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By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013

By A. Takala, H. Cline, D. Girard

"This article describes the project development and successful implementation of a particle sorter at the Kensington mine. The Kensington underground gold mine and associated milling facilities are located within the Berners Bay Mining District on the east side of Lynn Canal about 45 miles north-northwest of Juneau, Alaska. The paper describes the project from concept, through the development phase, including test work confirming feasibility, to a discussion of operational data and includes shared experiences from operation and maintenance. The project has proven successful in recovering gold that was previously lost to the waste dump and has already resulted in a positive return on investment. The payback was achieved in less than one year.INTRODUCTION The first paragraphs of this paper describe Coeur Mining and the Kensington Mine, its history, geology, mining operation and mill. The second part of this paper gives a quick introduction to sensor-based sorting in general and X-ray transmission sorting (XRT) in particular. This article does not cover costs or economic impacts apart from the pay-back period for the investment at Kensington. Interested readers find more in information on this in the literature (Kleine & Wotruba, 2010; Robben, 2013). Since the publication about XRT sorting at TGME in Pilgrim’s Rest (Kleine, Riedel, Ketelhodt, & Murray, 2010), this is the first time that a comprehensive data set on gold ore sorting using XRT is published. Following chapters highlight the aim of the project for Coeur Kensington, project development through testing and operation before concluding. ABOUT COEUR MINING’S KENSINGTON OPERATION Coeur Mining is the largest U.S.-based silver producer and a significant gold producer with five precious metals mines in the Americas employing approximately 2,100 people. Coeur produces from its wholly owned operations: the Palmarejo silver-gold mine in Mexico, the San Bartolomé silver mine in Bolivia, the Rochester silver-gold mine in Nevada, the Kensington gold mine in Alaska, and the Wharf gold mine in South Dakota. The Company also has a non-operating interest in the Endeavor mine in Australia in addition to royalties on the Cerro Bayo mine in Chile, the El Gallo complex in Mexico, the Zaruma mine in Ecuador, and the Correnso mine in New Zealand. In addition, the Company has two silver-gold feasibility stage projects—the La Preciosa project in Mexico and the Joaquin project in Argentina. The Company also conducts ongoing exploration activities in Alaska, Argentina, Bolivia, Mexico, and Nevada. The Company owns strategic investment positions in several silver and gold development companies with projects in North and South America."

Jan 1, 2017

By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right 'strength' is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By E. Adam, B. Milkereit, M. Salisbury, L. E. Reed, G. Perron

Integrating seismic reflection, borehole geophysical, and physical rock property studies is an effective means of mapping lithological contacts and structures in the crystalline crust. At Les Mines Selbaie in the northern volcanic zone of the Late Archean Abitibi Subprovince, a high-frequency seismic reflection profile has provided the first images of deep crustal structures of this important polymetallic mine site. Physical rock property and borehole geophysical studies confirm that prominent seismic reflections can be caused by lithological contacts, faults and sulphide mineralization. At Les Mines Selbaie, the first two of these are shown by this study. Clearly identifiable reflection images from sulphide mineralization have not been demonstrated in analysis of the profile. The seismic images provide useful information about gross structure in the vicinity of Les Mines Selbaie. They can also place important constraints on the sequence of tectonic events and, therefore, can aid future deep exploration programs.

Jan 1, 1997

By Tugba Cebeci, Bahjat Khoshaba, Bern Klein, Libin Tong, Andrew Bamber

"Sensor-based sorting technologies have potential to pre-concentrate low grade subeconomic ores through discarding the barren waste particles. However, the inability of sensors to accurately discriminate ore from waste is a barrier to prevent their wide applications. The present study focuses on the development of more intelligent sensing systems by using correlation and regression analysis of X-ray fluorescence (XRF) sensor responses on the copper ore samples obtained from Chile. The responses obtained through XRF scanning were reported both in the form of counts and the grades of elements. Linear and multiple linear correlation analyses were made between the XRF counts and the copper grades obtained through chemical analysis. Both the heterogeneity of the ore particles and the matrix effect in the XRF measurement are discussed in the study.INTRODUCTIONSorting can not only discard waste rocks away from the concentrator but also recover metal bearing ore particles that would be lost to the waste dump. The benefits of ore sorting include reduced energy consumption, water and reagent usage in the downstream operations (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). X-ray fluorescence belongs to sensor-based sorting technologies and Xrays are a high energy-high frequency form of electromagnetic radiation inhabiting the region between the ultraviolet radiation and gamma rays (Shackley, 2011). Recent XRF sorting studies on low grade copper ores were carried out at MineSense Technologies Ltd. aimed at increasing the capacity related to improving the understanding of ore heterogeneity as the basis for developing semi-bulk or bulk sorting systems (MineSense Technologies Ltd., 2016)."

