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By K M. Watling, F M, G K. Parker

Surface enhanced Raman scattering (SERS) spectroscopy at surfaces under electrochemical control has been applied to elucidate the adsorption of thiol collectors. SERS spectroelectrochemical studies at coinage metal electrodes have been carried out on ethyl xanthate and three iso-xanthates, O-isopropyl-N-ethylthionocarbamate, 2-mercaptobenzothiazole, diisobutyl- dithiophosphinate and butylethoxycarbonylthioura. For each collector, adsorption occurs via charge transfer to form a metal-sulfur bond and, in situations for which the reversible potential of the formation of the bulk phase is known, at underpotentials.

Jan 1, 2005

By M Wen, J Gerit, C A. Pelletier, D Muggli

On-land waste rock dumps at BHP Billiton Base MetalsÆ Island Copper Mine (ICM) near the northern end of Vancouver Island, B.C. continue to discharge ARD. These waters, which amount to approximately five million cubic metres each year, are injected into a three-layer, meromictic pit lake for treatment. The top layer is brackish water, replenished by each yearÆs rainfall (amounting to nearly 2 m/year). This top layer of water must meet effluent permit limits for heavy metals. This water eventually exfiltrates through a æbeachÆ waste rock dump, which is 93 per cent submerged along the north shore of Rupert Inlet. The middle and bottom layers of the Pit Lake are saline and currently oxic (2 mg/L dissolved oxygen) and anoxic (0.03 mg/L dissolved oxygen), respectively. Spreading of a liquid fertilizer every ten days throughout the top layer results in plankton and bacterial blooms that scavenge zinc, copper and cadmium out of this layer eventually to become mineral sediment in the bottom of the pit lake. Adsorption on planktonic skeletons and mineral precipitates also scavenges these dissolved metals from the middle and bottom layers to form bottom sediment. Sulfate reduction has recently begun in the bottom sediments. Diagenetic processes in the bottom sediments will eventually transform most of the dissolved heavy metals into insoluble sulfides. Cycling of ferric iron between the sediment and the water column and back seems to contribute dramatically to the biogeochemical metal removal processes. This biogeochemical system serves to maintain the top-layer water well within permit limits for discharge to the environment.

Jan 1, 2003

By M Battersby, F Parra, S Sanchez-Pino

Pneumatic flotation, as developed by Dr Rainer Imhof, has been applied in commercial beneficiation operations since 1987. Over 85 flotation cells have been installed in more than 30 operations, successfully beneficiating a wide range of minerals. Pneumatic flotation is however still considered as a non-conventional flotation process. Due to its highly selective nature in operation it has generally found its market in difficult applications where conventional flotation equipment has struggled. Compa±fa Minera Huasco (CMH) operates an iron ore pellet plant in central Chile. CMH desired to produce a low silica pellet for the export market where the SiO2 grade should not exceed 1.5 per cent. It is common practice in other countries to float quartz from hematite with relative ease. However, the silicates contained in the magnetite ore of CMH are only present as quartz in small quantities and the major undesirable silicates are difficult to float. CMH spent considerable time on developing a reverse flotation process and a reagent suite to try and reduce the silica content to acceptable levels. However, extensive laboratory and pilot plant tests with conventional mechanical tank type cells and with column cells failed to produce the required reduction in impurities. A series of tests with pneumatic flotation cells indicated that this type of flotation technology could achieve the required silica target. A 500 tph Imhoflot pneumatic flotation plant was subsequently constructed and successfully commissioned by CMH, making it one of the largest iron ore flotation plants in the world. This paper details the background and testing that was undertaken by CMH which led them to choose pneumatic flotation as the preferred process and compares the test results with that achieved in the industrial plant.

Jan 1, 2005

IT is very difficult for a founder engaged in jobbing work, comprising all sizes and classes of castings, to appreciate that the analysis of the iron he is using cannot entirely fill the situation he desires for his varied classes of work. Neither is there any panacea in the shape of an iron mixture that will suit the whole of his floor for the day.From his own experience he generally alters his cupola charges during the cast, endeavouring to meet at the same time the requisite metal composition for the castings he is about to pour.The founder on repetition work is in a much better position to stabilise his methods, arrive at a certain pig-iron' analysis, regulate...

