Cu Project in Northwestern Ontario (Figure 1.0) serves as a case study to describe the process involved in advancing a deposit from grass roots exploration to the completion of several feasibility studies and the parallel commencement of environmental permitting. Through the following examination of historical exploration activities, it is clear that these activities are directly related to economic stimulus, mostly measured by downturns in the mineral industry. Other factors that influence the success of exploration advancing to feasibility and new mine development includes the ownership of the mineral claims, which also changes under these economic influences and the crucial role of interactions between the Company, the Crown and First Nations. The Marathon PGM-Cu deposit is hosted within the Eastern Gabbro Series of the Proterozoic Coldwell Complex, which intrudes and bisects the much older Archean Schreiber-Hemlo Greenstone Belt. The sub-circular complex has a diameter of 25 km and a surface area of 580 km2 and is the largest alkaline intrusive complex in North America (Walker et al., 1993). Mineralization at the Marathon PGM-Cu deposit is part of a very large magmatic system that consists of at least three cross-cutting intrusive olivine gabbro units that comprise the Eastern Gabbro Series of the Coldwell Complex (Figure 3.2.4-3). In order of intrusion, the three gabbroic units consist of (1) Layered Gabbro Series, (2) Layered Magnetite Olivine Cumulate (LMOC) and (3) Two Duck Lake (TDL) Gabbro. The relative size and abundance of the gabbroic units decrease in the order Layered Gabbro Series>TDL Gabbro>>LMOC. Late quartz syenite and augite syenite dikes cut all of the gabbros but form a minor component of the intrusive assemblage.

May 1, 2010

By G. W. Clark

"The mining of the ore bodies at Rabbit Lake has in the past been by the open pit method. This method is presently being used to develop the B-zone and will continue into the future with the development of two smaller ore bodies, the A-zone and D-zone. The Eagle Point orebody will be developed by an underground method which will provide production and employment into the next century.The ore bodies at B-zone, A-zone and D-zone are unique in that they are located under Wollaston Lake. To permit mining by the open pit method a steel-celled dyke has been constructed around the north end of the B-zone. This same dyking method will be used for the A -zone and D-zone. INTRODUCTIONMine development at Rabbit Lake commenced in 1970when a detailed engineering feasibility study established the viability of the Rabbit Lake deposit. In 1972 construction of the mill and camp site began. Construction materials were seasonally hauled to the site over a winter road until November 1973when the government of Saskatchewan completed an all-weather road to within six miles of the operation.In October 1974, stripping of the Rabbit Lake open pit began with the removal of overburden and lake bottom sediments from the previously drained Rabbit Lake. The first ore was processed by the mill in June 1975and by October the mill was producing three million pounds per year. The design capacity of five million pounds annually was first achieved in 1977 and maintained until 1981, when lower ore grades resulted in lower production rates .It was clear when mining at Rabbit Lake began that, without additional reserves, the Rabbit Lake operation had a life of less than 10 years. Exploration, therefore, continued in the immediate area in an attempt to discover additional uranium mineralization."

Jan 1, 1989

By C. M. Diaz, S. W. Marcuson

In the late 19th century, the discovery of rich nickel-copper sulfide ore bodies in Sudbury and the need for tonnage quantities of the metal to be used in nickel steel armor provided the foundation for establishing the Canadian nickel industry. For almost 50 years, International Nickel was the key player. In 1930, Falconbridge Nickel entered the field. These two companies remain the key Canadian nickel producers. This paper discusses the factors that have influenced the evolution of nickel smelting processes. The initial Sudbury ore smelting and nickel copper separation technologies were imported from abroad. It was only in 1937 that International Nickel established a process research laboratory in Copper Cliff The explosive post WW II industrial development created a strong demand for a broader variety of nickel products. For both International Nickel and Falconbridge, R&D became an essential business tool to succeed in the new market scenery. In the last few decades, new technologies were developed and commercialized to respond to the raising cost of energy, society pressing environmental concerns, the advent of nickel laterites as an important source of new metal, the incorporation of new nickel producers to the market, and, therefore, the need to increase productivity. Canada thus became an important exporter of technology. In this paper, the authors review this history with the objective of highlighting the forces that have triggered the most important changes in Canadian nickel smelting.

