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By Sehic OA

One aim of testwork and flowsheet development is to ultimately provide a reliable and flexible plant that is simple to operate and maintain. Testwork can indicate amenability of ores to CIP treatment and provide a basis for process design and economic appraisal. Batch cyanidation and CIP tests are often sufficient for small projects. Continuous multistage test rigs can be operated to simulate plant operation and to provide data for flowsheet optimisation. Operating requirements, gold recoveries and potential problem areas can be anticipated at an early stage with more confidence. Subsequent project development involving decisions on the basic flowsheet, equipment types and general plant arrangements are based on practical considerations and experience. Computer aided process modeling and economic appraisal can be useful in analysing various tradeoffs, firming up the flowsheet and equipment sizes, and in specifying operating targets for the future CIP plant. INTRODUCTION Carbon-in-pulp (CIP) technology which has developed rapidly since 1974 is now accepted as an economically and technically viable process for the efficient recovery of gold. This paper describes testwork and flowsheet development procedures used for CIP evaluation and design.

Jan 1, 1982

By Y Peng, D J. Bradshaw, X Chen

At NewcrestÆs Telfer gold mine, a strategy of regrinding pyrite rougher flotation concentrates has been proposed to increase gold recovery and reduce cyanide consumption in the CIL circuit. The regrinding will be followed by an additional copper/gold flotation stage, where copper minerals need to be separated from pyrite. However, although the minerals are well liberated, the separation of chalcopyrite from pyrite in the cleaner stage is not always straightforward. The surfaces of the fine particles, produced during regrinding, are more easily oxidised and contaminated than coarse particles, directly influencing the particle floatability. The depression of pyrite is difficult in the cleaner stage as well due to copper activation, a process which is also highly dependent on the grinding environment. In this study, different grinding media, including mild steel and stainless steel, was used in the regrinding to produce different regrinding chemistry, such as, pH, Eh, and iron hydroxide contamination. The effects of regrinding conditions on chalcopyrite flotation and its separation from pyrite were studied. It was found that the stainless steel grinding media, which produced an oxidising environment, was more beneficial for the separation of chalcopyrite from pyrite after regrinding. The mild steel grinding media had a detrimental effect on both chalcopyrite and pyrite flotation. This study addresses the importance of choosing suitable regrinding conditions in the pyrite and copper flotation circuit.CITATION:Chen, X, Peng, Y and Bradshaw, D J, 2012. Effect of regrinding conditions on the flotation of chalcopyrite and its separation from pyrite in the cleaner stage, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 279-286 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By Johnston R. F

The factors which influence the reduction of chromite are investigated with special reference to Coobina chromite. This was compared with a South African chromite ore. The reduction characteristics are outlined and the reduction kinetics studied Temperature has the most significant effect, followed by particle size, silica addition and type of coal.Electron microprobe analysis of the products indicates that iron in the chromite is first reduced at temperatures above 1100°C, followed by chromium at around 1200°C. At temperatures greater than 1200°C metallic iron and chromium are formed simultaneously and subsequently give an iron-chromium-carbon alloy. It was observed that the metallic carbide contains a small amount of silicon. The decomposition of the chromite spinel was observed to pass through the FeO.Cr2O3, MgO.Cr2O3 and MgO.AI2O3 forms before slag formation. It is concluded that Coobina chromite is suitable for the production of ferrochrome if direct prereduction followed by intensive bath smelting is used.

Jan 1, 1994

By Shrivastava P

The iron orebodies of the Pilbara region are formed by supergene enrichment of banded iron formation and rarely do such processes produce orebodies with uniform grade distrib- utions. The orebodies being mined or developed have to be worked to grade/quality constraints imposed by contractual agreement rather than natural characteristics. Hence it is imperative to use a non-biased ore reserve calculation method. The geostatistical study of a typical iron orebody is presented. Emphasised are the geological characteristics of the orebody manifested as a variable grade distribution of iron and impurities; the determination of variogram model; subsequent uses of the model for computation of ore reserves and kriged lock estimates; computation of dispersion variance and conditional simulation of orebody.