Jan 1, 1926

In order to satisfy environmental and mine operational requirements it is becoming increasingly important to minimise ground blast vibrations at certain locations. These locations are often in soil or on large resonant structures such as grain silos, highway bridges or even the walls of an open pit. A soil monitoring exercise was carried out to evaluate the common practice of coupling vibration detectors to the ground using spikes. At a series of locations in an operating quarry the spiked array response to single blastholes was compared with that of an accelerometer array attached to a calibrated embedded mount. The results clearly showed that the spiked arrays over-estimated the true ground vibration by 46.5 per cent on average, with a maximum observed error of 99.2 per cent. These errors are considered too large for compliance monitoring where accurate vibration levels are required for comparison with prescribed limits. Although spike coupling is convenient, its use for compliance monitoring should be viewed with caution. Unfortunately, however, many manufacturers supply their detectors as spiked arrays. A structural monitoring exercise was also carried out to evaluate the vibration response of a grain silo, highway bridge and a pit wall to the initiation of single blastholes. In this case accelerometers and standard geophones were firmly attached to the bridge which resonated at low frequencies. The results clearly show that, due to their limited low-frequency response, the geophones typically measured only half the true vibration level as measured by the accelerometers.

Jan 1, 1995

Attempt has been made to determine the nature of charge on activated carbon surface by studying the electro-kinetic properties of the carbon in the presence of cations, anions and aurocyanide solutions. The zeta-potential measurements were made in the presence of individual ions and also in combinations. The cations and anions chosen were those commonly associated with gold bearing ores in Kalgoorlie area. It was found that the iso-electric point of Norit Carbon was at pH 4.45; below this pH the charge was positive, while above, it was negative. In the absence of gold cyanide solutions and in the presence of individual cations the i.e.p. shifted to the alkaline range (pH 7.2-8.5) while in the presence of anions the i.e.p. was shifted to less than pH 3.5. In the presence of aurocyanide solutions, the iso-electric point was still in the acid region irrespective of whether anions or cations were present. The probable mechanism for such a behaviour has been attempted after measuring the specific conductivities of solutions before and after gold adsorption, by studies using the electron- probe-mirco-analyser, and S.E.M. on the carbon surface.

Jan 1, 1982

By Lyman GJ

Systems for the routine on-line determination of ash content of process streams in coal preparation plants and handling systems have been in use in Australia for over four years. More recently, monitors for on-line moisture measurement have been developed to complement the ash measurement function. The technology for these systems is reviewed briefly. The development of reliable ash and moisture monitors has made the implementation of automatic systems of coal quality control practical. The emerging philosophies of automatic control in Australian preparation plants are examined with particular emphasis on systems involving dense medium circuit regulation. Related developments in flotation control and coal sorting are noted to complete this overview.

Jan 1, 1987

By Jowett A

To compare open circuit lead primary rougher results at Mount Isa Mines Ltd., eleven surveys were made over five weeks of plant operation with varying ore sources, including a specially hauled sample of 100% Black Star ore. Three of the surveys which represented extremes in performance were selected for sizing, cyclosizing and assaying for lead, zinc and iron. A comparison of the flotation kinetics has revealed the similarities (including common problems) and differences for the surveyed ores. The concepts of entrainment and collectorless flotability are used to aid interpretation of the kinetic data.

Jan 1, 1978

By Corrans I. J

A wide variety of copper-bearing gold ores exist throughout the world which have yet to be processed economically for gold recovery. The copper minerals present in these ores can be many and varied and usually result in high cyanide consumptions and problematical levels of copper in leach solutions. The copper content is often assessed as being of nuisance value as the ores are generally of the grade or type which can support neither a copper project nor a straight gold project, due to the interference of copper. Many of these problematical gold-copper ores could possibly be processed economically for gold recovery using a novel ammoniacal cyanide leaching system which utilises a copper-ammonia-cyanide complex as an effective lixiviant for gold, yet limits copper dissolution and conserves cyanide. Results from recent testing have promoted a re-evaluation of the economics of treating some gold-copper ores. This paper describes the novel leaching process and discusses the conditions employed to treat a variety of gold-copper ores.