Jan 1, 2005

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

Access to accurate real-time information is critical to maintaining efficiency and competitiveness in any modern minerals processing facility. At MMG LXML Sepon Copper Operation in Lao P.D.R., controlling the copper grade of the feed to the leaching circuit is paramount for maximising productivity and copper recovery. Since 2008, real-time analysis data has been available to process engineers from the Geoscan on-belt analyser installed on the Copper Mill feed conveyor. Access to accurate real-time results from the Geoscan has allowed the process engineers to strictly control blending based on copper grade to overcome variability in the plant feed, where conventional sampling and laboratory analysis is difficult, error prone and time consuming. In addition to enjoying these benefits since the Geoscan’s installation, in recent times the process engineers have expanded the use of the Geoscan by observing elemental results other than copper grade to control different aspects of the operation, focussing on the reduction of Gangue Acid Consumption. This paper discusses the process of expanding the Geoscan use at the operation, including an explanation of the calibration process. Additionally, a brief description of the Geoscan and its use at MMG LXML Sepon Copper Operation is provided, as well as a summary of recent calibration and analysis results. A discussion of future works concludes the paper.

Jan 1, 2016

By G. W. Neumann, J. R. Schnarr

The lead-zinc-copper-silver ores mined by Brunswick Mining and Smelting Corporation Limited at their No. 12 underground mine and No. 6 open-pit operation, and treated by distinct concentration processes in separate plants, present difficult metallurgical problems because of the extremely fine dissemination of the valuable minerals with pyrite and pyrrhotite. The problem of concentration is further complicated, in the No. 12 ore, by the presence of a varying content of graphitic carbon. This paper describes the milling of No. 12 ore and the production of copper, lead and zinc concentrates by differential flotation.

Jan 1, 1971

By Masahiro Eguchi, Giuseppe Granata, Chiharu Tokoro, Hiroki Fukuda, Yuichiro Toba, Shungo Hobo

"Currently, large amounts of wastewater containing boron are discharged from industries like coal-fired power plants. Although coagulation-sedimentation is widely employed for their treatment, only a little consideration has been given to its mechanism. An additional problem is that the produced sludge has poor solid-liquid separation. This study is focusing on coagulation-sedimentation using magnesium, examining the mechanism and improving the solid-liquid separation. First, the co-precipitation with magnesium hydroxide was conducted against high-concentration boron wastewater with 500 mg/dm3as B. Second, in order to improve the solid-liquid separation by maintaining high reactivity, low-crystalline magnesium oxide was synthesized from magnesium carbonate by calcination at 400–700°C. It was tested as an adsorbent of boron and compared to co-precipitation with magnesium hydroxide. Co-precipitation showed high removal capacity. X-ray diffraction (XRD) of the sludge revealed the presence of other compounds besides magnesium hydroxide. This result suggests that other processes play a role other than simple adsorption on to magnesium hydroxide, and provides a plausible explanation for the observed high separability. As for the adsorption, the synthesized magnesium oxide immobilized as much or more amount of boron than co-precipitation. Furthermore, the results of fourier transform infrared spectroscopy (FT-IR) suggested the residual magnesium carbonate improved solid-liquid separability due to its poor solubility.INTRODUCTIONBoron is used in various industrial applications. In glass industry, the addition of a little amount of boron into glass products can enhance heat-resistance and chemical-resistance. Semi-conductor industry also employs boron as dopant for silicon. From these industries, large amounts of wastewater containing boron have been discharged. Additionally, coal-fired power plants have been recently discharging highly concentrated boron wastewater because the amount of boron contained in coal has been increasing due to a gradual decrease of the quality of coal. Since boron is partially proved to be toxic for animals, plants, and human beings (WHO, 1998),the guideline of the World Health Organization limit the boron concentration in drinking water to 2.4 mg/dm3(WHO, 2009).Because boron does not precipitate from solutions by simply changing the pH, the removal could be carried by operations such as adsorption or ion exchange. However, since ion exchange is an expensive operation with relatively low capacity, it is not suitable to treat the large amounts of wastewater produced by heavy industries like the coal-fired power plants. Therefore, coagulation-sedimentation method is still widely used as a suitable alternative way."

