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By Vilela A. C F

In the present work, the process of dephosphorisation of stainless steel was developed in laboratory scale by adopting a high frequence induction furnace, using BaCO3 base flux. By using BaCO3 - CaO - BaC12 - Fe2O3 Flux of about 110 g/Kg-metal, 30 per cent dephosphorisation degree was obtained a stainless steel containing 18,8 per cent Cr and carbon between 0,08 and 2,0 per cent. In addition, a dessulfurisation degree of 89 per cent was achieved too.

Jan 1, 1991

By McPherson M. J

An experimental investigation was carried out to determine the various gas flow characteristics of bituminous coal samples. Adsorption and desorption tests were first conducted to estimate the quantity of methane that is retained by coal, and the rate at which it is released. Experiments were then carried out to study the variation in coal permeability with changes in applied stress and gas pressure - factors that change continuously with time. To further understand the phenomena involved in retention, release, and flow of gas, electron microscopy was used to study the microstructure of coal and how it affects these characteristics of coal.

Jan 1, 1988

Jan 1, 2004

By Graham J

The successful processing of arsenopyritic ores is difficult and will be facilitated by a better understanding of the mineralogy of gold within arsenopyrite and the type of arsenopyrite in which gold is taken up. Solid solution gold in arsenopyrite is now well documented, and is a significant cause of refractory behaviour in gold processing. Investigations of the crystal structure and stoichiometry of arsenopyrite by X-ray diffraction, electron microprobe analysis and convergent beam electron microscopy have been carried out in order to understand how the gold is incorporated into the structure. Variations in stoichiometry, particularly the As:S ratio, of arsenopyrite leads to variations in structural parameters. These variations result in slight changes in thermal behaviour. The distribution of invisible gold in an arsenopyrite grain is generally non-uniform and synthesised samples contain up to 2 wt per cent gold. A transmission electron microscopy (TEM) technique called ALCHEMI is being used to identify the substitution site. The process of gold agglomeration together with evidence of an ordered breakdown of arsenopyrite to pyrrhotite has been documented with the use of TEM. An arsenopyrite grain containing invisible gold was heated with an electron beam resulting in recrystallisation of arsenopyrite to pyrrhotite with arsenic being expelled. The gold is mostly insoluble in the pyrrhotite lattice and therefore exsolves out and combines with other gold atoms to form droplets at the boundary of the pyrrhotite.

Jan 1, 1992

By Jay W. H, Brown L. J

Several case studies are examined in which analysis of treated ores and extracted metal species by Mossbauer spectroscopy provides information not available by other competing techniques. The cases include poorly crystalline, surface iron oxides in titanium minerals and chalcopyrite, gold in ores and bacterially oxidised ores and the adsorbed species from gold extracted from cyanide and chloride solutions onto activated carbon and polyurethane foams. Some limitations on the use of the technique in terms of sample size, sensitivity and counting time are also discussed.

Jan 1, 1997

By Snowdowne J. B H

Rand Mines, Limited, located in Johannesburg, Republic of South Africa has recently completed feasibility studies which have lead to the initiation of two major coal strip mining ventures. A minicomputer based mine planning system was developed to perform the feasibility studies. The broad approach of this system is to utilise inter.-actively the specialist skills and interpretative abilities of mining engineers and geologists. This paper reports briefly on the outline of the system and at greater length upon certain aspects of its use.