Jan 1, 1977

By J G. Petrie, H von Blottnitz

The selection and design of process options to deliver outcomes consistent with sustainable development requires simultaneous consideration of multiple objectives, within a climate of uncertainty û including the environmental and social aspects of technology management in addition to the technical and economic aspects of such. An issue of particular relevance in primary metal production is the deportment of minor and trace components within orebodies, products and wastes and the implications of such deportment for eco-efficiency û in particular, the long-term environmental impact of solid waste management practices. The identification of opportunities to enhance recovery of valuable by-products and simultaneously improve the environmental acceptability of final waste output requires a clear understanding of the distribution of the relevant ore components, which results from the choice of processing route and unit operation efficiency. This is challenging, given that process streams generated during primary metal production are generally poorly characterised and the behaviour and deportment of trace to minor and trace components is not well understood. This paper demonstrates how current data gaps and inconsistencies can be systematically addressed through the meaningful reconciliation of empirical plant data with a fundamental understanding of the mechanisms and parameters influencing element behaviour and deportment during the formation and subsequent beneficiation of mineral ore deposits. On this basis, quantitative distribution data and a comprehensive and comprehensible inventory of unit process inputs and outputs as a function of ore compositions and processing technology options can be generated, which is consistent with early design stage information requirements, both in terms of detail and accuracy, ie is æfirst-orderÆ in nature. This predictive approach to element distribution during primary metal production provides decision-makers with key information in the early design stages of a project (in terms of developing processes within the context of sustainability), whilst simultaneously guiding further data collection and environmental impact prediction studies.

Jan 1, 2006

By I Ametov, G Levay

It is now common practice to use substantial amounts of recycled water in mineral processing plants to minimise both environmental discharge and withdrawal of fresh water from often limited water resources. Recycled water additions to process water are frequently obtained from sources such as tailings dams, tailings thickeners and concentrate dewatering. It has been suggested for some time that addition of recycled water to process water will impact the quality of the process water and that changes in water quality may influence flotation performance. To date, investigations of process water quality changes as a result of water recycling have been limited and as a consequence there are very few data available to substantiate these ideas. Thus the impact of recycling on process water quality remains largely unquantified. Over recent years we have conducted water quality studies at a number of mineral flotation plants with varying degrees of water recycle. This paper describes the results of these investigations, including data which suggest that build up of salinity due to recycling while it occurs, is reduced by fresh water make-up. The fate of flotation reagents such as collectors, promoters, frothers and flocculants during process water recycling has also been investigated. Results show that process water concentrations of these reagents vary from plant to plant, but that, with the exception of frothers, most reagents are generally removed from the system through mineral adsorption. In general, the results of these investigations suggest that recycling process water will not result in continuous increase in solute concentrations as appears to be the commonly held view.The effects of changing water quality on flotation can vary. In many cases, flotation conditions can be optimised to suit the water quality, while in others, treatment of the water may be necessary to obtain acceptable plant performance.