Jan 1, 2016

By P. Kordi, L. Egorova, R. J. Bowell, D. Gurevich, V. Sedov, A. Mikhailov, D. A. Holwell

ABSTRACT Reconnaissance exploration in the Kuene region Namibia has included geological mapping, soil and stream sediment geochemistry, and ground geophysical methods. Copper mineralization occurs within a well-defined belt with north-northwest to south-southeast trend, parallel to the regional strike of the sedimentary rocks. The occurrences vary in size but are generally stratabound. The mineralization is centred on the transition from calcareous shale and interbedded limestone, through carbonate rocks, to quartzite. Geochemical anomalies have been identified correlating to induced polarization (IP) and magnetic anomalies. The anomalies identify one potential metallogenic zone more than 17 km in strike length.

Jan 1, 2012

By J. Armitage, J. Erskine

Feed level and thickness measurements are essential in the optimization of an electric arc furnace. A precise measurement of the feed thickness and level gives operators the ability to increase the smelter efficiency and reduce the maintenance cost. Hatch has developed a radar system which is an affordable, low maintenance, and accurate level measurement system. The radar units can be installed across the furnace to measure the feed level and the feed thickness can be calculated with one slag level sounding. The present paper describes the development of radar systems as a process optimizing tool by furnace controls. The authors will discuss the challenges involved in installing eight radar units on the roof of a six-in-line electric furnace.

Jan 1, 2015

By C. Hunt, J. Vivas, D. M. Allen

"In this paper we present the results of a combined remote sensing - numerical modelling study to improve our understanding of groundwater seepage in open pit and natural rock slopes, and to investigate the interaction between groundwater, in-situ stress conditions and brittle fracture. The location of seepage is a key element in the characterisation of rock slope stability in open pits and natural slopes; definition of the fracture network geometry and its inter-relationship with seepage, however, remains a challenge in engineering practice. Current techniques used to characterize groundwater seepage locations require direct access to the rock slope for a detailed and exhaustive investigation, and can be severely limited due to access and the limited coverage of the survey methods both with respect to the height and length of the sampled rock slope. Herein, we describe remote sensing methods, which allow the collection of structural and seepage information over a wide spatial area. Remote sensing techniques are shown to have the potential to provide additional insights into the orientation and general connectivity of fractures that may play a major role in the general stability of a rock slope. A preliminary methodology for the use of remote sensing in the characterization of seepage zones in a natural slope through the application of ground-based LiDAR and Infrared Thermography (IRT) is presented.One of the most challenging problems in rock slope engineering is the realistic simulation of fluid flow through fractured and deforming rock slopes. Deformation and the development of brittle fractures can cause significant local changes in the permeability and strength of the rock mass, potentially affecting rock slope performance. Understanding fluid flow through fractured and deforming rock slopes, especially in highly-stressed environments is of great importance for slope stability analysis. Changes in the interconnectivity of fractures during slope failure are an important, yet are relatively unstudied in rock slope engineering. We present the results of hydromechanical UDEC-Trigon rock slope models focussing on the potential role of brittle fracture in rock slope failure, its interaction with groundwater pressures, and the influence of the assumed in-situ stress ratio. Damage intensity parameters are used to characterize damage within different regions of a biplanar slope failure."

Jan 1, 2015

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By W. H. Moore

It seems necessary, at times, that we should reconsider some of the more obscure causes that lead to explosions of gas and coal-dust in mines, in the hope that a recapitulation will keep before us that old and true saying "eternal vigilance is the price of safety". This explosion, while not extensive (resulting in only two much to be regretted deaths) enlarged our vision as to the possibility and probability of other explosions with more disastrous results. As this is only a partial report I shall have to omit many things that are generally included in describing a mine explosion. The mine was worked exclusively with electric cap-lamps -only firebosses and other officials carried safety-lamps. All shots were examined and fired by firebosses with a small hand-battery. Monobel was used exclusively for blasting, and clay for tamping. The system of haulage iri use was main-rope and winches, horses being employed for gathering. Compressed-air was the motive power for all winches and pumps, excepting the pumps at the shaft-bottom which were steam-driven. The mine was wet with practically no dust anywhere, except what was being made at the coal-face in the getting of the coal. Gas was found occasionally, generally in the brushing, especially where the brushing was carried up to a small seam, 2 to 6 feet above the main seam. The place where the explosion took place was known as Leigh's heading, which was being driven to the rise, immediately inbye of the siding (off No. 1 left, off the new slope) and was about 90 feet up from the level.