Jan 1, 1977

By Kasaneva S

The San Cristobal gold district is located 110 km east of the port of Antofagasta, Chile. It contains the San Cristobal gold mine, where Niugini Mining Ltd. commenced a heap leach operation, with initial reserves of 10.1 million tonnes grading 1.34 g/t An, in December, 1990. The San Cristobal district occurs within an upper Cretaceous-lower Tertiary magmatic arc. The main mineralisation occurs within a northwest trending subvertical zone, 1km long and 70-100 m wide, which contains rhyolite porphyry and minor breccia, and is locally termed the "subvolcanic complex". At the San Cristobal mine, most gold mineralisation occurs in subvertical quartz-pyrite veins which were emplaced in dilational sections of an imbricate fault system. The bulk gold resource comprises four ore shoots which formed where the vein system intersects the subvolcanic complex. Gold-bearing quartz-pyrite veins also occur at separate prospects, the Three Sisters and Sol prospects, west and south of the San Cristobal mine. Hydrothermal alteration consists of potassic and propylitic assemblages related to intrusion of the subvolcanic complex. This alteration is overprinted by a phyllic stage which is associated with the emplacement of the quartz-pyrite veins. The oxide zone is 180 m thick, and contains native gold, electrum, limonite, and manganocarbonates. The underlying hypogene zone contains pyrite with minor chalcopyrite, sphalerite, galena, covellite, bornite, chalcocite, and arsenopyrite. Fluid inclusion studies indicate that the deposit formed at approximately 270¦ C, and the mean salinity of the fluid was 4% NaCl equivalent. These observations enable the San Cristobal deposit to be classed as a porphyry-related, mesothermal quartz-vein system of the low sulphidation type.

Jan 1, 1995

A biological column leach testwork program was undertaken on a chalcocite ore. Three tests were conducted in all, using 65 in x 100 mm columns in three sections. The tests were started with varying acid strengths and inoculated with bacterial solutions from previous column testwork. The leaching of Cu was found to occur in three stages. These stages consisted of direct acid leaching, bacterial oxidation and ferric iron leaching. These leaching stages can most easily he described through the examination of not only Cu dissolution but also Fe dissolution and its subsequent oxidation and precipitation. The p11 of the system was found to he critical in establishing and maintaining the bacterial leaching system. The oxidation potential was seen to he influenced by the leaching system as the oxidation states altered. Test variables such as, 02, COz, and temperature were all found to influence the system. Final copper recoveries were in excess of 90 per cent in each column test over a leach time ranging from 211 to 328 days. Given similar leach conditions are applied, the application of this technology to site is expected to give comparable results.

Jan 1, 1994

Longhole stope overbreak has always been a source of unwanted cost within the underground mining industry, and efforts to control it using various rock reinforcement systems have long been a rock engineering challenge. At the Pasminco Mining Broken Hill Operations trials have been carried out using an innovative cable bolt reinforcement system known as Rib-Roc. The system, based loosely on the Swedish Rib-in-Roc concept, utilises zones or ribs of heavily reinforced rock in the troublesome hangingwall and back areas of longhole stoping. The trials were carried out under a strict qualitative and quantitative scientific stope measurement program utilising rock mechanics instrumentation. Not only did the trial demonstrate the success of the system but data obtained was useful in implementing the system virtually as standard practice throughout the operation.

Jan 1, 1995

By Poplawski R. F

A 32-channel PSS seismic monitoring system was commissioned at Mt Charlotte mine in 1994, and at the time it was the first such system in Australian mines. The system continuously observes the occurrence of seismic events and locates them accurately in space and time. Mt Charlotte has a history of seismicity, with the largest event in recent years of Richter magnitude 4.3. The decision to 'go seismic' was made despite some uncertainty regarding its potential usefulness. However after the first year of operation, benefits have been realised in terms of less production downtime, improved mine safety and mine planning, and better understanding of the nature of Mt Charlotte seismicity. The seismic network has performed well, recording 550 events in its first year of operation to a location accuracy averaging ¦ 12 metres. System reliability is excellent, with very little downtime, and acceptable operation and maintenance times and costs. Observations show major distinct changes in the rate of mining induced seismicity over time periods of weeks and months. Events have tended to cluster in specific mine areas and on particular faults and structures. Case examples of pillar preconditioning, breakout around an orepass, and a major stope rockburst, illustrate the role of seismic data and the benefits it brings to safety, productivity and planning.