Jan 1, 2009

This paper presents a review of heat illness in mining, including reference to several recent investigations by the author. Heat illness is a collective term, covering the conditions of heat stroke, heat exhaustion, heat cramps and miliaria rubra. Heat stroke is life-threatening and is by far the most serious condition. It is rare in mining, if appropriate control measures are instituted. Heat exhaustion is primarily due to hypohydration, following prolonged sweating in hot conditions. Symptoms include fatigue, headaches, dizziness, anorexia, nausea, vomiting, shortness of breath, or brief syncope. Confusion, ataxia, prolonged unconsciousness or convulsions are strongly suggestive of heat stroke. Heat cramps are painful involuntary contractions of skeletal muscle associated with work in hot conditions. The limbs are usually involved and the spasms typically last a few minutes, during which the affected part of the body is incapacitated. Heat cramps tend to occur in heat exhaustion, when hypohydration becomes marked. Miliaria rubra is a skin rash caused by extravasation of sweat into the skin, as a result of obstruction of the sweat glands. It occurs after prolonged and profuse sweating in hot environments. It can take three to four weeks of sedentary duties, in an air-conditioned surface environment, for the condition to resolve. Heat illness would be unlikely in underground mining, if the thermal environment was sufficiently well controlled by ventilation and refrigeration. This is however, often not practicable. Where engineering controls alone cannot provide sufficient control of risk, the residual risk can be assessed using an appropriate heat stress index. While procedural controls may further reduce the residual risk, it is important to remember that these are less reliable than engineering controls and cases of heat illness may still occur. Procedural controls include the application of heat stress limits, education, hydration, self-pacing, early symptom reporting, medical advice, acclimatisation procedures, air conditioned accommodation, support to achieve a healthy body mass index, and an effective emergency response capacity.

Jan 1, 2005

Market forces, particularly iron ore prices, demand that plant operators achieve higher throughput in the worldÆs iron ore beneficiation plants without compromising yields or efficiency. This means that production cost per ton is of paramount importance and that all major pieces of Processing Equipment have come under close scrutiny to improve throughput at their most efficient performance levels and for the longest possible continuous running time. Without doubt the use of modern engineering standards and materials of construction has contributed to matching these throughput, efficiency and availability demands. However, often not enough attention is paid to the so called æinsignificant elementsÆ connecting this metallurgical equipment, such as chutes, pipes or other conveying systems, and particularly to the sufficient protection of their wearing surfaces. The result can be an unplanned and expensive outage caused by the wear related failure of such components. This paper will discuss:the theory of wear and the multiple factors of material and design that contribute to a reduction in wear; and the combinations of modern wear resistant materials available to todayÆs engineer and how, by intelligent selection and correct application, plant availability can be optimised. Examples outlining how these principles have been applied in South Africa showing some improvements leading to increased plant availability.

Jan 1, 2002

By Khosia NK, Ravishankar SA, Sankar TAP

Alumina reduction in Rajhara iron ore slimes essentially involves separation of hematite from gibbsite in relatively coarser fraction and from kaolinite in the finer fraction. Selective dispersion flocculation studies on synthetic mixtures clearly indicated that while it was possible to achieve almost perfect separation of hematite from kaolinite using starch and PAMX (modified polyacrylamide containing hydroxamate functional groups) flocculants, no selectivity was observed in iron oxide-alumina system. A schematic flowsheet suggested on the basis of this work for the beneficiation of Indian ore slimes thus consists of classification in a hydrocyclone, followed by selective dispersion of coarse fraction (underflow) and selective flocculation of the overflow fraction. Starting with a feed assaying 46 per cent Fe and 11.6 per cent A1203, a concentrate assaying 60 per cent Fe and 4.7 per cent A1203 could be produced at an overall iron recovery of 60 per cent using conventional Reagents.

Jan 1, 1993

By E Werner, J J. Donovan, A J. Morris

Coal mining in the Pittsburgh coal seam, in the eastern United States, began in the late-1700s. Since that time numerous mining technologies have been used throughout the basin. Environmental concerns, particularly mine discharge quality, have only been considered since the early-1970s. During the last 20 years, many of the larger underground mines have closed and are now either flooding or already flooded. In order to understand the consequences and potential future effects of this flooding, mine mapping of the basin has been compiled utilising a geographic information system (GIS) with an emphasis on locating barrier pillars between mines. Mine flooding has been monitored at numerous sites utilising pressure transducers and data loggers. These data have been combined with historical data from mining companies and structure contour maps to yield chronological flooding maps of the basin from 1980 to present. Utilising these maps and the indicated flooding rates, future discharge locations have been identified along with estimates of when these discharges are likely to occur. Related work has identified barrier pillar hydraulic conductivities and vertical infiltration rates as a function of overburden thickness. All of this information has been integrated into a groundwater flow model that simulates mine flooding. This model is useful in defining mine to mine interactions as the various mines fill with water, and the testing of various flooding scenarios. The model will be used in evaluating mine discharge rates and evaluating the options for regional mine drainage treatment.