Jan 1, 1926

By A. Musschoot

"The paper will review general types and designs of vibratory feeders, describing briefly the design features and characteristics that apply to the application of specific types. Control considerations for selecting types will be dis• cussed, such as fixed or adjustable, manual or automatic, individual or multiple bank, and process requirements. Design parameters for hopper openings and installation geometry will be discussed, including consideration of material size distribution, segregation, moisture content and other characteristics, based on practical applications and experience as well as theory. Pan designs and the selection of pan materials will also be discussed with reference to wear, corrosion, impact and practical economic factors."

Jan 1, 1972

By T. Kerr, C. Mattich, J. Wilson

"In refractory gold concentrates, gold is occluded in sulphide minerals preventing efficient cyanide leaching. Hence, roasting is used to oxidize sulphur and organic carbon, the latter being necessary to minimize recovery loss through the preg-robbing effect. In 2009, Outotec commissioned the circulating fluidized bed roaster at Syama gold mine in Mali. Since 2013 Resolute and Outotec have been implementing improvements to the roaster performance with the capacity increasing from 8000 t/month in 2013 to above 13,000 t/month in 2016, while achieving a residual sulphide sulphur and organic carbon contents of below 0.1 wt.% and 0.4 wt.%, respectively. Thus a gold recovery in the CIL of above 90% is attained. In 2016, Outotec audited the Syama roaster. The analysis resulted in the Low Carbon Roaster (LCR) upgrade concept which (i) allows re-processing of calcine dust from the spray cooler and ESP after pelletization and (ii) allows the roasting of a further fine-organic carbon rich feed, i.e. de-slime circuit tailings. The LCR upgrade aims to reduce organic carbon to <0.2 wt.% and increase roaster-leaching gold recovery by >3%. Project development included extensive testwork. The LCR process is expected to become operational during FY 2019.INTRODUCTION Double refractory sulphide ores exhibit the characteristics of gold locked within pyrite grains, in the presence of preg-robbing natural (organic) carbon. Hence, to achieve high recovery during subsequent processing steps, i.e. cyanide leaching, oxidation of sulphide sulphur is required, producing a porous calcine by way of a roasting step. This allows for the gold contained within the pyrite grains to be accessible during cyanide leaching. Furthermore, it is necessary to oxidize the organic carbon. Oxidizing the organic carbon is essential as gold recovery loss occurs as a result of gold-cyanide complexes being adsorbed on organic carbon, this phenomenon is termed as preg-robbing (Miller et al., 2016). The gold absorbed on the organic carbon is lost, reporting to the tailings stream. Hence, the aforementioned oxidation of sulphide sulphur and organic carbon is the process goal. Nonetheless, the latter must occur at a controlled temperature which is concentrate/ ore specific, since the pores of the produced calcine should not sinter, as this makes the gold contained in the calcine less accessible during leaching, leading to gold recovery loss. The tight temperature control requirement is a decisive factor in the choice of a Circulating Fluidized Bed (CFB) as the roasting reactor, due to the excellent mixing characteristics of the CFB which results in temperature homogeneity of (+/-10°C). Roasting of double refractory ores, as described above, can be included in the flowsheet after comminution and grinding, a process termed as whole ore roasting, or by including a flotation circuit termed as concentrate roasting. Roasting the flotation concentrate results in less solid flow, increased sulphide sulphur grade and organic carbon content resulting in a higher heating value and higher gold content. A typical composition of the Syama ore and concentrate is given in Table 1. Ore average values presented correspond to the period 2015, while concentrate values are typical for the flotation performance throughout the period 2012–2015."