Jan 1, 1992

The underground mining of a narrow vein hard rock orebody is a capital and labour intensive method of extraction. Due to the nature of underground mining it is difficult for higher level managers to physically see the efficiencies and inefficiencies of a particular method. Extraction methods and sequencing often need to be altered from the original planned methods as a result of mine developent, providing more in depth information as it progresses. As a result of these issues contract mining of these orebodies is common practice. There are several types of contract structures for the purpose of underground contract mining with many complex permutations of them that reflect the different needs of each individual company and orebody. The different contracts are arranged dependent on the mining companyÆs desire to transfer or, alternatively, embrace risk. This presentation gives a brief overview on these different methods and their various advantages and limitations with regard to small scale and narrow vein underground mining. With respect to these different contracting methods, the presenter reviews the mutual growth benefits of emerging partnering opportunities, specifically with regard to smaller explorers exploring and developing prospective mining tenements. The specific advantages to small explorers include the resource flexibility and speed of project development that private mining contractors can provide. Given the contracting methods that are available, there is potential for small private mining companies to gain minor stakes in major projects and major stakes in medium sized projects by employing innovative contracting solutions to provide mutual benefits to the parties. Some potential scenarios to this effect are suggested in the presentation. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

By Distin P. A

The extraction of platinum and rhodium from scrapped honeycomb autocatalyst into hydrochloric acid/aluminum chloride/nitric acid solutions is described. Results are given for the effects of leachant composition, temperature and catalyst pre-reduction using hydrogen. Data are also presented for the recovery, by hydrogen reduction, of platinum and rhodium dissolved in the leach solution. Parameters studied include solution composition and temperature, hydrogen pressure, and platinum seed addition.

Jan 1, 1992

By J Bower

The JORC Code does not specify a definition for ælevel of confidenceÆ. The common approach in the mining industry is to use a certain drill spacing or number of data samples to classify resources by the confidence categories. Another approach includes application of the quantitative geostatistical criteria for non-subjective and consistent definition of the resource categories. This approach, which has become increasingly popular in the mining industry, provides a quantitative measure of the resource estimation uncertainty. In this study, uncertainties associated with the different drilling grids at the Weipa bauxite deposit (Queensland, Australia) have been modelled using conditional simulation methodology. Criteria used at Weipa for defining resource categories are as follows: mineralisation can be classified as a Measured Resource if tonnage and grade of its volume representing three months of production can be estimated with a precision error not exceeding ¦10 per cent (at 95 per cent probability, ie two standard deviations); and mineralisation can be classified as an Indicated Resource if grade and tonnage of its volume representing annual production can be estimated with a precision error not exceeding ¦10 per cent (at 95 per cent probability). Several different grids have been created by subsampling the drill hole database. The studied variables include Al2O3, SiO2, thickness of the bauxite seam and location of the footwall contact. The variables have been modelled by sequential Gaussian simulation. Based on this study the following drill spacings have been recommended: Measured Resources û 150 m by 150 m, Indicated Resources û 300 m by 300 m.

Jan 1, 2009

The basic methods to remove material from underground mines are to: convey continuously, batch in trucks, or batch in a shaft hoisting system. A critical aspect in shaft hoisting is accurately batch loading the conveyance or skip. During the 20th century, the almost universally accepted method of loading was via a measuring flask. A measured quantity of material was filled into the flask as the conveyance traveled through the shaft and then, when the conveyance arrived at the loading position, it was ædumpedÆ into the skip for hoisting. Two skip loading conveyor systems have been developed in Australia: BHP BillitonÆs Cannington Hoisting System, installed in 1996, is believed to be the first conveyor loading system designed for two skips. Two parallel conveyors were installed with a two-way gate controlling feed onto each belt. Cannington was ideally suited to conveyor loading as the very high ore density and relatively low production rate required a relatively small volumetric storage capacity on the weighed belt. Newcrest MiningÆs Telfer Hoisting System, which is to be commissioned in 2005, consists of a single slewing conveyor loading each skip with 32 tonnes of ore. The development of this system eliminates the two-way transfer, improves the accessibility and minimises the excavation required. While every hoisting system must be considered on its merits, conveyor loading offers significant advantages to the Mining Industry in the 21st century.

Jan 1, 2005

The Canada Centre for Mineral and Energy Technology (CANMET) /Calgary Coal Research Laboratory and the National Research Council in Ottawa established a joint working research group with industry to develop and test various computer models for application in surface coal mining operations in western Canada.The first part of the paper deals with the problems the group experienced during the past two years especially having model specification and requirements defined and understand site management practices.The second part of the paper deals with site specific development of general mine model for TransAlta Utilities' Highvale Mine in Alberta. Described here are the development of an interactive truck/shovel model for their three pit operation, selection and application of dragline model for tandem operation with the extended bench method, criteria for operational model of the five seams operation with selec-tive mining approach.