Jan 1, 2003

Permian ultramafic and associated rocks form a belt in East Nelson and contain widespread, but minor, chromite and copper mineralisation and some mining was carried out last century. Since mining ceased, about 1910, little mapping of the belt has been carried out although its origin has been debated vigorously. Recently it has been inferred to form part of a ophiolite sequence, which has been tectonically disrupted to form a melange, and several 'plate -tectonic' models have been proposed. Mapping in the central part of the belt has shown that mTlanges are to the east of the ophiolite sequence. Faulting is widespread so that in anyone section part of the sequence may be absent. Some of the faulting is difficult to recognise and probably took place during or soon after the sequence accumulated. Other faulting is clearly of Cenozoic age and includes major NNE striking faults, with large horizontal displacement, and approximately east-west striking faults with almost entirely vertical movement. The writer agrees that 'plate tectonics' could provide an acceptable explanation for the origin of the ophiolite sequence but the models so far proposed do not take into account the nature and field relationships of the rock units present. Copper Mineralisation is largely controlled by the younger faults, particularly those striking about north-east, and is largely confined to the western part of the ultramafic rocks particularly where slivers of the volcanics of the adjacent Lee River Group are enclosed. Mineralisation, along NNE striking shear zones, has recently been found in the volcanics some distance from the ultramafic rocks. The chromite mineralization is in the form of primary layering in the basal part of the ultramafic belt although in places it has been concentrated into lenses probably during serpentinisation.

Jan 1, 1977

The subject of octanes and knock in petrol engines is of general interest, not only to the engineers and chemists in the petroleum and automotive industries, but also to the motorist who wishes to see some light through the haze of propaganda regarding "super" petrols. A mixture of petrol vapour and air will explode when a spark is passed through it if it contains more than one and a half per cent. or less than six per cent. of petrol vapour by volume. In a petrol engine the mixture has to be within the explosive range before it will operate. When the spark is passed it 'ignites the petrol vapour-air mixture which burns with rapid but finite progress of the flame front 'through the unburnt gases in much the same manner that a charge of dynamite is consumed. The turbulence of the gases in the cylinder under normal operating conditions more than doubles the velocity of the flame front and enables the combustion to be completed by the end of the working (expansion) stroke:KNOCKIf the cylinder head 'is poorly designed or is covered with a deposit of carbon, it is possible for "hot spots" to develop, and these can ignite the mixture before the spark is passed. This pre-ignition gives rise to an engine knock but is accompanied by a dull thud rather than the ringing knock associated with the true "knocking" found in a petrol engine and attributed to the detonation of the mixture. Until a few years ago it was thought that this detonation was due to a shock wave produced by the rapid combustion of the mixture, and sufficiently intense to cause ignition of...