Jan 1, 1995

By Likar J, Janexic S, Zigman F

When driving mine roadways in the vicinity of tectonic disturbances and fault zones, sudden outbursts of gas, along with ejections of fine coal, occur. Substantial dynamic changes occur around the roadways in the coal and around the support. The problem has several aspects. Studies have been carried out on the technical analyses of the phenomena which occurred in the Velenje Lignite Mine from 1957 to 1988. The second part of the investigation involves systematic laboratory studies of strength and deformability characteristics of lignite samples and "in-situ" measurements of stress changes during the driving of some roadways. Analyses of events (using the model of limit convergence and the finite element method) showed the possibility of gas outbursts, taking into account the deformability conditions when crossing over from compact lignite to the disturbed region. The rate of advance of roadways and the method of support strongly influence the occurrence of the phenomenon. The preventative measures used in driving roadways under such conditions include trial drilling and the use of blasting instead of machine cutting.

Jan 1, 1992

By Taylor G. R

Fluid inclusions within quartz accompanying several stages of mineralization at Hillgrove are de cri bed. Pyrite-arsenopyrite-gold mineralization shows uncorrected filling temperatures of between 195°C and 250°C. Later stibnite-antimonide-siderite and stibnite-calcite mineralization has filling temperatures between 100°C and 195°C and a bimodal distribution of temperature peaking at 175°C and 145°C, possibly correlated with the two stages of mineral deposition. Secondary included fluids within an earlier generation of deformed quartz veins are derived from hydrothermal fluids contemporary with the main-stage mineralizing fluids described above. Primary inclusions within latestage, cross-cutting quartz-chlorite-calcite veins show these veins to be unrelated to the mineralization.A correlation between filling temperatures and salinities indicates that mineralization accompanied the mixing of a hot, partly saline, fluid (at 5 per cent equivalent NaCI) with cooler, less-saline meteoric or connate water. Over a vertical distance of 200 m, equivalent mineral assemblages were deposited over the same temperature range. Studies on single crystals suggest rapid deposition with fluid temperature dropping 45°C during their growth. Ore mineragraphy and the fluid inclusion data suggest that the metals were transported by sulphur-poor, relatively low-temperature, low-salinity solutions, possibly as carbonate complexe , and that a vertical zonation of the W-Sb-Au mineralization is compatible with the mixing of this hydrothermal fluid with cooler groundwater. Regional metallogenic and geological considerations suggest that ore metals are derived from the remobilization of deep-seated stratabound deposits or from metamorphic fluids expelled from deepseated volcanoclastic sediments.

Jan 1, 1984

The Circum-Pacific area is one of the most important gigantic skarn-metallogenic belts in the world. In more than 20 coastwise countries of this region, there exist thousands skarn deposits of different types. According to the differences of major metallic elements, the skarn deposits may be classified into seven subtypes, i.e. Fe, Cu, Pb-Zn, W, Sn, Mo and Au skarn deposits. In this paper, the distribution. and geological characteristics of above-mentioned types of skarn deposits are described briefly. Skarn deposits may also be classified on the basis of the dominant calc(magnesian)-silicate mineral assemblages into four types: magnesian, calcic, manganoan, and alkaline skarn types. Magnesian skarns may be associated with Fe, Cu, Au,, Sn, B, Be mineralization, calcic skarns with Fe, Cu, W, Mo, An, Be, Pb, Zn, Sn minerailization, while the alkaline skarns occur in U(Th, Nb) deposits. The skarn deposits of both East and West Pacific rims have many general characters, but have some diferences in geotectonic settings, intensities of mineralization, distribution, and metallogenic epoches. In this paper, the minerogenetic series and the mineralizing specialities of related magmatic rocks of the skarn deposits are also discussed.