Jan 1, 2017

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

By Paul L. Broughton

"IntroductionThe coal deposits, all of lignite rank, of economic interest in Saskatchewan are associated with the Ravenscrag Formation (Paleocene). Several Cretaceous formations have less significant lignite accumulations (Broughton, Irvine and W'hitaker, 1974). The Swan River Group (lower Cretaceous) and Judith River Formation (upper Cretaceous) have the only coalbearing strata in the shallow subsurface of central Saskatchewan. The Swan River Group coalfield is relatively small and underlies only 15 sq km of the surface approximately 40 km south of La Ronge, Saskatchewan. An estimated 36 billion short tons are within 45 m of the surface. No reserve estimates are known to have been calculated for the coal-bearing Judith River Formation exposed at the surface in the vicinity of the South Saskatchewan River valley in west-central Saskatchewan. Although no coalfields have been delineated, lignite beds up to 1.8 m thick have been intersected in test holes. The coal-bearing upper Cretaceous and lower Tertiary strata of the northern Williston Basin extends the full width of southern Saskatchewan for 650 km, and from the United States border 120 km north to 50° latitude (Fig. 1). Only the coalfields of the Ravenscrag Formation, because of their economic interest, will be considered further. There are four major coalfields. They are, from east to west: Estevan, Willow Bunch, Wood Mountain and Shaunavon (Cypress) coalfields. Cumulative lignite seam thickness for each basin is 10 -15 m (Figs. 2 and 3). The origin of each coal basin, resource calculations, seam stratigraphy, and mining activity are discussed. Regional Setting The Williston Basin is an ellipsoidal depression in the Precambrian basement, centered in western North Dakota and marginal to the exposed craton of northern Saskatchewan and central Manitoba (Fig. 1). The sediments of the basin range from Cambrian to Pleistocene in age and have a maximum known thickness of 4614 min western North Dakota. A maximum of 3200 m is recorded in southern Saskatchewan. Most structural deformation is late Cretaceous to early Tertiary (Paleocene) in age, coinciding with the Laramide Orogeny. The pre-Laramide Williston Basin, with a depocenter near Williston, North Dakota, began developing during the middle Ordovician, or possibly earlier."

Jan 1, 1985

By A. Warczok, T. A. Utigard

"Slags from smelting of copper concentrates contains from 1 to 15% of copper. Copper is present in the form of copper or copper matte inclusions of size from 2 to 1000 micro, and as dissolved cuprous oxide. Removal of the copper requires the slag reduction, primarily reduction of magnetite and co-reduction of cuprous oxide. Thus, the kinetics of the slag reduction play an important role in copper recovery. Instantaneously, at the contact of carbon and a slag the gaseous film is formed. The magnetite and cuprous oxide reduction is going through a gaseous film, separating the slag and carbon of a coke or electrodes. The thickness of a gaseous film grows to a critical value and gas bubbles, containing CO and CO2, are created and rise up in the slag. Results of measurements of kinetic of the slag reduction with graphite showed high value of activation energy, close to the value of activation energy of Boudouard reaction. Strong temperature dependence of the reaction rate points out the thermal instability of the reacting system. It was found that the slowest process in the reduction stages determines the loop of CO and CO2 transfer and magnetite diffusion to the slag/gas film boundary. Strongly endothermic Boudouard reaction seems to cause thermal instability on the reaction surface. So, heat transfer to the reaction surface is very important. Due to low thermal conductivity of a slag the convection dominates in the heat transfer. So, any slag stirring accelerates the rate of reduction and coalescence of metallic copper or copper matte inclusions."

Jan 1, 2015

By C. Pichler, C. Benigni, J. Antrekowitsch

"The recycling of steel mill dust results in zinc oxides which are sold to the primary industry in or-der to recover zinc in its metallic form. Due to the contained impurities - chlorine and fluorine - these sec-ondary oxides are usually charged into the roaster together with primary concentrates. Appearing problems in this furnace limit the application of secondary materials. Based on the zinc amount, a direct leaching, assumed that a low halide concentration is present, would be possible. To use the zinc solution directly in the electrowinning stage, the concentration of impurities, first of all iron, is limited. Iron can be found in secondary zinc oxides due to carry over during the recycling process. In order to reduce the iron content in the solution, the leaching has to be pH-controlled. This leads to a limited number of simple purification steps before the solution enters the electrolysis. Various trials were performed to evaluate the influence of temperature, time and sulphuric acid concentration on the iron dissolution. This paper deals with the results and also focuses on other impurities such as halides. Additionally, the soda washing process, usually done with secondary zinc oxides to remove most of the halides, and the challenges within this step are discussed.INTRODUCTION Recycling of steel mill dust, which is the main zinc containing residue, in the Waelz process dis-plays the common method worldwide. The product of the process is a secondary zinc oxide which is con-taminated with different elements like lead, iron and halides due to mechanical carry over or evaporation. Depending on the feeding material the concentration of each element in the dust is varying. The zinc con-tent of the product, also called Waelz oxide, lies around 65–68%. Based on these values it presents an al-ternative to the primary concentrate for the production of metallic zinc. The contained halides limit the direct utilization in the leaching stage and therefore have to be reduced. State of the art is a soda washing process but also solvent extraction gives a possibility to remove chlorine and fluorine but the desired con-centration for the electrolysis is hardly reachable (Antrekowitsch et al., 2016) Iron is present as an undesirable component of such secondary zinc oxides due to carry over. During the hot acidic leaching of the secondary concentrate, iron is dissolved too. Based on the higher electrical potential iron has to be removed before the zinc solution enters the electrowinning stage. It is usually removed by precipitation as goethite, hematite or jarosite, which is the common precipitation residue (Ismael et al., 2003)."