Jan 1, 1951

By S Prakash, P S. R Reddy, S K. Biswal, V N

The beneficiation potentials of two Indian iron ore slime samples by flotation technique using both cationic and anionic collectors are investigated. The direct and reverse flotation of slimes using oleic acid and dodecylamine as the collector have been studied using both conventional cell and flotation column to upgrade the iron content. The characterisation studies of iron ore slimes indicated that the samples are extremely fine in nature and contain substantial amounts of martite, magnetite, goethite, limonite, kaolinite and quartz beside hematite as the dominant iron mineral phase. The samples on average contain around 52 - 58 per cent Fe, four to seven per cent SiO2 and five to six per cent Al2O3. Taking into account the physico-chemical properties of the slimes, it is attributed that both the samples need to be deslimed by hydrocyclone before flotation. The results of both cell and column studies on sample I showed that a feed containing 57.5 per cent Fe could be upgraded to 65.5 per cent Fe at 50 per cent overall recovery with simultaneous decrease in SiO2 and Al2O3 content to 2.3 per cent and 1.8 per cent respectively by using oleic acid as the collector. In the case of sample II, it has been established that reverse flotation of silica is the better technique to improve both the grade and recovery of iron. Batch flotation studies in cell indicated that a product with 63.1 per cent Fe could be obtained at 40.0 per cent yield with 63.6 per cent iron recovery by the combination of reagents such as gum acacia, sodium hexa meta phosphate and dodecylamine. The performance of column flotation techniques is far superior to that of the cell with respect to both grade and recovery. The concentrates are found to be quite suitable for commercial exploitation as pellet feed.

Jan 1, 2005

Peko Mines, a Division of Peko-Wallsend Operations Limited (PWOL) has operated several small underground mines in the Tennant Creek district of the Northern Territory supplying ore to a central treatment plant. The Argo Mine is the most recently developed by Peko Mines. A magnetic anomaly was identified from low level airborne magnetics in 1960 and drilling, which commenced on the site in 1969, was halted in 1974 and resumed in 1980 following the rise in the price of gold. By mid 1983 a resource of + 200 000 tonnes of 12 g/tonne Au had been outlined and a decision to develop the resource was taken following the drilling of three further diamond drill holes which did not significantly alter the value of the resource. The small size of the orebody could not support the full capital cost of two shafts and a single entry mine plan was developed to extract the ore at a rate of 15 000 tonnes per month and to provide all the safety features, ventilation systems and services of a two shaft mine. In December 1983 a contract was let to Allied Constructions Pty. Limited (Allied) to sink and equip a 4.8m shaft to a depth of 410m and to convert the headframe and winder, which are leased for the life of the mine by PWOL from Allied, from a sinking to a production configuration. Shaft equipment designed by Hardcastle & Richards Pty. Ltd. (H & R) in conjunction with PWOL includes a skip/cage, counter- weight, and an auxiliary cage on rope guides, a sealed ladderway and exhaust air ducts.

Jan 1, 1986

By D R. Rankin, J J. Fuykschot

Forrestania Nickel Mines is owned and operated by Outokumpu Mining Australia Pty Ltd and is situated 400 km east of Perth, WA in the Forrestania Greenstone Belt. Production started in late-1992 at a rate of 600 ktpa and reserves were exhausted in August 1999. Cosmic Boy is the largest of three mines worked and operates in a high stress environment with both very high and very low rock mass strength domains. Stoping commenced in 1995 using conventional benching with long hole slot rises but because of drilling and blasting problems the mine switched to airleg rising. In 1997 the mining method was changed to smaller scale up hole retreat benching with each stope requiring a slot rise of up to 16 m length. This method does not allow top access to the rise location and so airleg rising was used until mid-1998. At this stage mining was approaching areas of higher stress for which it was clear that an alternative to this entry method of rising was required. Small diameter raise boring and Cubex rigs were considered but because of the set up costs were not considered to be viable. Since the ore is relatively soft, burn cuts were developed to make use of specially designed 152, 203 and 254 mm diameter reamer bits (depending on the rise length) and drilled with conventional long hole drilling equipment. These rises are fired in one blast together with the slot rings. In the northern lower section of the mine (below 400 m) the principle stress has been estimated at 60 MPa and this causes minor strain bursting in BIF development headings and loose material to form on walls and backs. Trials of destress blasting modelled on Canadian experience has greatly reduced strain bursting at the face. However only around 300 m of development was affected and so this method had not been optimised when mine development was completed.