Jan 1, 1985

By Sengstock G. W, Spathis A. T

Benchmarks of mine equipment involved in the excavation process of coal mines would suggest that such equipment is not always operating at an optimum level. Dragline operations and truck/shovel operations rely on efficient use of their plant in order to maintain high mine throughput. The first process which affects the material to be excavated is the drilling and blasting process. Drilling and blasting delivers a fragmented material with a given disposition ready for excavation by mine equipment. As mine operators demand more productivity from their major excavating equipment, many sites are considering the use of productivity monitors to measure their outputs. Some of these productivity improvements will be directly related to the drilling and blasting process, so that as the monitoring systems improve, the opportunities to evaluate all drilling and blasting variables will also improve. This paper reviews current and newer methods for monitoring equipment productivity in mines. These include simple time and motion studies obtained by either manual timing of processes or by automated data collection equipment being adopted by the industry. Case studies for truck/shovel operations are discussed and the productivity improvements are compared with typical industry standards. These improvements relate specifically to parts of the load, haul and dump cycle and the potential for significant improvements are identified. Particular opportunities for drilling and blasting improvements are also presented.

Jan 1, 1995

Blasting, particularly bench blasting, uses finite length cylinders of explosive close to two free faces. The rock to be blasted is usually intersected by a complex 3-D system of joints. To fully simulate a blast, a 3-D dynamic model is required. It is shown that the static stress distribution around a long cylinder can be reproduced by superposing the static stress distribution of a suitable chain of spheres. Thus, the dynamic results for individual spheres given by Favreau (1969) can now be substituted for the static results to give a dynamic model of the stress distribution around a long cylinder. Comparison of measured and computed waveforms show that the measured waveforms are much more attenuated and dispersed than expected. The consequences for explosive evaluation and design are Discussed.

Jan 1, 1990

The evolution of Hall process alumina reduction technology is des- cribed with particular attention to the pot lines. Future directions of tech- nological change are considered. It is predicted that the Hall process will continue to be the avenue for aluminium production for some time to come.

Jan 1, 1982

By Selby DW, Hamill J, Cauley ID, Thomas I, Thornton AJ

The main objective of sulphide flotation in a cassiterite concentrator is to remove sulphide minerals (pyrite, pyrrhotite and sometimes chalcopyrite) from the ore prior to gravity concentration. Tin losses in the sulphide flotation stage account for a significant proportion of the total tin loss. separate studies of the sulphide flotation circuits of Renison Ltd and Cleveland Tin Ltd were conducted to investigate reasons for the tin losses. Sampling surveys were conducted in the rougher-scavenger and also the regrind-cleaner sections of both plants. In both plants, the rougher circuits recover excessive quantities of liberated cassiterite, while recovery of the desired composite cassiterite-sulphide fraction is low. The regrind mills are successful in liberating the composite cassiterite in the rougher concentrate, but at the expense of increasing the proportion of very fine tin mineral. The cleaner circuits recover between 40 and 60% of the cassiterite received, and this is all lost.

Jan 1, 1978

Data logged on mineral beneficiation processes during normal operation are analysed using time series (correlation and spectral) methods to identify the dynamics of the processes for on-line computer control. Recursive least squares estimation techniques are used to identify parametric models for a cassiterite flotation circuit and a coal washery. Identification problems such as the determination of model order, process time delays and the 'contamination' of the data by process recycle streams (feedback) are discussed. Typical results are presented in which optimised models are identified from data logged during normal operation.

Jan 1, 1985

Magnetic separation using particle rotation in a continuously rotating magnetic field offers very low to insignificant non-magnetic particle entrapment, and precise magnetic fractions. The precision of rotating magnetic field separations makes the method ideal for dry laboratory magnetic analysis work, where conventional laboratory magnetic separators can give misleading or uncertain data. The very low entrapment characteristics make the method ideal for entrapment-critical separations within the diamond exploration industry or in gold recovery. A single wet rotating magnetic field (RMF) unit is able to achieve a cleaner separation (at similar or better recovery rates) than a three-stage separation using conventional wet drum separators. The RMF separator is able to work effectively at particle sizes below 50 ¦m, and RMF separation could, at least in theory, be used down to single domain particle sizes. Rotating magnetic field (RMF) separation is carried out by magnetically spinning the particles at frequencies up to 300 Hz. The particle rotation itself may be used to roll the particles out of the separator. At angular velocities of 100 Hz, magnetic flocs are unable to form, and any entrapped particles are energetically expelled. In an RMF separator, the outer drum can be stationary while the inner magnet rotor rotates, allowing, for example, the injection of cleaning water underneath the separating magnetics to help remove small suspended non-magnetic particles.

Jan 1, 2000