Jan 1, 2017

By A. Hussain

PAPER NOT SUBMITTED FOR PUBLICATION

Jan 1, 1987

By Kri Inwood

"IntroductionIn 1879, when the Dominion government initiated its controversial program of industrial promotion, iron smelting in Canada was limited to one company producing coke iron on the mainland of Nov a Scotia and three small charcoal blast furnaces in Quebec. There was no steel production. By the eve of the first great war, iron and steel were being produced in very large quantities, the companies active in 1879 had disappeared and new centres of integrated iron and rolled steel production at Hamilton, Sydney and Sault Ste. Marie had come to resemble the industry as we know it today.The most dramatic change was that at Sydney, Nova Scotia, where in the early 1900s, two steelmaking companies established works. The Sydney developments have been explained as the result of resource discovery and technical change. W.J. Donald, in his authoritative account of the Canadian iron and steel industry, observes:""The most rapid growth of the Canadian iron and steel industry has occured since 1897... The remarkable growth has been caused largely by the new conditions of the industry. The discovery and use of Newfoundland ores, together with the availability of Cape Breton coal, has made the Nova Scotia industry not only possible but profitable ... It is a safe conclusion that the Canadian industry would not have been an important one, had it not been for the discovery of the Michipicoten and especially the Wabana (Newfoundland) ores""Donald also argues that metallurgical progress had been necessary to render the ores valuable,""Newfoundland ores ... contain a considerable amount of phosphorus, and were made available for steel-making by recent inventions.""The purpose of this paper is to re-examine Donald's story. It will be argued that the origin of steel -making at Sydney is somewhat more complicated than Donald has indicated. The difficulty with Newfoundland ore extended beyond its phosphorus content and a resolution required more than the basic open hearth furnace identified by Donald. Moreover metallurgical change was only one of several developments necessary to induce industrial investment at Sydney. Surprisingly, however, the discovery of iron ore in the late nineteenth century does not appear to be part of the explanation."

Jan 1, 1983

By J. J. Baz-Dresch

"The Cannon Mine, a joint venture between Asamera Minerals (the operator) and Breakwater Resources, is located in the centre of Washington state at the eastern base of the Cascade Mountains. The mine complex is located three blocks south of the city limits of Wenatchee, part of an urban area with a total population of 47 000. The closest residence is 350 feet from the mine portal.The B-Neath zone is a narrow, high-grade, downward extension of the southern tail of the mine's main ore body, the B-North zone. It also underlies the northernmost portion of the B-West zone (Fig . I) . The ore is usually reasonably competent but completely surrounded by very weak rock consisting of shear zone and unsilicified sandstones and siltstones.The zone has maximum dimensions of 420 ft in thickness, 500 ft in length , and 200 ft in width . The economic reserves extend from the 70-ft elevation (elevation above sea level) to the 630-ft elevation and consist of about 1.3 million tons of geologic reserves (proven and probable) at an average grade of 0.33 ounces per ton.Acquisition and ExplorationInitial DiscoveryThe initial discovery of the B-Neath zone was made by Tenneco Minerals during July through September, 1984. Their 22-hole surface drilling program consisted of 18 200 ft of drilling. Tenneco Minerals had acquired the 91/2 acre lease from United Mining Corporation.Asamera Minerals subsequently purchased Tenneco's lease in July, 1985; Tenneco retained a royalty position which was later purchased by Echo Bay Mining.Follow-up drilling by Asamera Minerals consisted of both surface and underground drilling. Eight surface holes (7200 ft) were drilled commencing in December, 1985. Following evaluation of the geologic data, an access drift was driven on strike along the top of the ore zone on the 500 level. Diamond drilling from this platform consisted of 17 200 ft in 79 holes."