Jan 1, 2017

By M. F. Ameur, M. Habak, H. Aouici, M. Kenane

Present study interest by aluminium alloy (Al 7175-T5173) drilled without cooling fluid. The influence of the machining parameters (spindle speed and feed rate) on the holes quality was analyzed. Drilling tools are made of carbide (WC); high speed steel (HSS) and TiN coated carbide (WC-Ti).The Experiment design was reinforced by the application of statistical analysis of variance (ANOVA).The results show that the thrust force is influenced principally by the spindle speed and feed rate. Though, both feed rate and tool materials have statistical significance on the surface roughness. In addition, the objective of correlations between spindle speed and feed rate with the evolution of the machining parameters was established. These correlations were obtained by quadratic regression using the response surface methodology. Finally, useful to select optimum values of drilling parameters, that would minimize thrust force, torque, cutting temperature and surface roughness.

Jan 1, 2015

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

"Energy efficiency in mining and minerals processing has attracted considerable public and industry attention because of the significant quantities of energy consumption involved. In this context the question of what are worthwhile targets for energy efficiency improvements ought to be of the highest priority. It is however worth taking a step back to avoid falling in the trap of taking preconceived ideas that have been reiterated repeatedly before as gospel. The aim of this paper is to highlight areas where new or alternative approaches could potentially be the better way forward. Some may come as a surprise to conventional industry thinking. Ultimately any such solutions are attractive to practitioners not just in an environmental but also in an economic sense, and hence should be targeted through applied research and development efforts. This paper highlights key aspects of each group of opportunities and some of the individual approaches to provide an overview of the current status quo.MINING INDUSTRY POWER UTILISATION – WHERE IS THE BIGGEST BANG FOR THE BUCK?The question of where is the biggest bang for the buck when trying to determine worthwhile targets for energy efficiency improvements has not always been reported on broadly enough, typically because industry practitioners operate in specific areas of expertise and comfort zone. Looking beyond the familiar doesn’t always come easy. Any technology or methodology consideration to address energy efficiency needs to take into account the context of alternative opportunities of superior value or risks not achieving desired uptake. The following sub-chapters have been ordered by magnitude of improvement potential as best as is possible, starting with the biggest first, and the smallest last. Some may be a surprise relative to conventional mining industry thinking."

Jan 1, 2016

By V. S. Sastri, Elboujdaini. M.

"Economics of wear in mining industry and methods by which wear cost may be reduced will be discussed.IntroductionCanada loses more than $5 billion annually due to friction and wear (Table 1). It is estimated that about $1.3 billion, or about 25% of the losses, could be saved through better application of existing technology (Table 2). It should be noted that the costs given in Table 1 and 2 refer to 1986. The losses due to friction and wear and the savings would be much higher in 1996. Tribology combines the many branches and specialties in science and technology concerned with understanding and combatting friction and wear. Specifically, tribology is concerned with the design and manufacture of sliding and rolling bearings, piston rings, gears, cutting tools and other devices in which surfaces interact, in sliding or other relative motion. Tribology is concerned with the correct use of materials for interacting solid surfaces, with the interaction of the surfaces with the lubricants, with the chemistry, physics and use of lubricants. It is concerned with the reduction of friction and wear and the avoidance of associated failures in machinery. Similar tribological components such as bearings are used in different technologies and similar tribological problems such as abrasive wear occur in different industries. Thus, tribology is in itself a generic science and technology, concerned with the generation and dissemination of knowledge on friction, wear and lubrication, and the application of the knowledge, to a wide range of industrial products and equipment, from ploughs to space equipment, from prosthesis to engines, from washing machines to railways, from computers to power stations, from paper mills to mines. Avoidable losses due to friction and"

Jan 1, 1997

By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By Eddy Dénommé, Deni Villeneuve

"Niobec mine, a producer of pyrochlore concentrates since 1976, became a producer of ferroniobium in 1994 and achieved accreditation to the ISO 9002 standard in 1995. The goal of ISO 9002 is to ensure that the products supplied to clients regularly meet their specifications, through explicit work standards and procedures throughout the production process, from deposit appraisal to ferroniobium production.A key element of ISO 9002 implementation at Niobec consists of the quality control procedures applied to the raw materials: the ore fed to the mill and the pyrochlore concentrate fed to the reduction plant. These controls extend from exploration, deposit appraisal, mine planning and reserves estimation, mining, mineral processing and, finally, ferroniobium production. The implementation of ISO 9002 has allowed more efficient control of the quality of the final product sold to clients. It requires interactive team work, the role of the geologist being to relate all information pertaining to raw material and product quality to the geological framework of the deposits."

Jan 1, 1997

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012