Jan 1, 1999

Vatukoula, the Fijian equivalent of gold rock, is the name of the community embracing the gold mines owned and operated by Emperor Gold Mining Company Ltd., Loloma (Fiji) Gold Mines, N.L., and' Dolphin Mines Ltd. It is situated in the Tavua Goldfields approximately five miles from the northern coast of Viti Levu, the largest island of the Colony of Fiji.The climate is sub-tropical, there being a definite wet and dry season. The wet season is somewhat variable in length but usually extends from December to March, during which time most of the rainfall for the year is recorded.Although the average annual rainfall is 71 in., more than twice this amount has been recorded. Precipitation at the rate of 5 in. per hour is not uncommon and 15 in. of rain has been registered in 24 hours. The mining methods adopted, therefore, had to suit these wet conditions.The occurrence of gold in the Tavua area has been known since 1872, but it was not until 1932 that discoveries were made which led to the formation of the present operating companies. In 1934 the Emperor Gold Mining Company Ltd. commenced operations, followed in 1935 by the Loloma (Fiji) Gold Mines, N.L., and later by the Fiji Mines Development Ltd., now known as the Dolphin Mines Ltd. Up to the end of 1951 these three mines had produced 2,501,688 tons of ore from which 1,277,881 oz. of fine gold and 347,429oz. of silver were obtained, realizing in Fijian currency £13,025,153.The three mines are situated close togeth.er on contiguous mining leases, and, although under common management, are operated as separate en,tities. Since 1944 all the...

Jan 1, 1953

Solar Salt, Lunar Ambitions I Bauerti The title of this paper is `Solar Salt, Lunar Ambitions'. It is largely the result of a lack of imagination and a tight deadline. I was seeking a catchy title to convey the image of being 'here' and wanting to get `there', with `there' being a long way away and our being held 'here' by powerful gravitational forces. I tried `Solar Salt, Lunar Landings', but that implied we had already reached `there' when, on reflection, we had not. A colleague suggested 'Solar Salt, Luna Park' which is a fun park in Sydney and, I must admit, there was appeal in the image of having embarked on a wild roller coaster ride with stomach-wrenching twists and turns and the only reward being a pair of sweaty palms, and a feeling of nausea. That's sometimes how it feels when you launch into change. In the end I settled for the more sedate `Lunar Ambitions'. It contained that suggestion of hope and continual striving which are central to the idea of best practice. I will discuss our experiences in this area shortly, but I would firstly like to provide some background to our business. The salt industry is steeped in history and tradition. As one learned commentator observed, common salt is 'a substance seemingly too ordinary to think about, yet it is the oldest of man's raw materials and the basis of some of his newest inventions' (Multhauf, 1978). From ancient times, salt was recognised as a key necessity of life and it has played a role in the rise and fall of governments throughout history. The Romans recognised its importance when they gave their soldiers money regularly to purchase salt, hence our modern word 'salary'. Today, while culinary use remains important, the main consumer of salt is the chemical industry (Figure 1).

Jan 1, 1995

By N S. Rauert

The Barrick Gold Granny Smith underground operation located at the Wallaby deposit is currently in a transition period from a near surface operation in ramp up mode to a fully operational deep mining operation with annual production exceeding 1 Mt/a. A key element in this process has been the project execution of the Wallaby Deeps project from initial scoping study in 2007 to the major production component of the Wallaby operation by 2013.The Wallaby Deeps project serves as an example of how an ongoing detailed study program can be integrated into a day to day mining operation assessing risk and mining application in a perceived challenging narrow vein geotechnical environment prior to mining. A detailed study phase to feasibility level is carried out prior to the mining each zone of Wallaby with mining approval only granted on study completion with full justification.A central element in this process is an optimisation study that utilising the Mineable Shape Optimiser (MSO) and Schedule Optimisation Tool (SOT) software tools developed by AMIRA Ltd PRIMO research project is used to carry out an NPV value based option study. This optimisation process being then tempered to reality by a predefined practicality assessment process utilising extensive peer review by operational and study team members as well as industry experts.Other challenges facing the Wallaby Deeps project include the requirement to maintain the ramp up production profile to full production by 2012 without disruption but with pressures of an ongoing geological resource to reserve conversion program essential for the study process and mining approvals and also development rate achievement.To date these challenges are being met with integrated planning and the value of the study program itself. Production in 2012 year to date is well on the way to annual production rate exceeding 1 Mt/a.CITATION:Rauert, N S, 2012. Wallaby Deeps - from the optimal opportunity to reality, in Proceedings Narrow Vein Mining 2012 , pp 207-214 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Zamel GI