Jan 1, 1990

The Engineering Chemistry Division of the Government Chemical Laboratories of WA initiated an ongoing investigation into the possible utilisation of diatomites of this State. The work has shown that local diatomites can be beneficiated by hydro or pneumatic cyc- lone separator circuitry and that the better quality head materials can be upgraded by straight and flux calcination and associated processing to the equivalent of premium grade imported products. Western Australian diatomites vary con- siderably in quality, and the degree to which they can be upgraded and the yield of useful product are influenced by the proportion of impurities and the size, type, and degree of fragmentation of contained diatoms. Conseq- uently careful assessment of ore deposits will be necessary in order to relate ore reserves to planned production. The viability of commercial production from Western Australian resources would hinge on the establishment of markets - largely ex- port - capable of supporting a production level of the order of 30,000 tonnes per annum.

Jan 1, 1979

By Player R. L

Measurements of the rate of PbO reduction from high lead metallurgical slags were made under laboratory conditions using graphite, a CO-50%CO2 gas mixture and metallic iron as reductants. The results show a transition in rate-controlling step at low PbO contents (i.e. 6 wt.% PbO). At medium to high PbO contents in the slag, the reduction rate was found to be strongly affected by the slag chemistry, temperature and reductant type. The effect of stirring and hence mass transfer in the slag phase on the reduction rate of PbO was found to be insignificant at medium-high PbO contents. Attention is drawn to the importance of chemically controlled reaction rates at the slag-gas interface. Parallels between these results and test work on a 5 tph scale have been briefly drawn.

Jan 1, 1989

By Spencer GA, Saul SJ

The flight line spacing in low level aeromagnetic surveys is the principal factor governing both the cost and the amount of geological detail which can be extracted from the data. The rate at which geological resolution diminishes with wider line spacing is illustrated by progressive subsampling of a 200 m spaced data set from the Charters Towers region in Queensland.The usefulness of high frequency type filters in enhancing shallow structural features is seen to be limited to the 200 m data.It is concluded that each data set is suited to a particular scale and style of geological investigation with only the 200 m data having sufficient detail to identify the subtle structural patterns which are crucial to mineral exploration.

Jan 1, 1976

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

By Javad Koleini S M

The sources of arsenic compounds vary from As(lll) oxide produced from roasters to wastes containing arsenic from chemical or mineral processing plants. The removal of arsenic via co-precipitation with iron is currently proposed as an acce

Jan 1, 1994

Battle Mountain Gold Company's Paj ingo Mine is the first gold mine developed by the Company in Australia. The Mine located in northern Queensland commenced operations in September 1987. The high grade epithermal orebody is selectively mined and processed through a conventional carbon in leach/carbon in pulp (CIL/CIP) plant at a rate of 200000 tonnes per annum. In 1988 it produced 61000 oz gold and 152000 oz silver. Inadequate preoperational development of non technical management and organisational functions often leads to inefficiencies that last well into the operation. The Pajingo experience in this regard is oaTple ented by those from a number of other recently commissioned small operations. A checklist is discussed to assist any future preoperational group in focussing their attention into areas that seem to be of secondary importance at the time but often have a significant impact on overall management efficiency later.

Jan 1, 1989

By Houtgraaf M

The Far Fanning gold deposit is situated 60 kilometres south-west of Townsville (Fig. 1). Previous recorded production is 3756 tonnes returning about 1600 ounces of gold. This has been taken from surface and shallow underground workings- scattered over the strike length of the deposit of 1700 metres. The main production period was from 1895 to 1908.Previous exploration involving extensive trenching and sampling has been: carried out intermittently. since the 1930's, by Gold Mines of Australia (1932), Placer (1974), Anaconda (1975), Marathon (1980-8-1), Aberfoyle (1981-82), and The Northern Queensland Company (NQC) (1983-present).In 1980 Marathon undertook an extensive drilling programme to test the oxidised mineralisation. Over 200 percussion holes and- 7 diamond holes were drilled along traverse lines spaced 29 to 103 metres apart covering a strike length of around 1800 metres.

Jan 1, 1986