Jan 1, 1990

By Karl J. C. Harries

"2.1. INTRODUCTIONNo agreement can be perfect in the sense that it contemplates and provides for all eventualities. Mineral acquisition agreements are usually negotiated and drafted at a time when an orebody is no more than a gleam in a geologist’s eye, so it is hardly possible to provide for development and operation in other than the most general terms. However, an agreement that stops short of contemplating the possibility of an orebody and production is ill-advised. Accordingly, it is important to provide procedures to make decisions that will let the project proceed, even in the face of a fallingout between parties. Whether the parties are shareholders in a corporation or venturers in a contractual common undertaking like a joint venture, differences of opinion and disputes will occur. Unfortunately, more and more are ending up before the courts. Besides greed and the growing tendency in society to fight rather than talk, there are other factors that contribute to the increase of litigation. In some jurisdictions, agreements have tended to become complicated, often defying interpretation, even by a lawyer, and explorationists want their budgets to go into the ground as constructive work rather than into a lawyer’s pocket. All this has led to a growing tendency for corporations to take the attitude that the chances of finding a mine are, at best, marginal and there are lots of earlier agreements in the files to draw from, so why not prepare their own agreements? As discussed in the preceding chapter, this can be folly. All these factors can quickly have parties facing each other in court while a project sits idle. Added to this is the problem that, in some jurisdictions, lawyers may take cases on a contingency-fee basis, sometimes promoting the pursuit of a nebulous claim.When an orebody is discovered, someone will always want some, or more, for himself. There is a breed of “prospectors” who prospect for legal actions, on the somewhat sound grounds that a major corporation will buy off nuisance litigation, rather than incurring the cost and effort of attacking even a poorly founded claim in the courts. They may even find a winner. Besides, it is far more comfortable and relaxing to prospect for problems and legal niceties than to prospect for an orebody.1 In short, it is appropriate to consider briefly some of the factors relating to lawsuits and judgments. Although many of the comments are made in the context of the common law and the Canadian legal system, most of the concepts and suggestions are applicable to any legal system."

Jan 1, 2003

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By A. O. Sfriso

"Numerical modelling is becoming universal in rock engineering practice. Most applications focus on the prediction of failure loads of 2D problems, where the numerical models are useful extensions to analytical methods and experience-based design criteria. For 3D problems and problems where the assessment of serviceability indicators – displacements, ground-structure response, etc. – are of importance, the selection of the constitutive models themselves and the implications of the selection of material parameters may have a very heavy impact on the reliability of the model outcome and its predictive capability.This paper overviews basic common aspects of constitutive equations used in practical rock engineering and summarizes some challenges that are frequently observed when reviewing numerical models performed for routine problems in rock engineering. INTRODUCTIONNumerical methodsFrom a philosophical perspective models, either analytical or numerical, are idealizations of a perceived reality. For us engineers, models are just tools we use to guide our judgement and understanding of the problem in hand. When dealing with problems in rock engineering, we resort to a wide range of techniques:1. Closed form solutions like confinement-convergence methods for circular tunnels: these methods satisfy equilibrium and compatibility requirements at the cost of a crude simplification of the material behavior and geometry;2. Limit analysis methods, like bearing capacity formulas: lower bound methods satisfy equilibrium but sacrifice compatibility, and upper bound methods do the opposite. Material behavior must be simple, geometry admits limited freedom;3. Limit equilibrium methods, like method of slices for slope stability: they satisfy restricted forms of equilibrium, do not satisfy compatibility requirements, require simple material behavior but have a much greater flexibility on geometry;4. Numerical methods, where a mesh is employed to discretize the problem geometry: when properly formulated, these methods satisfy equilibrium and compatibility requirements and give reasonable approximations to the behavior of very complex geometries and construction sequences. Very little restrictions remain on geometry and material behavior, but the cost of calibrating the material parameters can be very high."

Jan 1, 2015

By T. Y. Chong, J. A. Folinsbee

Since milling began in 1909, the PJV Dome mill has been expanded several times, to the current throughput of 11,500 tonnes per day. PJV recovers free gold using crushing and grinding followed by gravity concentration. The remaining gold in the gravity tails is recovered by cyanide leaching followed by Carbon-In -Pulp processing. Prior to 1993, cyanide tailings were impounded in the tailings pond where cyanide was allowed to degrade naturally. Effluent was discharged seasonally during the summer and early autumn to maintain the water balance. In 1993, an Effluent Treatment Plant (ETP) was designed and constructed for the purpose of removing dissolved metals and suspended solids. In 1997, an INCO SO2/Air cyanide destruction process was added to the ETP. Even though the ETP was successful in meeting the cyanide, metals and total suspended solids (TSS) discharge limits, often the treated effluent failed to pass toxicity tests. Following successful laboratory and plant scale testing, the addition of the chelant EDTA (ethylene diamine-tetra-acetic-acid) was commenced in the 1999 operating season. To date, discharged effluent has passed all toxicity tests. This paper describes the evolution of the ETP from its early conception to the various phases of upgrade needed to meet the MISA discharge limits.

Jan 1, 2005