The utilisation of fossil fuels, including coal (of which Australia is a large producer and exporter) is a significant contributor to the emission of greenhouse gases. Methane gas, formed during the coalification process, is present in coal seams to varying levels depending on the rank and depth of the deposit. This gas usually escapes to the atmosphere during mining operations without prior conversion to C02 or utilisation as fuel. The quantity of methane released can represent from less than one percent to more than five percent of the carbon content of the coal mined. Per unit of carbon, methane has a greenhouse impact many times that of C02. The emission of uncombusted methane to the atmosphere can therefore represent a greenhouse impact of similar porportions to that of the CO2 formed by combusting the mined coal. However, greenhouse emissions from coal can be minimised by collecting the coal seam methane and converting it to water vapour and the less damaging form, CO2. If such conversion is carried out while performing useful work, the methane can further reduce greenhouse emissions by displacing other fossil fuels. Technology has been developed to allow coal seam methane gas to be economically collected in a pure form, uncontaminated with air. This pure methane can be used to supplement natural gas supplies, to generate power or for the production of chemicals or substitute transport fuels. By collecting and utilising coal seam methane, the greenhouse impact from the mining and use of coal can be minimised, with significant reductions possible in the case of gassy deposits.

Jan 1, 1989

By K S. Smith, B P. Jackson, P J. Lamothe

The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are possible non-point sources of acid and metal contamination to surface- and ground-water systems. We used stable-metal isotopes to help ascertain metal retention and release mechanisms that influence metal transport from the deposits to shallow ground-water systems. To accomplish this, we excavated an intact core from a small fluvial tailings deposit and performed laboratory column experiments to examine the amount of metals leaching through the core. Deionised water was continuously applied to the top of the core, and effluent was collected from the bottom of the core for a period of about two months. Three saturation conditions were used, including unsaturated, partially saturated, and fully saturated. Reducing conditions developed upon partial and complete saturation of the core. During the unsaturated leaching phase, core effluents were acidic (pH 2.8 - 3.5) and contained elevated metal concentrations. During a portion of the unsaturated leaching phase, stable-metal isotope spikes and conservative tracers were simultaneously applied to the top of the core. The isotopes provide a means to delineate metal behaviour within the core. During the unsaturated leaching phase, the isotope spikes did not exhibit breakthrough with simultaneously added conservative tracers. However, some of the stable-metal isotope spikes did break through when reducing conditions occurred in the core (during the partial- and completesaturation conditions). In this paper, we use Cd as an example of the utility of stable-metal isotopes in geochemical studies. In the case of Cd, after the core was partially saturated, the 111Cd spike was released as evidenced by a change in the Cd isotope ratios in the effluent. This release continued during the fully saturated leaching phase, however, the total Cd concentration did not increase. These results suggest that the 111Cd spike was retained inside the core during the unsaturated leaching phase, and only partially released as reducing conditions developed. Results from this core-leaching experiment indicate there is a large reservoir of water-soluble material within the fluvial tailings deposit, which yields elevated metal concentrations and high acidity, and which may degrade adjacent ground- and surface-water quality. Use of stable metal isotopes in this study facilitated the determination of different metal-retention processes, metal-release processes, and metal sources in the fluvial tailings deposit in response to changing geochemical conditions.

Jan 1, 2003